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Site-adapted energy crops for biogas
production cultivated under non-irrigated
conditions in the Comunidad Valenciana
(Spain)
                                            ainia
Paz Gómez
29.08.2011 Vienna, Austria
Analysis
                             Content




•   Introduction and aim
•   Methods
•   Results and Discussion
•   Conclusions
Introduction and aim
Introduction and aim




Introduction
• Climate change and rural development (Castilla la Mancha & Com. Valenciana)
• High number of pigs farms in inland villages of CV. But lack of co-substrates
• High percentage of non-irrigated land (<700 mm of annual pluviometry)
• Soil conditions of arable land: low organic matter, high percentage of carbonates,
loam soils



Aim of the study
• To evaluate different site-adapted energy crops for biogas production which
were cultivated under non-irrigated conditions
  • Cultivation of energy crops
  • Batch test
  • Estimation of methane potential per surface unit
Methods
Analysis
                                    Methods




Cultivation
 • Crops VARIETIES. Triticale (cv.
   Bondadoso), Barley (cv. Oralia; cv. Unia),
   Oat (var. Prevision), Mixture of ryegrass
   (45% cv. Trinova; 40% cv. Braulio) and
   clover (8% cv. Paradana; 7% cv. Laser).
 • Location: CASTELLON
 • Weather & Soil CONDITIONS
          • Thermal integral
          • Annual pluviometry
          • Soil conditions
 • HARVEST TIME considering TS for ensiling
   and max. biogas potential awaited in
   relation to maturity scale (BBCH scale)
 • ENSILING at pilot scale (MONITORING OF
   TS, VS)
Analysis
Methods




      Batch tests
          • VDI Standard 4630
          • Inoculum from agricultural biogas
            plant
          • Digester volume: 2L
          • Incubator at 38ºC ± 2ºC
          • Biogas production: counter 1 mL
            resolution
          • Gas analysis. Measurement range
            CH4 and CO2 sensors: 0-100%
Results and Discussion
Results



Cultivation

                         After harvesting                     After ensiling

Crop        Mat.         TS1         VS1          Crop        TS2          VS2
            Stage        (%)         (TS%)        yield       (%)          (TS%)
            (BBCH)                                (t/ha)
Triticale   77-83        32.44       93.49        21.25       20.50        88.90

Oats        71-81        27.13       93.65        23.20       17.90        80.70

Barley      77-83        48.40       95.77        15.50       23.19        80.92
                         (1)         (1)          (1)         (2)          (2)
R&C         59-60        30.92       93.75        6.00        25.10        79.30

1: Barley (cv. Oralia); 2: Mixture of Oralia and Unia varieties (ensiled together) .
Mean values (not available standard deviation)
Results

                      Biogas Potential Test
                                                                                                         CH4 (%)
                    700

                                                                                                           58%
                    600
                                                                                                           58%
                    500                                                                                    54%
Biogas [NL/kg VS]




                    400                                                                                    58%
                    300



                    200


                    100



                     0
                          0         10           20            30           40        50           60

                                                              Time (days)



                              Triticale (cv. Bondadoso)
                              Oats (cv. Prevision)
                              Barley (cv. Oralia; cv. Unia)
                              Mixture ryegrass (cv. Trinova; cv. Braulio) and clover (cv. Paradana; cv. Laser)
Results & Discussion

Estimation biogas potential per surface unit


                                               Methane
                                                     (Nm3/kg seeds               (Nm3/L
                   (Nm3/tVS)             (Nm3/ha)
                                                        sown)                  rainwater)

Triticale              353                 1,368                9                  1.1

Oats                   314                 1,051                7                 n.a.

Barley                 280                  814                 6                  0.6

Mixture R&C            221                  264                 2                  0.2



Discussion
 • Maximum methane potential per hectare estimated between 264-1,368 Nm3CH4/ha
 • Triticale shows best results for methane potential per hectare, per kilogram of
   seeds sown or per liter of rainwater. Most suitable under those cultivation conditions.
 • Methane potential per hectare of TRITICALE tested under DRY conditions was
   20% LOWER than under WET conditions (1,700 Nm3/ha; FNR, 2010)
 • Barley and Oat showed “similar” results of biogas potential per unit of volatile solids.
   Nevertheless, methane potential per hectare was HIGHER for OATS.
Conclusions
Conclusions




• Under non-irrigated conditions triticale and oats showed the best estimated
  results of maximum methane potential per unit of surface (both over
  1,000 Nm3 CH4/ha).
• Barley showed a good biodegradability and a better maximum slope of
  accumulated biogas production than oats. Nevertheless, methane potential
  per volatile solid unit was higher for oats. Therefore, at bigger scale should be
  analyzed in detail which is the most suitable crop for biogas production
  considering crop yield per hectare of each specific area, total solids after
  ensiling as well as volatile solids.
• The mixture of ryegrass and clover, with a potential per surface unit of 264
  Nm3CH4/ha seemed to be an inappropriate alternative for the studied areas
  with low pluviometry. But it´s needed further research in order to evaluate its
  suitability for biogas production as a rotation crop in those areas.




