Cationic reagent PTAC 65% information

山東兖州天成化工有限公司
Shandong Yanzhou Tiancheng Chemical Co., Ltd.
No.66 West of Beizhan Road, Yanzhou
Shandong, 272117 P.R. China
Tel:: +86-537-792-7788
Fax: +86-537-341-4528
Mobile/Whatsapp: +86 15230171102
Email: zhuyanhong@yztchg.com
Web: www.yztchg.com
CERTIFICATE OF ANALYSIS
Product Name
Cationic reagent
PTAC 1881
Lot No. 20150106
Production Date 15.01.06 Analysis Date 15.01.06
Executive standard: Q/0882YTC008-2012
Items Specification Analyzed Results
Appearance Transparent liquid Transparent liquid
Content ≥65.00 % 65.40%
ECH ＜5 ppm Not detected
1,3-Dichloro-2-propanol ＜10 ppm 1.9 ppm
Results
Qualified products
Analyst: Jin Xin Auditor:Zhang Yinguang

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Fax: +86-537-341-4528
Web: www.yztchg.com
PTAC 1881 Technical Data Sheet
Chemical name 3-Chloro-2-Hydroxypropyl Trimethyl Ammonium Chloride
Alias CHPTAC, PTAC, Quat 188, PTAC 1881, CTA 1881
Formula C6H15NOCl2
Mol. Wt. 188.1 CAS No. 3327-22-8
Structure
3-Chloro-2-Hydroxypropyl Trimethyl Ammonium Chloride ≥65%
Moisture content ≤35%
Relative Density 1.16 g/cm
2
(20℃) Appearance Colorless and clear liquid
Autoignition Temperature Non Hypergolic pH (10% aqueous
solution)
5.0-7.0
Crystallization Point -14 ℃ Viscosity 13-20 mpa.s (25℃)
Solubility in Water Very soluble Stability Stable
Prohibited content
Strong oxidant, strong
base, strong acid
Packing
200L plastic barrel or IBC ton
barrel
Test equipment Gas chromatograph Test temperature
Column temperature: 120℃
Sample injector: 200℃
Application
1．Paper Chemicals
Cationic reagent is an important additive in paper industry, widely used in starch, cellulose,
chitosan and other chemical modification. The cationic starch modified by cationic reagent can be
used as paper surface sizing, retention and drainage aids, enhancers etc., is a kind of largely
consumed papermaking additive.
2．Textile Industry
(3 - chloro-2-hydroxypropyl) trimethyl ammonium chloride modified cotton fibers, improves its
adhesion to the dye; the cationic starch can be used as warp sizing agent after reaction of starch.
Sales & Marketing Department：
Add： No. 66 west of Beizhan Rd, Yanzhou, China
Phone：+86-537-7927788 Fax：+86-537-3414528
Email： zhuyanhong@yztchg.com Web: www.yztchg.com

Tel: +86 537 7927788
Fax: +86-537-341-4528
Web: www.yztchg.com
Introduction of Cationic Reagent (PTAC 1881)
I. Production Status
Tiancheng uses DCS automated control system and continuous automated production equipment. The production
capacity of PTAC is 30,000 tons/year with good quality, high stability.
We established a complete quality control system. We detect products with advanced equipments such as US
Agilent 7890A Gas Chromatograph, Japan Shimadzu LC-10AT Liquid Chromatograph, and Switzerland Metrohm
Automatic Potentiometric Titrator to ensure the advancement and reliability of production process and product
testing.
II. Properties of Products
Liquid Cationic Reagent is a kind of multi-application fine chemical products. The main chemical composition is
3-Chloro-2- hydroxypropyltrimethyl ammonium chloride. Molecular Formula is C6H15Cl2NO. Molecular weight
is 188.10. Structural formula is as following:
1). Product Properties Indicators:
2). Product Features
Compared with most domestic products, our PTAC 1881 is more stable in quality, higher in purity, and higher
in degree of reaction. In addition, the effective solid content is higher and the degree of frozen crystallinity is
lower. Our PTAC 1881 is applicable to use for all seasons.
Compared with the solid reagent, this product is used without preparation or easy to prepare and there is no
water absorption phenomenon. The effective ingredients won’t change during storage and transportation.
3). Application
Reagent can immediately convert to epoxy structure under alkaline conditions and can achieve products
cationization reacted with base material, like starch and guar gum. The polymeride possesses cationic
properties after introduction of reagent perssad. The features are following.
① Increase the adhesive strength;
② Increase affinity for anionic substances;
③ Increase the solubility of water-insoluble substances.
Items Specification
Appearance transparent liquid
Content ≥65.00 %
pH 5-7（10% solution）
Freezing Crystallization
Point
≤ -10℃
1,3- Dichloro-Propanol ≤ 10PPM
ECH ≤5 PPM
Solubility
Soluble in water, soluble in lower alcohol, not soluble in
hydrocarbons, ether and other weak polar solvent.

