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Chapter 1
  An Introduction to Chemistry
The
spectacular
colors of the
aurora
borealis are
the result of
chemistry in
our
atmosphere.
                Foundations of College Chemistry, 13e
                      John Wiley & Sons, Inc
                    Morris Hein and Susan Arena
Chapter Outline

1.1 Why Study Chemistry?                  1.5 The Scientific Method
1.2 The Nature of Chemistry               1.6 The Particulate Nature of
1.3 Thinking Like a Chemist                   Matter

1.4 A Scientific Approach to              1.7 Physical States of Matter
    Problem Solving                       1.8 Classifying Matter




                     Copyright 2011 John Wiley & Sons, Inc                1-2
The Nature of Chemistry

Chemistry is the science dealing with the composition
  of matter and the changes in composition that matter
  undergoes.
Chemistry is also concerned with energy and energy
  changes of matter.




                   Copyright 2011 John Wiley & Sons, Inc   1-3
Thinking Like a Chemist




Figure 1.1 Inside a drop of lake water
we find water molecules, dissolved
substances and algae cells.
                     Copyright 2011 John Wiley & Sons, Inc   1-4
A Scientific Approach to Problem Solving

• Define the problem.
• Propose possible solutions.
   – Science refers to this as making an hypothesis.
• Decide which way to proceed or solve the problem.
   – Scientists perform an experiment.




                   Copyright 2011 John Wiley & Sons, Inc   1-5
The Scientific Method

1. Collect the facts or data relevant to the problem.
   – Done with carefully designed observations and
      experimentation.
2. Formulate a hypothesis that accounts for the data
    and that can be tested further.
3. Plan and do additional experiments to test the
    hypothesis.
4. Modify the hypothesis as necessary.


                   Copyright 2011 John Wiley & Sons, Inc   1-6
Your Turn!

A clear colorless liquid is combined with a second clear
  colorless liquid and the mixture is observed. Which
  of these is not an observation?
a. The test tube became hot.
b. The reaction is exothermic.
c. The mixture is cloudy.
d. The mixture is white.



                   Copyright 2011 John Wiley & Sons, Inc   1-7
The Scientific Method



                     Law: Statements of natural
                       phenomena to which there are
                       no known exceptions.
             Hypothesis: A tentative explanation of
               the facts that can be tested further
             Theory: Well-tested hypothesis.



     Copyright 2011 John Wiley & Sons, Inc        1-8
Your Turn!

Which of these is a law?
a. Atoms consist of protons, neutrons, and electrons.
b. All matter is composed of atoms.
c. Atoms can form chemical bonds by sharing
   electrons.
d. The volume of a gas increases with increasing
   temperature.



                   Copyright 2011 John Wiley & Sons, Inc   1-9
Your Turn!

The statement, “An atom consists of a dense nucleus
  surrounded by a cloud of electrons”, is an example of
a. a theory
b. a law
c. an hypothesis
d. an observation




                   Copyright 2011 John Wiley & Sons, Inc   1-10
The Particulate Nature of Matter

• Matter is anything that has mass and occupies space.
• Matter is composed of discrete, tiny, fundamental
  particles called atoms.




The surface of a penny is made up of tiny identical copper atoms
packed tightly together.
                      Copyright 2011 John Wiley & Sons, Inc    1-11
Physical States of Matter

How are they the same? How are they different?




                  Copyright 2011 John Wiley & Sons, Inc   1-12
Solids

• Crystalline solids have regular, repeating three
  dimensional patterns.
• This is a large crystal of table salt.




                    Copyright 2011 John Wiley & Sons, Inc   1-13
Solids

•   Definite shape
•   Definite volume
•   Essentially incompressible
•   Particles are tightly packed together
•   Particles are held together by very
    strong forces of attraction




                     Copyright 2011 John Wiley & Sons, Inc   1-14
Solids

• Crystalline solids
  exist in regular,
  repeating, three-
  dimensional geometric
  patterns.
• Amorphous solids do
  not have any regular,
  internal geometric
  pattern.


