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2018
Eds.: K. German, X. Gaona, M. Ozawa,
Ya. Obruchnikova, E. Johnstone, A.Maruk,
M. Chotkowski, I. Troshkina, A. Safonov
IPCE RAS - GRANICA
10th International Symposium on
Technetium and Rhenium –
Science and Utilization
International Symposium
Dedicated to
100th Anniversary of
Anna Kuzina
October 3-6, 2018 - Moscow - Russia
Eds.: K. German, X. Gaona, M. Ozawa, Ya. Obruchnikova,
E. Johnstone, A. Maruk, M. Chotkowski, I. Troshkina, A. Safonov
Moscow - 2018
10th International Symposium on Technetium and Rhenium – Science and Utilization, Moscow, 2018
Proceedings and selected lectures of the 10th International Symposium on
Technetium and Rhenium – Science and Utilization, October 3-6, 2018 - Moscow –
Russia, Eds: K. German, X. Gaona, M. Ozawa, Ya. Obruchnikova, E. Johnstone,
A. Maruk, M. Chotkowski, I. Troshkina, A. Safonov. Moscow: Publishing
House Granica, 2018, 525 p.
ISBN 978-5-9933-0132-7
Reviewers:
Doctor of Chemical Sciences, Professor, Honored Scientist of the Russian Federation,
Chief Researcher of A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Russian Academy of Sciences V.F. Peretrukhin
Ph.D., Associate Professor of the Mendeleev University Chemical and Technological of
Russia Ya.A. Obruchnikova
4
Russian Academy of Sciences, State Corporation on atomic energy (ROSATOM),
Interdisciplinary scientific council on radiochemistry, Japanese Nuclear Society,
Japanese Radiochemical society, Dmitry Mendeleev University of Chemical
Technology of Russia, SENA (CEA&CNRS-France), UNLV (USA), IAEA, IPCE
RAS, Burnasyan Federal SRC-FMBC hold on October 3-6, 2018 in Moscow the
10th International Symposium on Technetium and Rhenium – Science and
Utilization
Sections:
1. Fundamental Physics and Chemistry of Tc and Re
2. Analytical Chemistry of Tc and Re
3. Tc in Nuclear Fuel Cycle and in the Biosphere
4. Re Hydrometallurgy
5. Tc and Re in Nuclear Medicine
ISTR2018 is dedicated to the 100th birthday anniversary of Prof. Anna Kuzina,
the famous Russian chemist in the field of technetium chemistry.
The Symposium was prefaced with a separate School-seminar on Fundamental
basis for Advanced treatment of Radioactive waste
on Sept 28-Oct 02, 2018
Chairman - K.E. German, IPCE RAS guerman_k@mail.ru ;
Secretary: A.V. Safonov e-mail alexeysafonof@gmail.com
Org. committee A. Maruk amaruk@list.ru
The organizational and technical support was provided by MKC LLC -
professional congress organizer company.
Phone: +7 (495)-726-5135
E-mail: info@mkcongress.ru
Website: www.mkcongress.ru
Panorama of Moscow with the view at the hosting President hotel and Gorky Park (Photo by K. German)
CONTENT
1. Fundamental Physics and Chemistry of Tc and Re.
Chairs : K.E. German and Masaki Ozawa
Roald Hoffmann. MESSAGE TO INTERNATIONAL SYMPOSIUM ON TECHNETIUM
AND RHENIUM SCIENCE AND UTILIZATION, 2018
Aleksey Buryak. WELCOME ADDRESS FROM IPCE - RUSSIAN ACADEMY OF
SCIENCES
Andrey Romanov. WELCOME ADDRESS FROM THE MINISTRY OF SCIENCE AND
HIGHER EDUCATION OF RUSSIAN FEDERATION
Mikhail Igorevich Panasyuk. ANNA KUZINA: BIOGRAPHY.
K.E. German. PROF. ANNA FEDOROVNA KUZINA – 100TH ANNIVERSARY OF
BIRTHDAY
T. Yoshimura, M. Seike, H. Ikeda, K. Nagata, A. Ito, E. Sakuda, N. Kitamura, A. Shinohara
PHOTOLUMINESCENCE SWITCHING OF NITRIDORHENIUM(V) COMPLEXES
B. Grambow, X. Gaona, W. Runde, R. Konings, A.V. Plyasunov, L. Rao, A.L. Smith, E.
Moore, M.-E. Ragoussi, J. Martinez-Gonzalez, I. Grenthe. CHEMICAL
THERMODYNAMICS OF TECHNETIUM IN THE OECD/NEA UPDATE VOLUME
E.S. Kulikova, Zh.K. Majed, D.V. Drobot, E.I. Efremova. HIGHLY SELECTIVE
CATALYSTS BASED ON BIMETALLIC RHENIUM-RUTHENIUM COMPLEXES
OBTAINED BY ALKOXYTECHNOLOGY
E.S. Kulikova, D.V. Drobot, E.I. Efremova. THE FIRST EXAMPLE OF BI AND THREE-
METALLIC ALKOXIDES CONTAINING RHENIUM AND RUTHENIUM
T. Matsuzaki, H. Sakurai. A NEW PRODUCTION METHOD OF 99Mo BY MUON
NUCLEAR TRANSMUTATION
N. Budantseva, G. Andreev, A. Fedoseev THE U(VI), NP(VI) AND PU(VI) COMPLEXES
WITH TcO4-, ReO4-. THE DIFFICULTIES IN ASSIGNING OF AnO22+ GROUPS
VIBRATIONAL FREQUENCIES.
J.S. McCloy, C. Soderquist, J. Weaver, Jason Lonergan. SPECTROSCOPIC STUDIES OF
ALKALI PERTECHNETATES AND PERTECHNIC ACID
E. Il’in, V. Ivanov, A. Buryak, A. Kopytin, A.S. Parshakov, K.E. German. COMPLEXES OF
D- AND F-TRANSITION METALS - PRECURSORS FOR NANOSCALE REFRACTORY
OXIDES
16
17
17
18
25
34
35
51
61
62
81
82
83
5
6
A.A. Revina, M.A. Kuznetsov, A.M. Chekmarev. THE SELF-ASSEMBLY OF RHENIUM
NANOPARTICLES IN REVERSE MICELLAR SOLUTIONS
М. S. Grigoriev, A. M. Fedoseev. SYNTHESIS AND CRYSTAL STRUCTURE OF NEW
COMPLEX [Pu(DMSO)8](TcO4)3∙0.5H2O
K.E. German, Ya.A. Obruchnikova, A.A. Levtsova, M.S. Grigoriev, A.V. Afanasyev, S.N.
