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Atom – the smallest unit of matter “indivisible”




        Helium
        atom
electron shells
•   Atomic number = number of Electrons

•   Electrons vary in the amount of energy
    they possess, and they occur at certain
    energy levels or electron shells.

d) Electron shells determine how an atom
   behaves when it encounters other atoms
Electrons are placed in shells
        according to rules:
1) The 1st shell can hold up to two electrons,
   and each shell thereafter can hold up to 8
   electrons.
Octet Rule = atoms tend to gain, lose or share electrons so
as to have 8 electrons
       C would like to Gain 4 electrons
       N would like to Gain 3 electrons
       O would like to Gain 2 electrons
Why are electrons important?
1) Elements have different electron
   configurations
   different electron configurations mean
    different levels of bonding
Electron Dot Structures
 Symbols of atoms with dots to represent the valence-
 shell electrons

 1       2       13            14                15            16              17         18
H•                                                                                        He:
     •           •             •            ••            ••             ••         ••

Li• Be•      •
                 B•        •
                               C•           •
                                                N•        •
                                                              O•         : F • :Ne :
                           •            •                ••             ••         ••

     •               •         •            ••            ••             ••         ••

Na• Mg•          •
                     Al•       •
                                   Si •         •
                                                    P•         •
                                                                   S•        :Cl • :Ar :
                                    •               •          ••             ••         ••
Chemical bonds: an attempt to fill electron shells




    3. Ionic bonds –
    4. Covalent bonds –
    5. Metallic bonds
Learning Check
      
A.   X would be the electron dot formula for
     1) Na            2) K            3) Al
      
B.    X    would be the electron dot formula
       

     1) B             2) N            3) P
IONIC BOND
bond formed between
   two ions by the
 transfer of electrons
Formation of Ions from Metals
 Ionic compounds result when metals react with
  nonmetals
 Metals lose electrons to match the number of valence
  electrons of their nearest noble gas
 Positive ions form when the number of electrons are
  less than the number of protons
           Group 1 metals →       ion 1+
           Group 2 metals → ion 2+
•          Group 13 metals → ion 3+
Formation of Sodium Ion
Sodium atom            Sodium ion
 Na •     – e−   →     Na +

2-8-1              2-8 ( = Ne)

  11 p+                 11 p+
  11 e-                 10 e-
   0                      1+
Formation of Magnesium Ion
Magnesium atom       Magnesium ion
 •

 Mg •        – 2e−   →      Mg2+

2-8-2                        2-8 (=Ne)

     12 p+                   12 p+
     12 e-                   10 e-
      0                       2+
Some Typical Ions with Positive
            Charges (Cations)
Group 1        Group 2     Group 13
H+             Mg2+        Al3+
Li+            Ca2+
Na+            Sr2+
K+             Ba2+
Learning Check

A. Number of valence electrons in aluminum
    1) 1 e-         2) 2 e-          3) 3 e-

B.   Change in electrons for octet
      1) lose 3e-     2) gain 3 e-   3) gain 5 e-

C.    Ionic charge of aluminum
      1) 3-            2) 5-         3) 3+
Solution

A. Number of valence electrons in aluminum
    3)  3 e-

B.   Change in electrons for octet
      1)  lose 3e-

C.    Ionic charge of aluminum
      3) 3+
Learning Check

Give the ionic charge for each of the following:
A. 12 p+ and 10 e-
   1) 0        2) 2+       3) 2-
B. 50p+ and 46 e-
   1) 2+    2) 4+         3) 4-
C. 15 p+ and 18e-
   2) 3+     2) 3-        3) 5-
Ions from Nonmetal Ions

In ionic compounds, nonmetals in 15, 16, and 17
  gain electrons from metals

Nonmetal add electrons to achieve the octet
  arrangement

Nonmetal ionic charge:
  3-, 2-, or 1-
Fluoride Ion
      unpaired electron   octet
 ••                               ••   1-
:F•            + e−               : F:
 ••                               ••

2-7                               2-8 (= Ne)

9 p+                             9 p+
9 e-                            10 e-
0                               1-
                            ionic charge
Ionic Bond
• Between atoms of metals and nonmetals
  with very different electronegativity
• Bond formed by transfer of electrons
• Produce charged ions all states. Conductors
  and have high melting point.
• Examples; NaCl, CaCl2, K2O
Ionic Bonds: One Big Greedy Thief Dog!
1). Ionic bond – electron from Na is transferred to Cl,
this causes a charge imbalance in each atom. The Na
becomes (Na+) and the Cl becomes (Cl-), charged
particles or ions.
COVALENT BOND
bond formed by the
sharing of electrons
Covalent Bond
• Between nonmetallic elements of similar
  electronegativity.
• Formed by sharing electron pairs
• Stable non-ionizing particles, they are not
  conductors at any state
• Examples; O2, CO2, C2H6, H2O, SiC
Bonds in all the
polyatomic ions
 and diatomics
are all covalent
     bonds
NONPOLAR
COVALENT BONDS
when electrons are
 shared equally
     H2 or Cl2
2. Covalent bonds-   Two atoms share one or more pairs of outer-shell
electrons.


