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Triangle of conflicts


Water                    Energy
           Environment




           Food
Land type           Area             Natural        Fuel and yield        % area of 
                        (mio km2)       Productivity      (tons per ha /     corresponding 
                                       (tons of carbon      GJ per ha)         ecosystem 
                                     fixed per hectare                         required to 
                                          and year)                            cover 2030 
                                                                                 demand
 Tropical and             10.5             10.7               Palmoil           110%!!!
 subtropical                                                 biodiesel 
 evergreen forest                                            (5 / 189)
 Tropical and              4.7             7.67             Jatropha            765%!!
 Subtropical Dry                                            biodiesel 
 Forest                                                    (1.5 / 56.7 )
 Tropical Savanna,         6.7             6.65           Cane­ethanol          270 %!!
 Woodland                                                 (4.34 / 116)
 Mid lattitude             14              5.30            Miscanthus           95 %!!
 forests, abandoned                                         cellulosic 
 croplands                                                  ethanol*
                                                           (4.4 / 120)
 Warm                      33            1 – 3.50         Algae­biodiesel     5.4 – 8.2 %
 Shrubland/grassla                                          (20 / 756)
 nd or desert
Table 1 - Comparison of land use impact of various biofuel crops to the area of suitable
ecosystems available assuming full coverage of 2030 projected liquid fuel demand of 210
exajoules (1 Exajoule is 1 billion gigajoules).
*50% of cellulosic biomass is deduced for process energy!
Sustainability
driven
System Design;

Point of
Reference:
Roundtable on
Sustainable
Biofuels;

All demands
satisfied!
Effluent polishing – productive
         opportunities
Example 1: Water
                                            Does not include
                                            floodwater runoff from
                                            towns, roads or
                                            agriculture that
                                            require treatment!



800 - 1600 m 3 evaporation per ton biodiesel,
2030 demand for liquid fuels would be 5.55 billion tons
5.55 bln times 1600 = 8800 billion m3

Recovery of 25% of projected water demand in the form of
waste, drainage water would suffice to produce 20% of
projected global fuel demand.
90% of developing World’s
Water untreated!

Conventional treatment costs
energy, dissipates nitrogen!

Acting now for establishing
infrastructure!!
Sea Water (Or Fossil Ground Water):
            it’s not that simple!
For 4.5% Salinity:
•    75 tons biomass (25 GJ per ton) per year, pumping of 90000 m3 required;

•    1.50 GJ of pumping energy per ton of biomass

•    6% for maintaining 4.5% salinity at 100 m elevation;

•    ca 50% recoverable as hydroelectricity, ideal for storage of surplus solar or
     wind energy!

•    Fossil electricity prohibitive due to low efficiency
Salt Tolerance of Nannochloropsis sp
                140                                                                                                   Con (2.7 % NaCl)
                                                                                35
                                                                                                                      1.3% Na cl
                120                                                                                                   4% Na cl
                                                                                30
                100
  Chl (mg/l)




                                                                   Chl (mg/l)
                                                                                25
                80
                                                                                20
                60
                                                      Control
                40                                    1.3% Nacl                 15
                                                      4% Nacl
                20
                                                                                10
                    0                                                                   0       2   4        6    8   10
                                                                                                    Time(days )
                        0   2      4       6
                                   Time (days)   8     10

                8                                                               6

                                                                                5
                6
   DW (mg/ml)




                                                                                4




                                                                   DW(mg/ml)
                                                                                                                      Con (2.7 % Na Cl)

                4                                                               3                                     1.3% Na cl
                                                     C ontrol
                                                                                                                      4% Na cl
                                                     1.3% N acl                 2

                2                                    4% N acl
                                                                                1

                                                                                0
                0                                                                   0       2       4        6    8    10
                        0   2     4       6      8    10                                            Time(days )
                                  Time (days )

Growth of Nannochloropsis under control                           Growth of Nannochloropsis under nitrogen
conditions at 3 different salt concentrations                     stress at 3 different salt concentrations
determined as chlorophyll concentration                           determined as chlorophyll concentration
(top) or dryweight (bottom)                                       (top) or dryweight (bottom)
Land
                                 Elevation!
 Climate                         100 m elevation costs 3% of energy
                                 produced for pumping!




