1. Sandighad dravya(Controversial)
Defination (संदिग्ध द्रव्य) :-
"Sandigdha Dravya" means doubtful or controversial medicinal
substances. These are the dravyas (herbs/minerals) where
confusion exists about their identity, properties, nomenclature, or
therapeutic use
why dravya becomes sandigdha :-
1. नामभेि (Naam Bhed) – Same name used for different herbs.
2. स्वरूप भेि (Swaroop Bhed) – Similar physical appearance of
different
dravyas.
3. ग
णु भेि (Guna Bhed) – Different attributes described in
different text.
4.
Types Discription
Naam janyaDue to name of confusion
Swaroop janya Due to physical similarity
Guna janya Due to differences of
properties
Prayog janya Due to variations in use
Jati janya Due to different botnical
species
Types of Sandigdha Dravyas:-
5.
Common Examples :-
Ayurvedicname Possible botnical name
Brahmi Bacopa mnnieri centella
asiatica
Shankhapushpi Convolvulus pluricaculis
Gokshura Pedalium murex
Tagara Valeriana wallichii
Yavani Trachyspermum ammi
Vaikrant:-
Introduction:
Vaikrant is knownas a controversial or doubtful mineral drug in Ayurveda.
It is a mineral-origin substance and is considered to belong to the
gemstone category (Ratnavarga). Although it is mentioned in Ayurvedic
texts for use in specific pathological conditions, there are disagreements
regarding its chemical identity, properties, and therapeutic applications.
Synonyms:
• Vaikrant
• Vikrant
• Black Tourmaline (According to modern
identification) Probable Identity:
•According to some Ayurvedic opinions, Vaikrant is equated with
Black Tourmaline.
•In other sources, it is considered to be a mineral form of iron silicates or
silica- containing minerals.
8.
Properties:
•Rasa (Taste): Pungent(Katu), Bitter (Tikta)
•Guna (Qualities): Light (Laghu), Dry (Ruksha)
•Veerya (Potency): Hot (Ushna)
•Vipaka (Post-digestive effect): Pungent (Katu)
Uses: •Rejuvenative (Rasayana)
•Strength-promoting (Balya)
•Pacifies Vata and Kapha doshas
•Anti-inflammatory (Shothahara)
•Sometimes mentioned in the treatment of Kushtha (skin
diseases), urinary disorders, and neuromuscular diseases 6.
Controversy:
9.
Controversy:-
•There is noclear scientific evidence regarding its exact
chemical identity, purification methods, or standardized
therapeutic usage.
•Hence, Vaikrant is classified under “Sandigdha Dravya”
(doubtful substances).
Conclusion:-
Vaikrant is an ancient mineral substance mentioned in Ayurveda,
but its nature remains uncertain. There is a need for modern
scientific research to confirm its identity, properties, and safe
therapeutic applications.
Chapala
• Chapala isthe drug mentioned in the group of
maharasa
•considered as controversy because of lack of
identification and scarcity of drug.
•There are different opinions regarding the
mineralogical identification of Chapala.
•According to Sri D.A.Kulkarni, commentator of Rasa
Ratna Samuchchaya, Chapala is a Bismuth.
• Few scholars opines it as Selenium.
•As maharasa group contains the drugs which are in
the form of mineral or ore of metal, Some says it as
Cassiterite, ore of Tin.
12.
Sr. No. PropertiesChapala Selenium bismuth Cassiterite
1. Melting Point Vangavat 221°C 271.5°C 232°C
2. Crystal System Shadasra Hexagonal Rhombohedral Tetragonal
3. Occurrence Makshika
boomyod
Bhava
Usually found
in conjunction
with copper
and sulphur
(copper pyrite)
Often associated
with lead, zinc,
copper, tin, silver
ores from which
it is obtained as a
byproduct during
refining
Found
mainly in
acid igneous
rocks with
tourmaline,
topaz aseno-
pyrite
bearing
minerals in
high
temperature
4. Specific gravity Guru 4.8 9.8 6.4-7.1
13.
Sr.
no.