                 Copyright 2011 John Wiley & Sons, Inc   1-15
Liquids

• Indefinite shape
• Definite volume
• Only slightly compressible
• Particles are mobile, able to move
  around each other
• Particles are held together by strong
  forces of attraction



                    Copyright 2011 John Wiley & Sons, Inc   1-16
Gases

• Indefinite shape
• Indefinite volume
• Compressible
• Particles are far apart and are small
  compared to the volume they occupy
• The attractive forces are so weak that
  the particles are independent of each
  other


                   Copyright 2011 John Wiley & Sons, Inc   1-17
Solid        StatesLiquid
                           of Matter                                     Gas
Definite shape         Indefinite shape                        Indefinite shape
                       (Takes shape of                         (Takes shape of
                       container)                              container)
Definite volume        Definite volume                         Indefinite (Expands
                                                               to fill the container)
Incompressible         Slightly                                Compressible
                       compressible
Strong attractive      Weaker attractive                       Energy of particles
forces, so particles   forces so particles                     are greater than
are locked in place    can move around                         their attractive
                       freely                                  forces
Rigidly clinging;      Mobile; adhering                        Independent of each
tightly packed                                                 other and far apart
                       Copyright 2011 John Wiley & Sons, Inc                      1-18
Your Turn!

Which form of water has a definite volume, but no
  definite shape?
a. Ice
b. Liquid water
c. Steam




                   Copyright 2011 John Wiley & Sons, Inc   1-19
Your Turn!

Which form of water has molecules that are held
  together tightly by very strong intermolecular forces?
a. Ice
b. Liquid water
c. Steam




                   Copyright 2011 John Wiley & Sons, Inc   1-20
Your Turn!

Which form of water is compressible?
a. Ice
b. Liquid water
c. Steam




                  Copyright 2011 John Wiley & Sons, Inc   1-21
Your Turn!

What physical state is found in the container?
a. Solid
b. Liquid
c. Gas




                   Copyright 2009 John Wiley & Sons, Inc
                             2011                          1-22
                                                             22
Your Turn!

What physical state is found in the container?
a. Solid
b. Liquid
c. Gas




                   Copyright 2009 John Wiley & Sons, Inc
                             2011                          1-23
                                                             23
Classifying Matter

• A substance has a definite, fixed composition
  – Element (Na, Cl2, Al)
  – Compound (NaCl, H2O, CO2)
  – also called pure substance




                   Copyright 2011 John Wiley & Sons, Inc   1-24
Your Turn!

Which of these is not a pure substance?
a. Fe
b. Fe2O3
c. Fe and O2
d. All of these are pure substances




                   Copyright 2011 John Wiley & Sons, Inc   1-25
Classifying Matter

• A mixture has a composition that can be varied
  – Solutions are mixtures
  – Strong coffee versus weak coffee
  – 5% salt solutions versus 10% salt solutions




                  Copyright 2011 John Wiley & Sons, Inc   1-26
Classifying Matter

Homogeneous matter is uniform in appearance and has
  the same properties throughout.
Examples:
Pure substance: Water
Mixture: Sugar and water
 Solutions are always
      homogeneous mixtures

    (a) water is the liquid in the beaker, and the white solid in the spoon is sugar.
    (b) Sugar can be dissolved in the water to produce a solution.
                            Copyright 2011 John Wiley & Sons, Inc               1-27
Your Turn!

Which of these is an example of a solution?
a. Oil and vinegar salad dressing
b. Iced tea
c. Lemonade
d. Iced water




                   Copyright 2011 John Wiley & Sons, Inc   1-28
Classifying Matter

Heterogeneous matter consists of two or
 more physically distinct phases.
 A phase is a homogeneous part of a
 system separated from other parts by
 physical boundaries.

                                                          Liquid and gaseous
Examples:                                                 bromine

Pure Substance: liquid and gaseous bromine; iced water
Mixture: Iced tea

                  Copyright 2011 John Wiley & Sons, Inc                   1-29
Classifying Matter




   Copyright 2011 John Wiley & Sons, Inc   1-30
Your Turn!

Freshly opened Coke is an example of a
a. An element
b. A compound
c. A homogeneous mixture
d. A heterogeneous mixture




                  Copyright 2011 John Wiley & Sons, Inc   1-31
Your Turn!

Air is an example of a
a. An element
b. A compound
c. A homogeneous mixture
d. heterogeneous mixture




                Copyright 2011 John Wiley & Sons, Inc   1-32
Distinguishing Mixtures from
               Pure Substances
Mixtures can be separated by physical means.




(a) When iron and sulfur exist as pure substances, only the iron is
attracted to a magnet.
(b) A mixture of Fe and S can be separated by using the difference
in magnetic attraction.
                      Copyright 2011 John Wiley & Sons, Inc    1-33
Your Turn!

