3. Polymers
Poly means ‘Many’ & ‘Mers’ means
‘Parts’
Polymer built of several repeating
units(Monomer)
Monomer – small molecules
Polymer is made up of thousands of
monomers jointed together to form
large molecule.
Plastics – Organic polymer
4. Polymerization process
A Polymer is made up of linking thousands
of monomer and thus obtaining large
molecule is called Polymerization process
Additives – Plasticizers (liquid form) –
Water, Organic solvents & resins
Catalyst – Promote faster & complete
Polymerization
Dyes – Impart desired colour
Initiators – Initiate the reaction (H2O2)
Hydrogen peroxide
5. Plastics
Can be moulded into required shape
with the help of pressure or heat or
both heat and pressure
Resin – liquid form of plastics, also raw
material for making plastics
Types of resin: acrylic resin,
Polyethylene resin & amino resin –
Produced by polymerization process
Catalysts, Binders & Lubricants added
with resin to form plastics
6. Modifiers – To improve the mechanical
properties of plastics
Lubricants – To reduce friction during processing ,
Avoid sticking to mould walls(Oils, Soaps and
waxes)
Solvents – Dissolve fillers or Plasticizers & Allow
the processing in fluid state(Alcohol)
Fillers – Mica, Cloth fiber
Elastomers – To enhance the elastic properties
7. Properties of Plastics
Elongation
Heat resistance
High rigidity
Surface hardness
High viscosity
Density
Chemical resistance
8. Thermosetting Plastics
Thermosetting - Plastics which are hardened by
heat effecting non reversible chemical change .
Molecules are formed by condensation
polymerization process.
All the molecules have three dimensional
network and very strong binding force between
molecules
Bakelite, Polyester resin, Epoxy resin(Araldite),
Silicones, Urea formaldehyde(Amino resin) &
Alkyds
9. Thermo Plastics
Have separate long and large size molecule arranged
side by side
When thermoplastics are heated it becomes very soft
and rehardens on cooling
During heating the linear bonding links between
molecules are breakup and separated. Relinking takes
place on cooling and retains their hardness.
Cellulose nitrate – pen bodies, Table tennis balls, Frames
Ethyl cellulose – Jigs, Fixtures, hose nozzles
Cellulose acetate - Radio cabinets, steering wheels,
Insulating tapes
11. S.
No
Thermoplastics Thermosetting plastics
1 Softened by heating Cannot be softened by
heating
2 Structure is made of linear
chain molecule
Structure is made of cross-
linked molecule
3 Produced by addition
polymerization process
Produced by condensation
polymerization process
4 Can be reproduced by
heating and cooling
Cannot be reproduced
5 When the temp increases
the plasticity also
increases
Plasticity is stable at high
temperature
6 Softer and less strong Harder and strong
7 Scrap can be reused Scrap can not be reused