Ryagin PRECIPITATION OF POORLY SOLUBLE TECHNETIUM COMPOUNDS FROM
MODEL RADIOACTIVE WASTE AND THEIR CONVERSION INTO SOLID MATRICES
FOR TRANSMUTATION
K.E. German, N.S. Legkodimova, M.S. Grigoriev, Ya.A. Obruchnikova, G.V. Kolesnikov,
Yu.A. Ustynyuk, F. Poineau, E.V. Belova, O.S. Kryzhovets. SUPRAMOLECULAR
INTERACTIONS OF CAFFEINE MOLECULES WITH EACH OTHER, WATER
MOLECULES AND OXYGEN ATOMS OF TETRAOXIDOANIONS IN THE THREE
NEW DIFFERENT COMPOUNDS Me(H2O)6[ReO4]2. CAFFEINE (Me= Co, Cd, Mg)
A.G. Matveeva, I.Yu. Kudryavtsev, M.P. Pasechnik, R.R. Aysin, T.V. Baulina, S.V. Matveev,
A.N. Turanov, V.K. Karandashev. TRIPODAL ORGANOPHOSPHORUS LIGANDS FOR
THE LIQUID EXTRACTION OF PERRHENIC ACID (ReVII): IR, NMR and DFT
INVESTIGATION OF PROTON LOCATION
A.N. Turanov, V.K. Karandashev, A.V. Kharlamov, N.A. Bondarenko EXTRACTIVE AND
SORPTION PRECONCENTRATION OF REO4- IONS WITH AZAPODANDS
CONTAINING DIPHENYL- AND DIBUTYLPHOSPHORYL TERMINAL GROUPS
A.M. Fedosseev, M.S. Grigoriev, K.E. German, F. Poineau, G.A. Kirakosyan, K. Czerwinski,
A. Sattelberger. SINGLE CRYSTAL STRUCTURE OF TETRA-HYDROXONIUM-
DIAQUA TETRATECHNETYL(V)HEXADECATECHNETYL(VII) TETRAHYDRATE
[H7O3]4[TcV TcVII О68]·4H2O CALLED EARLIER “RED SOLID HTcO4”
T.I.A. Gerber, J. Mukiz, E. Hosten. DIMERIC RHENIUM(IV) COMPOUNDS OF
HYDROXY-PICOLINIC ACID
2. Analytical Chemistry of Tc and Re - Chairs : Xavier Gaona and Alesya Maruk
D.S. Ostapenko, N.V. Zarubuna, V.V. Ivanov. DETERMINATION OF RHENIUM IN
CARBON-TERIGENOUS, ORGANO-MINERAL AND ORGANOGENIC GEOLOGICAL
SAMPLES BY ICP-MS METHOD
M. Chotkowski. ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL
INVESTIGATIONS OF TcO4- REDUCTION IN ALKALINE SOLUTIONS
A.P. Mel'nikov, L.Yu.Martynov, N.K. Zaitsev. MOBILE METHODS FOR CONTROL OF
THE UNDERGROUND LEACHING SOLUTION COMPOSITION
G.А. Kirakosyan, K.E. German, A.V. Afanasiev, S.N. Ryagin, A.V. Safonov, E.A. Kataev, F.
Poineau, K.R. Czerwinski, E.V. Johnstone, A.P. Sattelberger APPLICATIONS OF 99Tc-
NMR IN CHEMISTRY AND NUCLEAR MEDICINE
Wangsuo Wu, Xuejie Sun, Keliang Shi. RAPID DETERMINATION OF LONG-LIVED
FISSION PRODUCT TECHNETIUM-99 IN UO2 SAMPLES
K.E. German, T. Reich, G.A. Kirakosyan, E.V. Johnstone, K.R. Czerwinski, F. Poineau, A.P.
Sattelberger TECHNETIUM METAL, TECHNETIUM CHLORIDES AND CHLORINE
SPECIES IN PYROMETALLURGICALLY FORMED SEDIMENTS AND MELTS -
SPECIATION BY Tc-99 AND Cl-35,36,37-NMR AND EXAFS / XANES
Keliang Shi, Xuejie Sun, Wangsuo Wu, Xiaolin Hou. ANALYSIS OF TECHNETIUM
SPECIES AND FRACTIONS IN NATURAL SEAWEED USING BIOCHEMICAL
SEPARATION AND ICP-MS MEASUREMENT
A. V. Kopytin, A.V. Afanasiev, K. E. German, T.V. Zhukova, V. F. Peretrukhin. A NEW
PERTECHNETATE-SELECTIVE ELECTRODE BASED ON SUPRAMOLECULAR
POLYMER COMPOSITION
86
88
90
92
94
96
97
100
110
111
113
114
115
117
118
125
126
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2. Tc in Nuclear Fuel Cycle and in the Biosphere –
Chairs: John McCloy and Mikhail Grigoriev
L. Bondareva. RHENIUM (AS ANALOG TECHNETIUM) - ACCUMULATION AND
DISTRIBUTION IN MACROALGAE, FONTINALIS ANTIPIRETICA
K. Dardenne, J. Rothe, T. Vitova, X. Gaona, M. Herm, E. González-Robles, V. Metz, M.
Altmaier, H. Geckeis. USE OF ADVANCED SPECTROSCOPIC TECHNIQUES FOR THE
CHARACTERIZATION OF Tc AQUEOUS SPECIES AND SOLID COMPOUNDS: ACT
BEAMLINE AT KIT SYNCHROTRON SOURCE
X. Gaona, M. Altmaier, H. Geckeis. SOLUTION CHEMISTRY OF Tc UNDER
CONDITIONS RELEVANT FOR NUCLEAR WASTE DISPOSAL
S. Duckworth, A. Baumann, X. Gaona, M. Altmaier, H. Geckeis. IMPACT OF SULFATE
ON THE SOLUBILITY OF TC(IV) UNDER REDUCING CONDITIONS
M. Altmaier, A. Baumann, X. Gaona, E. Yalcintas, R. Polly, K. Dardenne, H. Geckeis.
SOLUBILITY AND COMPLEXATION OF Tc(IV) IN THE PRESENCE OF CARBONATE
E. Yalcintas, A. Baumann, X. Gaona, M. Altmaier, H. Geckeis. SOLUBILITY AND
HYDROLYSIS OF Tc(IV) IN DILUTE TO CONCENTRATED SALT SYSTEMS:
APPLICATION TO COMPLEX MIXTURES
A. Baumann, S. Duckworth, E. Yalcintas, X. Gaona, K. Dardenne, M. Altmaier, H. Geckeis.
IMPACT OF NITRATE ON THE REDOX CHEMISTRY OF Tc
A.B. Melentev, A.N. Mashkin, S.A. Lukin, N.S. Samarina, V.S. Ermolin. THE
TECHNETIUM BEHAVIOR IN THE NEW SNF REPROCESSING FLOWSHEETS OF
THE RT-1 PLANT
S.S. Danilov, S.A. Kulikova, S.E. Vinokurov. IMMOBILIZATION OF TECHNETIUM-99
IN SODIUM-ALUMINUM- IRON-PHOSPHATE GLASS
M.A. Volkov, K.E. German, V.V. Kuznetsov. ELECTROCHEMICAL RECOVERY OF Tc
FROM SOLUTIONS ISSUING FROM SNF REPROCESSING
A.V. Voit, L.A. Zemskova. SIMULATION OF THE INTERACTION OF ReO4
- and MoO2
-
ANIONS WITH CHITOSAN. QUANTUM CHEMISTRY APPROACH
W. Um. 99Tc IMMOBILIZATION IN VARIOUS WASTE FORMS
M. Khan, S. Hong, W. Um. INCORPORATION OF RHENIUM IN TIN DIOXIDE FOR 99Tc
IMMOBILIZATION
A. Laplace, E. Régnier, M. Neyret, I. Giboire, N. El Jeaidi, J.C. Laugier, M. Chartier, V.
Ansault, C. Vallat, O. Pinet . RHENIUM BEHAVIOR IN A MOLTEN BOROSILICATE
GLASS
K. Uruga, T. Usami, T. Tsukada . IMMISCIBILITY AND VOLATILITY OF RHENIUM IN
VITRIFICATION PROCESS OF SIMULATED PUREX RAFFINATE
K. Schmeide, A. Rossberg, S. Weiss, A.C. Scheinost. SPECTROSCOPIC AND BATCH
STUDIES OF TECHNETIUM UPTAKE BY SIDERITE
D.M. Rodríguez, N. Mayordomo, T. Stumpf, K. Müller. 99Tc RETENTION ON PYRITE
AND ALUMINA: THE EFFECT OF Fe2+
A. Ledoux, Jf. Hollebecque, C. Michel, S. Schuller, E. Sauvage, M. Delaunay, V-Labe, S.
Lemonnier, L. Meslin. VOLATILITY MECHANISM STUDY IN THE WASTE
VITRIFICATION PROCESS
K. E. German, V. F. Peretrukhin, Ya.A. Obruchnikova, A.V. Afanasiev, S.N. Ryagin.
VOLATILITY OF PERTECHNETATES
J. Lin, L. Zhu, J.-Q. Wang, S. Wang. IMMOBILIZATION OF ReO4– BY A FAMILY OF
RARE-EARTH PLUMBITE PERCHLORATES BASED ON SINGLE CRYSTAL-TO-
SINGLE CRYSTAL TRANSFORMATION
S.V. Stefanovsky, B.S. Nikonov, A.L. Trigub. RHENIUM SPECIATION IN SODIUM
ALUMINO(IRON) PHOSPHATE GLASSES
E.V. Johnstone, K.R. Czerwinski, T. Hartmann, F. Poineau, D.J. Bailey, N.C. Hyatt, N.
Mayordomo, A. Nuñez, F.Y. Tsang, A.P. Sattelberger, K.E. German, E. J. Mausolf.
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237
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270
8
CALCIUM MOLYBDATE, CaMoO4: A PROMISING TARGET MATERIAL FOR 99mTc
AND ITS POTENTIAL APPLICATIONS IN NUCLEAR MEDICINE AND NUCLEAR
WASTE DISPOSITION 277
I. Zinicovscaia, A. Safonov, I. Troshkina, I. Shirokova, K. German. SORPTION OF Re(VII)
BY CYANOBACTERIA SPIRULINA PLATENSIS 287
A.Safonov, R. Aldabaev, N. Andryshchenko, K. Boldyrev, T. Babich, E. Zakharova, K.
German. BIOGEOCHEMICAL IMPACT OF TECHNETIUM MIGRATION IN
SUBSURFACE WATER NEAR TO RW REPOSITORY 288
D.A. Kamorny, A.V. Safonov, I.M. Proshin, E.A. Tyupina, K.E. German, O.A. Gorbunova
STABILIZATION OF TECHNETIUM BY ORGANIC MODIFIERS FOR
LONG-TERM STORAGE IN A CEMENT COMPOUND 297
A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF
99Tc ON THE SHUNGITE 312
A.Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. 99Tc SORPTION
ON THE CARBONE MATERIALS (LIDITE AND SHALE) 314
A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF
99Tc ON ACTIVATED CHARCOAL 315
A. Makarov, N. Andryshchenko, A. Safonov, E. Zakharova, E.V. Belova, K. German.
SORPTION OF 99Tc ON NANODIAMONDS 316
A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF
99Tc ON TAUNITE 317
4. Re Hydrometallurgy - Chairs : I.D. Troshkina and Ya. Obruchnikova 318
V.N. Rychkov, A.O. Taukin, E.V. Kirillov, S.V. Kirillov, G.M. Bunkov, V.S. Semenishchev.
THE STUDY OF SORPTION CONCENTRATION OF RHENIUM FROM ACIDIC
SOLUTIONS 319
I.A. Lebedev, T.D. Batueva, N.B. Kondrashova, M.G. Scherban. SORPTION RHENIUM ON
MESOPOROUS SILICAS MODIFIED WITH DIMETHYLHYDRAZIDE GROUPS 320
Yu.V. Sokolova, V.I. Shishkevich. EXTRACTION OF RHENIUM FROM RECYCLE
SULFURIC ACID SOLUTION OF UNDERGROUND URANIUM LEACHING 321
I.P. Sandalov, V.I. Bogdanov. EXTRACTION OF PLATINUM AND RHENIUM FROM
IRON COLLECTOR OBTAINED BY PLASMA FUSION METHOD 322
S.N. Rasulova, V.P. Guro, R.D. Allabergenov. METHOD FOR RE RECOVERY FROM THE
TAILING DUMP OF RESEARCH-AND-PRODUCTION ASSOCIATION OF ALMALYK
GMK JSC (FORMER UZKTZHM) 323
S.N. Rasulova, V.P. Guro, R.D. Allabergenov. METHOD FOR RECOVERY RHENIUM
FROM THE TAILING DUMP OF RESEARCH-AND- PRODUCTION ASSOCIATION OF
ALMALYK GMK JSC (FORMER UZKTZHM) 331
K.Ya. Agapova, S.K. Kilibayeva, A.N. Zagorodnyaya, A.S. Sharipova, Z.S. Abisheva, Zh.E.
Yakhiyayeva. RECOVERY OF RHENIUM FROM THE WASTES OF HEAT-RESISTANT
NICKEL ALLOYS 333
S.K. Kilibayeva, L.Ya. Agapova, Z.S. Abisheva, Zh.E. Yakhiyayev, G.S. Ruzakhunova, A.V.
Panichkin . ELECTROLYTIC DEPOSITION OF RHENIUM-CONTAINING ALLOYS
FROM AQUEOUS SOLUTIONS OF ELECTROLYTES 334
S.A. Temerov, S.I. Plechkina, M.P. Loseva. ON THE PRODUCTION OF RHENIUM ACID 335
V. Korovin, Yu. Pogorelov, A. Zontov, L. Zontova. EQUILIBRIUM AND KINETICS OF
RHENIUM SORPTION FROM SULPHURIC SOLUTIONS WITH AMR ANIONITE 336
N.A. Bektenov, E.E. Ergozhin, L.K. Ybraimzhanova, B.K. Masalimova. STUDY OF THE
SORPTION CAPACITY OF RHENIUM IONS BY NEW MODIFIED ION EXCHANGERS 337
S.V. Zakharyan, E.I. Gedgagov, A.B. Yun. NEW POSSIBILITIES OF SORPTION
PROCESSES WITH THE USE OF FINELY DISPERSED FORMS OF ION EXCHANGE
RESINS (ON THE EXAMPLE OF RHENIUM RECOVERY) 343
9
L.M. Gapoyan, A.A. Blokhin, M.A. Mikhaylenko, Yu V. Murashkin. EVALUATION OF
USING ZWITTERIONIC ION EXCHANGE RESINS FOR RECOVERY OF RHENIUM
I.D. Troshkina, N.V. Balanovskyi, Ya.A. Obruchnikova, F.Ya. Vatsura, I.A. Vanin, O.A.
Zhukova, K.A. Ratchina. RECOVERY OF RHENIUM BY AMINE-CONTAINED
SORBENTS
I.D. Troshkina, N.B. Balanovskiy, Ya.A. Obruchnikova, V.A. Vanin, F.Ya. Vatsura.
