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Assessment of Potential for CCS in
the Calabarzon Region in the
Philippines

                                          Raymond R. Tan, Ph.D.
Director, Center for Engineering & Sustainable Development Research
              University Fellow and Professor of Chemical Engineering
                              De La Salle University, Manila, Philippines
Consulting Team

•   Carlo Arcilla, Ph.D.         (Local Team Leader)
•   Susan Roces, Ph.D.           (DLSU Team Leader)
•   Raymond Tan, Ph.D.           (Decision Analyst)
•   Michael Promentilla, Ph.D.   (Decision Analyst)
•   Nathaniel Dugos, Ph.D.       (Process Analyst)
•   Pag-asa Gaspillo, Ph.D.      (Process Analyst)
•   Alyanna Uy                   (Research Assistant)
Outline of Presentation
•   Overview of Philippine CO2 Emission Statistics
•   Geographic Scope of Study (Calabarzon)
•   Major CO2 Sources in Calabarzon
•   Criteria
•   Screening and Ranking of CO2 Sources
•   Evaluation of Potential CO2 Storage Sites
•   Social Acceptability Issues
•   Status and Further Work
Philippine Primary Energy Mix in Mtoe/y
                           (Source: DOE, 2009)


                                                    Despite the relatively
                            Coal, 6.1
                                                    large share of
                                                    renewable and non-
 Others, 16.8                                       conventional energy,
                                                    fossil fuels still comprise
                                        Oil, 13.5   more than half of the
                                                    primary energy demand
                Natural
                Gas, 3.2                            of about 40 Mtoe/y
Philippine CO2 Emissions in Mt/y by Sector
                                    (Source: DOE, 2009)


                      Others, 4.8                              Industry and power
                                                               generation account for
                                    Industry, 11.7
                                                               more than half of the 70
       Power                                                   Mt/y energy-based CO2
   generation, 27.5                                            emissions
                                             Transport, 24.5
Philippine Power Mix in GWh/y
                                         (Source: DOE, 2009)

                                                                        Natural gas and coal are
                                         Oil         Hydroelectricity   the largest contributors
                                        5,381            9,788
                 Natural Gas                                            to the Philippine power
                   19,887
                                                                        mix. Annual generation
                                                                        is about 60 GWh.
                                                Geothermal
                                                  10,324
                                Coal
                               16,476




Wind and Solar
      79
Geographic Scope of Study
   (Source: Wikipedia, 2010)

                   Calabarzon (Region IV-A)
                   consists of provinces
                   immediately to the south or
                   east of the National Capital
                   Region.

                   This region accounts for a
                   disproportionately large
                   share of total Philippine CO2
                   emissions.
Hierarchical Decision Criteria

Hard requisites or “musts”      Soft requisites or “wants”
• Remaining service life        • CO2 stream concentration
• Capacity utilization factor   • CO2 stream volume
  factor                        • Stream impurity levels
                                  (NOx, SO2, PM)
                                • Space availability and
                                  local geography
                                • Proximity to storage sites
                                • Declared interest in CCS
Major CO2 Sources in Calabarzon
    Source     Estimated CO2 Flowrate                     Notes
                       (Mt/y)
Coal Plant 1            3.80
Coal Plant 2            1.60
Coal Plant 3            3.44            Estimated from publicly reported rated
NG Plant 1              2.86            capacities and typical CO2 emission factors
NG Plant 2              1.38
NG Plant 3              3.23
Refinery                0.38
Offshore NG             0.17
Platform
Cement                  1.35            Estimated from publicly reported
Plants 1 - 4                            production volume and capacity utilization
TOTAL                  18.21
Screening of CO2 Sources in Calabarzon
           Source               Remaining Life        Capacity Utilization (>80%)
                                   (>20 y)
Coal Plant 1                         Yes                          Yes
Coal Plant 2                          No                          No
Coal Plant 3                         Yes                          Yes
NG Plant 1                           Yes                          Yes
NG Plant 2                           Yes                          Yes
NG Plant 3                           Yes                          Yes
Refinery                             Yes                          Yes
Offshore NG Platform                 Yes                          Yes
Cement Plants 1 - 4                No data                     No data*
*Cement industry average capacity utilization in 2009 is reported by CeMAP to be
54%
Assessment of CO2 Sources in Calabarzon
               Criterion            Coal      Coal       NG        NG        NG         NG      Refinery
                                   Plant 1   Plant 3   Plant 1   Plant 2   Plant 3   Platform
Stream CO2 concentration             9         10        1         1         1          1          5