                                 250000 km2
                                              250000 km2


                                                                    250000 km2
             250000 km 2

Population


                                                              250000 km 2



                   Below 200 m
Examples 2: Nutrients
Not a burden, a blessing in algal sustainability assessments!




http://en.wikipedia.org/wiki/File:Aquatic_Dead_Zones.jpg
Pollution by agriculture --Integrated resource management
      Pollution by agriculture Integrated resource management




Israel: Cattle contributes 35 % of total water pollution
FAO: Livestock farming is responsible for 18 % of global greenhouse gas emissions
Nutrient Run-Off and Dead Zones
Many areas around the world are suffering from the problem of eutrophication. The Gulf
of Mexico, Caspian Sea, Bering Sea and Arabian Sea. The Gulf of Mexico already has a
huge Dead Zone which the scientists warn could expand further.




Phytoplankton concentration along the North American Coastline
Efficient Use Of Fertilizers
Most fertilizers contain Phosphorus and Nitrogen on which these algae thrive hence it is
that we use fertilizers that a) are biodegradable and b) contain lesser quantities of these
elements. Also the farmers need to irrigate their lands in a scientific manner. Each crop
requires a definite amount of water to give the best yield hence the farmers shouldn’t
over-irrigate their lands since it could lead to more voluminous runoffs.
Nitrogen Load Mississippi




41% of Continental
   US water
   discharge!
35% of Continental
   US area!
Modern Farming Produces Enormous Nitrogen Surpluses




       200 mio hectares of European farmland times 50 kg recoverable excess:

                 10 million tons of nitrogen per year!
Immediately Applicable
Integrated Biological Systems for Exploitation of Humid Agro-Industrial Waste
                                 Resources
                       IBSEHAWR - FP7 Useful Waste
PURPOSE:

      GHG NEGATIVE

ENERGY NEUTRAL PRODUCTIVE
         SYSTEMS
Biological resource recovery from agro-industrial waste:
            Several Project Ideas developed,
 Four to five project ideas with implementation details!
               NEW CALLS REQUIRED!


           Algal Pond:                                  Biogas Reactor
   Biomass for Fodder or Energy

                                                       Biogas
                                                                        Nutrients
                                   CO2   Gas Turbine
                                                                Water
                                                                Flow




       Constructed Wetland:                                 Agro-Industrial
    Biomass for Fodder or Energy
                                                              Enterprise
Full System Integration (Project ALTEC):
             The Challenge – Co-location of Resources
         The Answer – Integrated Infrastructure Development
                 Electricity, Process Heat                   Biogas
                    Fertilizer                Fermentation residues


                                                                           Biogas plant
                                                        O2
                                                                                            Algae
                                                                                           Residues


   Biomass or Fossil                CO2                                 Algae                Oil
                                                                      dehydration         extraction
                 Power plant                    Algae
                                                                                           Algae oil
                                                                      Effluent



                                                Nutrients

                Bioethanol plant
                                                                                          Biodiesel plant

Cane Ethanol:
Ca 80% of biomass as CO2!
                                              Waste Water               Urban
                                             Treatment Plant          community            Petrol station
Again Brazil!
Integrated Exploitation of Agro-Industrial Emissions




     More Favorable Economic and Environmental Balance!
Resource Recovery from Landfill Effluent
                                                                                 17-4before
                                                                     0.30

                                                                     0.25
                                                      Control
                                                                     0.20
                                                      Pond1




                                                                OD
                                                      Pond2          0.15
                                                      Pond3
                                                                     0.10
                                                      Pond4
                                                                     0.05

                                                                     0.00
                                                                         250    300       350        400   450    500
                     Degradation of Recalcitrant Toxic Organics
                                                                                                nm