Propertirs Chapla SeleniumBismuth Cassiteritr
5. Hardness Snigdha
(smooth
)
2 2-2.5 6-7
6. Luster/tra
nsperenc
y
Sahatika
chaya
Metallic/opaque mrtallic/opaqu
e
Adamantine or
greasy/
generally
opaque but is
translucent in
thin crystals
14.
Sr.
No.
properties Chapala SeleniumBismuth cassiteri
te
7. Colour Goura
shweta
aruna
krshna
Ores are Green, Bluish grey,
Bronzy grey, Tin white, Grey
Brown, Dark grey, Blue,
White, Steel grey, lead grey,
Reddish brown, Black
Grayish white
metal with a
reddish tinge ores
are red, black and
golden yellow
Brown
black,
reddish
brown,
browins
h black
8. Therapeuti
c use
Lekhna
ativrshya
deha
lohakara
Antioxident, immuno booster
,hep in the deve lopment and
maintence of healthy sperm
cells ,reduce the risk of skin
G.I. Disorders as
soothing and
demulcent
9. Dhatu
vada
Rasa
bandakar
a
Selenium occurs with
mercury, in compound form
as its ores halcite and tiema-
nnite it blinds mercury firmly
Not binds
mercury
Not
binds
mercury
15.
By comparing theabove factors,
•Cassiterite does not match with the properties of Chapala and hence
this
cannot be considered as Chapala.
•Although studies done on the physical properties of Chapala says that
Bismuth match more with the acceptable characteristics of Chapala as
described in Ayurvedic classics with metallic luster, high specific gravity
and low melting point Bismuth is mainly used in digestive disorders.
•Metal selenium has many amorphous forms, its particles have
hexagonal structure, found admixture with Chalcopyrite, it is mainly
used in sexual disorder and also as best anti-oxidant. So Chapala can be
better considered as selenium
Rasanjana:-
Rasanjana is oneof the type of Anjana,which is mentioned in
the group of Uparasa.
Since ancient times Rasanjana is considered to be a
controversial drug.
Rasanjana – Properties (गणधममु ):
1.Rasa (Taste) - Tikta (bitter), Kashaya (astringent)
2.Guna (Quality) - Laghu (light), Ruksha (dry)
3.Veerya (Potency) - Ushna (hot)
4.Vipaka - Katu (pungent – post-digestive effect)
5.Prabhava - Netrya (specific action on eyes), Krimighna
(anti- parasitic)
18.
"ि ारु हरिद्राया क् वाथात ् स् यात ् ि साञ् जनं भवे त।्
तत्तु ने त्र
दहतं ततक
् तं लघु रुक
् षं कषायकम॥् "
• Identity and Preparation: -
• There's debate about the identity of Rasanjan, but it's
often
associated with Rasot, which is derived from
Daruharidra (Berberis aristata).
• According to some texts, Rasanjan can be prepared by
boiling Daruharidra with goat's milk and reducing it to a
thick consistency.
19.
Uses of Rasanjana:-
1.NetraRogas (Eye diseases) Used in collyrium (Anjana) form for
treating conjunctivitis, infections.
2.Krimi (worm infestations) Internal use in some formulations to
remove intestinal parasites.
3. Vrana (Wounds/Ulcers) Applied topically due to its antimicrobial
and
wound-healing properties.
4.Kustha (Skin disorders) Used for skin diseases due to its Tikta
and Kashaya rasa, and Shodhana action.
5.Raktapitta (Bleeding disorders) Its cooling and astringent
properties help control bleeding.
Types of Rasanjana :-
6. Shailaja - obtained naturally from mountains
7.Kritrima - prepared out of peeta chandana kwath or Niryasa
Pushpanjana:-
Pushpanjana is oneof the type of Anjana, which is mentioned in the
group of Uparasa. Different opinions about Pushpanjana:-
1.According to Ayurveda prakasha, Pushpanjana is white in colour
and the author says, some opines it as Ritikitta. Riti is Pittala (Brass), an
alloy of Copper and Zinc.its kitta may be obtained by frying it.
2.Dr. D. A. Kulkarni, commentator of Rasaratna samucchaya says
that, as derived from the name, it may be anjana formed from the
flower. It may be the nectar of the flower seen in the region of
Kashmir, which is called as Kashmiri madhu,which is used in anjana.