CO2 flowrate                         10        10        10        6         10         0          0

Stream SO2 concentration             0         5         10        10        10        10          0

Stream O2 concentration              8         9         0         0         0          0          1

Stream NOx concentration             0         6         9         9         10         0          0

Particulates content                 0         0         10        10        10        10          0
Trace pollutants content             0         0         10        10        10        10          0
Implementation date                  4         6         6         7         7          7          4
Distance from storage site           0         0         0         0         0          0          0
Existing infrastructure              0         0         0         0         0          0          0
Space availability                   10        10        0         0         10         0         10
Plant efficiency                     0         0         5         5         5          0          0
Proximity to water supply            0         0         0         0         0          0          0
Company willingness to implement     0         5         0         0         5          5          5
CCS
TOTAL                                4         6         9         8         10         3          2
Results of CO2 Source Assessment
• Coal Plant 2 has been eliminated from further
  consideration due to age
• Full analysis of four cement plant will not be done until
  acquisition of site-specific data
• Three natural-gas fired combined cycle plants are
  promising candidates due to their age and large size
• Coal Plant 3 is also a promising candidate as it is
  relatively new compared to the others
Determining the Potential for Carbon Capture and
              Storage in Southeast Asia [RETA 7575]

                 Philippine Geology :
             Initial Storage Assessment

Dr. Carlo A. Arcilla
Professor and Director
National Institute of Geological Sciences
University of the Philippines

Dr. Chelo Pascua
Assistant Professor
National Institute of Geological Sciences
University of the Philippines
Complex tectonics of the Philippines

• Diffuse plate boundary (unclear as to what plate
  it belongs)
• Amalgamation of continental materials, ocean
  floor (ophiolites), younger volcanics, and
  immature basins
• Currently traversed by left-lateral Philippine fault
• 20 active volcanoes, 200 dormant
• Sedimentary basins formed due to complex
  tectonics, are max. 25 Million years old
FAULTS &
TRENCHES
SEDIMENTARY &
OCEANIC BASINS
OPHIOLITES AND
GEOTHERMAL
SITES
GEOTHERMAL
SITES WITH
ACTIVITIES
SEDIMENTARY BASINS
 OF THE PHILIPPINES
1.    Cagayan Basin
2.    Central Luzon Basin
3.    Ilocos Trough
4.    West Luzon Platform
5.    Bicol Shelf/Lamon Bay
6.    Southeast Luzon Basin
7.    Iloilo Basin
8.    Visayan and Samar Basin
9.    Agusan-Davao Basiin
10.   Cotabato Basin
11.   Sulu Sea Basin
12.   South Palawan Basin
13.   North Palawan-Mindoro Basin
Sedimentary Basins of the Philippines
  Basin Name           Area     Wildcat wells                Total Resources
                       (km2)        drill
                                                Discovered    Undiscovered       % Gas
     Ilocos           19,500         1              -              19             100%
    Cagayan           24,000         30            0.4            396             99%
  West Luzon          16,000        none            -              23             100%
 Central Luzon        16,500         17             -             902             100%
      Bicol           32,500         6              -              44             100%
 Mindoro-Cuyo         58,000         15            25             806              7%
W. Masbate-Iloilo     25,000         10             -              5              72%
   SE Luzon           66,000         26             -             301             36%
    Visayan           46,500        143            0.5           1,259            28%
   Reed Bank          71,000         4              -             440             92%
  NW Palawan          36,000         58            942           1,376         72% (13%-C)
  SW Palawan          44,000         23             -            1,355            60%
 East Palawan         92,000         4              -             443             28%
    Sulu Sea          115,000        17             -             203             36%
    Cotabato          14,000         10             5             152             45%
 Agusan-Davao         33,000         3              -             196             70%
Data under collection
LUZON