                                                                               Total N and P
                                                      1600
                                                      1400
                                                      1200
                                                      1000


                                               ppm
                                                       800
                                                       600
                                                       400
                                                       200
                                                         0
                                                     N (ppm)     Effluent        Pond 1         Pond 2       Pond 3
                                                     P (ppm)
Identification of Novel Interesting
           Algal Species                   95% Nitrogen Recovery as Struvite (pond 1) and biomass
                                           (ponds 2 and 3), load reduction from 1400 ppm to ca 70 ppm
Cultivation of Scenedesmus on Biogas
Recover 10 from
   waste 5 for
       reuse
                                                                       Effluent
  = Recover 10
+5=15 available,
  7.5 for reuse
                                                       Growth of Scenedesmus in mBG11 or Conditionned
Recover 10 +7.5                                                        Biogas Effluent
 = 17.5 availabe
 8.75 for reuse
  Recover 10 +                                   1.4       mBG11
                      d ry w eig h t (m g /m l




8.75 = 18.75, 9.4                                1.2       Biogas effluent
     for reuse                                     1
   Recover 10
                                                 0.8
  10, Recover 8
  18, recover 9
                                                 0.6
 19, recover 9.5                                 0.4
        19.5                                     0.2
         10                                        0
       11 +8                                           0              2        4           6            8
      12+ 9.5
     13+10.75                                                                 days
      14+ 12
      15+ 13
       16+14        A local Scenedesmus strain displays similar maximal growth rates in mBG11 as in
  N- and other      conditioned 1:20 diluted biogas effluent. No bacterial or other contaminations were
  nutrient pool     observed in the effluent during 10 days of cultivation, resources were exhausted after
   tripled in 30
       years
                    6 days (picture right).
Implications on LCA
                        A Scientists View
Major Reassessments Required for Integrated Production Systems:
   Abiotic Depletion (water, nutrients, fossil fuels) can be negative in algae if
   nutrients and water are recovered from waste materials etc!

   Eutrophication: can be negative if wastewater is treated and effluent is
   adequately polished!

   GWP: can be reduced if methane and N2O emissions from organic waste and
   sludge are reduced!

   Land (and other impacts): may be reduced if protein production is
   incorporated (integrated fuel-food LCA)!

   Land is not land: must be corrected for land value, land scarcity, productivity
   and biodiversity potentials, economic and environmental value!
Waste Water in – Treated Water out!!




                    Algal Biodiesel

            Water Footprint           Numbers are
                                      Arbitrary!




                    Algal Biodiesel


      Eutrophication - Ecotoxicity
Nitrogen Recovered - Exported as fertilizer




                     Algal Biodiesel
Methane and N2O Emissions Avoided
– Negative GHG Emissions




                 Algal Biodiesel
Indirect Land-Use:
Protein as By Product,
1 ha replaces up to 10 ha of Soy beans!




                     Algal Biodiesel
Waste Water in – Treated Water out!!




                    Algal Biodiesel
April 2003   Hartbeespoort   Dam
Exploitation of Algal Blooms




       Chlorophyll-a distribution
Integrated Remediation Approach

                                          Lake
                                                   Nutrient
                                                   Rich
        Harvest and Dry Algae Mat and Water-       Lake Water
             Hyacinth 15000 tons/year

                                                                    Nutrient
                                                      Green
                                                                    Depleted
                                                      Algae
                                                                    Water
                                           CO2        Ponds
                  Gasification
                     Plant                       Algae Suspension


                                                         Tilapia Pond
               Electricity: 4 MW
               Heat: 6 MW
Biochar –Soil Enrichment – Carbon Sequestration               Fish
Integrated Carbon Capture –                 Cost
Waste Water Treatment – Algal
Biomass Arawa:                              6 bln
Resource Mapping

