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Richard Teague, Dmitry Semenov, Stephane Guilloteau,
Thomas Henning, Anne Dutrey & the CID Collaboration
Disk Diagnostics
with Deuteration
DSS  Consor)um,  SDSS,  NASA/ESA,  Akira  Fujii
DCO+
in DM Tau
Hydrosta)c  equilibrium  leads  to  a  strongly  stra)fied  structure.
Molecular  line  emission  will  probe  the  intermediate  layer.
Henning  &  Semenov  (2013)
RD  is  the  ra)o  of  a  deuterated  isotopologue  
to  the  non-­‐deuterated  isotopologue.
In  protoplanetary  disks  HCO+  is  a  readily  observable  molecule.  
It  allows  for  comparisons  with  other  epochs  in  the  evolu)on  of  molecular  gas.
We  imaged  with  the  Plateau  de  Bure  Interferometer  
HCO+  J=(3-­‐2),  (1-­‐0)  and  DCO+  J=(3-­‐2)  emission  in  DM  Tau.
a  hRp://www.iram.fr/IRAMFR/GILDAS/
Obtained  a  ~1.5’’  spaCal  and  ~0.2  km  s-­‐1  velocity  resoluCon.  
Data  was  reduced  with  the  standard  MAPPINGa  soXware.
Column  densi)es  of  HCO+  and  DCO+  were  extracted  using  DISKFITa.  
Describes  physical  properCes  of  the  disk  with  power  laws.  
Assumes  LTE  and  fits  the  visibili)es  in  the  uv-­‐plane.
Column  DensiCes RD  =  N(DCO+)  /  N(HCO+)
RD  varies  between  0.1  and  0.2.  
!
Computa)onal  model  used  similar  physical  structure  of  D’Alessio  et  al.  (1999).  
Chemical  model  run  with  ALCHEMICa  which  includes  an  
extended  deuterium  networkb  and  ortho/para  chemistryc.
!
a  Semenov  et  al.  (2010),  b  Albertsson  et  al.  (2013),  c  Albertsson  et  al.  (2014a)
Column  densi)es  were  found  to  agree  well  with  observaConally  derived  values.  
RD  clearly  evolves  with  Cme,  and  also  fits  qualita)vely  well  with  observa)ons…
Column  DensiCes RD  =  N(DCO+)  /  N(HCO+)
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
What  controls  the  abundances  of  HCO+  and  DCO+?  
An  incredibly  simplified  chemical  network  for  the  molecular  layer…
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
Cold  region  chemistry  driven  by  ion  -­‐  neutral  reac)ons.  
Requires  ini)al  ionizaCon  of  H2  to  kick  start  chemistry.
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
…deuterium  fracConaCon  will  occur  in  cold  environments…
(here  we  neglect  the  doubly  and  triply  deuterated  isotopologues.)
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
…due  to  the  energy  barrier  which  deters  backwards  reac)ons.
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
Assuming  CO  is  present  in  the  gas  phase  and  has  not  frozen  out…
(or  other  forms  of  deple)on)
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
…fast  ion-­‐neutral  reac)ons  with  CO  transfer  this  
deuterium  ra)o  to  HCO+  and  DCO+.
H2 H2
  H2D+
H2
  HCO+
  DCO+
  H3
+
  H2
+
  H2
CO
HD
H2
H2
ice
ice
CO
Ioniza)on,  frac)ona)on  efficiency  and  CO  deple)on  all