3.In Atreya samhita, there is a reference of Padma madhu which is
nothing but the nectar derived from lotus, which possess the property
of curing netra rogas. This can also be considered as pushpanjana.
22.
4.Some opines that,Sphatika when roasted becomes shuddha and
attains the laja form. This roasted sphatika can be considered as
Pushpanjana, as it is white in colour and used for treating eye disease
5.Pushpa kasisa can also be considered as Pushpanjana as it is
having the synonyms of Nayanoushadha or netroushadha, signifying
its usage in netra rogas.
6.Dr. Siddhinandan Mishra, in his Ayurvediya Rasashastra, narrates
that when zinc is roasted in open air,it turns to laja swaroopa,which
can be considered as pushpanjana
23.
Research works toclear the controversies of Pushpanjana are not
available till now. Based on the literature available, it can be inferred
that Pushpanjana could be the drug which is chemically Zinc oxide.
It is having a synonym as Reetija, Riti is the Pittala (Brass), an alloy
of Copper and Zinc, suggesting that it might be a Zinc compound.
Based on its appearance, it might have been named as pushpa, so
directly any flower or its nector cannot be taken as Pushpanjana.
Pushpanjana available in Market is usually prepared in laboratories
which is chemically Zinc oxide (ZnO). Yadavji and some other
Acharyas has accepted the same. So Pushpanjana can be taken as a
drug which is chemically ZnO.
24.
5.Vahnijara
What is Vahnijara?
Vahnijararefers to substances that are tested or processed using
fire (heat). These substances undergo thermal treatment as part
of their purification or preparation process.
Uses of Vahnijara:
•Purification in metallurgy/Rasa Shastra – Metals and
minerals are purified using heat-based processes.
•Agni Sanskar (Thermal processing) – Certain plant or mineral
substances exhibit medicinal properties only after being
subjected to
fire.
25.
Examples:
1.Gandhaka (Sulphur) –It is purified through fire-
based processing.
2.Loha (Iron) – Fire is used during the preparation of its
bhasma (ash formulation).
3.Shilajit – Its therapeutic properties are enhanced
after heat processing.
Girisindura:-
• Introduction 6thmineral of Sadharanarasa group
• Identified as Mercuric oxide (HgO)
• A red to orange coloured dry mercuric powder obtained
naturally on selected mountain peaks
• Solid at room temperature and pressure
• Prepared artificially by heating Mercury and Oxygen at
roughly 350°C or by pyrolysis of mercuric nitrate
• Occurrence:-
• Artificial preparation is called Nagasindhura.
• Grahyalakshanam
28.
• Synonyms:- Sinduram,Mahila baala bhushanam,
Sringara bhushanam,Naagajam, Naagagarbha,
Nagarenuka,Mangal ya ,Bhalasoubhaagya
•
अततसू क्ष्मकणम् स्स्नग्धम् गु रु व
ण
म
स्मृ तु ज्ज
ज्ज
व
ल
म
।्
मृ िु लं ववमलं चैव ससन्िू ि
ं
ज्जयोततममु च्यते॥
ि.त. 9/150
29.
• Types (Accordingto Rasajalanidhi)
• Girisindhura (Natural): Mercuric oxide
• Nagasindhira (Artificial): Lead oxide
• Aamayika Prayoga
• Not found for internal use
• Along with ghrita, used externally for Anjana Namika
• With ghee, guggulu, honey, guda used in cracked soletreatment
त्र
त्रि
ो
ष
घ्नं भेदि स्तम्भनघ्नं तिनग्रु हम।् िे हिोषघ्नं न
ेत्र्यं गगरिससन्ििू मच्यतेु
॥
30.
7.kankushtha:-
"कन् कष् ुटं ववद् रमच् छायु ं तच् च सत् वमयं
वप्रये ।”
SYNONYMS
"ककष्ु ं टं क
ा
क
कु ष्टं च बां गं कोलावालु कम् ॥"
Viranga, Rangadayaka, Rechaka, Talakushta,
Tikshnadugdha, Swarnakshiriniryasa, Hemavati.
