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New flexible, weather resistant,
monomer-free urethane acrylate
Laromer® UA 9089
Dr. Delphine Kimpel
European Coatings Show 2015
Laromer® UA 9089 at a glance
Table of contents
Applications
Closing the gap
Properties
 Adhesion
 Chemical resistance
 Weathering
Conclusion
® = Registered trademark of the BASF Group
Performance highlights
2
Performance highlights
 Perfect adhesion
on flexible substrates
 Low color
 No curling
 High weathering stability
 Monomer-free
 Tin-free
3
Applications
Rigid plastic
parts
Outdoor
coatings
3C
coatings
Flexible resilient
floorings
4
Laromer UA 9089 at a glance
Chemistry
Aliphatic urethane acrylate,
tin-free & monomer-free
Viscosity @ 23 °C 18-24 Pa*s
Iodine color number < 2
Functionality 2
Labelling (GHS) signal word: warning
Sustainability category Accelerator, i.e. substantial contribution
to sustainability
5
Closing the gap
0
20
40
60
80
100
120
0 50 100 150 200 250
Glossretention[%]afterscratch
Elongation [%]
Scratch resistant:
Laromer UA 9050
Laromer LR 8987
Laromer UA 9047
Laromer UA 9089
Flexible:
Laromer UA 9072
Laromer LR 9033
Laromer UA 9028
6
Perfect adhesion combined with high flexibility
Laromer® Laromer® Laromer® Laromer® Competition Competition
Properties UA 9089 UA 9033 a) LR 8987 b) UA 9048 c) 1 2 d)
Reactivity [m/min] 20 55 15 5 35 20
Pendulum hardness [osc.] 26 37 79 108 34 90
Erichsen cupping [mm] 6,9 6,7 3,0 1,0 5,5 2,6
b* after curing [a. u.] -0,8 -1,1 -0,7 -0,7 -0,5 -0,7
b* after 72 h exposure [a. u.] 0,3 0,0 0,8 2,4 0,1 0,6
Martindale rating [MSR-B] 4 4 5 5 3 4
Adhesion auf PVC [a. u.] 0 0 3 0 5 5
Indentation hardness [N/m2] 39 39 124 187 48 140
Tear force [N] 15,9 16,1 too brittle too brittle 14,8 too brittle
Elongation at break [%] 18,9 23,4 too brittle too brittle 8,5 too brittle
c) 75 %
in DPGDA
a) 70 %
in LR 8887
b) 70 %
in HDDA
d) 80 %
in HDDA
7
Good chemical resistance
representative of binder chemistry
Chemical resistance [a. u.] Laromer® Laromer® Laromer® Laromer® Competition Competition
5 best – 1 worst UA 9089 UA 9033 LR 8987 UA 9048 1 2
Powder coffee (16 h) 3 3 3-4 4 3 4
Blackcurrant juice (16 h) 4 3 4 5 3 5
Mustard (6 h) 3 3 3 4 3 4
Red wine (6 h) 3 3 3 5 3 4
Ethanol (1 h) 5 4 5 5 4 5
Detergent (1 h) 5 4 5 5 5 5
Antiseptic (10 min) 5 5 5 5 5 5
Ammoniac (2 min) 5 5 5 5 5 5
Acetone (10 s) 5 5 5 5 5 5
Iodine (30 min) 3 3 3 3 3 3
KMnO4 (30 min) 3 3 3 3 3 3
Eosine (30 min) 3 3 3 3 3 3
8
High weathering stability
0
5
10
15
20
25
30
0 2000 4000 6000
∆E*
DIN EN ISO 11341 exposure [h]
0
20
40
60
80
100
120
0 2000 4000 6000
60°glossretetnion[%]
DIN EN ISO 11341 exposure [h]
Laromer UA 9089 Competition 2
Laromer UA 9089 + Tinuvin® 400 + Tinuvin® 152 Competition 2 + Tinuvin® 400 + Tinuvin® 152
Cracks
® = Registered trademark of the BASF Group 9
Conclusion
Laromer UA 9089 combines
 Perfect adhesion on flexible substrates
 Unique balance hardness / flexibility
 Good chemical resistance
 Excellent weather stability (with right light stabilizer package)
10
Please get in touch
You are highly welcome at our booth No. 523, hall 7a
Dr. Delphine Kimpel
Technical Marketing
delphine.kimpel@basf.com
150 years

