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International Journal of Trend in Scientific Research and Development (IJTSRD)
Volume 6 Issue 4, May-June 2022 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1282
Physico-Chemical Properties of Light Greywater for
Residential Society in Badlapur, Thane District Maharashtra
Suresh D. Suryawanshi1
, Prof. Padmakar J Salunke2
, Prof. Shreeshail Panchu Gaikwad3
1
M.E. Student, 2
Associate Professor, 3
Assistant Professor,
1, 2, 3
SES Yadavrao Tasgaonkar College of Engineering & Management, Karjat, Maharashtra, India
ABSTRACT
Water plays a vital role and one of the basic necessities of human
being. As per the report from the United Nations has estimated that in
the year 2025, about 2.6 billion people will be facing water scarcity
problems which mean more than half of the population will be
affected by water scarcity and even it will not be exerted to say that
third world war may occur due to water. [1] Water dearth has turn out
to be one of the most critical problems of the current era. Some
experts have also suggested that water shortage will turn out to be
more severe than oil dearth in the future. The need for increased
water requirement for the growing population in the new century is
generally assumed, without considering whether available water
resources could meet these needs in a sustainable manner.
The question about from where the extra water is to come, has led to
this study. It is necessary to learn physico-chemical properties of
contamination of water to understand its reuse in a residential
building. It is possible to intercept this grey water, at the household
level, treat it so that it can be recycled for using other purposes. In
this report we are going to study the domestic light grey water i.e.
washing clothes, wash basin, bathroom from day to day life of case
study of residential building Mohan Willows in Bhosale Nagar,
Shirgaon, Balapur. The samples were analysed for the physical and
chemical characteristics of the water. The parameters examined were:
pH, Turbidity, TDS, COD, BOD, Oil & Grease, Conductivity, Total
Hardness, Calcium, Magnesium, Alkanity, Sulphate, Iron, Lead,
Zinc, DO and Nitrate. The research showed that the quality of light
greywater with respect to COD, BOD, turbidity and total hardness
requires adequate treatment prior to household reuse. With regard to
the trace and heavy metal contents, no further treatment is required.
KEYWORDS: Physio-Chemical Parameters, Grey Water, Water
Scarcity, Residential Building
How to cite this paper: Suresh D.
Suryawanshi | Prof. Padmakar J Salunke
| Prof. Shreeshail Panchu Gaikwad
"Physico-Chemical Properties of Light
Greywater for Residential Society in
Badlapur, Thane District Maharashtra"
Published in
International Journal
of Trend in
Scientific Research
and Development
(ijtsrd), ISSN: 2456-
6470, Volume-6 |
Issue-4, June 2022,
pp.1282-1288, URL:
www.ijtsrd.com/papers/ijtsrd50260.pdf
Copyright © 2022 by author(s) and
International Journal of Trend in
Scientific Research and Development
Journal. This is an
Open Access article
distributed under the
terms of the Creative Commons
Attribution License (CC BY 4.0)
(http://creativecommons.org/licenses/by/4.0)
1. INTRODUCTION
1.1. General
Around one-fifth of the world’s population, belongs
to the areas of physical scarcity of water occurs (i.e.
the countries where water in scarcity form) and
almost one-fourth of the world’s population, faces
economic water lack (i.e., the countries that lack the
necessary infrastructure to obtain water from rivers
and aquifers). The world population has been rising at
a pace of about 1% per year, similarly other infusing
factors like economic growth, changing lifestyle
patterns (due to pandemic diseases like covid-19) will
continue to grow, and resulting in water scarcity in
various parts of the world. [2]
Residential water consumption approximatelymakes
up 10% of overall water consumption, preceded only
by water consumed by agricultural irrigation and
water consumption by industries. Building industry
practitioners like Designers and Engineers have
begun to pay consideration to scheming and
controlling the ecological damage due to their
activities. Particularly civil engineers have a unique
IJTSRD50260
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1283
opportunity to reduce ecological impact through
treating the greywater at the course only.
Domestic wastewater can contain physical, chemical
and biological pollutants. Broadly we can classify
waste water as blackwater and greywater. Black water
can contain feces, urine, water and toilet paper from
flush toilets. Black water is distinguished from grey
water, which comes from kitchen sinks, bathrooms,
washing machines, and other kitchen appliances apart
from toilets. Greywater can be further categorized
based on the source of waste like light greywater and
dark grey water. In the recent past, there is
comparatively increased awareness among the
governments and bodies dealing with water
management to address the challenges related to
water security. Measures to reduce water usage
through increased awareness, installation of rainwater
harvesting and grey water (GW) treatment systems
are seen as promising solutions, especially in
developing countries that are more vulnerable to
water scarcity like India. Water is an essential part of
human’s life. In water shortages, three key methods:
water conservation, desalination and recycling could
be considered. Due to lower costs and possibility of
wastewater treatment in waste production site, water
recycling is much better than the other two methods.
Greywater reuse is increasingly emerging as an
integral part of water demand management. [3, 4]
1.2. Aim and Objective
Aim: “The ultimate aim of this work is to
systematically understand the physicochemical
parameters of light grey water generated from
bathroom, wash basin & washing machine and its
scope of reuse for a residential building”.
Objective: The research objectives for execution of
thesis are as follows:
1. To study and understand physico-chemical
properties of light grey water of case study
building.
2. To study scope of reuse of light greywater in case
study building.
2. LITERATURE REVIEW
A literature review of scholarly articles, books, dissertations, conference proceedings and other resources which
are relevant to the study of light greywater effluent, carried out to set the background on what has been explored
on the topic so far. An extensive literature review provides background information on current knowledge
related to the research topic.
Table No. 1: Characteristics of Effluent from Various Research Paper
Sr.
No.
Paper
Year of
Publication
Remarks
Characteristics of
Laundry Effluent
Value
1.
Commercial Laundry Water
Characterization by J. K. Braga and M. B.