SORPTION OF RHENIUM FROM SULFURIC ACID SOLUTIONS OF POLYMETALLIC
ORES LEACHING
I.D. Troshkina, W.M. Aung, M.V. Marchenko, O.A. Zhukova, Pyae Phyo Aung, V.M.
Muchin RHENIUM ADSORPTION FROM SULFURIC ACID SOLUTIONS BY ACTIVE
COALS
Kasikov A.G., Dvornikova A.M., Areshina N.S. RHENIUM AND RUTHENIUM
RECOVERY FROM SUBSTANDARD WASTE OF NICKEL-BASED LAST
GENERATION SUPERALLOYS
Kasikov A.G., Shchelokova E.A., Dvornikova A.M. NEW SOLVENT IMPREGNATED
SORBENTS FOR RHENIUM RECOVERY FROM ACID MEDIA, BASED ON
MESAPOROUS SILICA OBTAINED BY COPPER-NICKEL WASTE PROCESSING
355
356
357
381
382
384
5. Tc and Re in Nuclear Medicine - Chairs : G.E. Kodina and T. Gerber
A.O. Malysheva, G.E. Kodina, O.Е. Klementyeva, N.A. Taratonenkova, E.A. Lyamtseva,
N.A. Konstantinov, M.V. Zhukova. BEHAVIOR OF THE THERAPEUTIC
RADIOPHARMACEUTICALS WITH RHENIUM-188 ELUATES OF HIGH VOLUME
ACTIVITY
A. Avetisyan, R. Dallakyan, I. Kerobyan CYCLOTRON BASED TECHNETIUM-99M AND
RHENIUM-186 PRODUCTION TECHNOLOGY DEVELOPMENT AT YEREVAN
PHYSICS INSTITUTE
Tsugio Yokoyama, Masaki Ozawa. PRODUCTION OF LOW SPECIFIC RADIOACTIVITY
RHENIUM IN FAST REACTORS
S.A. Dorovatovskiy, A.V. Zverev, V.M. Petriev, V.G. Skvortsov. RESEARCH AND
DEVELOPMENT OF INNOVATIVE RADIOPHARMACEUTICALS BASED ON
THERAPEUTIC RADIONUCLIDE 188Re
T. Ohtsuki, S. Sekimoto, T. Tadokoro, Y. Kani, Y. Ueno. Mo-99/Tc-99m PRODUCTION
USING AN ELECTRON LINEAR ACCELERATOR
Yu.А. Naumova, А.Е. Miroslavov, А.А. Lumpov, G.V. Sidorenko. OXIDATIVE
DECRABONYLATION OF TECHNETIUM PENTACARBONYL IODIDE IN THE
PRESENCE OF IRON(III)
А.А. Кuznetsov, N.A. Nerozin, A.A. Semenova, D.V. Stepchenkov, E.V. Sulim
“GREN-1” 188W/188Re GENERATOR. CURRENT STATUS
R.R. Kumar, D.K. Dhawan, V.D. Chadha. 99mTc LABELED N-ACETYL NEURAMINIC
ACID AS A NEW RADIOTRACER FOR RENAL IMAGING, PREPARATION AND
PRECLINICAL STUDY
Yu.A. Mitrofanov, A.Ya. Maruk, M. Behe. LABELING OF EXENDIN DERIVATE WITH
99mTc
G.E. Kodina, A.O. Malysheva. HISTORY AND PERSPECTIVES OF RHENIUM-188
APPLICATION IN NUCLEAR MEDICINE
Toktosinov Mansur Yangivaevich. PROSPECTS FOR THE USE OF Re-188.
O.E. Klementieva, A.B. Bruskin, V.B. Bubenshchikov, M.G. Rakhimov, A.Ya. Maruk, A.S.
Lunev, D.N. Tumanova, K.A. Luneva, M.G. Gezina, G.E. Kodina. NEW RADIOPHAR-
MACEUTICAL BASED ON α-MSH FRAGMENT FOR DIAGNOSIS OF MELANOMA
B.L. Garashchenko, R.Y. Yakovlev, K.E. German, B.F. Myasoedov SURFACE-MODIFIED
NANODIAMONDS AS CARRIERS FOR 99mTc
M.A. Klenner, G. Pascali, M. Massi, G. Ciancaleoni, B.H. Fraser RHENIUM ENHANCED
386
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RADIOPHARMACEUTICAL PRODUCTION OF FLUORINE-18 LABELLED
BIDENTATE LIGANDS
A. Avetisyan, R. Dallakyan, G. Elbakyan, N. Dobrovolski, A. Manoukyan, A. Melkonyan
CYCLOTRON BASED TECHNETIUM-99M PRODUCTION TECHNOLOGY
DEVELOPMENT AT YEREVAN PHYSICS INSTITUTE
K. Nagata, N. Otsuji, S. Akagi, S. Fujii, N. Kitamura, T. Yoshimura. SYNTHESIS AND
PHOTOPHYSICAL PROPERTIES OF TRICYANIDONITRIDORHENIUM(V)
COMPLEXES WITH BIPYRIDINE DERIVATIVES
A.T. Filyanin, M.P. Zykov, G.E. Kodina, A.Yu.Tsivadze, O.A. Filyanin. ON THE
INDUSTRIAL PRODUCTION OF PHARMACEUTICAL GRADE 99MTc AND 188Re
RADIONUCLIDES ON THE CENTRIFUGAL SEMICOUNTERCURRENT SPINNING
GENERATOR
M.Yu. Petrov, K.E. German, A.V. Afanasiev, O. I. Slyusar, V. G. Taktarov,
V.M. Petriev, V.G. Skvortsov, A.Ya. Maruk, Ya.A. Obruchnikova, O.Vlasova, S.N.