             Oxygen Atom                  Oxygen Atom




                 Oxygen Molecule (O2)
POLAR COVALENT
    BONDS
when electrons are
shared but shared
    unequally
       H2O
Polar Covalent Bonds: Unevenly
 matched, but willing to share.
- water is a polar molecule because oxygen is more
electronegative than hydrogen, and therefore electrons
are pulled closer to oxygen.
METALLIC BOND
  bond found in
metals; holds metal
 atoms together
   very strongly
Metallic Bond
• Formed between atoms of metallic elements
• Electron cloud around atoms
• Good conductors at all states, lustrous, very
  high melting points
• Examples; Na, Fe, Al, Au, Co
Metallic Bonds: Mellow dogs with plenty
         of bones to go around.
Ionic Bond, A Sea of Electrons
Metals Form Alloys
Metals do not combine with metals. They form
Alloys which is a solution of a metal in a metal.
Examples are steel, brass, bronze and pewter.
Formula Weights
• Formula weight is the sum of the atomic
  masses.
• Example- CO2
• Mass, C + O + O
        12.011 + 15.994 + 15.994
        43.999
Practice
• Compute the mass of the following compounds
  round to nearest tenth & state type of bond:
• NaCl;
• 23 + 35 = 58; Ionic Bond
• C2H6;
• 24 + 6 = 30; Covalent Bond
• Na(CO3)2;
• 23 + 2(12 + 3x16) = 123; Ionic & Covalent
Here are the formula weights for the given compounds rounded to the nearest tenth:- NaCl: 58.0 g/mol, ionic bond- C2H6: 30.1 g/mol, covalent bond - Na2CO3: 123.0 g/mol, ionic and covalent bonds
Here are the formula weights for the given compounds rounded to the nearest tenth:- NaCl: 58.0 g/mol, ionic bond- C2H6: 30.1 g/mol, covalent bond - Na2CO3: 123.0 g/mol, ionic and covalent bonds

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Here are the formula weights for the given compounds rounded to the nearest tenth:- NaCl: 58.0 g/mol, ionic bond- C2H6: 30.1 g/mol, covalent bond - Na2CO3: 123.0 g/mol, ionic and covalent bonds