A. Varesche
2015
pH 5.6
Total Alkalinity 25.9
COD 1710
TSS 80
Nitrate 8.4
Nitrite 2.1
Sulphate 21.1
Sulphide 0.2
2.
Characterization of domestic gray water
from point source to determine the potential
for urban residential reuse by Golda A.
Edwin Et. al
2017
pH 9.1
EC 641.6
Hardness 721
BOD 5 186.5
COD 1545.8
DO N.D
TS 586
TSS 141.2
Nitrate 0.3
Nitrite 0.2
3.
Study of physico-chemical characteristics of
domestic Wastewater in Vishnupuri,
Nanded, India by Sonune NA Et. al
2019
pH 7 – 8
BOD 56 – 96
COD 180 – 300
Ammonical Nitrogen 129 – 146
Nitrate 74 – 181
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1284
Phosphate 0.4 – 2.1
TDS 1228 – 1440
TSS 43 – 65.43
4
Qualitative Characterization of Greywater
from a Residential Complex in Bengaluru
City, Karnataka, India by Parameshwara
Murthy Et. al
2019
pH 5.7
BOD 35-138
COD 123 - 540
Nitrate 0.67 – 2.3
Phosphate 6 – 12.8
TDS 144 - 212
TSS 86 - 300
5
Characteristics and Treatment of Greywater
– A Review
2021
pH 7 -7.3
BOD 155 - 205
COD 386 - 587
Total N 6.6 – 10.4
Total P 0.69 – 1.1
TDS 215 - 279
TSS 153 - 259
3. METHODOLOGY
At preliminary level the research work will be carried out to identify the reusability of waste water in residential
building by studying to the physico-chemical parameters of light grey effluent and particularizing the scope of
reuse of same waste water for multipurpose uses like vechile washing, house & society cleaning, gardening etc.
4. CASE STUDY
4.1. Case Study Details
Primarily the data will be collected from case study that is residential building - Mohan Willows, Bhosale Nagar,
Shirgoan, Badlapur(E) . Data will be composed in the form of survey from all the households of the case study
building.
Building Name Mohan Willows Phase II, Ashwood building
Address Bopkhel, Vishrantwadi, Pune - 411031
Total No of flats 131
Data Collection Period April - May 2022
4.2. Case Study Location
Badlapur is a beautiful city in the district of Thane in the Indian state of Maharashtra. Badlapur is in proximity
with Mumbai, Navi Mumbai, Kalyan, Panvel and Karjat locations. The city is having decent infrastructural
amenities with beautiful natural view. The latitude and longitude of study area is 19°15'48.7"N, 73°23’13”E.
Figure No. 1: Showing Map of Case Study Area
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@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1285
4.3. Method Used for Analysis
Grey wastewater samples were characterised to determine the physical and chemical parameters. Some physical
test should be performed for testing of its physical appearance such as colour, pH, turbidity, TDS, while
chemical tests should be perform for its COD, BOD, Oil & Grease, Conductivity, Total Hardness, Calcium,
Magnesium, dissolved oxygen, alkalinity, Sulphate, Iron, Lead, Zinc, DO and Nitrate. All parameters were
analysed in accordance with standard method for the examination of water and wastewater.
Table No. 2: Physico-chemical Parameters and Methods Adopted for the Analysis
Sr. No. Analysis Parameters Method used
01 pH pH meter, IS: 3025 (part – 11 – 2): Reaff. 2012
02 COD IS: 3025 (part – 58): Reaff. 2014
03 BOD IS: 3025 (part – 44): Reaff. 2014
04 Oil and Grease IS: 3025 (part – 39- 5): Reaff. 2014
05 Turbidity Nephelometer, IS: 3025 (part – 10): Reaff. 2012
06 Conductivity Conductivity meter IS: 3025 (part – 14): Reaff. 2013
07 Total Dissolved Solids Gravimetric Method, IS: 3025 (part – 16): Reaff. 2012
08 Total Hardness Titrimetric Method, IS: 3025 (part – 21- 2): Reaff. 2014
09 Calcium Titrimetric Method, IS: 3025 (part – 40- 5): Reaff. 2014
10 Magnesium Titrimetric Method, IS: 3025 (part – 46- 6): Reaff. 2014
11 Total Alkalinity Titrimetric Method IS: 3025 (part – 23): Reaff. 2014
12 Sulphate Spectrometer IS: 3025 (part – 24- 4): Reaff. 2014
13 Iron Spectrometer IS: 3025 (part – 53- 6): Reaff. 2014
14 Lead Atomic Absorption, APHA 3111 - D
15 Zinc Atomic Absorption, APHA 3111 - D
16 Dissolved Oxygen Atomic Absorption IS: 3025 (part – 44): Reaff. 2003
17 Nitrate IS 3025 (Part 34): Reaff. 2014
4.4. Analysis of Physico-chemical Properties
The sample analyses of the collected greywater are represented in to the tabular form in following section.
Table No. 3: Physico-chemical analysis of light greywater effluent
Sr.