Ryagin. REVIEW OF PROSPECTIVE RADIOPHARMACEUTICALS BASED ON
PROSTATE-SPECIFIC INHIBITORS OF MEMBRANE ANTIGEN FOR
DIAGNOSTICS AND THERAPY OF METASTATIC PROSTATE CANCER
J.S. McCloy, C. Soderquist, J. Weaver, Jason Lonergan. SPECTROSCOPIC STUDIES
OF ALKALI PERTECHNETATES AND PERTECHNIC ACID. Supplimentary data
A.A. Kozar’, V.F. Peretrukhin, K.E. German . INFLUENCE OF THE NEUTRON
SPECTRUM IN THE 99Тс TRANSMUTATION CAMPAIGN ONTO THE ISOTOPE
COMPOSITION OF ARTIFICIAL RUTHENIUM
A.A. Kozar’. ESTIMATION OF GRAIN SIZES OF STUFF OF HETEROGENEOUS
TRANSMUTATION TECHNETIUM TARGETS
486
488
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511
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International Advisory Committee
Chairman – K.E. German
Chairman – I.D. Troshkina
U. Abram
V. Gaona
R. Alberto
M. Chotkowski
K. Czerwinski
F. Poineau
M. Fattahi
Ph. Moisy
T.I.A. Gerber
M.S. Grigoriev
G.E. Kodina
M. Ozawa
T. Suzuki
T. Ohtsuki
H. Sakurai
T. Yoshimura
A. Sattelberger
Ya. Obruchnikova
G. Thorogood
A.Yu. Tsivadze
S. Wang
Y. Wei
W. Wu
Y. Taihong
Germany
Germany
Switzerland
Poland
USA
France/USA
France
France
SouthAfrica
Russia
Russia
Japan
Japan
Japan
Japan
Japan
USA
Russia
Australia
Russia
China
China
China
China

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2018 istr book technetium rhenium content

  • 1. 2018 Eds.: K. German, X. Gaona, M. Ozawa, Ya. Obruchnikova, E. Johnstone, A.Maruk, M. Chotkowski, I. Troshkina, A. Safonov IPCE RAS - GRANICA 10th International Symposium on Technetium and Rhenium – Science and Utilization
  • 2. International Symposium Dedicated to 100th Anniversary of Anna Kuzina October 3-6, 2018 - Moscow - Russia Eds.: K. German, X. Gaona, M. Ozawa, Ya. Obruchnikova, E. Johnstone, A. Maruk, M. Chotkowski, I. Troshkina, A. Safonov Moscow - 2018
  • 3. 10th International Symposium on Technetium and Rhenium – Science and Utilization, Moscow, 2018 Proceedings and selected lectures of the 10th International Symposium on Technetium and Rhenium – Science and Utilization, October 3-6, 2018 - Moscow – Russia, Eds: K. German, X. Gaona, M. Ozawa, Ya. Obruchnikova, E. Johnstone, A. Maruk, M. Chotkowski, I. Troshkina, A. Safonov. Moscow: Publishing House Granica, 2018, 525 p. ISBN 978-5-9933-0132-7 Reviewers: Doctor of Chemical Sciences, Professor, Honored Scientist of the Russian Federation, Chief Researcher of A.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences V.F. Peretrukhin Ph.D., Associate Professor of the Mendeleev University Chemical and Technological of Russia Ya.A. Obruchnikova
  • 4. 4 Russian Academy of Sciences, State Corporation on atomic energy (ROSATOM), Interdisciplinary scientific council on radiochemistry, Japanese Nuclear Society, Japanese Radiochemical society, Dmitry Mendeleev University of Chemical Technology of Russia, SENA (CEA&CNRS-France), UNLV (USA), IAEA, IPCE RAS, Burnasyan Federal SRC-FMBC hold on October 3-6, 2018 in Moscow the 10th International Symposium on Technetium and Rhenium – Science and Utilization Sections: 1. Fundamental Physics and Chemistry of Tc and Re 2. Analytical Chemistry of Tc and Re 3. Tc in Nuclear Fuel Cycle and in the Biosphere 4. Re Hydrometallurgy 5. Tc and Re in Nuclear Medicine ISTR2018 is dedicated to the 100th birthday anniversary of Prof. Anna Kuzina, the famous Russian chemist in the field of technetium chemistry. The Symposium was prefaced with a separate School-seminar on Fundamental basis for Advanced treatment of Radioactive waste on Sept 28-Oct 02, 2018 Chairman - K.E. German, IPCE RAS guerman_k@mail.ru ; Secretary: A.V. Safonov e-mail alexeysafonof@gmail.com Org. committee A. Maruk amaruk@list.ru The organizational and technical support was provided by MKC LLC - professional congress organizer company. Phone: +7 (495)-726-5135 E-mail: info@mkcongress.ru Website: www.mkcongress.ru
  • 5. Panorama of Moscow with the view at the hosting President hotel and Gorky Park (Photo by K. German) CONTENT 1. Fundamental Physics and Chemistry of Tc and Re. Chairs : K.E. German and Masaki Ozawa Roald Hoffmann. MESSAGE TO INTERNATIONAL SYMPOSIUM ON TECHNETIUM AND RHENIUM SCIENCE AND UTILIZATION, 2018 Aleksey Buryak. WELCOME ADDRESS FROM IPCE - RUSSIAN ACADEMY OF SCIENCES Andrey Romanov. WELCOME ADDRESS FROM THE MINISTRY OF SCIENCE AND HIGHER EDUCATION OF RUSSIAN FEDERATION Mikhail Igorevich Panasyuk. ANNA KUZINA: BIOGRAPHY. K.E. German. PROF. ANNA FEDOROVNA KUZINA – 100TH ANNIVERSARY OF BIRTHDAY T. Yoshimura, M. Seike, H. Ikeda, K. Nagata, A. Ito, E. Sakuda, N. Kitamura, A. Shinohara PHOTOLUMINESCENCE SWITCHING OF NITRIDORHENIUM(V) COMPLEXES B. Grambow, X. Gaona, W. Runde, R. Konings, A.V. Plyasunov, L. Rao, A.L. Smith, E. Moore, M.-E. Ragoussi, J. Martinez-Gonzalez, I. Grenthe. CHEMICAL THERMODYNAMICS OF TECHNETIUM IN THE OECD/NEA UPDATE VOLUME E.S. Kulikova, Zh.K. Majed, D.V. Drobot, E.I. Efremova. HIGHLY SELECTIVE CATALYSTS BASED ON BIMETALLIC RHENIUM-RUTHENIUM COMPLEXES OBTAINED BY ALKOXYTECHNOLOGY E.S. Kulikova, D.V. Drobot, E.I. Efremova. THE FIRST EXAMPLE OF BI AND THREE- METALLIC ALKOXIDES CONTAINING RHENIUM AND RUTHENIUM T. Matsuzaki, H. Sakurai. A NEW PRODUCTION METHOD OF 99Mo BY MUON NUCLEAR TRANSMUTATION N. Budantseva, G. Andreev, A. Fedoseev THE U(VI), NP(VI) AND PU(VI) COMPLEXES WITH TcO4-, ReO4-. THE DIFFICULTIES IN ASSIGNING OF AnO22+ GROUPS VIBRATIONAL FREQUENCIES. J.S. McCloy, C. Soderquist, J. Weaver, Jason Lonergan. SPECTROSCOPIC STUDIES OF ALKALI PERTECHNETATES AND PERTECHNIC ACID E. Il’in, V. Ivanov, A. Buryak, A. Kopytin, A.S. Parshakov, K.E. German. COMPLEXES OF D- AND F-TRANSITION METALS - PRECURSORS FOR NANOSCALE REFRACTORY OXIDES 16 17 17 18 25 34 35 51 61 62 81 82 83 5