    Basin        Area   Thickness of   Estimated   Percentage    Ave. Porosity      Basin     Basin      Ave.
    Name        Covered Sedimentary      Basin     Permeable      of Permeable     Pressure   Temp.   Geothermal
                 (km2)    Fill (km)     Volume         Units          Units         Range     Range    Gradient
                                         (km3)      (lithology         (%)                            (C/100 m)
                                                      based)     (include range)

Cagayan         28,000       ~9
Central Luzon   16,000       >9                                                                          1.9
Ilocos          15,000       ~8
West Luzon      12,500       ~9
Bicol           34,000       ~3
Shelf/Lamon
Bay
Southeast       40,000      3.5-8                                                                     4.01-3.29
Luzon                     (onshore)
                             ~7.5
                          (offshore)
CAGAYAN




*well location, CCOP-DOE, Aug 2002
CENTRAL LUZON




*well location, CCOP-DOE, Aug 2002
Possible CCS options in the Philippines
GENERAL:

 Saline aquifers (work in progress)
 Depleted oil and gas fields (need past production data and reserves)

NOVEL:
 Geothermal systems (commercial partner for technology assessment)
 Mineral trapping in ophiolite sequences (access via fractures)
    Mineral carbonation i.e. calcite, magnesite
    Laterite carbonation i.e. siderite
 Direct sequestration from atmospheric CO2
    Hyperalkaline springs i.e. tufa deposits
 Engineered systems similar to these natural CCS mechanisms
Additional Social Acceptability Issues

• Public awareness of CCS as a low-carbon option in the
  Philippines remains low
• Added cost of power resulting from CCS energy
  penalties have been raised as a major cause for concern
  in previous public discussions held at DOE
• Grid-wide losses due to CCS energy penalties will need
  to be compensated for by new plants
Status and Further Work

•   Data verification
•   Filling of data gaps
•   Performing sensitivity analysis on decision matrix
•   Techno-economic analysis for identified CO2 sources
•   Qualitative analysis of other decision criteria
•   Integrated analysis of CO2 source and sink matches
Thank you for your attention
   Questions and comments are welcome
          Or contact us via e-mail:
 Dr. Carlo Arcilla (caloy.arcilla@gmail.com)
Dr. Susan Roces (susan.roces@dlsu.edu.ph)

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CCS Assessment in the Philippines - Carlo Arcilla and Raymond Tan