No
Analysis
Parameters
Samples
Mean
S1 S2 S3 S4 S5 S6 S7 S8 S9 S10
1 pH 9.6 8.4 8.4 9.3 9.6 9.1 9.1 9.2 8.8 8.9 9.0
2 COD 1512 1551 1769 1546 1431 1535.0 1572 1545 1493 1520 1547.4
3 BOD 154 167 167 189 193 181.6 187.5 181 189 184 179.3
4 Oil and Grease 3.6 3.9 ND ND ND ND ND 4.3 ND 6.3 1.8
5 Turbidity 118.7 111.5 98 100.5 77.1 106.3 81.7 105.1 110.6 169.5 107.9
6 Conductivity 700.6 533.4 551.2 687.2 687.7 641.2 624 631.9 695.1 647.5 640.0
7 TDS 701 712.5 722 728 740 708.0 710 722.4 751.1 732.3 722.7
8 Total Hardness 637 582 572 629 637 611.6 628 645 660 614 621.6
9 Calcium 3.9 3.9 3.2 3.7 4.2 4.1 4.1 4.2 4.9 4.1 4.0
10 Magnesium 1.5 1.1 0.9 1.32 1.6 1.3 1.3 1.41 1.6 1.6 1.4
11 Total Alkalinity 36.5 37 31.2 39.21 43 36.7 32.8 32.7 38.7 39.4 36.7
12 Sulphate 24.8 22.1 21.2 25.2 28.1 25.3 26.7 27.3 25.9 26.2 25.3
13 Iron ND 1.14 0.9 ND 0.77 0.8 1.2 1.12 ND 1.3 0.7
14 Lead <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003
15 Zinc ND <0.01 ND <0.01 <0.01 <0.01 <0.01 ND ND <0.01 <0.01
16 Dissolved Oxygen ND ND ND ND ND ND ND ND ND ND ND
17 Nitrate 0.1 0.2 0.1 0.3 0.2 0.2 0.1 0.2 0.2 0.2 0.2
The classical use of light greywater analysis of residential building is to produce information concerning the
water quality and scope of reuse of waste water. The waste water quality may yield information about the
environment through which it been reused and the treatment required for recycling the water. The
physicochemical composition of collected samples was statistically analyzed and presented in below section.
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1286
pH:-The pH value of water is very important
indicator of its quality. The pH values of water are
controlled by the amount of dissolved carbon dioxide,
carbonate and bicarbonates. pH is a term used
universally to express the intensity of the acid or
alkaline condition of a solution. The pH values of
water samples vary between 8.4 to 9.6 and some of
the values were not found within the limit prescribed
by BIS and WHO.
Chemical Oxygen Demand (COD):-Is an indicative
measure of the amount of oxygen that can be
consumed by reactions in a sample solution. It is
commonly expressed in mass of oxygen consumed
over volume of solution which in SI units is
milligrams per liter (mg/L). A COD test can be used
to easily quantify the amount of organics in water.
The concentration of COD varied from 1431 mg/l to
1769 mg/l. High COD value in effluent shows the
presence of oxidisable organic materials. High COD
concentration in samples indicates the presence of
organic contaminants in the water to a large extent.
Biochemical Oxygen Demand (BOD):-Also known
as biological oxygen demand is the amount of
dissolved oxygen needed by aerobic biological
organisms to break down organic material present in a
given water sample at certain temperature over a
specific time period. The BOD value in this study has
been expressed in milligrams of oxygen consumed
per liter of sample during 3 days of incubation at 27
°C. BOD concentration of these samples is ranged
from 154 mg/l to 193 mg/l. High BOD concentration
in effluent of waste water samples indicates the
presence of organic contaminants in the water.
Oil and Grease: - Oil and grease is also a major
threat to surface and ground water through infiltration
and seepage, thereby reducing the quality of the
affected resources. Oil and grease concentration is
ranged from 3.6 mg/l to 6.3 mg/l. In 60% of the
samples it is not detected and in remaining 40% it is
detected.
Turbidity: - Turbidity in water is the reduction of
transparency due to the presence of particulate matter
such as dirt or slit, finely divided organic matter etc.
These can cause light to be scattered or absorbed
rather than transmitted in straight lines through the
sample. The turbidity was due to the colloidal fine
dispersion of suspended solids. Some microorganism
might also contribute the turbidity. In present study
turbidity was found between 81.7 NTU to 169.5
NTU. The values were found with high values then
that prescribed by IS: 10500.
Conductivity: -The conductivity values varied from
533.4 µs/cm to 700.6 µs/cm in the samples analysed
from the respective case study. Electrical conductivity
gives an idea about the concentration of ions in
solution that determines the quality of water for reuse
purposes.
Total Dissolved Solids (TDS):- TDS is generally
considered not as a primary pollutant, but it is rather
used as an indication of aesthetic characteristics of
water and as an aggregate indicator of presence of a
broad array of chemical contaminants. Total
dissolved solids indicate the salinity behaviour of
grey water. Water containing more than500 mg/L of
TDS is not considered desirable for drinking water
supplies, but in unavoidable cases 1500 mg/L is also
allowed. The amount of Total Dissolved Solids varied
from 701 mg/lit to 751.1 mg/L in study of collected
samples.
Total Hardness:- Hardness is the property of water
which prevents the lather formation with soap and
increases the boiling points of water. Hardness is one
of the important properties of grey water from utility
point of view for different purposes. In grey water,
hardness is primarily due to presence of carbonates,
bicarbonates, sulphates and chlorides of calcium and
magnesium. For potable water the TH should be
limited up to 300 mg/L and maximum permissible
value is 600 mg/L. If the hardness is less than 50 mg/l
the water will be soft. If the hardness is from 50
mg/lit to 100 mg/l, the water will be moderate soft. If
the hardness is from 101 mg/lit to 200 mg/l and more
than 200 mg/l, the water will be slightly hard and
quite hard, respectively. In the analysis total hardness
values were ranged between 572 to 660 mg/L. Again
the study confirmed the excess quantity of hardness
creating cations and anions were present in and
around the grey water samples.
Calcium:- Calcium is the most abundant of the
alkaline earth minerals. Calcium is directly related to
hardness. The concentration up to 100 mg/l of
calcium is capable of forming scales in pipes and
boiler; fortunately it has no adverse physiological
manifestation on human system. Calcium is the third
most abundant metal in the earth’s crust. Excess of ca
ions causes concretions in the kidney and causes
irritation and pain in the urinary passages. The Ca
concentration was ranged between 3.2 mg/lit – 4.9
mg/lit and found below permissible limit.
Magnesium: - The WHO standards prescribed the
limit for the presence of magnesium in water is 50 –
100 mg/l. The concentration of magnesium ranged
between 0.9 to 1.6 mg/l. High concentration of Mg
can cause laxative effect in human being but in our
case it is within the permissible limit.