  • 6. 6 A.A. Revina, M.A. Kuznetsov, A.M. Chekmarev. THE SELF-ASSEMBLY OF RHENIUM NANOPARTICLES IN REVERSE MICELLAR SOLUTIONS М. S. Grigoriev, A. M. Fedoseev. SYNTHESIS AND CRYSTAL STRUCTURE OF NEW COMPLEX [Pu(DMSO)8](TcO4)3∙0.5H2O K.E. German, Ya.A. Obruchnikova, A.A. Levtsova, M.S. Grigoriev, A.V. Afanasyev, S.N. Ryagin PRECIPITATION OF POORLY SOLUBLE TECHNETIUM COMPOUNDS FROM MODEL RADIOACTIVE WASTE AND THEIR CONVERSION INTO SOLID MATRICES FOR TRANSMUTATION K.E. German, N.S. Legkodimova, M.S. Grigoriev, Ya.A. Obruchnikova, G.V. Kolesnikov, Yu.A. Ustynyuk, F. Poineau, E.V. Belova, O.S. Kryzhovets. SUPRAMOLECULAR INTERACTIONS OF CAFFEINE MOLECULES WITH EACH OTHER, WATER MOLECULES AND OXYGEN ATOMS OF TETRAOXIDOANIONS IN THE THREE NEW DIFFERENT COMPOUNDS Me(H2O)6[ReO4]2. CAFFEINE (Me= Co, Cd, Mg) A.G. Matveeva, I.Yu. Kudryavtsev, M.P. Pasechnik, R.R. Aysin, T.V. Baulina, S.V. Matveev, A.N. Turanov, V.K. Karandashev. TRIPODAL ORGANOPHOSPHORUS LIGANDS FOR THE LIQUID EXTRACTION OF PERRHENIC ACID (ReVII): IR, NMR and DFT INVESTIGATION OF PROTON LOCATION A.N. Turanov, V.K. Karandashev, A.V. Kharlamov, N.A. Bondarenko EXTRACTIVE AND SORPTION PRECONCENTRATION OF REO4- IONS WITH AZAPODANDS CONTAINING DIPHENYL- AND DIBUTYLPHOSPHORYL TERMINAL GROUPS A.M. Fedosseev, M.S. Grigoriev, K.E. German, F. Poineau, G.A. Kirakosyan, K. Czerwinski, A. Sattelberger. SINGLE CRYSTAL STRUCTURE OF TETRA-HYDROXONIUM- DIAQUA TETRATECHNETYL(V)HEXADECATECHNETYL(VII) TETRAHYDRATE [H7O3]4[TcV TcVII О68]·4H2O CALLED EARLIER “RED SOLID HTcO4” T.I.A. Gerber, J. Mukiz, E. Hosten. DIMERIC RHENIUM(IV) COMPOUNDS OF HYDROXY-PICOLINIC ACID 2. Analytical Chemistry of Tc and Re - Chairs : Xavier Gaona and Alesya Maruk D.S. Ostapenko, N.V. Zarubuna, V.V. Ivanov. DETERMINATION OF RHENIUM IN CARBON-TERIGENOUS, ORGANO-MINERAL AND ORGANOGENIC GEOLOGICAL SAMPLES BY ICP-MS METHOD M. Chotkowski. ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL INVESTIGATIONS OF TcO4- REDUCTION IN ALKALINE SOLUTIONS A.P. Mel'nikov, L.Yu.Martynov, N.K. Zaitsev. MOBILE METHODS FOR CONTROL OF THE UNDERGROUND LEACHING SOLUTION COMPOSITION G.А. Kirakosyan, K.E. German, A.V. Afanasiev, S.N. Ryagin, A.V. Safonov, E.A. Kataev, F. Poineau, K.R. Czerwinski, E.V. Johnstone, A.P. Sattelberger APPLICATIONS OF 99Tc- NMR IN CHEMISTRY AND NUCLEAR MEDICINE Wangsuo Wu, Xuejie Sun, Keliang Shi. RAPID DETERMINATION OF LONG-LIVED FISSION PRODUCT TECHNETIUM-99 IN UO2 SAMPLES K.E. German, T. Reich, G.A. Kirakosyan, E.V. Johnstone, K.R. Czerwinski, F. Poineau, A.P. Sattelberger TECHNETIUM METAL, TECHNETIUM CHLORIDES AND CHLORINE SPECIES IN PYROMETALLURGICALLY FORMED SEDIMENTS AND MELTS - SPECIATION BY Tc-99 AND Cl-35,36,37-NMR AND EXAFS / XANES Keliang Shi, Xuejie Sun, Wangsuo Wu, Xiaolin Hou. ANALYSIS OF TECHNETIUM SPECIES AND FRACTIONS IN NATURAL SEAWEED USING BIOCHEMICAL SEPARATION AND ICP-MS MEASUREMENT A. V. Kopytin, A.V. Afanasiev, K. E. German, T.V. Zhukova, V. F. Peretrukhin. A NEW PERTECHNETATE-SELECTIVE ELECTRODE BASED ON SUPRAMOLECULAR POLYMER COMPOSITION 86 88 90 92 94 96 97 100 110 111 113 114 115 117 118 125 126
  • 7. 7 2. Tc in Nuclear Fuel Cycle and in the Biosphere – Chairs: John McCloy and Mikhail Grigoriev L. Bondareva. RHENIUM (AS ANALOG TECHNETIUM) - ACCUMULATION AND DISTRIBUTION IN MACROALGAE, FONTINALIS ANTIPIRETICA K. Dardenne, J. Rothe, T. Vitova, X. Gaona, M. Herm, E. González-Robles, V. Metz, M. Altmaier, H. Geckeis. USE OF ADVANCED SPECTROSCOPIC TECHNIQUES FOR THE CHARACTERIZATION OF Tc AQUEOUS SPECIES AND SOLID COMPOUNDS: ACT BEAMLINE AT KIT SYNCHROTRON SOURCE X. Gaona, M. Altmaier, H. Geckeis. SOLUTION CHEMISTRY OF Tc UNDER CONDITIONS RELEVANT FOR NUCLEAR WASTE DISPOSAL S. Duckworth, A. Baumann, X. Gaona, M. Altmaier, H. Geckeis. IMPACT OF SULFATE ON THE SOLUBILITY OF TC(IV) UNDER REDUCING CONDITIONS M. Altmaier, A. Baumann, X. Gaona, E. Yalcintas, R. Polly, K. Dardenne, H. Geckeis. SOLUBILITY AND COMPLEXATION OF Tc(IV) IN THE PRESENCE OF CARBONATE E. Yalcintas, A. Baumann, X. Gaona, M. Altmaier, H. Geckeis. SOLUBILITY AND HYDROLYSIS OF Tc(IV) IN DILUTE TO CONCENTRATED SALT SYSTEMS: APPLICATION TO COMPLEX MIXTURES A. Baumann, S. Duckworth, E. Yalcintas, X. Gaona, K. Dardenne, M. Altmaier, H. Geckeis. IMPACT OF NITRATE ON THE REDOX CHEMISTRY