affect  the  measured  RD  values.
100
R, AU
11.5
12.0
12.5
13.0
13.5
14.0
14.5
Log10[N(X),cm-2
]
HCO+
DCO+
Best-fit
LX=1031
erg/s
100
R, AU
11.5
12.0
12.5
13.0
13.5
14.0
14.5
Log10[N(X),cm-2
]
HCO+
DCO+
Best-fit
LX=3x1028
erg/s
Reduced  X-­‐RaysIncreased  X-­‐Rays
LX  =    3x1028  erg  s-­‐1LX  =  1031  erg  s-­‐1
Solid  lines  are  the  HCO+  column  densi)es  and  the  dashed  DCO+
Comparisons  between  the  best  fit  model  
and  a  model  with  an  altered  physical  parameter.
X-­‐rays  are  the  dominant  ionizaCon  source  where  HCO+  is  present.  
High  ioniza)on  can  suppress  frac)ona)on  by  increasing  ortho-­‐H2  abundances.
Solid  lines  are  the  HCO+  column  densi)es  and  the  dashed  DCO+
100
R, AU
11.5
12.0
12.5
13.0
13.5
14.0
14.5
Log10[N(X),cm-2
]
HCO+
DCO+
Best-fit
no IS UV
100
R, AU
11.5
12.0
12.5
13.0
13.5
14.0
14.5
Log10[N(X),cm-2
]
HCO+
DCO+
Best-fit
agr=1um
No  Interstellar  UV Increased  Grain  Sizes
a  =  1  um
Comparisons  between  the  best  fit  model  
and  a  model  with  an  altered  physical  parameter.
CO  deple)on  is  sensi)ve  to  UV  driven  photodesorpCon  of  heavy  ices  
and  efficiency  of  CO  freeze  out  onto  grains.
Conclusions
• In  DM  Tau  RD  ~  0.1  -­‐  0.2  between  50  and  550  au.

Consistent  with  con)nued  gaseous  processing  and  values  found  in  other  
disks.  
!
• X-­‐rays  are  the  dominant  ionizaCon  source  in  the  molecular  layer.

Different  depths  of  HCO+  and  DCO+  layers  result  in  the  two  being  affected  
by  changes  in  X-­‐ray  luminosity  differently  .  
!
• DepleCon  of  CO  strongly  affects  the  local  RD.

CO  deple)on  is  sensi)ve  to  the  freeze  out  efficiency  and  the  level  of  UV  
driven  photodesorp)on.


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Disk Diagnostics with Deuteration: Observations of DCO+ in DM Tau