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1287
Total Alkalinity: - Alkalinity of water is its capacity
to neutralize a strong acid and it is normally due to
the presence of bicarbonate, carbonate and hydroxide
compound of calcium, sodium and potassium. Total
alkalinity values for all the investigated samples were
found in the range of 31.2 to 39.4 mg/l.
Sulphate: - Sulphate can be found in almost all
natural water. The origin of most sulphate compounds
is the oxidation of sulphite ores, the presence of
shales, or the industrial wastes. Sulphate is one of the
major dissolved components of rain. High
concentrations of sulphate in the water we drink can
have a laxative effect when combined with calcium
and magnesium, the two most common constituents
of hardness. The Sulphates concentration of grey
water samples ranged between is 21.2 mg/L to 28.1
mg/L and found within the prescribed limit.
Iron:- High iron concentrations generally cause a
bitter and astringent taste. It also clogs and pits pipes,
discolors clothes and plumbing fixtures and causes
scaling which encrusts pipes. The values for all the
investigated samples were found to be in the range of
0.77 mg/L to 1.3 mg/L which is within the
permissible limit of BIS and WHO (i.e. 5 mg/L).
Lead: - Lead is a toxic metal that is harmful to
human health; there is no safe level for lead exposure.
The degree of exposure depends on the concentration
of lead, route of exposure, current medical condition,
and age. It has been estimated that up to 20 % of the
total lead exposure in children can be attributed to a
waterborne route, i.e., consuming contaminated
water. The permissible limit BIS and WHO (i.e. 0.01
mg/L) for drinking and for recycle/reuse the
permissible limit is 0.5 mg/L. In the study area
analysis the lead has been detected in some sample bit
at very low value of less than 0.003 mg/L
Zinc: - Zinc is an essential mineral, including to
prenatal and postnatal development. Zinc deficiency
affects about two billion people in the developing
world and is associated with many diseases. In
children, deficiency causes growth retardation,
delayed sexual maturation, infection susceptibility,
and diarrhea. Consumption of excess zinc can cause
ataxia, lethargy and copper deficiency. In the study
area analysis the zinc concentration has been detected
in some sample bit at very low value of less than
0.001 mg/L.
Dissolved Oxygen: -Dissolved oxygen is important
parameter in water quality assessment and reflects the
physical and biological processes prevailing in water.
The DO values indicate the degree of pollution in
grey water. In the analysis all the samples, the
concentrations of DO is not at all detected.
Nitrate: - The excess levels can cause
methemoglobinemia, or "blue baby" disease.
Although nitrate levels that affect infants do not pose
a direct threat to older children and adults, they do
indicate the possible presence of other more serious
residential contaminants, such as bacteria or some
kinds of pesticides. The permissible limit for the
nitrate is 30 - 45 mg/L. The nitrates concentration of
groundwater samples were very low than the
permissible limit.
5. CONCLUSION
In case study building, the characteristics of light
greywater were evaluated using wastewater samples
(10 numbers) of case study building. The samples
were analysed for the physical and chemical
characteristics of the water. The parameters examined
were: pH, Turbidity, TDS, COD, BOD, Oil & Grease,
Conductivity, Total Hardness, Calcium, Magnesium,
Alkanity, Sulphate, Iron, Lead, Zinc, DO and Nitrate.
The research showed that the quality of light
greywater with respect to COD, BOD, turbidity and
total hardness requires adequate treatment prior to
household reuse. With regard to the trace and heavy
metal contents, no further treatment is required.
REFERENCES
[1] Shirazi MMA, Kargari A, Shiraz MJA (2012)
Direct contact membrane distillation for
seawater desalination. Desalin Water Treat 49:
368-375. Link: https://goo.gl/gvo7AS
[2] Nemerow Nelson Leonard, Dasgupta Avijit,
”Industrial and Hazardous Waste Treatment”,
van Nostrand Reinhold, 1991
[3] Dolnicar S, Schafer AI (2009) Desalinated
versus recycled water: public perceptions and
profi les of the accepters. J Environ Manag 90:
888-900. Link: https://goo.gl/r6RDEs
[4] Lu W, Leung AYT (2003) A preliminary study
on potential of developing shower/laundry
wastewater reclamation and reuse system.
Chemosphere 52: 1451-1459. Link:
https://goo.gl/2kYyQn.
[5] Shirazi MMA, Kargari A, Shiraz MJA (2012)
Direct contact membrane distillation for
seawater desalination. Desalin Water Treat 49:
368-375. Link: https://goo.gl/gvo7AS
[6] Dolnicar S, Schafer AI (2009) Desalinated
versus recycled water: public perceptions and
profi les of the accepters. J Environ Manag 90:
888-900. Link: https://goo.gl/r6RDEs
[7] Lu W, Leung AYT (2003) A preliminary study
on potential of developing shower/laundry
wastewater reclamation and reuse system.
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1288
Chemosphere 52: 1451-1459. Link:
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[8] Wendland C, Albold A (2010) Sustainable and
Cost-effective Wastewater Systems for Rural
and Peri-urban Communities up to 10,000
Population Equivalents: Guidance Paper.
Women in Europe for a Common Future
(WECF), Munch, Germany. Link:
https://goo.gl/Kv4Neq
[9] Pakula C, Stamminger R (2010) Electricity and
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[10] Ciabatti I, Cesaro F, Faralli L, Fatarella E,
Tognotti F (2009) Demonstration of a treatment
system for purifi cation and reuse of laundry
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https://goo.gl/wbyLPt
[11] Dolnicar S, Saunders C (2005) Marketing
recycled water: review of past studies and
research agenda. Integrated concepts in water
recycling. Wollongong: University of
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https://goo.gl/e2Xut2
[12] Ngo HH, Chuang H, Guo WS, Ho DP, Pham
TTN, et al. (2009) Resident’s strategy survey
on a new end use of recycled water in
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[13] Pham TTN, Ngo HH, Guo WS, Dang HPD,
Mainali B, et al. (2011) Response of
community to the public use of recycled water
for washing machine: a case study in Sydney,
Australia. Resource Conservation Recycling
55: 535-540. Link: https://goo.gl/utc1kc
[14] Janpoor F, Torabian A, Khatibikamal V (2011)
Treatment of laundry wastewater by
electrocoagulation. J Chem Technol Biotechnol
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[15] Berstein M (1986) Water and Wastewater: a
Guide for Industrial Launderers, first ed.