OF Tc A.B. Melentev, A.N. Mashkin, S.A. Lukin, N.S. Samarina, V.S. Ermolin. THE TECHNETIUM BEHAVIOR IN THE NEW SNF REPROCESSING FLOWSHEETS OF THE RT-1 PLANT S.S. Danilov, S.A. Kulikova, S.E. Vinokurov. IMMOBILIZATION OF TECHNETIUM-99 IN SODIUM-ALUMINUM- IRON-PHOSPHATE GLASS M.A. Volkov, K.E. German, V.V. Kuznetsov. ELECTROCHEMICAL RECOVERY OF Tc FROM SOLUTIONS ISSUING FROM SNF REPROCESSING A.V. Voit, L.A. Zemskova. SIMULATION OF THE INTERACTION OF ReO4 - and MoO2 - ANIONS WITH CHITOSAN. QUANTUM CHEMISTRY APPROACH W. Um. 99Tc IMMOBILIZATION IN VARIOUS WASTE FORMS M. Khan, S. Hong, W. Um. INCORPORATION OF RHENIUM IN TIN DIOXIDE FOR 99Tc IMMOBILIZATION A. Laplace, E. Régnier, M. Neyret, I. Giboire, N. El Jeaidi, J.C. Laugier, M. Chartier, V. Ansault, C. Vallat, O. Pinet . RHENIUM BEHAVIOR IN A MOLTEN BOROSILICATE GLASS K. Uruga, T. Usami, T. Tsukada . IMMISCIBILITY AND VOLATILITY OF RHENIUM IN VITRIFICATION PROCESS OF SIMULATED PUREX RAFFINATE K. Schmeide, A. Rossberg, S. Weiss, A.C. Scheinost. SPECTROSCOPIC AND BATCH STUDIES OF TECHNETIUM UPTAKE BY SIDERITE D.M. Rodríguez, N. Mayordomo, T. Stumpf, K. Müller. 99Tc RETENTION ON PYRITE AND ALUMINA: THE EFFECT OF Fe2+ A. Ledoux, Jf. Hollebecque, C. Michel, S. Schuller, E. Sauvage, M. Delaunay, V-Labe, S. Lemonnier, L. Meslin. VOLATILITY MECHANISM STUDY IN THE WASTE VITRIFICATION PROCESS K. E. German, V. F. Peretrukhin, Ya.A. Obruchnikova, A.V. Afanasiev, S.N. Ryagin. VOLATILITY OF PERTECHNETATES J. Lin, L. Zhu, J.-Q. Wang, S. Wang. IMMOBILIZATION OF ReO4– BY A FAMILY OF RARE-EARTH PLUMBITE PERCHLORATES BASED ON SINGLE CRYSTAL-TO- SINGLE CRYSTAL TRANSFORMATION S.V. Stefanovsky, B.S. Nikonov, A.L. Trigub. RHENIUM SPECIATION IN SODIUM ALUMINO(IRON) PHOSPHATE GLASSES E.V. Johnstone, K.R. Czerwinski, T. Hartmann, F. Poineau, D.J. Bailey, N.C. Hyatt, N. Mayordomo, A. Nuñez, F.Y. Tsang, A.P. Sattelberger, K.E. German, E. J. Mausolf. 130 131 132 134 162 164 165 167 168 181 182 184 185 208 209 216 226 237 253 254 257 270
  • 8. 8 CALCIUM MOLYBDATE, CaMoO4: A PROMISING TARGET MATERIAL FOR 99mTc AND ITS POTENTIAL APPLICATIONS IN NUCLEAR MEDICINE AND NUCLEAR WASTE DISPOSITION 277 I. Zinicovscaia, A. Safonov, I. Troshkina, I. Shirokova, K. German. SORPTION OF Re(VII) BY CYANOBACTERIA SPIRULINA PLATENSIS 287 A.Safonov, R. Aldabaev, N. Andryshchenko, K. Boldyrev, T. Babich, E. Zakharova, K. German. BIOGEOCHEMICAL IMPACT OF TECHNETIUM MIGRATION IN SUBSURFACE WATER NEAR TO RW REPOSITORY 288 D.A. Kamorny, A.V. Safonov, I.M. Proshin, E.A. Tyupina, K.E. German, O.A. Gorbunova STABILIZATION OF TECHNETIUM BY ORGANIC MODIFIERS FOR LONG-TERM STORAGE IN A CEMENT COMPOUND 297 A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF 99Tc ON THE SHUNGITE 312 A.Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. 99Tc SORPTION ON THE CARBONE MATERIALS (LIDITE AND SHALE) 314 A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF 99Tc ON ACTIVATED CHARCOAL 315 A. Makarov, N. Andryshchenko, A. Safonov, E. Zakharova, E.V. Belova, K. German. SORPTION OF 99Tc ON NANODIAMONDS 316 A. Makarov, N. Andryushchenko, A. Safonov, E. Zakharova, K. German. SORPTION OF 99Tc ON TAUNITE 317 4. Re Hydrometallurgy - Chairs : I.D. Troshkina and Ya. Obruchnikova 318 V.N. Rychkov, A.O. Taukin, E.V. Kirillov, S.V. Kirillov, G.M. Bunkov, V.S. Semenishchev. THE STUDY OF SORPTION CONCENTRATION OF RHENIUM FROM ACIDIC SOLUTIONS 319 I.A. Lebedev, T.D. Batueva, N.B. Kondrashova, M.G. Scherban. SORPTION RHENIUM ON MESOPOROUS SILICAS MODIFIED WITH DIMETHYLHYDRAZIDE GROUPS 320 Yu.V. Sokolova, V.I. Shishkevich. EXTRACTION OF RHENIUM FROM RECYCLE SULFURIC ACID SOLUTION OF UNDERGROUND URANIUM LEACHING 321 I.P. Sandalov, V.I. Bogdanov. EXTRACTION OF PLATINUM AND RHENIUM FROM IRON COLLECTOR OBTAINED BY PLASMA FUSION METHOD 322 S.N. Rasulova, V.P. Guro, R.D. Allabergenov. METHOD FOR RE RECOVERY FROM THE TAILING DUMP OF RESEARCH-AND-PRODUCTION ASSOCIATION OF ALMALYK GMK JSC (FORMER UZKTZHM) 323 S.N. Rasulova, V.P. Guro, R.D. Allabergenov. METHOD FOR RECOVERY RHENIUM FROM THE TAILING DUMP OF RESEARCH-AND- PRODUCTION ASSOCIATION OF ALMALYK GMK JSC (FORMER UZKTZHM) 331 K.Ya. Agapova, S.K. Kilibayeva, A.N. Zagorodnyaya, A.S. Sharipova, Z.S. Abisheva, Zh.E. Yakhiyayeva. RECOVERY OF RHENIUM FROM THE WASTES OF HEAT-RESISTANT NICKEL ALLOYS 333 S.K. Kilibayeva, L.Ya. Agapova, Z.S. Abisheva, Zh.E. Yakhiyayev, G.S. Ruzakhunova, A.V. Panichkin . ELECTROLYTIC DEPOSITION OF RHENIUM-CONTAINING ALLOYS FROM AQUEOUS SOLUTIONS OF ELECTROLYTES 334 S.A. Temerov, S.I. Plechkina, M.P. Loseva. ON THE PRODUCTION OF RHENIUM ACID 335 V. Korovin, Yu. Pogorelov, A. Zontov, L. Zontova. EQUILIBRIUM AND KINETICS OF RHENIUM SORPTION FROM SULPHURIC SOLUTIONS WITH AMR ANIONITE 336 N.A. Bektenov, E.E. Ergozhin, L.K. Ybraimzhanova, B.K. Masalimova. STUDY OF THE SORPTION CAPACITY OF RHENIUM IONS BY NEW MODIFIED ION EXCHANGERS 337 S.V. Zakharyan, E.I. Gedgagov, A.B. Yun. NEW POSSIBILITIES OF SORPTION PROCESSES WITH THE USE OF FINELY DISPERSED FORMS OF ION EXCHANGE RESINS (ON THE EXAMPLE OF RHENIUM RECOVERY) 343