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Laromer® UA 9089 – A New, Flexible, Weather-Resistant, Monomer-Free Urethane Acrylate

  • 1. New flexible, weather resistant, monomer-free urethane acrylate Laromer® UA 9089 Dr. Delphine Kimpel European Coatings Show 2015
  • 2. Laromer® UA 9089 at a glance Table of contents Applications Closing the gap Properties  Adhesion  Chemical resistance  Weathering Conclusion ® = Registered trademark of the BASF Group Performance highlights 2
  • 3. Performance highlights  Perfect adhesion on flexible substrates  Low color  No curling  High weathering stability  Monomer-free  Tin-free 3
  • 5. Laromer UA 9089 at a glance Chemistry Aliphatic urethane acrylate, tin-free & monomer-free Viscosity @ 23 °C 18-24 Pa*s Iodine color number < 2 Functionality 2 Labelling (GHS) signal word: warning Sustainability category Accelerator, i.e. substantial contribution to sustainability 5
  • 6. Closing the gap 0 20 40 60 80 100 120 0 50 100 150 200 250 Glossretention[%]afterscratch Elongation [%] Scratch resistant: Laromer UA 9050 Laromer LR 8987 Laromer UA 9047 Laromer UA 9089 Flexible: Laromer UA 9072 Laromer LR 9033 Laromer UA 9028 6
  • 7. Perfect adhesion combined with high flexibility Laromer® Laromer® Laromer® Laromer® Competition Competition Properties UA 9089 UA 9033 a) LR 8987 b) UA 9048 c) 1 2 d) Reactivity [m/min] 20 55 15 5 35 20 Pendulum hardness [osc.] 26 37 79 108 34 90 Erichsen cupping [mm] 6,9 6,7 3,0 1,0 5,5 2,6 b* after curing [a. u.] -0,8 -1,1 -0,7 -0,7 -0,5 -0,7 b* after 72 h exposure [a. u.] 0,3 0,0 0,8 2,4 0,1 0,6 Martindale rating [MSR-B] 4 4 5 5 3 4 Adhesion auf PVC [a. u.] 0 0 3 0 5 5 Indentation hardness [N/m2] 39 39 124 187 48 140 Tear force [N] 15,9 16,1 too brittle too brittle 14,8 too brittle Elongation at break [%] 18,9 23,4 too brittle too brittle 8,5 too brittle c) 75 % in DPGDA a) 70 % in LR 8887 b) 70 % in HDDA d) 80 % in HDDA 7
  • 8. Good chemical resistance representative of binder chemistry Chemical resistance [a. u.] Laromer® Laromer® Laromer® Laromer® Competition Competition 5 best – 1 worst UA 9089 UA 9033 LR 8987 UA 9048 1 2 Powder coffee (16 h) 3 3 3-4 4 3 4 Blackcurrant juice (16 h) 4 3 4 5 3 5 Mustard (6 h) 3 3 3 4 3 4 Red wine (6 h) 3 3 3 5 3 4 Ethanol (1 h) 5 4 5 5 4 5 Detergent (1 h) 5 4 5 5 5 5 Antiseptic (10 min) 5 5 5 5 5 5 Ammoniac (2 min) 5 5 5 5 5 5 Acetone (10 s) 5 5 5 5 5 5 Iodine (30 min) 3 3 3 3 3 3 KMnO4 (30 min) 3 3 3 3 3 3 Eosine (30 min) 3 3 3 3 3 3 8
  • 9. High weathering stability 0 5 10 15 20 25 30 0 2000 4000 6000 ∆E* DIN EN ISO 11341 exposure [h] 0 20 40 60 80 100 120 0 2000 4000 6000 60°glossretetnion[%] DIN EN ISO 11341 exposure [h] Laromer UA 9089 Competition 2 Laromer UA 9089 + Tinuvin® 400 + Tinuvin® 152 Competition 2 + Tinuvin® 400 + Tinuvin® 152 Cracks ® = Registered trademark of the BASF Group 9
  • 10. Conclusion Laromer UA 9089 combines  Perfect adhesion on flexible substrates  Unique balance hardness / flexibility  Good chemical resistance  Excellent weather stability (with right light stabilizer package) 10
  • 11. Please get in touch You are highly welcome at our booth No. 523, hall 7a Dr. Delphine Kimpel Technical Marketing delphine.kimpel@basf.com