  • 1. Richard Teague, Dmitry Semenov, Stephane Guilloteau, Thomas Henning, Anne Dutrey & the CID Collaboration Disk Diagnostics with Deuteration
  • 2. DSS  Consor)um,  SDSS,  NASA/ESA,  Akira  Fujii DCO+ in DM Tau
  • 3. Hydrosta)c  equilibrium  leads  to  a  strongly  stra)fied  structure. Molecular  line  emission  will  probe  the  intermediate  layer. Henning  &  Semenov  (2013)
  • 4. RD  is  the  ra)o  of  a  deuterated  isotopologue   to  the  non-­‐deuterated  isotopologue. In  protoplanetary  disks  HCO+  is  a  readily  observable  molecule.   It  allows  for  comparisons  with  other  epochs  in  the  evolu)on  of  molecular  gas.
  • 5. We  imaged  with  the  Plateau  de  Bure  Interferometer   HCO+  J=(3-­‐2),  (1-­‐0)  and  DCO+  J=(3-­‐2)  emission  in  DM  Tau. a  hRp://www.iram.fr/IRAMFR/GILDAS/ Obtained  a  ~1.5’’  spaCal  and  ~0.2  km  s-­‐1  velocity  resoluCon.   Data  was  reduced  with  the  standard  MAPPINGa  soXware.
  • 6. Column  densi)es  of  HCO+  and  DCO+  were  extracted  using  DISKFITa.   Describes  physical  properCes  of  the  disk  with  power  laws.   Assumes  LTE  and  fits  the  visibili)es  in  the  uv-­‐plane.
  • 7. Column  DensiCes RD  =  N(DCO+)  /  N(HCO+) RD  varies  between  0.1  and  0.2.   ! Computa)onal  model  used  similar  physical  structure  of  D’Alessio  et  al.  (1999).   Chemical  model  run  with  ALCHEMICa  which  includes  an   extended  deuterium  networkb  and  ortho/para  chemistryc. ! a  Semenov  et  al.  (2010),  b  Albertsson  et  al.  (2013),  c  Albertsson  et  al.  (2014a)
  • 8. Column  densi)es  were  found  to  agree  well  with  observaConally  derived  values.   RD  clearly  evolves  with  Cme,  and  also  fits  qualita)vely  well  with  observa)ons… Column  DensiCes RD  =  N(DCO+)  /  N(HCO+)
  • 9. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO What  controls  the  abundances  of  HCO+  and  DCO+?   An  incredibly  simplified  chemical  network  for  the  molecular  layer…
  • 10. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO Cold  region  chemistry  driven  by  ion  -­‐  neutral  reac)ons.   Requires  ini)al  ionizaCon  of  H2  to  kick  start  chemistry.
  • 11. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO …deuterium  fracConaCon  will  occur  in  cold  environments… (here  we  neglect  the  doubly  and  triply  deuterated  isotopologues.)
  • 12. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO …due  to  the  energy  barrier  which  deters  backwards  reac)ons.
  • 13. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO Assuming  CO  is  present  in  the  gas  phase  and  has  not  frozen  out… (or  other  forms  of  deple)on)
  • 14. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO …fast  ion-­‐neutral  reac)ons  with  CO  transfer  this   deuterium  ra)o  to  HCO+  and  DCO+.
  • 15. H2 H2  H2D+ H2  HCO+  DCO+  H3 +  H2 +  H2 CO HD H2 H2 ice ice CO Ioniza)on,  frac)ona)on  efficiency  and  CO  deple)on  all
 affect  the  measured  RD  values.
  • 16. 100 R, AU 11.5 12.0 12.5 13.0 13.5 14.0 14.5 Log10[N(X),cm-2 ] HCO+ DCO+ Best-fit LX=1031 erg/s 100 R, AU 11.5 12.0 12.5 13.0 13.5 14.0 14.5 Log10[N(X),cm-2 ] HCO+ DCO+ Best-fit LX=3x1028 erg/s Reduced  X-­‐RaysIncreased  X-­‐Rays LX  =    3x1028  erg  s-­‐1LX  =  1031  erg  s-­‐1 Solid  lines  are  the  HCO+  column  densi)es  and  the  dashed  DCO+ Comparisons  between  the  best  fit  model   and  a  model  with  an  altered  physical  parameter. X-­‐rays  are  the  dominant  ionizaCon  source  where  HCO+  is  present.   High  ioniza)on  can  suppress  frac)ona)on  by  increasing  ortho-­‐H2  abundances.
  • 17. Solid  lines  are  the  HCO+  column  densi)es  and  the  dashed  DCO+ 100 R, AU 11.5 12.0 12.5 13.0 13.5 14.0 14.5 Log10[N(X),cm-2 ] HCO+ DCO+ Best-fit no IS UV 100 R, AU 11.5 12.0 12.5 13.0 13.5 14.0 14.5 Log10[N(X),cm-2 ] HCO+ DCO+ Best-fit agr=1um No  Interstellar  UV Increased  Grain  Sizes a  =  1  um Comparisons  between  the  best  fit  model   and  a  model  with  an  altered  physical  parameter. CO  deple)on  is  sensi)ve  to  UV  driven  photodesorpCon  of  heavy  ices   and  efficiency  of  CO  freeze  out  onto  grains.
  • 18. Conclusions • In  DM  Tau  RD  ~  0.1  -­‐  0.2  between  50  and  550  au.
 Consistent  with  con)nued  gaseous  processing  and  values  found  in  other   disks.   ! • X-­‐rays  are  the  dominant  ionizaCon  source  in  the  molecular  layer.
 Different  depths  of  HCO+  and  DCO+  layers  result  in  the  two  being  affected   by  changes  in  X-­‐ray  luminosity  differently  .   ! • DepleCon  of  CO  strongly  affects  the  local  RD.
 CO  deple)on  is  sensi)ve  to  the  freeze  out  efficiency  and  the  level  of  UV   driven  photodesorp)on.