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SUBMITTED TO:
Mr. TARUN BENARA
Mr. ABHAY KUMAR SHARMA
(SEMINAR CORDINATOR)
PRESENTED & SUBMITTED BY:
MUKESH KUMAR KUMAWAT
EC-37
V SEMETER
CARBON NANOTUBES
CONTENTS
 INTRODUCTION
 STRUCTURE of CNT
 SYNTHISIS of CNT’S
 PROPERTIES of CNT’S
 ADVANTAGES
 APPLICATIONS
 LIMITATIONS of CNT’S
 FUTURE ENHANCEMENTS
 CONCLUSION
 REFERENCES
INTRODUCTION
What is a Carbon Nanotube?
Carbon nanotubes (CNTs) are allotropes of
carbon with a cylindrical nanostructure.
Nanotubes have been constructed with length-
to-diameterratioof up to 132,000,000:1.
Contd......
 CNT is configurationallyequivalent toa two dimensional
graphene sheet rolled intoa tube.
STRUCTURE
Folded version of twodimensional graphite sheets
Depending on the dimension of the graphite
sheetand typeof folding, different typescan be
created. Eg :SWNTS, MWNT’S
Sidewallsconsistof only hexagonal carbon rings
TYPES OF CNT’S
Thereare two types of CNT’S
1. Single walled Nanotubes(SWNT’S)
2.Multi walled Nanotubes (MWNT’S)
1.SINGLE WALLED NANOTUBES
Most single-walled nanotubes(SWNT)
have a diameterof close to 1 nanometer,
with a tube length that can be many
millionsof times longer.
Single-walled nanotubes are an
importantvarietyof carbon nanotube
because theyexhibitelectric properties
thatare not shared by the multi-walled
carbon nanotube (MWNT) variants.
Schematic of a SWNT
2.MULTIWALLNANOTUBES
Multi-walled nanotubes
(MWNT) consist of multiple
rolled layers (concentric
tubes) of graphene.
MWNTs are zero-gap
metals.
Schematic of a MWNT
SYNTHISIS of CNT’S
Thereare three techniques to produced
nanotubes
1. Arcdischarge method
2. Laser Ablation method
3. Chemical Vapour Deposition (CVD) Method
a)Arc discharge method
Graphite electrodes placed in an inert Helium atmosphere
When DC current 50-300amps at 20 volts to the rods and
creates a high temperature discharge between the two
electrodes.
The discharge vaporizes the anode rod, and it forms carbon
nanotubes For SWNT mixed metal catalyst is inserted into
anode
b) Laser Ablation method
In this process, an oven filled with inert gas is
brought up to a temperature of about 1200 °C, at high
pressure, and agraphite target is placed inside.
A laser is shot at the target, which vaporizes the
graphite on the surface. Very hot vapor forms,
expands, and then cools, leaving carbon nanotubes
c)Chemical Vapor Deposition
Hydrocarbon + Fe/Co/Ni catalyst 550-750°C CNT
CVD is the most common method for producing carbon
nanotubes .
An energy source, such as resistively heated coil, transfers
energy tocarbon molecules thatare in thegas phase.
sources are methane, carbon
Common gaseous carbon
monoxideand acetylene.
The energy source causes carbon atoms to separate from the
molecules and the carbon atoms attach themselves to the metal
catalysts. After this, thecarbon nanotubes start togrow
Contd...
CNT PROPERTIES
a)Electronic and Electrical property
Electrical conductivity is six orders of magnitude higher than
copper.
Very high current carrying capacity.
b)Thermal property
 The thermal conductivity of CNT’S is very high in the axial
direction and very low in the lateral direction.
 Thermal conductivity, along the axial direction, has been
found to be at least double thatof diamond(~3000 W/mK ).
c)Mechanical property
SWNT’S possess incredible mechanical resistance because
theircarbon atoms are united by the strongest bonds in nature .In
addition, theyare highly flexible, and can be bent repeatedly up to
90° without being damaged.
They haveavery low density, about 1/6 of thedensityof steel,
butare much stronger than steel.
Theywould have the highestYoung’s modulus (or stiffness) of
any material—1 Tpawhich is five times the stiffness of steel.
Advantages
Ultra Strength
Fastelectron conductivity
Verysmall with high frequencyand low power
consumption.
Velocityof electrons in carbon nanotubes isequal to
velocityof light.
Mobilityof electron in carbon nanotubes is 200 times
thatof silicon.
Applications
Contd......
1.IN ELECTRONICS
A) Flat Panel Display
Low powerconsumption, High brightness
Wideviewing angle
Fast response rate
Wideoperating temperaturerange
B) As Conductors and Transistors
C) Ultra-capacitors
High surfacearea to mass ratioof graphene.