A clear, colorless liquid is heat in a beaker until all of
  the liquid is gone. The walls of the beaker are coated
  with a white crystalline solid. The liquid was:
a. An element
b. A compound
c. A homogeneous mixture
d. A heterogeneous mixture



                    Copyright 2011 John Wiley & Sons, Inc   1-34

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Ch01

  • 1. Chapter 1 An Introduction to Chemistry The spectacular colors of the aurora borealis are the result of chemistry in our atmosphere. Foundations of College Chemistry, 13e John Wiley & Sons, Inc Morris Hein and Susan Arena
  • 2. Chapter Outline 1.1 Why Study Chemistry? 1.5 The Scientific Method 1.2 The Nature of Chemistry 1.6 The Particulate Nature of 1.3 Thinking Like a Chemist Matter 1.4 A Scientific Approach to 1.7 Physical States of Matter Problem Solving 1.8 Classifying Matter Copyright 2011 John Wiley & Sons, Inc 1-2
  • 3. The Nature of Chemistry Chemistry is the science dealing with the composition of matter and the changes in composition that matter undergoes. Chemistry is also concerned with energy and energy changes of matter. Copyright 2011 John Wiley & Sons, Inc 1-3
  • 4. Thinking Like a Chemist Figure 1.1 Inside a drop of lake water we find water molecules, dissolved substances and algae cells. Copyright 2011 John Wiley & Sons, Inc 1-4
  • 5. A Scientific Approach to Problem Solving • Define the problem. • Propose possible solutions. – Science refers to this as making an hypothesis. • Decide which way to proceed or solve the problem. – Scientists perform an experiment. Copyright 2011 John Wiley & Sons, Inc 1-5
  • 6. The Scientific Method 1. Collect the facts or data relevant to the problem. – Done with carefully designed observations and experimentation. 2. Formulate a hypothesis that accounts for the data and that can be tested further. 3. Plan and do additional experiments to test the hypothesis. 4. Modify the hypothesis as necessary. Copyright 2011 John Wiley & Sons, Inc 1-6
  • 7. Your Turn! A clear colorless liquid is combined with a second clear colorless liquid and the mixture is observed. Which of these is not an observation? a. The test tube became hot. b. The reaction is exothermic. c. The mixture is cloudy. d. The mixture is white. Copyright 2011 John Wiley & Sons, Inc 1-7
  • 8. The Scientific Method Law: Statements of natural phenomena to which there are no known exceptions. Hypothesis: A tentative explanation of the facts that can be tested further Theory: Well-tested hypothesis. Copyright 2011 John Wiley & Sons, Inc 1-8
  • 9. Your Turn! Which of these is a law? a. Atoms consist of protons, neutrons, and electrons. b. All matter is composed of atoms. c. Atoms can form chemical bonds by sharing electrons. d. The volume of a gas increases with increasing temperature. Copyright 2011 John Wiley & Sons, Inc 1-9
  • 10. Your Turn! The statement, “An atom consists of a dense nucleus surrounded by a cloud of electrons”, is an example of a. a theory b. a law c. an hypothesis d. an observation Copyright 2011 John Wiley & Sons, Inc 1-10
  • 11. The Particulate Nature of Matter • Matter is anything that has mass and occupies space. • Matter is composed of discrete, tiny, fundamental particles called atoms. The surface of a penny is made up of tiny identical copper atoms packed tightly together. Copyright 2011 John Wiley & Sons, Inc 1-11
  • 12. Physical States of Matter How are they the same? How are they different? Copyright 2011 John Wiley & Sons, Inc 1-12
  • 13. Solids • Crystalline solids have regular, repeating three dimensional patterns. • This is a large crystal of table salt. Copyright 2011 John Wiley & Sons, Inc 1-13
  • 14. Solids • Definite shape • Definite volume • Essentially incompressible • Particles are tightly packed together • Particles are held together by very strong forces of attraction Copyright 2011 John Wiley & Sons, Inc 1-14
  • 15. Solids • Crystalline solids exist in regular, repeating, three- dimensional geometric patterns. • Amorphous solids do not have any regular, internal geometric pattern. Copyright 2011 John Wiley & Sons, Inc 1-15
  • 16. Liquids • Indefinite shape • Definite volume • Only slightly compressible • Particles are mobile, able to move around each other • Particles are held together by strong forces of attraction Copyright 2011 John Wiley & Sons, Inc 1-16