  • 1. Assessment of Potential for CCS in the Calabarzon Region in the Philippines Raymond R. Tan, Ph.D. Director, Center for Engineering & Sustainable Development Research University Fellow and Professor of Chemical Engineering De La Salle University, Manila, Philippines
  • 2. Consulting Team • Carlo Arcilla, Ph.D. (Local Team Leader) • Susan Roces, Ph.D. (DLSU Team Leader) • Raymond Tan, Ph.D. (Decision Analyst) • Michael Promentilla, Ph.D. (Decision Analyst) • Nathaniel Dugos, Ph.D. (Process Analyst) • Pag-asa Gaspillo, Ph.D. (Process Analyst) • Alyanna Uy (Research Assistant)
  • 3. Outline of Presentation • Overview of Philippine CO2 Emission Statistics • Geographic Scope of Study (Calabarzon) • Major CO2 Sources in Calabarzon • Criteria • Screening and Ranking of CO2 Sources • Evaluation of Potential CO2 Storage Sites • Social Acceptability Issues • Status and Further Work
  • 4. Philippine Primary Energy Mix in Mtoe/y (Source: DOE, 2009) Despite the relatively Coal, 6.1 large share of renewable and non- Others, 16.8 conventional energy, fossil fuels still comprise Oil, 13.5 more than half of the primary energy demand Natural Gas, 3.2 of about 40 Mtoe/y
  • 5. Philippine CO2 Emissions in Mt/y by Sector (Source: DOE, 2009) Others, 4.8 Industry and power generation account for Industry, 11.7 more than half of the 70 Power Mt/y energy-based CO2 generation, 27.5 emissions Transport, 24.5
  • 6. Philippine Power Mix in GWh/y (Source: DOE, 2009) Natural gas and coal are Oil Hydroelectricity the largest contributors 5,381 9,788 Natural Gas to the Philippine power 19,887 mix. Annual generation is about 60 GWh. Geothermal 10,324 Coal 16,476 Wind and Solar 79
  • 7. Geographic Scope of Study (Source: Wikipedia, 2010) Calabarzon (Region IV-A) consists of provinces immediately to the south or east of the National Capital Region. This region accounts for a disproportionately large share of total Philippine CO2 emissions.
  • 8. Hierarchical Decision Criteria Hard requisites or “musts” Soft requisites or “wants” • Remaining service life • CO2 stream concentration • Capacity utilization factor • CO2 stream volume factor • Stream impurity levels (NOx, SO2, PM) • Space availability and local geography • Proximity to storage sites • Declared interest in CCS
  • 9. Major CO2 Sources in Calabarzon Source Estimated CO2 Flowrate Notes (Mt/y) Coal Plant 1 3.80 Coal Plant 2 1.60 Coal Plant 3 3.44 Estimated from publicly reported rated NG Plant 1 2.86 capacities and typical CO2 emission factors NG Plant 2 1.38 NG Plant 3 3.23 Refinery 0.38 Offshore NG 0.17 Platform Cement 1.35 Estimated from publicly reported Plants 1 - 4 production volume and capacity utilization TOTAL 18.21
  • 10. Screening of CO2 Sources in Calabarzon Source Remaining Life Capacity Utilization (>80%) (>20 y) Coal Plant 1 Yes Yes Coal Plant 2 No No Coal Plant 3 Yes Yes NG Plant 1 Yes Yes NG Plant 2 Yes Yes NG Plant 3 Yes Yes Refinery Yes Yes Offshore NG Platform Yes Yes Cement Plants 1 - 4 No data No data* *Cement industry average capacity utilization in 2009 is reported by CeMAP to be 54%
  • 11. Assessment of CO2 Sources in Calabarzon Criterion Coal Coal NG NG NG NG Refinery Plant 1 Plant 3 Plant 1 Plant 2 Plant 3 Platform Stream CO2 concentration 9 10 1 1 1 1 5 CO2 flowrate 10 10 10 6 10 0 0 Stream SO2 concentration 0 5 10 10 10 10 0 Stream O2 concentration 8 9 0 0 0 0 1 Stream NOx concentration 0 6 9 9 10 0 0 Particulates content 0 0 10 10 10 10 0 Trace pollutants content 0 0 10 10 10 10 0 Implementation date 4 6 6 7 7 7 4 Distance from storage site 0 0 0 0 0 0 0 Existing infrastructure 0 0 0 0 0 0 0 Space availability 10 10 0 0 10 0 10 Plant efficiency 0 0 5 5 5 0 0 Proximity to water supply 0 0 0 0 0 0 0 Company willingness to implement 0 5 0 0 5 5 5 CCS TOTAL 4 6 9 8 10 3 2
