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BHOPAL GAS TRAGEDY
Gaurav Singh Rajput
SOE, CUSAT
@gauravkrsrajput
OVERVIEW
UNION CARBIDE INDIA LIMITED(UCIL)
PESTICIDE PLANT IN BHOPAL,MP.
2nd & 3rd DECEMBER 1984
LEAK OF METHYL ISOCYNATE
25,000 DIED
5,58,125 INJURED
PROCESS
• Methlyamine rea
cts with Phosgene
producing Methyl
Isocyanate (MIC)
which reacts with
1-Naphthol to pr
oduce pesticide C
arbaryl, also kno
wn as Sevin.
METHYL ISOCYNATE
• Liquid form, Volatile
• Colourless
• Strong, sharp odour
• Flash Point – -7oC
• Molecular weight: 57.05 daltons
• Boiling point (760 mm Hg): 102ºF (39.1ºC)
• Freezing point: -49ºF
• Vapor pressure: 348 mm Hg at 68ºF (20ºC)
• Vapor density: 1.42 (air = 1.00)
• Water solubility: Reactive 6.7% at 68ºF (20ºC)
• Flammability: Highly flammable
• Flammable Range: 5.3% to 26% (concentration in air)
• Night of 2nd December 1984
• Water entered Tank E610 containg 42 tonnes
of MIC
• EXOTHERMIC REACTION
Toxic Materials in Soil and Water
CAUSES
•OVERSTORAGE
•POOR MAINTENANCE
•DENSELY POPULATED AREAS
•FAILURE OF SAFETY SYSTEMS
•LACK OF AWARENESS ABOUT MIC
•LACK OF SAFETY TRAINING
VENT GAS SCRUBBER WAS SHUT
DOWN
FLARE TOWER PIPE WAS CORRO
DED
MIC REFRIGERATION SYSTEM WA
S NOT FUNCTIONING.
SINGLE MANUAL BACKUP SYSTE
M.
Gas Vent Scrubber Gas Vent Scrubber Stack
AFFECTED AREA
Bhopal Disaster | Gaurav Singh Rajput

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Bhopal Disaster | Gaurav Singh Rajput

  • 1. BHOPAL GAS TRAGEDY Gaurav Singh Rajput SOE, CUSAT @gauravkrsrajput
  • 2. OVERVIEW UNION CARBIDE INDIA LIMITED(UCIL) PESTICIDE PLANT IN BHOPAL,MP. 2nd & 3rd DECEMBER 1984 LEAK OF METHYL ISOCYNATE 25,000 DIED 5,58,125 INJURED
  • 3. PROCESS • Methlyamine rea cts with Phosgene producing Methyl Isocyanate (MIC) which reacts with 1-Naphthol to pr oduce pesticide C arbaryl, also kno wn as Sevin.
  • 4. METHYL ISOCYNATE • Liquid form, Volatile • Colourless • Strong, sharp odour • Flash Point – -7oC • Molecular weight: 57.05 daltons • Boiling point (760 mm Hg): 102ºF (39.1ºC) • Freezing point: -49ºF • Vapor pressure: 348 mm Hg at 68ºF (20ºC) • Vapor density: 1.42 (air = 1.00) • Water solubility: Reactive 6.7% at 68ºF (20ºC) • Flammability: Highly flammable • Flammable Range: 5.3% to 26% (concentration in air)
  • 5. • Night of 2nd December 1984 • Water entered Tank E610 containg 42 tonnes of MIC • EXOTHERMIC REACTION
  • 6. Toxic Materials in Soil and Water
  • 7. CAUSES •OVERSTORAGE •POOR MAINTENANCE •DENSELY POPULATED AREAS •FAILURE OF SAFETY SYSTEMS •LACK OF AWARENESS ABOUT MIC •LACK OF SAFETY TRAINING
  • 8. VENT GAS SCRUBBER WAS SHUT DOWN FLARE TOWER PIPE WAS CORRO DED MIC REFRIGERATION SYSTEM WA S NOT FUNCTIONING. SINGLE MANUAL BACKUP SYSTE M.
  • 9. Gas Vent Scrubber Gas Vent Scrubber Stack