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UNIT II
Electrochemical cells :
a) Concepts of electrochemical cell – cell diagram and terminology – conventions
regarding signs of cell emf – calculation of cell emf from single electrode potential – standard
emf of the cell – Nernst equation
b) Reversible and irreversible cells – thermodynamics and electromotive force –
calculation of ΔG, ΔH, ΔS and Keq for cell reaction
c) Single electrode potentials and emf measurement - electrochemical series and its
applications – types of electrodes – reference electrode ( SHE, Calomel electrode, Ag-AgCl
electrode) – standard electrode potential –experimental determination of cell emf – Weston
cadmium cell
d) Determination of pH using hydrogen electrode, glass electrode and quinhydrone
electrode- determination of I, II, III order dissociation constant of H3PO4 by pH measurement –
Potentiometric and conductometric titrations (15 Hours)
Electrochemical cells
Electrochemical cells
Electrochemical cells
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Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
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Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells
Electrochemical cells

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Electrochemical cells

  • 1. UNIT II Electrochemical cells : a) Concepts of electrochemical cell – cell diagram and terminology – conventions regarding signs of cell emf – calculation of cell emf from single electrode potential – standard emf of the cell – Nernst equation b) Reversible and irreversible cells – thermodynamics and electromotive force – calculation of ΔG, ΔH, ΔS and Keq for cell reaction c) Single electrode potentials and emf measurement - electrochemical series and its applications – types of electrodes – reference electrode ( SHE, Calomel electrode, Ag-AgCl electrode) – standard electrode potential –experimental determination of cell emf – Weston cadmium cell d) Determination of pH using hydrogen electrode, glass electrode and quinhydrone electrode- determination of I, II, III order dissociation constant of H3PO4 by pH measurement – Potentiometric and conductometric titrations (15 Hours)