Material Safety Data Sheet
Section 1：Chemical Product and Company Identification
Product Name 3-Chloro-2-Hydroxypropyltrimethyl Ammonium Chloride
Alias CHPTAC, PTAC, Quat 188, PTAC 1881, CTA 1881
CAS No. 3327-22-8 HS code 2923900090
Company Yanzhou Tiancheng Chemical Co., Ltd.
Address 66 West of Beizhan Rd, Yanzhou, China Zip code 272117
Telephone 0537-7927788 Fax 0537-3414528
Mail zhuyanhong@yztchg.com
Section 2: Composition/Information on Ingredient
Formula C6H15NO CL2
Section 3: Hazards Identification
Risk Category Non hazardous chemical
Health effect Irritable to eyes, skin and respiratory tracts.
Environmental hazards： No harm
Section 4：First Aid Measures
Skin exposure： Use soap to help assure removal.
Eye contact： Wash with copious quantities of water.
Inhalation： Wash with copious quantities of water and seek medical attention.
Section 5: Fire Fighting Measures
Extinguishing Alcohol-resistant foam, dry chemical, carbon dioxide etc.
Fire fighting procedures
Fire fighters must wear self-contained breathing apparatus, full protective clothing
when extinguishes fire. Keep the containers cool and prevent rupture with water at
the scene.
Conditions to avoid Keep away from fire, strong oxidant, strong acid, strong base etc
Hazardous Combustion Products Carbon monoxide, carbon dioxide
Section 6: Accidental Release Measures
If the product is not contaminated, put it in a clean container. If the product is contaminated, put it in a container and make
appropriate disposal. Once accidental spills refer to section 8, personal protective apparatus, and general health habits.
Section 7: Handling and Storage
General Store in shady and dry places, 5-35°C. Tightly close the opening of containers if not used.
Attention
Pay attention to moisture. Avoid storing products in incompatible materials nearby. Refer to section 10.
Away from fire and heat.
Section 8: Exposure Controls/Personal Protection
Engineering controls Pay attention to ventilation, airtight operation.
General Health Habit Avoid its contact with eyes, skin and clothing. Eat and drink after thoroughly clean.
Personal Protective Apparatus Wear waterproof gloves and proper protective clothing.
Maintenance/Protective measures Completely isolate and clean all equipment and pipes before maintenance.
Section 9: Physical and Chemical Properties
Product Name 3-Chloro-2-Hydroxypropyltrimethyl Ammonium Chloride
Item Description
Appearance Colorless liquid
Active content / % ≥65.0
DCH content % ≤10×10-4
ECH content / % ≤5×10-4
pH value（10% water solution） 5.0-7.0
Section 10: Stability and Reactivity
Decomposition product No
Hazardous Polymerization No Hazardous Polymerization under specified operation and storage.
Stability Stable under specified operation and storage.
Section 11: Toxicological Information
Carcinogenicity National Toxicology Program does not classify it as carcinogen, Occupational Safety and Health

Administration does not require it as a carcinogen, IARC does not assess it as carcinogen.
Effect on human It will not cause skin irritation or skin sensitization after the human patch test.
Effect on animals
Acute toxicity Rat oral LD50 ： > 5g/k g
Stimulus No
Sub acute No
Chronic toxicity No
Sensitization No
Teratogenicity No
Section 12: Ecological Information
Ecotoxicity No
Enrichment No
Section 13: Waste Disposal Measures
Waste disposal
Recommend to stack in solid or hazardous waste device. Avoid dust hazards during disposal and
transportation. Load them into container before handling, exposure and protective measures to
be taken when exposed. To ensure there is no quantitative restrictions to process bulk or semi-
bulk waste. Comply with federal and local laws.
Section 14: Packing and Transformation
Not restrict to DOT rules
Packing
This product is packed by polyethylene plastic barrel or polyethylene plastic square box barrel
with net weight 250kg / barrel or 1000 kg / barrel respectively.
Transportation Avoid frozen and sunlight during transportation
Storage
Avoid storage at high temperature or below freezing. The optimum storage temperature is 5-
35 ℃ . Compliance with the above conditions, the product is valid for six months since the
production date. If it exceeds the storage period, recheck by indicator; if the test results meet the
standards, it can still be used.
Section 15: Regulatory Information
Chemical list TSCA is inclusive of the product ingredients
SARA Title Ш—302/304： No harm to health
SARA Title Ш—311&312： No harm to body
SARA Title Ш—313: Not contain any chemical composition of SARA Title Ш—313 provision
CERCLA：
Not contain any hazardous chemical composition under the regulation of Comprehensive
Environmental Response, Compensation and Liability.
RCRA：
Not classified as hazardous chemical by 40CFR261.33; No hazardous properties listed
by 40CFR261,Subpart C
Section 16: Other Information
HMIS probility
Health 0 Min risk
Flammability 1 ECLH
Reactivity 0 Min risk
Tel: +86 537 7927788
Fax: +86-537-341-4528
Web: www.yztchg.com