Drug: Revand chini (Rheum
emodi) Local Names:
Hindi: Revand chini
Latin : Botanical Name: Garcinia
31.
Varieties:-
According to R.R.S.:-
NalikaKankushta नसलका कन्कष्ु ठा —
पीता, गरुु स्स्नग्धा स
वपणीम स
भु गा।
Renuka Kankushta ि
े णकाु कन्कष्ु ठा —
कृ ष्णा तीव्रा स
स्ु ष्कका लघ्वी।
In Brihatrasaraja Sundaram, it is described as:-
• Nalika kankushta: Yellow, heavy, smooth, like rock salt,
tubular.
32.
Properties and Uses:-
FromR.R.S:-
1. िसैैः स
ा
य
प्रं शोभंतत सत्वं बन्धं च कृ त्वताम।्
2. कटु ं तीक्तं कटु क
ं वीथीयं चाततवविेचनम।्
व्रणोििशलू ाततसािगल्मऽे ु व
प
ह
स्
न्तत
त्
त्र
त
म
।् ु ।
3. भजे ते नवं कार्शयधात् म
वस्ग् नवधमनमायसहा। नाशयत्ते ाम्र मत्रत् वू ं
व् यथनं मात्रतोऽ वप च।।
Unwanted Effects &Management:
• Ati virechanat vamanam — Due to excessive purgation, vomitingmay
occur.
• Management: Light diet and virechanopashamak yoga.
Important Formulations:-
• Peeta rasa (AFI Part 1)
• Udavartanaghrita
• Mrityunjayeevanarasa
35.
2. Krutrima dravya
Introduction
•Some mineral drugs were rare or unavailable in
ancient times.
• Artificial preparations are described in classics to
overcome scarcity.
• These drugs are equally potent as natural ones.
• Used during scarcity in place of natural drugs
36.
1. Sasyaka Dravya
•Sanskrit Name: Sasyaka (सस्यक)
• English Name: Blue Vitriol / Copper Sulphate
• Chemical Formula: CuSO4.5H2O
Synonyms:Tamragairika,Neelatuttha,Tuttha, Neeloshtha,
Shitdravya Group: Uparasa (उपिस)
• Semi-metallic compound used in Rasoushadhi
• Not used directly requires Shodhana
Physical Properties
•Blue crystalline powder
•Soluble in water
•Astringent and bitter taste
•Hygroscopic in nature
37.
Ayurvedic
Properties
Property Detail
Rasa Tikta(bitter), kashaya (Astrigent)
Guna Laghu (Light),Ruksha (Dry)
Veerya Ushna (Hot)
Vipaka Katu(Pungent)
Prabhava Krimighna (Anti-Parasitic)
Therapeutic Use
• Antiseptic – used externally
• Wound healing in Lepa (pastes)
• Eye diseases in classical Ayurvedic formulations
• Krimighna – destroys worms and parasites
• Used in Rakta vikaras (blood disorders) with other
drugs
38.
2.Gandhaka Dravya
• SanskritName: Gandhaka (गन्धक)
• English Name: Sulphur
• Chemical Formula: S8 (elemental Sulphur, usually in octa-
atomic form)
• Synonyms (Sanskrit):
• Shulva (शु ल्व)
• Guggulu (गु ग्गु ल)–sometimes mentioned
• Belongs to Rasa Dravya
• Comes under Rasavarga or sometimes Maharas
Gandhaka (Sulphur) -Materials
• Hydrogen sulfide (H₂S) source
• Air or oxygen source
• Catalytic reactor or furnace
• Condenser
• Sulfur collection and storage system
Gandhaka (Sulphur) - Procedure
• Oxidation: H₂S + 3O₂ → 2SO₂ + 2H₂O
• Catalytic Reaction: 2H₂S + SO₂ → 3S + 2H₂O
• Condensation of sulfur vapor
• Collection of liquid sulfur
• Solidification into yellow crystals
• Purification by filtration or distillation
41.
3.Kasisa Dravya
• SanskritName: Kasisa कसीस
• English Name: Green Vitriol / Ferrous Sulphate
• Chemical Formula: FeSO4.7H2O (Ferrous sulphate
heptahydrate)
Synonyms (Sanskrit): -
•Kasika
•Tuttha
•Harital
•Lohalohita
Classification:-
•Uparasa ( उपिस)
•Mineral compound used after proper Shodhana
42.