         Algal Cultivation for
                                            Returns?
         Waste water treatment –
         Energy
         Red Sea-Dead Sea
         Channel
        Waste Water + CO2 from
        Aqaba Power Plant
                                              Red sea-Deadsea 2
   • 1 Mio Inhabitants                        billion m3 per year
   • 200000 Cattle and Livestock              pumped, half used for
   • Intensive Agriculture-Drainage Water     algae, 2/3 recovered
                                              (loss 450 mio cubes) (or
   • About 30000 t N / 3000 t P per year      supplemented by waste
   • 1 mio tons Algae at 3% N                 and drainage waters):
   • Water required 450 mio cubes, 15
     cubes/sec
   • 300000 tons oil – 10% of annual
     consumption
   • Land required: 150 km2
Not a Task for 3-Men Startups

A Question of National
 Infrastructure

(with corresponding economic
 rules!)
All That’s Required: VISION




Cost $ 20 bln, return maybe in 50 years,
But significant socioeconomic and
 environmental impact

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066 presentation%20 %20-s.%20leu%20(ben%20gurion%20university)%20-%20algae%20biofuels%20sustainability[1]

  • 1. Triangle of conflicts Water Energy Environment Food
  • 2. Land type Area  Natural  Fuel and yield  % area of  (mio km2) Productivity (tons per ha /  corresponding  (tons of carbon  GJ per ha) ecosystem  fixed per hectare  required to  and year) cover 2030  demand Tropical and  10.5 10.7 Palmoil 110%!!! subtropical  biodiesel  evergreen forest (5 / 189) Tropical and  4.7 7.67 Jatropha 765%!! Subtropical Dry  biodiesel  Forest (1.5 / 56.7 ) Tropical Savanna,  6.7 6.65 Cane­ethanol 270 %!! Woodland (4.34 / 116) Mid lattitude 14 5.30 Miscanthus 95 %!! forests, abandoned  cellulosic  croplands ethanol* (4.4 / 120) Warm  33 1 – 3.50 Algae­biodiesel  5.4 – 8.2 % Shrubland/grassla (20 / 756) nd or desert Table 1 - Comparison of land use impact of various biofuel crops to the area of suitable ecosystems available assuming full coverage of 2030 projected liquid fuel demand of 210 exajoules (1 Exajoule is 1 billion gigajoules). *50% of cellulosic biomass is deduced for process energy!
  • 3. Sustainability driven System Design; Point of Reference: Roundtable on Sustainable Biofuels; All demands satisfied!
  • 4. Effluent polishing – productive opportunities
  • 5. Example 1: Water Does not include floodwater runoff from towns, roads or agriculture that require treatment! 800 - 1600 m 3 evaporation per ton biodiesel, 2030 demand for liquid fuels would be 5.55 billion tons 5.55 bln times 1600 = 8800 billion m3 Recovery of 25% of projected water demand in the form of waste, drainage water would suffice to produce 20% of projected global fuel demand.
  • 6. 90% of developing World’s Water untreated! Conventional treatment costs energy, dissipates nitrogen! Acting now for establishing infrastructure!!
  • 7. Sea Water (Or Fossil Ground Water): it’s not that simple! For 4.5% Salinity: • 75 tons biomass (25 GJ per ton) per year, pumping of 90000 m3 required; • 1.50 GJ of pumping energy per ton of biomass • 6% for maintaining 4.5% salinity at 100 m elevation; • ca 50% recoverable as hydroelectricity, ideal for storage of surplus solar or wind energy! • Fossil electricity prohibitive due to low efficiency