  • 1.
  • 2. Atom – the smallest unit of matter “indivisible” Helium atom
  • 3. electron shells • Atomic number = number of Electrons • Electrons vary in the amount of energy they possess, and they occur at certain energy levels or electron shells. d) Electron shells determine how an atom behaves when it encounters other atoms
  • 4. Electrons are placed in shells according to rules: 1) The 1st shell can hold up to two electrons, and each shell thereafter can hold up to 8 electrons.
  • 5. Octet Rule = atoms tend to gain, lose or share electrons so as to have 8 electrons C would like to Gain 4 electrons N would like to Gain 3 electrons O would like to Gain 2 electrons
  • 6. Why are electrons important? 1) Elements have different electron configurations  different electron configurations mean different levels of bonding
  • 7.
  • 8.
  • 9. Electron Dot Structures Symbols of atoms with dots to represent the valence- shell electrons 1 2 13 14 15 16 17 18 H• He: • • • •• •• •• •• Li• Be• • B• • C• • N• • O• : F • :Ne : • • •• •• •• • • • •• •• •• •• Na• Mg• • Al• • Si • • P• • S• :Cl • :Ar : • • •• •• ••
  • 10. Chemical bonds: an attempt to fill electron shells 3. Ionic bonds – 4. Covalent bonds – 5. Metallic bonds
  • 11. Learning Check  A. X would be the electron dot formula for 1) Na 2) K 3) Al  B.  X would be the electron dot formula  1) B 2) N 3) P
  • 12. IONIC BOND bond formed between two ions by the transfer of electrons
  • 13. Formation of Ions from Metals  Ionic compounds result when metals react with nonmetals  Metals lose electrons to match the number of valence electrons of their nearest noble gas  Positive ions form when the number of electrons are less than the number of protons Group 1 metals → ion 1+ Group 2 metals → ion 2+ • Group 13 metals → ion 3+
  • 14. Formation of Sodium Ion Sodium atom Sodium ion Na • – e− → Na + 2-8-1 2-8 ( = Ne) 11 p+ 11 p+ 11 e- 10 e- 0 1+
  • 15. Formation of Magnesium Ion Magnesium atom Magnesium ion • Mg • – 2e− → Mg2+ 2-8-2 2-8 (=Ne) 12 p+ 12 p+ 12 e- 10 e- 0 2+
  • 16. Some Typical Ions with Positive Charges (Cations) Group 1 Group 2 Group 13 H+ Mg2+ Al3+ Li+ Ca2+ Na+ Sr2+ K+ Ba2+
  • 17. Learning Check A. Number of valence electrons in aluminum 1) 1 e- 2) 2 e- 3) 3 e- B. Change in electrons for octet 1) lose 3e- 2) gain 3 e- 3) gain 5 e- C. Ionic charge of aluminum 1) 3- 2) 5- 3) 3+
  • 18. Solution A. Number of valence electrons in aluminum 3) 3 e- B. Change in electrons for octet 1) lose 3e- C. Ionic charge of aluminum 3) 3+
  • 19. Learning Check Give the ionic charge for each of the following: A. 12 p+ and 10 e- 1) 0 2) 2+ 3) 2- B. 50p+ and 46 e- 1) 2+ 2) 4+ 3) 4- C. 15 p+ and 18e- 2) 3+ 2) 3- 3) 5-
  • 20. Ions from Nonmetal Ions In ionic compounds, nonmetals in 15, 16, and 17 gain electrons from metals Nonmetal add electrons to achieve the octet arrangement Nonmetal ionic charge: 3-, 2-, or 1-
  • 21. Fluoride Ion unpaired electron octet •• •• 1- :F• + e− : F: •• •• 2-7 2-8 (= Ne) 9 p+ 9 p+ 9 e- 10 e- 0 1- ionic charge
  • 22. Ionic Bond • Between atoms of metals and nonmetals with very different electronegativity • Bond formed by transfer of electrons • Produce charged ions all states. Conductors and have high melting point. • Examples; NaCl, CaCl2, K2O
  • 23.
  • 24. Ionic Bonds: One Big Greedy Thief Dog!
  • 25. 1). Ionic bond – electron from Na is transferred to Cl, this causes a charge imbalance in each atom. The Na becomes (Na+) and the Cl becomes (Cl-), charged particles or ions.
  • 26.
  • 27. COVALENT BOND bond formed by the sharing of electrons
  • 28. Covalent Bond • Between nonmetallic elements of similar electronegativity. • Formed by sharing electron pairs • Stable non-ionizing particles, they are not conductors at any state • Examples; O2, CO2, C2H6, H2O, SiC
  • 29.
  • 30. Bonds in all the polyatomic ions and diatomics are all covalent bonds
  • 31. NONPOLAR COVALENT BONDS when electrons are shared equally H2 or Cl2
  • 32. 2. Covalent bonds- Two atoms share one or more pairs of outer-shell electrons. Oxygen Atom Oxygen Atom Oxygen Molecule (O2)
  • 33. POLAR COVALENT BONDS when electrons are shared but shared unequally H2O
  • 34. Polar Covalent Bonds: Unevenly matched, but willing to share.
  • 35. - water is a polar molecule because oxygen is more electronegative than hydrogen, and therefore electrons are pulled closer to oxygen.
  • 36. METALLIC BOND bond found in metals; holds metal atoms together very strongly
  • 37. Metallic Bond • Formed between atoms of metallic elements • Electron cloud around atoms • Good conductors at all states, lustrous, very high melting points • Examples; Na, Fe, Al, Au, Co
  • 38. Metallic Bonds: Mellow dogs with plenty of bones to go around.
  • 39. Ionic Bond, A Sea of Electrons
  • 40. Metals Form Alloys Metals do not combine with metals. They form Alloys which is a solution of a metal in a metal. Examples are steel, brass, bronze and pewter.
  • 41. Formula Weights • Formula weight is the sum of the atomic masses. • Example- CO2 • Mass, C + O + O 12.011 + 15.994 + 15.994 43.999
  • 42. Practice • Compute the mass of the following compounds round to nearest tenth & state type of bond: • NaCl; • 23 + 35 = 58; Ionic Bond • C2H6; • 24 + 6 = 30; Covalent Bond • Na(CO3)2; • 23 + 2(12 + 3x16) = 123; Ionic & Covalent