  • 12. Results of CO2 Source Assessment • Coal Plant 2 has been eliminated from further consideration due to age • Full analysis of four cement plant will not be done until acquisition of site-specific data • Three natural-gas fired combined cycle plants are promising candidates due to their age and large size • Coal Plant 3 is also a promising candidate as it is relatively new compared to the others
  • 13. Determining the Potential for Carbon Capture and Storage in Southeast Asia [RETA 7575] Philippine Geology : Initial Storage Assessment Dr. Carlo A. Arcilla Professor and Director National Institute of Geological Sciences University of the Philippines Dr. Chelo Pascua Assistant Professor National Institute of Geological Sciences University of the Philippines
  • 14.
  • 15.
  • 16. Complex tectonics of the Philippines • Diffuse plate boundary (unclear as to what plate it belongs) • Amalgamation of continental materials, ocean floor (ophiolites), younger volcanics, and immature basins • Currently traversed by left-lateral Philippine fault • 20 active volcanoes, 200 dormant • Sedimentary basins formed due to complex tectonics, are max. 25 Million years old
  • 21. SEDIMENTARY BASINS OF THE PHILIPPINES 1. Cagayan Basin 2. Central Luzon Basin 3. Ilocos Trough 4. West Luzon Platform 5. Bicol Shelf/Lamon Bay 6. Southeast Luzon Basin 7. Iloilo Basin 8. Visayan and Samar Basin 9. Agusan-Davao Basiin 10. Cotabato Basin 11. Sulu Sea Basin 12. South Palawan Basin 13. North Palawan-Mindoro Basin
  • 22. Sedimentary Basins of the Philippines Basin Name Area Wildcat wells Total Resources (km2) drill Discovered Undiscovered % Gas Ilocos 19,500 1 - 19 100% Cagayan 24,000 30 0.4 396 99% West Luzon 16,000 none - 23 100% Central Luzon 16,500 17 - 902 100% Bicol 32,500 6 - 44 100% Mindoro-Cuyo 58,000 15 25 806 7% W. Masbate-Iloilo 25,000 10 - 5 72% SE Luzon 66,000 26 - 301 36% Visayan 46,500 143 0.5 1,259 28% Reed Bank 71,000 4 - 440 92% NW Palawan 36,000 58 942 1,376 72% (13%-C) SW Palawan 44,000 23 - 1,355 60% East Palawan 92,000 4 - 443 28% Sulu Sea 115,000 17 - 203 36% Cotabato 14,000 10 5 152 45% Agusan-Davao 33,000 3 - 196 70%
  • 23. Data under collection LUZON Basin Area Thickness of Estimated Percentage Ave. Porosity Basin Basin Ave. Name Covered Sedimentary Basin Permeable of Permeable Pressure Temp. Geothermal (km2) Fill (km) Volume Units Units Range Range Gradient (km3) (lithology (%) (C/100 m) based) (include range) Cagayan 28,000 ~9 Central Luzon 16,000 >9 1.9 Ilocos 15,000 ~8 West Luzon 12,500 ~9 Bicol 34,000 ~3 Shelf/Lamon Bay Southeast 40,000 3.5-8 4.01-3.29 Luzon (onshore) ~7.5 (offshore)
  • 25. CENTRAL LUZON *well location, CCOP-DOE, Aug 2002
  • 26. Possible CCS options in the Philippines GENERAL:  Saline aquifers (work in progress)  Depleted oil and gas fields (need past production data and reserves) NOVEL:  Geothermal systems (commercial partner for technology assessment)  Mineral trapping in ophiolite sequences (access via fractures)  Mineral carbonation i.e. calcite, magnesite  Laterite carbonation i.e. siderite  Direct sequestration from atmospheric CO2  Hyperalkaline springs i.e. tufa deposits  Engineered systems similar to these natural CCS mechanisms
  • 27. Additional Social Acceptability Issues • Public awareness of CCS as a low-carbon option in the Philippines remains low • Added cost of power resulting from CCS energy penalties have been raised as a major cause for concern in previous public discussions held at DOE • Grid-wide losses due to CCS energy penalties will need to be compensated for by new plants
  • 28. Status and Further Work • Data verification • Filling of data gaps • Performing sensitivity analysis on decision matrix • Techno-economic analysis for identified CO2 sources • Qualitative analysis of other decision criteria • Integrated analysis of CO2 source and sink matches
  • 29. Thank you for your attention Questions and comments are welcome Or contact us via e-mail: Dr. Carlo Arcilla (caloy.arcilla@gmail.com) Dr. Susan Roces (susan.roces@dlsu.edu.ph)