Institute of Industrial Launderers, Washington
DC, USA.

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Physico Chemical Properties of Light Greywater for Residential Society in Badlapur, Thane District Maharashtra

  • 1. International Journal of Trend in Scientific Research and Development (IJTSRD) Volume 6 Issue 4, May-June 2022 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1282 Physico-Chemical Properties of Light Greywater for Residential Society in Badlapur, Thane District Maharashtra Suresh D. Suryawanshi1 , Prof. Padmakar J Salunke2 , Prof. Shreeshail Panchu Gaikwad3 1 M.E. Student, 2 Associate Professor, 3 Assistant Professor, 1, 2, 3 SES Yadavrao Tasgaonkar College of Engineering & Management, Karjat, Maharashtra, India ABSTRACT Water plays a vital role and one of the basic necessities of human being. As per the report from the United Nations has estimated that in the year 2025, about 2.6 billion people will be facing water scarcity problems which mean more than half of the population will be affected by water scarcity and even it will not be exerted to say that third world war may occur due to water. [1] Water dearth has turn out to be one of the most critical problems of the current era. Some experts have also suggested that water shortage will turn out to be more severe than oil dearth in the future. The need for increased water requirement for the growing population in the new century is generally assumed, without considering whether available water resources could meet these needs in a sustainable manner. The question about from where the extra water is to come, has led to this study. It is necessary to learn physico-chemical properties of contamination of water to understand its reuse in a residential building. It is possible to intercept this grey water, at the household level, treat it so that it can be recycled for using other purposes. In this report we are going to study the domestic light grey water i.e. washing clothes, wash basin, bathroom from day to day life of case study of residential building Mohan Willows in Bhosale Nagar, Shirgaon, Balapur. The samples were analysed for the physical and chemical characteristics of the water. The parameters examined were: pH, Turbidity, TDS, COD, BOD, Oil & Grease, Conductivity, Total Hardness, Calcium, Magnesium, Alkanity, Sulphate, Iron, Lead, Zinc, DO and Nitrate. The research showed that the quality of light greywater with respect to COD, BOD, turbidity and total hardness requires adequate treatment prior to household reuse. With regard to the trace and heavy metal contents, no further treatment is required. KEYWORDS: Physio-Chemical Parameters, Grey Water, Water Scarcity, Residential Building How to cite this paper: Suresh D. Suryawanshi | Prof. Padmakar J Salunke | Prof. Shreeshail Panchu Gaikwad "Physico-Chemical Properties of Light Greywater for Residential Society in Badlapur, Thane District Maharashtra" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456- 6470, Volume-6 | Issue-4, June 2022, pp.1282-1288, URL: www.ijtsrd.com/papers/ijtsrd50260.pdf Copyright © 2022 by author(s) and International Journal of Trend in Scientific Research and Development Journal. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0) (http://creativecommons.org/licenses/by/4.0) 1. INTRODUCTION 1.1. General Around one-fifth of the world’s population, belongs to the areas of physical scarcity of water occurs (i.e. the countries where water in scarcity form) and almost one-fourth of the world’s population, faces economic water lack (i.e., the countries that lack the necessary infrastructure to obtain water from rivers and aquifers). The world population has been rising at a pace of about 1% per year, similarly other infusing factors like economic growth, changing lifestyle patterns (due to pandemic diseases like covid-19) will continue to grow, and resulting in water scarcity in various parts of the world. [2] Residential water consumption approximatelymakes up 10% of overall water consumption, preceded only by water consumed by agricultural irrigation and water consumption by industries. Building industry practitioners like Designers and Engineers have begun to pay consideration to scheming and controlling the ecological damage due to their activities. Particularly civil engineers have a unique IJTSRD50260
  • 2. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1283 opportunity to reduce ecological impact through treating the greywater at the course only. Domestic wastewater can contain physical, chemical and biological pollutants. Broadly we can classify waste water as blackwater and greywater. Black water can contain feces, urine, water and toilet paper from flush toilets. Black water is distinguished from grey water, which comes from kitchen sinks, bathrooms, washing machines, and other kitchen appliances apart from toilets. Greywater can be further categorized based on the source of waste like light greywater and dark grey water. In the recent past, there is comparatively increased awareness among the governments and bodies dealing with water management to address the challenges related to water security. Measures to reduce water usage through increased awareness, installation of rainwater harvesting and grey water (GW) treatment systems are seen as promising solutions, especially in developing countries that are more vulnerable to water scarcity like India. Water is an essential part of human’s life. In water shortages, three key methods: water conservation, desalination and recycling could be considered. Due to lower costs and possibility of wastewater treatment in waste production site, water recycling is much better than the other two methods. Greywater reuse is increasingly emerging as an integral part of water demand management. [3, 4] 1.2. Aim and Objective Aim: “The ultimate aim of this work is to systematically understand the physicochemical parameters of light grey water generated from bathroom, wash basin & washing machine and its scope of reuse for a residential building”. Objective: The research objectives for execution of thesis are as follows: 1. To study and understand physico-chemical properties of light grey water of case study building. 2. To study scope of reuse of light greywater in case study building. 