Property Detail
Rasa Tikta(bitter), kashaya (Astrigent)
Guna Laghu (Light), Rukha(Dry)
Veerya Ushna (Hot)
Vipaka Katu(Pungent)
Prabhava Pandughna (useful in anemia)
Ayurvedic Properties :-
Therapeutic Use :-
• Pandu (Anemia) – Hematinic (improves blood)
• Netra roga (Eye diseases) – Used in external
preparations
• Twak vikara (Skin diseases)
• Used in Kasisa Bhasma, Anjana (collyrium) and other
rasa preparations
43.
Procedure :-
• Lohachurna + dilute sulphuric acid (slowly
added).
• Heat generates foam which is allowed to
subside.
• Filtered through Saraka Patra.
• Add absolute alcohol to the liquid.
• Kasisa settles at the bottom, dried in sun
44.
4. Rasanjan Dravya
•EnglishName:Berberis Extract Berberis Resin
•Synonyms ( sanskrit) :-
•Darvi Ras (as it comes from Daruharidra)
•Daruharidra Ghana
Chemical Constituents / Formula:-
Rasanjana is not a pure
chemical but a plant extract, mainly containing the
alkaloid:Berberine - C20H18NO4+ main active C
45.
Uses in ayurveda
•Netra roga (Eye disorders)
• Vrana ( wound healing)
• Prameha (Urinary disorders)
• Twak vikara (Skin diseases)
• It has Tikta Rasa, Katu Vipaka, Ruksha, Laghu, and Ushna
Procedure
• Daruharidra churna + 16 parts water → Boil & reduce to
1/4th.
• Filter the decoction.
• Add Aja Ksheera (goat milk) and boil again.
• Reduce to thick paste and dry.
• Used as Rasanjana.
46.
5. Hingula Dravya:-
• English Name:Cinnabar
• Chemical Formula: HgS (Mercury Sulphide)
• Synonym
• Haratal Varna
• Rakt Haratal
• Rasa Ratna
• Shuddha Hingula (after purification)
Categories
• िस शास्र : महािस
• Often used as a p primary source of parad
(mercury)
• It is naturally occurring in red coloured mineral
47.
Ayurvedic Uses:-
• Rasayanas(rejuvenators)
• Kharaliya Rasayanas
• Bhasma preparation (especially mercurybased
ones)
• Acts as Yogavahi (catalyst)
• Useful in Jwara, Rajayakshma, Kustha, Vataroga
Procedure
• 8 parts Gandhaka + 42 parts Parada in
• Mrudanga Yantra.
• Seal with vessels having circular ridges.
• Heat mildly then cool and open.
• Soft, shining Hingula powder collected.
48.
3. Pratinidhi Dravya(Substitute)
• Substitution is a replacement of equivalent drugs in place of
original drugs on the basis of similar pharmacological actions
and therapeutic uses.
• There are several reasons for substitution, but in
Rasashastra the main reason is the cost effectiveness.
• Some drugs like Vajra, Swarna are more costly, so they
are substituted by less expensive drugs like in Vaikranta,
Swarna makshika respectively.
Vajrabhave Vaikranta :-
•Vajra is one among of the precious stones.
• Among all the ratnas, Vajra is most costliest due to its luster
and hardness.
• The common man cannot afford for its preparations. So our
Acharyas mentioned the use of Vaikranta in the place of Vajra for
those who
cannot afford it.
• The definition of vaikranta suggests that its therapeutic
property resembles that of vajra, supporting the fact of using
Vaikranta as a substitute of Vajra.
51.
• वज्रवत ्स
वि
म ोगाणां हिणाय यतस्स्त्विम।् ध
त्ते ववक्रास्न्तमतलांु व
ैक्रान्तं कथ्यते ततैः
।।
(R.T. 23/156)
• Vaikranta is the drug which cures all diseases like Vajra when used
judiciously. That which gives uncomparable power is called as Vaikranta.
