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estion 5 of 34 Sapling Learning Which is the correct name of the following molecule? O 3,6-
diethyl-5-isobutyl-8-rnethylinonane O 4.7-diethyl-5-isobutyl 2 methyinonane 3,6-diethyl-5-
isopropyl-8-methylinonane 2.3-dimethyl-5-butyl-8-methylnonane
Solution
Basic IUPAC rules for alkanes
Step 1 The longest continuous chain of carbon atoms is the parent chain. If there is no longest
chain because two or more chains are the same longest length, then the parent chain is defined as
the one with the most branches. (The idea here is to keep the name simpler. More branches
numbered from the parent chain means fewer parentheses needed later.)
Carbon atoms connected to the parent chain but not part of it are parts of branches. To avoid
ambiguity, branches are numbered based on the carbon number of the parent chain at the point of
attachment to the parent chain.
Step 2 The general idea in naming organic compounds is to always aim for the smallest numbers
possible. Whenever two or more possibilities exist, which is usually the case, because there are
two ends you can start numbering from on all acyclic chains, "smallest numbers" means
smallest at the first difference.
Step 3 Once all the numbers for the branches are determined, the branches are named using -yl,
and ordered alphabetically. If branches themselves are branched, then the complete name of the
branch (with numbers) must be determined at this time. It is the complete name of the branch
which is alphabetized.
Step 4 Finally, when more than one of the same branch is present, the prefixes di, tri, tetra, etc.
for simple branches and bis, tris, tetrakis, etc. for branches containing numbers, are added just
after the numbers locating the branch on the parent chain. The name is constructed by separating
numbers with commas and adding hyphens before and after sets of numbers so that they don't
run into words. Branches with numbers are set off with parentheses so that it is clear that the
numbers only refer to that branch. Other than that, there is no punctuation and there are no
spaces in the names.
Hence option (b) is correct
4,7 di methyl 5 isobutyl 2 methyl nonane

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estion 5 of 34 Sapling Learning Which is the correct name of the fo.pdf

  • 1. estion 5 of 34 Sapling Learning Which is the correct name of the following molecule? O 3,6- diethyl-5-isobutyl-8-rnethylinonane O 4.7-diethyl-5-isobutyl 2 methyinonane 3,6-diethyl-5- isopropyl-8-methylinonane 2.3-dimethyl-5-butyl-8-methylnonane Solution Basic IUPAC rules for alkanes Step 1 The longest continuous chain of carbon atoms is the parent chain. If there is no longest chain because two or more chains are the same longest length, then the parent chain is defined as the one with the most branches. (The idea here is to keep the name simpler. More branches numbered from the parent chain means fewer parentheses needed later.) Carbon atoms connected to the parent chain but not part of it are parts of branches. To avoid ambiguity, branches are numbered based on the carbon number of the parent chain at the point of attachment to the parent chain. Step 2 The general idea in naming organic compounds is to always aim for the smallest numbers possible. Whenever two or more possibilities exist, which is usually the case, because there are two ends you can start numbering from on all acyclic chains, "smallest numbers" means smallest at the first difference. Step 3 Once all the numbers for the branches are determined, the branches are named using -yl, and ordered alphabetically. If branches themselves are branched, then the complete name of the branch (with numbers) must be determined at this time. It is the complete name of the branch which is alphabetized. Step 4 Finally, when more than one of the same branch is present, the prefixes di, tri, tetra, etc. for simple branches and bis, tris, tetrakis, etc. for branches containing numbers, are added just after the numbers locating the branch on the parent chain. The name is constructed by separating numbers with commas and adding hyphens before and after sets of numbers so that they don't run into words. Branches with numbers are set off with parentheses so that it is clear that the numbers only refer to that branch. Other than that, there is no punctuation and there are no spaces in the names. Hence option (b) is correct 4,7 di methyl 5 isobutyl 2 methyl nonane