  • 9. 9 L.M. Gapoyan, A.A. Blokhin, M.A. Mikhaylenko, Yu V. Murashkin. EVALUATION OF USING ZWITTERIONIC ION EXCHANGE RESINS FOR RECOVERY OF RHENIUM I.D. Troshkina, N.V. Balanovskyi, Ya.A. Obruchnikova, F.Ya. Vatsura, I.A. Vanin, O.A. Zhukova, K.A. Ratchina. RECOVERY OF RHENIUM BY AMINE-CONTAINED SORBENTS I.D. Troshkina, N.B. Balanovskiy, Ya.A. Obruchnikova, V.A. Vanin, F.Ya. Vatsura. SORPTION OF RHENIUM FROM SULFURIC ACID SOLUTIONS OF POLYMETALLIC ORES LEACHING I.D. Troshkina, W.M. Aung, M.V. Marchenko, O.A. Zhukova, Pyae Phyo Aung, V.M. Muchin RHENIUM ADSORPTION FROM SULFURIC ACID SOLUTIONS BY ACTIVE COALS Kasikov A.G., Dvornikova A.M., Areshina N.S. RHENIUM AND RUTHENIUM RECOVERY FROM SUBSTANDARD WASTE OF NICKEL-BASED LAST GENERATION SUPERALLOYS Kasikov A.G., Shchelokova E.A., Dvornikova A.M. NEW SOLVENT IMPREGNATED SORBENTS FOR RHENIUM RECOVERY FROM ACID MEDIA, BASED ON MESAPOROUS SILICA OBTAINED BY COPPER-NICKEL WASTE PROCESSING 355 356 357 381 382 384 5. Tc and Re in Nuclear Medicine - Chairs : G.E. Kodina and T. Gerber A.O. Malysheva, G.E. Kodina, O.Е. Klementyeva, N.A. Taratonenkova, E.A. Lyamtseva, N.A. Konstantinov, M.V. Zhukova. BEHAVIOR OF THE THERAPEUTIC RADIOPHARMACEUTICALS WITH RHENIUM-188 ELUATES OF HIGH VOLUME ACTIVITY A. Avetisyan, R. Dallakyan, I. Kerobyan CYCLOTRON BASED TECHNETIUM-99M AND RHENIUM-186 PRODUCTION TECHNOLOGY DEVELOPMENT AT YEREVAN PHYSICS INSTITUTE Tsugio Yokoyama, Masaki Ozawa. PRODUCTION OF LOW SPECIFIC RADIOACTIVITY RHENIUM IN FAST REACTORS S.A. Dorovatovskiy, A.V. Zverev, V.M. Petriev, V.G. Skvortsov. RESEARCH AND DEVELOPMENT OF INNOVATIVE RADIOPHARMACEUTICALS BASED ON THERAPEUTIC RADIONUCLIDE 188Re T. Ohtsuki, S. Sekimoto, T. Tadokoro, Y. Kani, Y. Ueno. Mo-99/Tc-99m PRODUCTION USING AN ELECTRON LINEAR ACCELERATOR Yu.А. Naumova, А.Е. Miroslavov, А.А. Lumpov, G.V. Sidorenko. OXIDATIVE DECRABONYLATION OF TECHNETIUM PENTACARBONYL IODIDE IN THE PRESENCE OF IRON(III) А.А. Кuznetsov, N.A. Nerozin, A.A. Semenova, D.V. Stepchenkov, E.V. Sulim “GREN-1” 188W/188Re GENERATOR. CURRENT STATUS R.R. Kumar, D.K. Dhawan, V.D. Chadha. 99mTc LABELED N-ACETYL NEURAMINIC ACID AS A NEW RADIOTRACER FOR RENAL IMAGING, PREPARATION AND PRECLINICAL STUDY Yu.A. Mitrofanov, A.Ya. Maruk, M. Behe. LABELING OF EXENDIN DERIVATE WITH 99mTc G.E. Kodina, A.O. Malysheva. HISTORY AND PERSPECTIVES OF RHENIUM-188 APPLICATION IN NUCLEAR MEDICINE Toktosinov Mansur Yangivaevich. PROSPECTS FOR THE USE OF Re-188. O.E. Klementieva, A.B. Bruskin, V.B. Bubenshchikov, M.G. Rakhimov, A.Ya. Maruk, A.S. Lunev, D.N. Tumanova, K.A. Luneva, M.G. Gezina, G.E. Kodina. NEW RADIOPHAR- MACEUTICAL BASED ON α-MSH FRAGMENT FOR DIAGNOSIS OF MELANOMA B.L. Garashchenko, R.Y. Yakovlev, K.E. German, B.F. Myasoedov SURFACE-MODIFIED NANODIAMONDS AS CARRIERS FOR 99mTc M.A. Klenner, G. Pascali, M. Massi, G. Ciancaleoni, B.H. Fraser RHENIUM ENHANCED 386 387 388 424 428 429 430 442 450 451 452 465 471 472
  • 10. 10 RADIOPHARMACEUTICAL PRODUCTION OF FLUORINE-18 LABELLED BIDENTATE LIGANDS A. Avetisyan, R. Dallakyan, G. Elbakyan, N. Dobrovolski, A. Manoukyan, A. Melkonyan CYCLOTRON BASED TECHNETIUM-99M PRODUCTION TECHNOLOGY DEVELOPMENT AT YEREVAN PHYSICS INSTITUTE K. Nagata, N. Otsuji, S. Akagi, S. Fujii, N. Kitamura, T. Yoshimura. SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF TRICYANIDONITRIDORHENIUM(V) COMPLEXES WITH BIPYRIDINE DERIVATIVES A.T. Filyanin, M.P. Zykov, G.E. Kodina, A.Yu.Tsivadze, O.A. Filyanin. ON THE INDUSTRIAL PRODUCTION OF PHARMACEUTICAL GRADE 99MTc AND 188Re RADIONUCLIDES ON THE CENTRIFUGAL SEMICOUNTERCURRENT SPINNING GENERATOR M.Yu. Petrov, K.E. German, A.V. Afanasiev, O. I. Slyusar, V. G. Taktarov, V.M. Petriev, V.G. Skvortsov, A.Ya. Maruk, Ya.A. Obruchnikova, O.Vlasova, S.N. Ryagin. REVIEW OF PROSPECTIVE RADIOPHARMACEUTICALS BASED ON PROSTATE-SPECIFIC INHIBITORS OF MEMBRANE ANTIGEN FOR DIAGNOSTICS AND THERAPY OF METASTATIC PROSTATE CANCER J.S. McCloy, C. Soderquist, J. Weaver, Jason Lonergan. SPECTROSCOPIC STUDIES OF ALKALI PERTECHNETATES AND PERTECHNIC ACID. Supplimentary data A.A. Kozar’, V.F. Peretrukhin, K.E. German . INFLUENCE OF THE NEUTRON SPECTRUM IN THE 99Тс TRANSMUTATION CAMPAIGN ONTO THE ISOTOPE COMPOSITION OF ARTIFICIAL RUTHENIUM A.A. Kozar’. ESTIMATION OF GRAIN SIZES OF STUFF OF HETEROGENEOUS TRANSMUTATION TECHNETIUM TARGETS 486 488 490 491 494 496 511 515
  • 11. 11 International Advisory Committee Chairman – K.E. German Chairman – I.D. Troshkina U. Abram V. Gaona R. Alberto M. Chotkowski K. Czerwinski F. Poineau M. Fattahi Ph. Moisy T.I.A. Gerber M.S. Grigoriev G.E. Kodina M. Ozawa T. Suzuki T. Ohtsuki H. Sakurai T. Yoshimura A. Sattelberger Ya. Obruchnikova G. Thorogood A.Yu. Tsivadze S. Wang Y. Wei W. Wu Y. Taihong Germany Germany Switzerland Poland USA France/USA France France SouthAfrica Russia Russia Japan Japan Japan Japan Japan USA Russia Australia Russia China China China China