Liquid Cationic Reagent
(PTAC 1881)
(3-Chloro-2-hydroxypropyltrimethyl) ammonium chloride
Instructions
No.66 West of Beizhan Road, Yanzhou Shandong, 272117 P.R. China
Paper chemicals dept.: +86-537-792-7788
Rubber &Plastic chemicals dept.: +86-537-792-7888
Fax: +86-537-341-4528
Webe:www.yztchg.com

Cl CH2 CH2 N CH3CH
OH CH3
CH3
Cl+
(PTAC 1881)
(3-Chloro-2-hydroxypropyltrimethyl) ammonium chloride
Ⅰ . Product Introduction：
(3-Chloro-2-hydroxypropyltrimethyl) ammonium chloride is a kind of cationic reagent, belongs to quaternary
ammonium salt, which is an important organic synthesis intermediates too. Molecular formula is C6H15NOCL2
and weight is 188.1. Structural formula is the following:
Under the normal temperature, this product is 65% aqueous solution and immediately transforms into epoxy
structure in alkaline conditions. So it is widely used for cationic modification of starch, guar gum, cellulose and
other material.
Ⅱ . Product Performance indicators:
(1) Appearance: colorless and transparent liquid
(2) Active content: ≥65%
(3) 1, 3 - dichloro-propanol: ≤10PPM
(4) Epichlorohydrin: ≤5PPM
(5) PH value: 5-7(10% Solution)
(6) Solubility: soluble in water and 2-propanol
Ⅲ . Product Features
Liquid Cationic Reagent has the following advantages.
(1) Product appearance is colorless and transparent liquid, low impurity content, less than 20 ppm
(2) Product quality is stable for using advanced continuous production technology.
(3) Reaction of products is high, up to 90% above.
Ⅳ . Scope of Application
Liquid of Cationic Reagent can be widely used in the following areas.
(1) Papermaking Industry
As an important auxiliary agent, PTAC is widely applied to starch, cellulose, and chitosan chemical
modification. The cationic starch, which is modified from raw starch, can be used as the paper's additives for
surface sizing agent, retention and filtration aid, enhancer and so on.

Tel: +86 537 7927788
Fax: +86-537-341-4528
Web: www.yztchg.com
(2) Textile Industry
The cotton fiber, which is modified by PTAC, can enhance the dye’s bonding. And cationic starch can be
used as warp sizing agent.
(3) Water Treatment Industry
The electronegative suspended solids of water react with PTAC to get cationic polymer. As flocculant, it can
be widely used in the purification of water
(4) Daily Chemical Industry
The cationic guar gum and other chemicals, which are formed by PTAC modification, are all important daily
chemicals.
Ⅴ. . Note
(1) If there is crystal before use (in winter), pls heat and stir to dissolve.
(2) If eyes contact, wash with water for 15 minutes and go to hospital.
(3) Storage conditions: sealed storage in a cool, ventilated and dry place.
Ⅵ. . Packaging specifications
250 kg drum
1100kg IBC
22MT flexitank

The Enterprise Criterion of
Yanzhou Tiancheng Chemical Co., Ltd.
Q/0882YTC008-2012
Published on March 24th
, 2012 Carried out on April 24th
, 2012
Published by Yanzhou Tiancheng Chemical Co., Ltd.

Q/0882YTC008-2012
Preface
This standard published firstly on April, 2012
Since the release of this standard is valid for three year from the date of maturity, re-examination.
This standard was issued by Yanzhou Tiancheng Chemical Co., Ltd.
This standard was drafted by Yanzhou Tiancheng Chemical Co., Ltd.
The main drafters: Zhu Niande, Wang Guidong, Zhang Yinguang.