2. LITERATURE REVIEW A literature review of scholarly articles, books, dissertations, conference proceedings and other resources which are relevant to the study of light greywater effluent, carried out to set the background on what has been explored on the topic so far. An extensive literature review provides background information on current knowledge related to the research topic. Table No. 1: Characteristics of Effluent from Various Research Paper Sr. No. Paper Year of Publication Remarks Characteristics of Laundry Effluent Value 1. Commercial Laundry Water Characterization by J. K. Braga and M. B. A. Varesche 2015 pH 5.6 Total Alkalinity 25.9 COD 1710 TSS 80 Nitrate 8.4 Nitrite 2.1 Sulphate 21.1 Sulphide 0.2 2. Characterization of domestic gray water from point source to determine the potential for urban residential reuse by Golda A. Edwin Et. al 2017 pH 9.1 EC 641.6 Hardness 721 BOD 5 186.5 COD 1545.8 DO N.D TS 586 TSS 141.2 Nitrate 0.3 Nitrite 0.2 3. Study of physico-chemical characteristics of domestic Wastewater in Vishnupuri, Nanded, India by Sonune NA Et. al 2019 pH 7 – 8 BOD 56 – 96 COD 180 – 300 Ammonical Nitrogen 129 – 146 Nitrate 74 – 181
  • 3. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1284 Phosphate 0.4 – 2.1 TDS 1228 – 1440 TSS 43 – 65.43 4 Qualitative Characterization of Greywater from a Residential Complex in Bengaluru City, Karnataka, India by Parameshwara Murthy Et. al 2019 pH 5.7 BOD 35-138 COD 123 - 540 Nitrate 0.67 – 2.3 Phosphate 6 – 12.8 TDS 144 - 212 TSS 86 - 300 5 Characteristics and Treatment of Greywater – A Review 2021 pH 7 -7.3 BOD 155 - 205 COD 386 - 587 Total N 6.6 – 10.4 Total P 0.69 – 1.1 TDS 215 - 279 TSS 153 - 259 3. METHODOLOGY At preliminary level the research work will be carried out to identify the reusability of waste water in residential building by studying to the physico-chemical parameters of light grey effluent and particularizing the scope of reuse of same waste water for multipurpose uses like vechile washing, house & society cleaning, gardening etc. 4. CASE STUDY 4.1. Case Study Details Primarily the data will be collected from case study that is residential building - Mohan Willows, Bhosale Nagar, Shirgoan, Badlapur(E) . Data will be composed in the form of survey from all the households of the case study building. Building Name Mohan Willows Phase II, Ashwood building Address Bopkhel, Vishrantwadi, Pune - 411031 Total No of flats 131 Data Collection Period April - May 2022 4.2. Case Study Location Badlapur is a beautiful city in the district of Thane in the Indian state of Maharashtra. Badlapur is in proximity with Mumbai, Navi Mumbai, Kalyan, Panvel and Karjat locations. The city is having decent infrastructural amenities with beautiful natural view. The latitude and longitude of study area is 19°15'48.7"N, 73°23’13”E. Figure No. 1: Showing Map of Case Study Area
  • 4. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1285 4.3. Method Used for Analysis Grey wastewater samples were characterised to determine the physical and chemical parameters. Some physical test should be performed for testing of its physical appearance such as colour, pH, turbidity, TDS, while chemical tests should be perform for its COD, BOD, Oil & Grease, Conductivity, Total Hardness, Calcium, Magnesium, dissolved oxygen, alkalinity, Sulphate, Iron, Lead, Zinc, DO and Nitrate. All parameters were analysed in accordance with standard method for the examination of water and wastewater. Table No. 2: Physico-chemical Parameters and Methods Adopted for the Analysis Sr. No. Analysis Parameters Method used 01 pH pH meter, IS: 3025 (part – 11 – 2): Reaff. 2012 02 COD IS: 3025 (part – 58): Reaff. 2014 03 BOD IS: 3025 (part – 44): Reaff. 2014 04 Oil and Grease IS: 3025 (part – 39- 5): Reaff. 2014 05 Turbidity Nephelometer, IS: 3025 (part – 10): Reaff. 2012 06 Conductivity Conductivity meter IS: 3025 (part – 14): Reaff. 2013 07 Total Dissolved Solids Gravimetric Method, IS: 3025 (part – 16): Reaff. 2012 08 Total Hardness Titrimetric Method, IS: 3025 (part – 21- 2): Reaff. 2014 09 Calcium Titrimetric Method, IS: 3025 (part – 40- 5): Reaff. 2014 10 Magnesium Titrimetric Method, IS: 3025 (part – 46- 6): Reaff. 2014 11 Total Alkalinity Titrimetric Method IS: 3025 (part – 23): Reaff. 2014 12 Sulphate Spectrometer IS: 3025 (part – 24- 4): Reaff. 2014 13 Iron Spectrometer IS: 3025 (part – 53- 6): Reaff. 2014 14 Lead Atomic Absorption, APHA 3111 - D 15 Zinc Atomic Absorption, APHA 3111 - D 16 Dissolved Oxygen Atomic Absorption IS: 3025 (part – 44): Reaff. 2003 17 Nitrate IS 3025 (Part 34): Reaff. 2014 4.4. Analysis of Physico-chemical Properties The sample analyses of the collected greywater are represented in to the tabular form in following section. Table No. 3: Physico-chemical analysis of light greywater effluent Sr. No Analysis Parameters Samples Mean S1 S2 S3 S4 S5 S6 S7 S8 S9 S10 1 pH 9.6 8.4 8.4 9.3 9.6 9.1 9.1 9.2 8.8 8.9 9.0 2 COD 1512 1551 1769 1546 1431 1535.0 1572 1545 1493 1520 1547.4 3 BOD 154 167 167 189 193 181.6 187.5 181 189 184 179.3 4 Oil and Grease 3.6 3.9 ND ND ND ND ND 4.3 ND 6.3 1.8 5 Turbidity 118.7 111.5 98 100.5 77.1 106.3 81.7 105.1 110.6 169.5 107.9 6 Conductivity 700.6 533.4 551.2 687.2 687.7 641.2 624 631.9 695.1 647.5 640.0 7 TDS 701 712.5 722 728 740 708.0 710 722.4 751.1 732.3 722.7 8 Total Hardness 637 582 572 629 637 611.6 628 645 660 614 621.6 9 Calcium 3.9 3.9 3.2 3.7 4.2 4.1 4.1 4.2 4.9 4.1 4.0 10 Magnesium 1.5 1.1 0.9 1.32 1.6 1.3 1.3 1.41 1.6 1.6 1.4 11 Total Alkalinity 36.5 37 31.2 39.21 43 36.7 32.8 32.7 38.7 39.4 36.7 12 Sulphate 24.8 22.1 21.2 25.2 28.1 25.3 26.7 27.3 25.9 26.2 25.3 13 Iron ND 1.14 0.9 ND 0.77 0.8 1.2 1.12 ND 1.3 0.7 14 Lead <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 15 Zinc ND <0.01 ND <0.01 <0.01 <0.01 <0.01 ND ND <0.01 <0.01 16 Dissolved Oxygen ND ND ND ND ND ND ND ND ND ND ND 17 Nitrate 0.1 0.2 0.1 0.3 0.2 0.2 0.1 0.2 0.2 0.2 0.2 The classical use of light greywater analysis of residential building is to produce information concerning the water quality and scope of reuse of waste water. The waste water quality may yield information about the environment through which it been reused and the treatment required for recycling the water. The physicochemical composition of collected samples was statistically analyzed and presented in below section.