Greaterenergystoragedensity than currently
available.
2.Electrical
(A)Field emission in vacuum electronics
(B)Nano lithography
3.Energy storage
(A)Lithium batteries
(B)Hydrogen storage
.
4.Biological
(A)Manufacture of
Artificial muscles
(B)DNA sequencing
(C)Bio-sensors
5.Auto parts
 60 percent of cars produced today
now have fuel lines made with
carbon nanotubes.
 The carbon nanotubes inside the
fuel lines are intended to reduce the
risk of explosions by inhibiting
staticelectricity.
Thesingle-seatercar's
6.Sporting Equipment
Carbon nanotubes have already
been added to sports equipment
such as bats, bicycles, golf clubs,
and hockey sticks in order to
impart more strength and absorb
vibrations.
Carbon Nanotube hockey stick
Limitations of CNT’S
High-Quality nanotubes can only be produced in very
limited quantities -commercial nanotube soot costs 10
timesas muchas gold.
Since these particles are very small, problems can
actually arise from the inhalation of these minute
particles.
FUTURE ENHANCEMENTS
In futurecarbon nanotubes replaces carbon fiber.
It is also used in VLSI interconnections and in water
purification.
It replaces silicon based diodes and transisters in
future.
CONCLUSION
Carbon nanotubes are the next step in miniaturizing
electroniccircuits, replacing silicon transistors and
diodes, which are fast reaching the theoretical limits
of size and speed of operation.
Using CNTs, nanochips can be made with entire
circuits on it. Ideal diodes can be made from CNTs,
resulting in highly efficient electroniccircuits. Further,
CNTs have a number of other uses other than in the
electronic industry, as seen here.
REFERENCES
 http://en.wikipedia.org/wiki/Carbon_nanotube
 http://www.nanocyl.com/CNT-Expertise-Centre/Carbon-
Nanotubes
 http://www.understandingnano.com/nanotubes-
carbon.html
 http://www.research.ibm.com/nanoscience/nanotubes.ht
ml
 http://ebookee.org/Carbon-Nanotubes-Synthesis-
Structure-Properties-and-Applications_251435.html
 http://nanogloss.com/nanotubes/what-is-carbon-
nanotube-synthesis/
 http://www.azonano.com/article.aspx?ArticleID=1199
Than
k
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Carbon nanotubes.pptx is a presentation on carbon nanotubes

  • 1. SUBMITTED TO: Mr. TARUN BENARA Mr. ABHAY KUMAR SHARMA (SEMINAR CORDINATOR) PRESENTED & SUBMITTED BY: MUKESH KUMAR KUMAWAT EC-37 V SEMETER
  • 3. CONTENTS  INTRODUCTION  STRUCTURE of CNT  SYNTHISIS of CNT’S  PROPERTIES of CNT’S  ADVANTAGES  APPLICATIONS  LIMITATIONS of CNT’S  FUTURE ENHANCEMENTS  CONCLUSION  REFERENCES
  • 4. INTRODUCTION What is a Carbon Nanotube? Carbon nanotubes (CNTs) are allotropes of carbon with a cylindrical nanostructure. Nanotubes have been constructed with length- to-diameterratioof up to 132,000,000:1.
  • 5. Contd......  CNT is configurationallyequivalent toa two dimensional graphene sheet rolled intoa tube.
  • 6. STRUCTURE Folded version of twodimensional graphite sheets Depending on the dimension of the graphite sheetand typeof folding, different typescan be created. Eg :SWNTS, MWNT’S Sidewallsconsistof only hexagonal carbon rings
  • 7. TYPES OF CNT’S Thereare two types of CNT’S 1. Single walled Nanotubes(SWNT’S) 2.Multi walled Nanotubes (MWNT’S)
  • 8. 1.SINGLE WALLED NANOTUBES Most single-walled nanotubes(SWNT) have a diameterof close to 1 nanometer, with a tube length that can be many millionsof times longer. Single-walled nanotubes are an importantvarietyof carbon nanotube because theyexhibitelectric properties thatare not shared by the multi-walled carbon nanotube (MWNT) variants. Schematic of a SWNT
  • 9. 2.MULTIWALLNANOTUBES Multi-walled nanotubes (MWNT) consist of multiple rolled layers (concentric tubes) of graphene. MWNTs are zero-gap metals. Schematic of a MWNT
  • 10. SYNTHISIS of CNT’S Thereare three techniques to produced nanotubes 1. Arcdischarge method 2. Laser Ablation method 3. Chemical Vapour Deposition (CVD) Method
  • 11. a)Arc discharge method Graphite electrodes placed in an inert Helium atmosphere When DC current 50-300amps at 20 volts to the rods and creates a high temperature discharge between the two electrodes. The discharge vaporizes the anode rod, and it forms carbon nanotubes For SWNT mixed metal catalyst is inserted into anode
  • 12. b) Laser Ablation method In this process, an oven filled with inert gas is brought up to a temperature of about 1200 °C, at high pressure, and agraphite target is placed inside. A laser is shot at the target, which vaporizes the graphite on the surface. Very hot vapor forms, expands, and then cools, leaving carbon nanotubes
  • 13. c)Chemical Vapor Deposition Hydrocarbon + Fe/Co/Ni catalyst 550-750°C CNT CVD is the most common method for producing carbon nanotubes . An energy source, such as resistively heated coil, transfers energy tocarbon molecules thatare in thegas phase.