Q/0882YTC008-2012
1
1. Main Scope
This standard specifies the liquid cationic reagent requirements, experimental methods, examining rules,
package, symbol, carriage and storage.
This standard applies to liquid cationic reagent obtained from ECH, hydrochloric acid, TMA solution. The
products are widely used in the paper industry, textile industry, water treatment industry and daily chemical
industry and other industries.
Structure:
2. Referenced document
The referenced terms of the following documents are also provisions of this standard. Its subsequent
amendments (excluding corrigenda) or revised versions do not apply to this standard, but encourage the parties
to reach an agreement in accordance with the standard to use the latest version of these documents.
GB/T191-2000 Signs for packaging and transportation
GB/T601-2002 Chemical reagents, preparation of standard titration solution
GB/T603-2002 Chemical reagents, testing methods and preparations
GB/T6678-2003 The general rules of sampling.
GB/T6680-2003 The general rule of liquid sampling.
3. Technical Requirement
Technical Index of liquid Cationic Reagent shown in Table 1:
Liquid Cationic Reagent technical requirements:
4. Experimental methods
4.1 Appearance
Fetch 200 ml sample to a colorless glass beaker, and visual measurement. Liquid cationic reagent is colorless
and clear.
4.2 Active matter content
4.2.1 Instruments
One Over Ten-thousand Analytical Balance:
Acid-base burette, 25ml;
Lodine flask, 250ml.
4.2.2 Reagents
Sodium hydroxide standard solution: c（NaOH=0.5 mol / L），refer GB/T601 Chemical Reagent, preparation
of standard titrationliquor to make up.
Hydrochloric acid standard solution: c（HCl）=0.1 mol / L, refer GB/T603 Chemical Reagent, Test
methods used in the preparation of formulations and preparations to make up.
Items Technical index
Appearance Colorless and clear liquid
Active matter content/% ≥65.0
1,3dichlorhydrin content/% ≤10×10-4
ECH content/% ≤5×10-4
PH value 5-7

Q/0882YTC008-2012
2
Phenolphthalein indicator：10 g / L, refer GB/T603 Chemical Reagent, Test methods used in the
preparation of formulations and preparations to make up.
4.2.3 Operation steps
1）Blank titration
Weigh 2.6-3.4g cationic reagent sample precisely (exact to 0.0002g). Put it into an arid iodine flask,
add 60 ml distilled water and three drops phenolphthalein indicator to it, and use 0.1 mol / L sodium
hydroxide standard solution to titrate to reddish color.
2）Active content titration
Weigh 1.0-1.1g cationic reagent sample precisely (exact to 0.0002g). Put it into an arid iodine flask,
use pipette to fetch 10 ml 0.5 mol / L sodium hydroxide standard solution into an iodine flask, add
10 ml distilled water and three drops phenolphthalein indicator to it, seal it off, Shake it evenly
enough, use 0.1 mol / L hydrochloric acid standard solution to titrate sample, continue dripping until
the red color vanishes.
4.2.4 Calculation
Active substance content samples, according to formula （1）、（2）:
1 1 2 2( ) 0.1881
100%
c V c V A
X
m
• •− − ×
= × （1）
3 3C V
A =
W
×
（2）
In the formula:
X——test samples of active substance content;
c1——Concentration of sodium hydroxide standard solution mol / L;
V1——Volume of the sodium hydroxide standard solution consumed by test sample, ml;
c2——Concentration of hydrochloric acid standard solution, mol/L;
V2——Volume of hydrochloric acid standard solution consumed by test sample, ml;
m——Quality of test sample, g;
C3——Concentration of sodium hydroxide standard solution mol / L;
V3——Consumed Volume of sodium hydroxide standard solution，ml;
0.1881—mass of the reagent in 1 ml hydrochloric acid standard titration liquid [c（HCl）=1.000 mol /
L], g.
4.3 Measurement of ECH content and 1,3-dichloropropanol content
4.3.1 Reagent
ECH, HPLC grade;
1, 3 - dichloro propyl alcohol, HPLC grade.
4.3.2 Instruments
GC: Rui Hong SP-6800A or other similar instruments.
Detector: FID split/splitless
Capillary column: SE-30 0.35 mm x 30 m x 0.1 µm
4.3.3 Operation
1）Confection of standard solution
Use 5 μL micro-injector to fetch 1 μL、2 μL、3 μL、4 μL ECH and injected into 50 ml colorimetric
cylinder separately, and use the same way to injected into the above 50 ml colorimetric cylinder
separately. Thin up to scale, fully shake, and reserve.
2）Confection of sample
Weigh cationic reagent about 40g, put it into distillation flask and vacuum distillation to near
dryness slowly, collect the liquid slip out, test.
3）Gas chromatography
Chromatographic column: SE-30 0.35 mm x 30 m x 0.1 µm
Carrier gas: nitrogen 0.06 MPa;
Hydrogen: 0.06 MPa;

