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______________________________________________________________________________________________________________ 
TerutakaKitagawa; AbhishekDey; Priscilla Lugo-Mas; Jason B. Benedict; Werner Kaminsky; Edward Solomon; Julie A. Kovacs; 
J. Am. Chem. Soc.2006, 128, 14448-14449. 
1
Kovacs et al., Eur. J. Inorg. Chem. 2007, 29–38 
2
Coulter et al, J BiolInorgChem(2002) 7: 653–658 3
Rees et al, (2000) Biochemistry 39:2499–2508 
4
[FeII(cyclam-PrS)]+ 
5
6
7
8 
[FeIII(cyclam-PrS)(OOH)]+
9
10
11
νν 
Favours superoxide reduction and Fe−O, 
as opposed to O−O bond cleavage. 
12
Journal of Biological Inorganic ChemistryIssue:Volume 7, Number 6 Date:June 2002 Pages:647 -652 
13

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