• वैक्रान्तो वज्रसद
् िशो िे हलोहकािो मतैः। ववषघ्नो िसिाजर्शच ज्ज
वि
क
ष्ठु
क्ष
य
प्र
ण
त
।् ु ।
•(R.R.S. 2/57)
• Vaikranta can bestove both Dehasiddhi and Lohasiddhi, like Vajra. It
cures Visha, Jwara, Kushta, Yakshma and it excels all the minerals.
• वैक्रान्तो वज्रवच्छोध्यो ध्मातैः ससक्तोऽर्शवमत्रक।े ू वज्रवन्मतृ तमापन्नो वज्रस्थाने प्रयोजयते
।।१६९।। (A.P.5/169)
• Vaikranta shodhana is done similar to that of Vajra by intense heating
and sprinkling Ashwa mootra on it. The process of bhasmikarana of
Vaikranta is also same as that of Vajra and this vaikranta Bhasma can
2. Suvarna -Suvarna Makshika
• Swarna (Gold) is a noble and costly metal that has the
enormous therapeutic properties to the mankind.
• The substitute for swarna is said as Swarnamakshika
(Chalcopyrite).
ईषद्रौप्यस्य सादहत्याद् िौप्यगु णसाम्यतैः ।। (RT 21/2)
• Little amount of Swarna is present in Swarnamakshika, so its
quality have the resemblance with that of Swarna.
• Chemical composition of Swarna makshika are Iron, Sulphur and
traces of Copper.
• न क
े वलं स्वणमगु णा वतमन्ते स्व
ण
म
म
ा
क्ष
क्ष
क
े । द्रव्यांतिस्य संसगामत्सन्यन्येऽवप गु णा यतैः
।। ककन्तु तस्यानु कल्पत्वास्त्कस्र्शचिू ना गु णास्तत: l तथाऽवप काञ्चनाभावे िीयते
स् वणममाक
् षक
् षकम ् ।। (A. P.4/3-4)
• Swarnamakshikais not only having the properties of swarna but
also the properties of the other drugs.
• To summarise, as swarna is present in swarnamakshika and as it
55.
Properties Swarnamakshika Swarna
RasaKashaya, Tikta, Madhura Kashaya, Tikta, Madhura
Guna Sheeta, Laghu, Rooksha Sheeta, Guru, Snigdha, Picchila
Veerya Sheeta Sheeta
Vipaka Katu madhura
Doshaghnata Tridoshagna Tridoshaghna
Karma Balya, Rasayana, Swarya,
Chakshusya, Yogavahi,
Sakalamayaghna, Vrishya
Balya, Rasayana, Sakalamayaghna,
Vrishya, Medhya, Vishagna, Hridyam,
Netryam, Kanthikara, Ayushyam,
Pushtikara, Vayastha-pana, Yogavahi
By comparing the properties of Swarna makshika and swarna, it can be
inferred that Swarnamakshika bhasma can be used as a substitute of
Swarna bhasma.
56.
4. ANUPALABDHA (NOTAVAILABLE)
Some of the drugs that are explained by RasAcharyas regarding
their properties and grahyagrahya laxanas cannot be assessed in
present mineral drugs. It is because of non-availability or scarcity of
native forms of mineral or ore-mineral.
Some of there types are :
1. Rasaka :-
• Rasaka, which is the ore mineral of Yashada is out of use.
• In classics Acharyas mentioned 3 varieties of Rasaka.
• Now a days often Processed Yashada is used in place of
processed Rasaka which is also recommended by AFI.
• Varieties of Rasaka or their substitutes commonly assumed or
used in present days are dissimilar as compared with Yashada.
2. Sauviranjana :-
Sauviranjanais said to be obtained from the mountains of
Sauvira, a country along the Indus.
Its vernacular name surma is the sulphide of lead
ore. Surma is usually translated as sulphide of
antimony.
The sulphide of antimony occurs in fine streaky,
fibrous, crystalline
masses of a radiated texture.
The lead ore on the contrary, occurs in cubic masses
destitute of rays and is tabular in its crystalline arrangement.
In the single drug monographs published in API ,
Sauviranjana is considered as lead ore.
But due to its ambiguity, still it cannot be assessed exactly to
the present available minerals .