Q/0882YTC008-2012
3
Air: 0.15 MPa;
Column pressure: 0.04 MPa;
Oven temperature: 120 ºC;
Sample injector temperature: 200 ºC;
Detector temperature: 200 ºC;
Sample injection volume: 1µl.
4.3.4 Calculation
1）Draw standard curve
Calculate the standard sample solution as ECH, 1, 3-dichloro-propanol the corresponding peak
area average value, use content as the abscissa, the corresponding peak area as the ordinate. Draw
the standard curve of ECH, 1,3-dichloropropanol separately.
Or application of the calculation method, use content as the abscissa, the corresponding peak area
as the ordinate, calculated the standard curvilinear equation of ECH, 1, 3-dichloropropanol
separately.
1 1
n n
i i
i i
y b x
a y bx
n
= =
−
= = −
∑ ∑
（3）
1
2
1
( )( )
( )
n
i i
i
n
i
i
x x y y
b
x x
=
=
− −
=
−
∑
∑
（4）
Correlation coefficient r:
2
1
2
1
( )
( )
n
i
i
b n
i
i
y y
r
x x
=
=
−
=
−
∑
∑
（5）
From （3）、（4）、（5）get the standard curvilinear equation:
Standard curve of ECH 500 141y x= − + (6)
Standard curve of1, 3-dichloropropanol 1999 141y x= + (7)
2）Cubature
Sample mapping processing method with standard solution map processing method. From the
sample get ECH, 1,3-dichloro-propanol the corresponding peak area average value, brought into
equation （6）、（7）separately and calculated, from the sample get the content of
ECH,1,3-dichloro-propanol.
4.3.5 Standard gas chromatogram
4.4 Determine pH value
4.4.1 Definition
It also called hydrogen ion concentration index, which is a scale of hydrogen ion activity from solution.
And it usual sense measurement of the solution pH value.
4.4.2 Principle:
Use PHS-25 type acidometer, namely the use of pH combination electrode in solution of different
acidity measured direct current generate by bit, through pre-amplifier transport pH to A/D converter, in
order to achieve the pH value digital display purposes.
4.4.3 Instruments
1）Acidometer, PHS-25 type;
2）Beaker, 250 ml;
3）Wash bottle.
4.4.4 Operating steps:

Q/0882YTC008-2012
4
Add 90 mL distilled water into 250 mL beaker, weigh 10 g sample to the beaker (exact to 0.0002 g), stir
with a glass rod, until the sample completely dissolved in distilled water. Refer PHS-25 type acidometer
operating instruction manual to operate and mark. Measure twice; take the average of two measurements
as measured result.
4.4.5 Calculation of measurement results:
Direct readings, is the pH value.
4.4.6 Measurement accuracy
The results of two parallel measurements, the relative error should be less than 1%.
5. Marks, Package, Carriage and Storage.
5.1 Marks
Products pail pack should be attached with clear and firm label. Marked: product name, product standard mark,
net content, batch number (or date of manufacture), maker, address and so on. Storage and transportation signs
should be consistent with the relevant provisions of GB/T191
5.2 Package
In plastic bucket, 240±0.005 kg net weight per barrel, other options negotiated by both parties.
5.3 Carriage
Product during transport should pay attention to waterproof, freeze-proofing, avoid contact with
open flame, not mix with corrosion, flammable, explosive items; ban discards during loading and unloading.
5.4 Storage
Product should be stored in dry, ventilated, shady and cool storeroom. Keep away from heat and fire, pay
attention to keep warm in winter.
5.5 Shelf life
Accord with above conditions, shelf life of the product is 12 months. It can’t be used after shelf life unless it
is qualified after inspection.
Tel: +86 537 7927788
Fax: +86-537-341-4528
Web: www.yztchg.com

Cationic reagent PTAC 65% information

Cationic reagent PTAC 65% information

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