  • 8. Salt Tolerance of Nannochloropsis sp 140 Con (2.7 % NaCl) 35 1.3% Na cl 120 4% Na cl 30 100 Chl (mg/l) Chl (mg/l) 25 80 20 60 Control 40 1.3% Nacl 15 4% Nacl 20 10 0 0 2 4 6 8 10 Time(days ) 0 2 4 6 Time (days) 8 10 8 6 5 6 DW (mg/ml) 4 DW(mg/ml) Con (2.7 % Na Cl) 4 3 1.3% Na cl C ontrol 4% Na cl 1.3% N acl 2 2 4% N acl 1 0 0 0 2 4 6 8 10 0 2 4 6 8 10 Time(days ) Time (days ) Growth of Nannochloropsis under control Growth of Nannochloropsis under nitrogen conditions at 3 different salt concentrations stress at 3 different salt concentrations determined as chlorophyll concentration determined as chlorophyll concentration (top) or dryweight (bottom) (top) or dryweight (bottom)
  • 9. Land Elevation! Climate 100 m elevation costs 3% of energy produced for pumping! 250000 km2 250000 km2 250000 km2 250000 km 2 Population 250000 km 2 Below 200 m
  • 10. Examples 2: Nutrients Not a burden, a blessing in algal sustainability assessments! http://en.wikipedia.org/wiki/File:Aquatic_Dead_Zones.jpg
  • 11. Pollution by agriculture --Integrated resource management Pollution by agriculture Integrated resource management Israel: Cattle contributes 35 % of total water pollution FAO: Livestock farming is responsible for 18 % of global greenhouse gas emissions
  • 12. Nutrient Run-Off and Dead Zones Many areas around the world are suffering from the problem of eutrophication. The Gulf of Mexico, Caspian Sea, Bering Sea and Arabian Sea. The Gulf of Mexico already has a huge Dead Zone which the scientists warn could expand further. Phytoplankton concentration along the North American Coastline Efficient Use Of Fertilizers Most fertilizers contain Phosphorus and Nitrogen on which these algae thrive hence it is that we use fertilizers that a) are biodegradable and b) contain lesser quantities of these elements. Also the farmers need to irrigate their lands in a scientific manner. Each crop requires a definite amount of water to give the best yield hence the farmers shouldn’t over-irrigate their lands since it could lead to more voluminous runoffs.
  • 13. Nitrogen Load Mississippi 41% of Continental US water discharge! 35% of Continental US area!
  • 14.
  • 15. Modern Farming Produces Enormous Nitrogen Surpluses 200 mio hectares of European farmland times 50 kg recoverable excess: 10 million tons of nitrogen per year!
  • 16. Immediately Applicable Integrated Biological Systems for Exploitation of Humid Agro-Industrial Waste Resources IBSEHAWR - FP7 Useful Waste
  • 17. PURPOSE: GHG NEGATIVE ENERGY NEUTRAL PRODUCTIVE SYSTEMS
  • 18. Biological resource recovery from agro-industrial waste: Several Project Ideas developed, Four to five project ideas with implementation details! NEW CALLS REQUIRED! Algal Pond: Biogas Reactor Biomass for Fodder or Energy Biogas Nutrients CO2 Gas Turbine Water Flow Constructed Wetland: Agro-Industrial Biomass for Fodder or Energy Enterprise
  • 19. Full System Integration (Project ALTEC): The Challenge – Co-location of Resources The Answer – Integrated Infrastructure Development Electricity, Process Heat Biogas Fertilizer Fermentation residues Biogas plant O2 Algae Residues Biomass or Fossil CO2 Algae Oil dehydration extraction Power plant Algae Algae oil Effluent Nutrients Bioethanol plant Biodiesel plant Cane Ethanol: Ca 80% of biomass as CO2! Waste Water Urban Treatment Plant community Petrol station Again Brazil!
  • 20. Integrated Exploitation of Agro-Industrial Emissions More Favorable Economic and Environmental Balance!