  • 17. Gases • Indefinite shape • Indefinite volume • Compressible • Particles are far apart and are small compared to the volume they occupy • The attractive forces are so weak that the particles are independent of each other Copyright 2011 John Wiley & Sons, Inc 1-17
  • 18. Solid StatesLiquid of Matter Gas Definite shape Indefinite shape Indefinite shape (Takes shape of (Takes shape of container) container) Definite volume Definite volume Indefinite (Expands to fill the container) Incompressible Slightly Compressible compressible Strong attractive Weaker attractive Energy of particles forces, so particles forces so particles are greater than are locked in place can move around their attractive freely forces Rigidly clinging; Mobile; adhering Independent of each tightly packed other and far apart Copyright 2011 John Wiley & Sons, Inc 1-18
  • 19. Your Turn! Which form of water has a definite volume, but no definite shape? a. Ice b. Liquid water c. Steam Copyright 2011 John Wiley & Sons, Inc 1-19
  • 20. Your Turn! Which form of water has molecules that are held together tightly by very strong intermolecular forces? a. Ice b. Liquid water c. Steam Copyright 2011 John Wiley & Sons, Inc 1-20
  • 21. Your Turn! Which form of water is compressible? a. Ice b. Liquid water c. Steam Copyright 2011 John Wiley & Sons, Inc 1-21
  • 22. Your Turn! What physical state is found in the container? a. Solid b. Liquid c. Gas Copyright 2009 John Wiley & Sons, Inc 2011 1-22 22
  • 23. Your Turn! What physical state is found in the container? a. Solid b. Liquid c. Gas Copyright 2009 John Wiley & Sons, Inc 2011 1-23 23
  • 24. Classifying Matter • A substance has a definite, fixed composition – Element (Na, Cl2, Al) – Compound (NaCl, H2O, CO2) – also called pure substance Copyright 2011 John Wiley & Sons, Inc 1-24
  • 25. Your Turn! Which of these is not a pure substance? a. Fe b. Fe2O3 c. Fe and O2 d. All of these are pure substances Copyright 2011 John Wiley & Sons, Inc 1-25
  • 26. Classifying Matter • A mixture has a composition that can be varied – Solutions are mixtures – Strong coffee versus weak coffee – 5% salt solutions versus 10% salt solutions Copyright 2011 John Wiley & Sons, Inc 1-26
  • 27. Classifying Matter Homogeneous matter is uniform in appearance and has the same properties throughout. Examples: Pure substance: Water Mixture: Sugar and water Solutions are always homogeneous mixtures (a) water is the liquid in the beaker, and the white solid in the spoon is sugar. (b) Sugar can be dissolved in the water to produce a solution. Copyright 2011 John Wiley & Sons, Inc 1-27
  • 28. Your Turn! Which of these is an example of a solution? a. Oil and vinegar salad dressing b. Iced tea c. Lemonade d. Iced water Copyright 2011 John Wiley & Sons, Inc 1-28
  • 29. Classifying Matter Heterogeneous matter consists of two or more physically distinct phases. A phase is a homogeneous part of a system separated from other parts by physical boundaries. Liquid and gaseous Examples: bromine Pure Substance: liquid and gaseous bromine; iced water Mixture: Iced tea Copyright 2011 John Wiley & Sons, Inc 1-29
  • 30. Classifying Matter Copyright 2011 John Wiley & Sons, Inc 1-30
  • 31. Your Turn! Freshly opened Coke is an example of a a. An element b. A compound c. A homogeneous mixture d. A heterogeneous mixture Copyright 2011 John Wiley & Sons, Inc 1-31
  • 32. Your Turn! Air is an example of a a. An element b. A compound c. A homogeneous mixture d. heterogeneous mixture Copyright 2011 John Wiley & Sons, Inc 1-32
  • 33. Distinguishing Mixtures from Pure Substances Mixtures can be separated by physical means. (a) When iron and sulfur exist as pure substances, only the iron is attracted to a magnet. (b) A mixture of Fe and S can be separated by using the difference in magnetic attraction. Copyright 2011 John Wiley & Sons, Inc 1-33
  • 34. Your Turn! A clear, colorless liquid is heat in a beaker until all of the liquid is gone. The walls of the beaker are coated with a white crystalline solid. The liquid was: a. An element b. A compound c. A homogeneous mixture d. A heterogeneous mixture Copyright 2011 John Wiley & Sons, Inc 1-34