  • 5. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1286 pH:-The pH value of water is very important indicator of its quality. The pH values of water are controlled by the amount of dissolved carbon dioxide, carbonate and bicarbonates. pH is a term used universally to express the intensity of the acid or alkaline condition of a solution. The pH values of water samples vary between 8.4 to 9.6 and some of the values were not found within the limit prescribed by BIS and WHO. Chemical Oxygen Demand (COD):-Is an indicative measure of the amount of oxygen that can be consumed by reactions in a sample solution. It is commonly expressed in mass of oxygen consumed over volume of solution which in SI units is milligrams per liter (mg/L). A COD test can be used to easily quantify the amount of organics in water. The concentration of COD varied from 1431 mg/l to 1769 mg/l. High COD value in effluent shows the presence of oxidisable organic materials. High COD concentration in samples indicates the presence of organic contaminants in the water to a large extent. Biochemical Oxygen Demand (BOD):-Also known as biological oxygen demand is the amount of dissolved oxygen needed by aerobic biological organisms to break down organic material present in a given water sample at certain temperature over a specific time period. The BOD value in this study has been expressed in milligrams of oxygen consumed per liter of sample during 3 days of incubation at 27 °C. BOD concentration of these samples is ranged from 154 mg/l to 193 mg/l. High BOD concentration in effluent of waste water samples indicates the presence of organic contaminants in the water. Oil and Grease: - Oil and grease is also a major threat to surface and ground water through infiltration and seepage, thereby reducing the quality of the affected resources. Oil and grease concentration is ranged from 3.6 mg/l to 6.3 mg/l. In 60% of the samples it is not detected and in remaining 40% it is detected. Turbidity: - Turbidity in water is the reduction of transparency due to the presence of particulate matter such as dirt or slit, finely divided organic matter etc. These can cause light to be scattered or absorbed rather than transmitted in straight lines through the sample. The turbidity was due to the colloidal fine dispersion of suspended solids. Some microorganism might also contribute the turbidity. In present study turbidity was found between 81.7 NTU to 169.5 NTU. The values were found with high values then that prescribed by IS: 10500. Conductivity: -The conductivity values varied from 533.4 µs/cm to 700.6 µs/cm in the samples analysed from the respective case study. Electrical conductivity gives an idea about the concentration of ions in solution that determines the quality of water for reuse purposes. Total Dissolved Solids (TDS):- TDS is generally considered not as a primary pollutant, but it is rather used as an indication of aesthetic characteristics of water and as an aggregate indicator of presence of a broad array of chemical contaminants. Total dissolved solids indicate the salinity behaviour of grey water. Water containing more than500 mg/L of TDS is not considered desirable for drinking water supplies, but in unavoidable cases 1500 mg/L is also allowed. The amount of Total Dissolved Solids varied from 701 mg/lit to 751.1 mg/L in study of collected samples. Total Hardness:- Hardness is the property of water which prevents the lather formation with soap and increases the boiling points of water. Hardness is one of the important properties of grey water from utility point of view for different purposes. In grey water, hardness is primarily due to presence of carbonates, bicarbonates, sulphates and chlorides of calcium and magnesium. For potable water the TH should be limited up to 300 mg/L and maximum permissible value is 600 mg/L. If the hardness is less than 50 mg/l the water will be soft. If the hardness is from 50 mg/lit to 100 mg/l, the water will be moderate soft. If the hardness is from 101 mg/lit to 200 mg/l and more than 200 mg/l, the water will be slightly hard and quite hard, respectively. In the analysis total hardness values were ranged between 572 to 660 mg/L. Again the study confirmed the excess quantity of hardness creating cations and anions were present in and around the grey water samples. Calcium:- Calcium is the most abundant of the alkaline earth minerals. Calcium is directly related to hardness. The concentration up to 100 mg/l of calcium is capable of forming scales in pipes and boiler; fortunately it has no adverse physiological manifestation on human system. Calcium is the third most abundant metal in the earth’s crust. Excess of ca ions causes concretions in the kidney and causes irritation and pain in the urinary passages. The Ca concentration was ranged between 3.2 mg/lit – 4.9 mg/lit and found below permissible limit. Magnesium: - The WHO standards prescribed the limit for the presence of magnesium in water is 50 – 100 mg/l. The concentration of magnesium ranged between 0.9 to 1.6 mg/l. High concentration of Mg can cause laxative effect in human being but in our case it is within the permissible limit.