  • 21. Resource Recovery from Landfill Effluent 17-4before 0.30 0.25 Control 0.20 Pond1 OD Pond2 0.15 Pond3 0.10 Pond4 0.05 0.00 250 300 350 400 450 500 Degradation of Recalcitrant Toxic Organics nm Total N and P 1600 1400 1200 1000 ppm 800 600 400 200 0 N (ppm) Effluent Pond 1 Pond 2 Pond 3 P (ppm) Identification of Novel Interesting Algal Species 95% Nitrogen Recovery as Struvite (pond 1) and biomass (ponds 2 and 3), load reduction from 1400 ppm to ca 70 ppm
  • 22. Cultivation of Scenedesmus on Biogas Recover 10 from waste 5 for reuse Effluent = Recover 10 +5=15 available, 7.5 for reuse Growth of Scenedesmus in mBG11 or Conditionned Recover 10 +7.5 Biogas Effluent = 17.5 availabe 8.75 for reuse Recover 10 + 1.4 mBG11 d ry w eig h t (m g /m l 8.75 = 18.75, 9.4 1.2 Biogas effluent for reuse 1 Recover 10 0.8 10, Recover 8 18, recover 9 0.6 19, recover 9.5 0.4 19.5 0.2 10 0 11 +8 0 2 4 6 8 12+ 9.5 13+10.75 days 14+ 12 15+ 13 16+14 A local Scenedesmus strain displays similar maximal growth rates in mBG11 as in N- and other conditioned 1:20 diluted biogas effluent. No bacterial or other contaminations were nutrient pool observed in the effluent during 10 days of cultivation, resources were exhausted after tripled in 30 years 6 days (picture right).
  • 23. Implications on LCA A Scientists View Major Reassessments Required for Integrated Production Systems: Abiotic Depletion (water, nutrients, fossil fuels) can be negative in algae if nutrients and water are recovered from waste materials etc! Eutrophication: can be negative if wastewater is treated and effluent is adequately polished! GWP: can be reduced if methane and N2O emissions from organic waste and sludge are reduced! Land (and other impacts): may be reduced if protein production is incorporated (integrated fuel-food LCA)! Land is not land: must be corrected for land value, land scarcity, productivity and biodiversity potentials, economic and environmental value!
  • 24. Waste Water in – Treated Water out!! Algal Biodiesel Water Footprint Numbers are Arbitrary! Algal Biodiesel Eutrophication - Ecotoxicity
  • 25. Nitrogen Recovered - Exported as fertilizer Algal Biodiesel
  • 26. Methane and N2O Emissions Avoided – Negative GHG Emissions Algal Biodiesel
  • 27. Indirect Land-Use: Protein as By Product, 1 ha replaces up to 10 ha of Soy beans! Algal Biodiesel
  • 28. Waste Water in – Treated Water out!! Algal Biodiesel
  • 29. April 2003 Hartbeespoort Dam
  • 30. Exploitation of Algal Blooms Chlorophyll-a distribution
  • 31.
  • 32. Integrated Remediation Approach Lake Nutrient Rich Harvest and Dry Algae Mat and Water- Lake Water Hyacinth 15000 tons/year Nutrient Green Depleted Algae Water CO2 Ponds Gasification Plant Algae Suspension Tilapia Pond Electricity: 4 MW Heat: 6 MW Biochar –Soil Enrichment – Carbon Sequestration Fish
  • 33. Integrated Carbon Capture – Cost Waste Water Treatment – Algal Biomass Arawa: 6 bln Resource Mapping Algal Cultivation for Returns? Waste water treatment – Energy Red Sea-Dead Sea Channel Waste Water + CO2 from Aqaba Power Plant Red sea-Deadsea 2 • 1 Mio Inhabitants billion m3 per year • 200000 Cattle and Livestock pumped, half used for • Intensive Agriculture-Drainage Water algae, 2/3 recovered (loss 450 mio cubes) (or • About 30000 t N / 3000 t P per year supplemented by waste • 1 mio tons Algae at 3% N and drainage waters): • Water required 450 mio cubes, 15 cubes/sec • 300000 tons oil – 10% of annual consumption • Land required: 150 km2
  • 34. Not a Task for 3-Men Startups A Question of National Infrastructure (with corresponding economic rules!)
  • 35. All That’s Required: VISION Cost $ 20 bln, return maybe in 50 years, But significant socioeconomic and environmental impact