  This research was carried out with funding from The Spanish Ministry of
  Environment and Agriculture (Ministerio de Medio Ambiente, Rural y Marino),
  under the Project ENERAL. http://eneral.info/
Thank you for your attention!
pgomez@ainia.es                 ainia

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Desarrollo de cultivos energéticos para producción de biogás en condiciones de baja pluviometría

  • 1. Site-adapted energy crops for biogas production cultivated under non-irrigated conditions in the Comunidad Valenciana (Spain) ainia Paz Gómez 29.08.2011 Vienna, Austria
  • 2. Analysis Content • Introduction and aim • Methods • Results and Discussion • Conclusions
  • 4. Introduction and aim Introduction • Climate change and rural development (Castilla la Mancha & Com. Valenciana) • High number of pigs farms in inland villages of CV. But lack of co-substrates • High percentage of non-irrigated land (<700 mm of annual pluviometry) • Soil conditions of arable land: low organic matter, high percentage of carbonates, loam soils Aim of the study • To evaluate different site-adapted energy crops for biogas production which were cultivated under non-irrigated conditions • Cultivation of energy crops • Batch test • Estimation of methane potential per surface unit
  • 6. Analysis Methods Cultivation • Crops VARIETIES. Triticale (cv. Bondadoso), Barley (cv. Oralia; cv. Unia), Oat (var. Prevision), Mixture of ryegrass (45% cv. Trinova; 40% cv. Braulio) and clover (8% cv. Paradana; 7% cv. Laser). • Location: CASTELLON • Weather & Soil CONDITIONS • Thermal integral • Annual pluviometry • Soil conditions • HARVEST TIME considering TS for ensiling and max. biogas potential awaited in relation to maturity scale (BBCH scale) • ENSILING at pilot scale (MONITORING OF TS, VS)
  • 7. Analysis Methods Batch tests • VDI Standard 4630 • Inoculum from agricultural biogas plant • Digester volume: 2L • Incubator at 38ºC ± 2ºC • Biogas production: counter 1 mL resolution • Gas analysis. Measurement range CH4 and CO2 sensors: 0-100%
  • 9. Results Cultivation After harvesting After ensiling Crop Mat. TS1 VS1 Crop TS2 VS2 Stage (%) (TS%) yield (%) (TS%) (BBCH) (t/ha) Triticale 77-83 32.44 93.49 21.25 20.50 88.90 Oats 71-81 27.13 93.65 23.20 17.90 80.70 Barley 77-83 48.40 95.77 15.50 23.19 80.92 (1) (1) (1) (2) (2) R&C 59-60 30.92 93.75 6.00 25.10 79.30 1: Barley (cv. Oralia); 2: Mixture of Oralia and Unia varieties (ensiled together) . Mean values (not available standard deviation)
  • 10. Results Biogas Potential Test CH4 (%) 700 58% 600 58% 500 54% Biogas [NL/kg VS] 400 58% 300 200 100 0 0 10 20 30 40 50 60 Time (days) Triticale (cv. Bondadoso) Oats (cv. Prevision) Barley (cv. Oralia; cv. Unia) Mixture ryegrass (cv. Trinova; cv. Braulio) and clover (cv. Paradana; cv. Laser)
  • 11. Results & Discussion Estimation biogas potential per surface unit Methane (Nm3/kg seeds (Nm3/L (Nm3/tVS) (Nm3/ha) sown) rainwater) Triticale 353 1,368 9 1.1 Oats 314 1,051 7 n.a. Barley 280 814 6 0.6 Mixture R&C 221 264 2 0.2 Discussion • Maximum methane potential per hectare estimated between 264-1,368 Nm3CH4/ha • Triticale shows best results for methane potential per hectare, per kilogram of seeds sown or per liter of rainwater. Most suitable under those cultivation conditions. • Methane potential per hectare of TRITICALE tested under DRY conditions was 20% LOWER than under WET conditions (1,700 Nm3/ha; FNR, 2010) • Barley and Oat showed “similar” results of biogas potential per unit of volatile solids. Nevertheless, methane potential per hectare was HIGHER for OATS.
  • 13. Conclusions • Under non-irrigated conditions triticale and oats showed the best estimated results of maximum methane potential per unit of surface (both over 1,000 Nm3 CH4/ha). • Barley showed a good biodegradability and a better maximum slope of accumulated biogas production than oats. Nevertheless, methane potential per volatile solid unit was higher for oats. Therefore, at bigger scale should be analyzed in detail which is the most suitable crop for biogas production considering crop yield per hectare of each specific area, total solids after ensiling as well as volatile solids. • The mixture of ryegrass and clover, with a potential per surface unit of 264 Nm3CH4/ha seemed to be an inappropriate alternative for the studied areas with low pluviometry. But it´s needed further research in order to evaluate its suitability for biogas production as a rotation crop in those areas. This research was carried out with funding from The Spanish Ministry of Environment and Agriculture (Ministerio de Medio Ambiente, Rural y Marino), under the Project ENERAL. http://eneral.info/
  • 14. Thank you for your attention! pgomez@ainia.es ainia