  • 6. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1287 Total Alkalinity: - Alkalinity of water is its capacity to neutralize a strong acid and it is normally due to the presence of bicarbonate, carbonate and hydroxide compound of calcium, sodium and potassium. Total alkalinity values for all the investigated samples were found in the range of 31.2 to 39.4 mg/l. Sulphate: - Sulphate can be found in almost all natural water. The origin of most sulphate compounds is the oxidation of sulphite ores, the presence of shales, or the industrial wastes. Sulphate is one of the major dissolved components of rain. High concentrations of sulphate in the water we drink can have a laxative effect when combined with calcium and magnesium, the two most common constituents of hardness. The Sulphates concentration of grey water samples ranged between is 21.2 mg/L to 28.1 mg/L and found within the prescribed limit. Iron:- High iron concentrations generally cause a bitter and astringent taste. It also clogs and pits pipes, discolors clothes and plumbing fixtures and causes scaling which encrusts pipes. The values for all the investigated samples were found to be in the range of 0.77 mg/L to 1.3 mg/L which is within the permissible limit of BIS and WHO (i.e. 5 mg/L). Lead: - Lead is a toxic metal that is harmful to human health; there is no safe level for lead exposure. The degree of exposure depends on the concentration of lead, route of exposure, current medical condition, and age. It has been estimated that up to 20 % of the total lead exposure in children can be attributed to a waterborne route, i.e., consuming contaminated water. The permissible limit BIS and WHO (i.e. 0.01 mg/L) for drinking and for recycle/reuse the permissible limit is 0.5 mg/L. In the study area analysis the lead has been detected in some sample bit at very low value of less than 0.003 mg/L Zinc: - Zinc is an essential mineral, including to prenatal and postnatal development. Zinc deficiency affects about two billion people in the developing world and is associated with many diseases. In children, deficiency causes growth retardation, delayed sexual maturation, infection susceptibility, and diarrhea. Consumption of excess zinc can cause ataxia, lethargy and copper deficiency. In the study area analysis the zinc concentration has been detected in some sample bit at very low value of less than 0.001 mg/L. Dissolved Oxygen: -Dissolved oxygen is important parameter in water quality assessment and reflects the physical and biological processes prevailing in water. The DO values indicate the degree of pollution in grey water. In the analysis all the samples, the concentrations of DO is not at all detected. Nitrate: - The excess levels can cause methemoglobinemia, or "blue baby" disease. Although nitrate levels that affect infants do not pose a direct threat to older children and adults, they do indicate the possible presence of other more serious residential contaminants, such as bacteria or some kinds of pesticides. The permissible limit for the nitrate is 30 - 45 mg/L. The nitrates concentration of groundwater samples were very low than the permissible limit. 5. CONCLUSION In case study building, the characteristics of light greywater were evaluated using wastewater samples (10 numbers) of case study building. The samples were analysed for the physical and chemical characteristics of the water. The parameters examined were: pH, Turbidity, TDS, COD, BOD, Oil & Grease, Conductivity, Total Hardness, Calcium, Magnesium, Alkanity, Sulphate, Iron, Lead, Zinc, DO and Nitrate. The research showed that the quality of light greywater with respect to COD, BOD, turbidity and total hardness requires adequate treatment prior to household reuse. With regard to the trace and heavy metal contents, no further treatment is required. REFERENCES [1] Shirazi MMA, Kargari A, Shiraz MJA (2012) Direct contact membrane distillation for seawater desalination. Desalin Water Treat 49: 368-375. Link: https://goo.gl/gvo7AS [2] Nemerow Nelson Leonard, Dasgupta Avijit, ”Industrial and Hazardous Waste Treatment”, van Nostrand Reinhold, 1991 [3] Dolnicar S, Schafer AI (2009) Desalinated versus recycled water: public perceptions and profi les of the accepters. J Environ Manag 90: 888-900. Link: https://goo.gl/r6RDEs [4] Lu W, Leung AYT (2003) A preliminary study on potential of developing shower/laundry wastewater reclamation and reuse system. Chemosphere 52: 1451-1459. Link: https://goo.gl/2kYyQn. 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  • 7. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD50260 | Volume – 6 | Issue – 4 | May-June 2022 Page 1288 Chemosphere 52: 1451-1459. Link: https://goo.gl/2kYyQn [8] Wendland C, Albold A (2010) Sustainable and Cost-effective Wastewater Systems for Rural and Peri-urban Communities up to 10,000 Population Equivalents: Guidance Paper. Women in Europe for a Common Future (WECF), Munch, Germany. Link: https://goo.gl/Kv4Neq [9] Pakula C, Stamminger R (2010) Electricity and water consumption for laundry washing by washing machine worldwide. Energy Effi c 3: 365-382. Link: https://goo.gl/FSRrSJ [10] Ciabatti I, Cesaro F, Faralli L, Fatarella E, Tognotti F (2009) Demonstration of a treatment system for purifi cation and reuse of laundry wastewater. Desalination 245: 451-459. Link: https://goo.gl/wbyLPt [11] Dolnicar S, Saunders C (2005) Marketing recycled water: review of past studies and research agenda. Integrated concepts in water recycling. Wollongong: University of Wollongong, Australia. 181-92. Link: https://goo.gl/e2Xut2 [12] Ngo HH, Chuang H, Guo WS, Ho DP, Pham TTN, et al. (2009) Resident’s strategy survey on a new end use of recycled water in Australia. Desalination Water Treatment 11: 93-97. Link: https://goo.gl/ps92VH [13] Pham TTN, Ngo HH, Guo WS, Dang HPD, Mainali B, et al. (2011) Response of community to the public use of recycled water for washing machine: a case study in Sydney, Australia. Resource Conservation Recycling 55: 535-540. Link: https://goo.gl/utc1kc [14] Janpoor F, Torabian A, Khatibikamal V (2011) Treatment of laundry wastewater by electrocoagulation. J Chem Technol Biotechnol 86: 1113-1120. Link: https://goo.gl/jkVdB9 [15] Berstein M (1986) Water and Wastewater: a Guide for Industrial Launderers, first ed. Institute of Industrial Launderers, Washington DC, USA.