  • 14. sources are methane, carbon Common gaseous carbon monoxideand acetylene. The energy source causes carbon atoms to separate from the molecules and the carbon atoms attach themselves to the metal catalysts. After this, thecarbon nanotubes start togrow Contd...
  • 15. CNT PROPERTIES a)Electronic and Electrical property Electrical conductivity is six orders of magnitude higher than copper. Very high current carrying capacity. b)Thermal property  The thermal conductivity of CNT’S is very high in the axial direction and very low in the lateral direction.  Thermal conductivity, along the axial direction, has been found to be at least double thatof diamond(~3000 W/mK ).
  • 16. c)Mechanical property SWNT’S possess incredible mechanical resistance because theircarbon atoms are united by the strongest bonds in nature .In addition, theyare highly flexible, and can be bent repeatedly up to 90° without being damaged. They haveavery low density, about 1/6 of thedensityof steel, butare much stronger than steel. Theywould have the highestYoung’s modulus (or stiffness) of any material—1 Tpawhich is five times the stiffness of steel.
  • 17. Advantages Ultra Strength Fastelectron conductivity Verysmall with high frequencyand low power consumption. Velocityof electrons in carbon nanotubes isequal to velocityof light. Mobilityof electron in carbon nanotubes is 200 times thatof silicon.
  • 19. Contd...... 1.IN ELECTRONICS A) Flat Panel Display Low powerconsumption, High brightness Wideviewing angle Fast response rate Wideoperating temperaturerange B) As Conductors and Transistors C) Ultra-capacitors High surfacearea to mass ratioof graphene. Greaterenergystoragedensity than currently available.
  • 20. 2.Electrical (A)Field emission in vacuum electronics (B)Nano lithography 3.Energy storage (A)Lithium batteries (B)Hydrogen storage
  • 22. 5.Auto parts  60 percent of cars produced today now have fuel lines made with carbon nanotubes.  The carbon nanotubes inside the fuel lines are intended to reduce the risk of explosions by inhibiting staticelectricity. Thesingle-seatercar's
  • 23. 6.Sporting Equipment Carbon nanotubes have already been added to sports equipment such as bats, bicycles, golf clubs, and hockey sticks in order to impart more strength and absorb vibrations. Carbon Nanotube hockey stick
  • 24. Limitations of CNT’S High-Quality nanotubes can only be produced in very limited quantities -commercial nanotube soot costs 10 timesas muchas gold. Since these particles are very small, problems can actually arise from the inhalation of these minute particles.
  • 25. FUTURE ENHANCEMENTS In futurecarbon nanotubes replaces carbon fiber. It is also used in VLSI interconnections and in water purification. It replaces silicon based diodes and transisters in future.
  • 26. CONCLUSION Carbon nanotubes are the next step in miniaturizing electroniccircuits, replacing silicon transistors and diodes, which are fast reaching the theoretical limits of size and speed of operation. Using CNTs, nanochips can be made with entire circuits on it. Ideal diodes can be made from CNTs, resulting in highly efficient electroniccircuits. Further, CNTs have a number of other uses other than in the electronic industry, as seen here.
  • 27. REFERENCES  http://en.wikipedia.org/wiki/Carbon_nanotube  http://www.nanocyl.com/CNT-Expertise-Centre/Carbon- Nanotubes  http://www.understandingnano.com/nanotubes- carbon.html  http://www.research.ibm.com/nanoscience/nanotubes.ht ml  http://ebookee.org/Carbon-Nanotubes-Synthesis- Structure-Properties-and-Applications_251435.html  http://nanogloss.com/nanotubes/what-is-carbon- nanotube-synthesis/  http://www.azonano.com/article.aspx?ArticleID=1199