Properties of enantiomers?: Their NMR and IR spectra are identical. However,
enantiomers behave differently in the presence of other chiral molecules or objects. For example,
enantiomers do not migrate identically on chiral chromatographic media, such as quartz or
standard media that have been chirally modified. The NMR spectra of enantiomers are affected
differently by single-enantiomer chiral additives such as Eufod. Chiral compounds rotate plane
polarized light. Each enantiomer will rotate the light in a different sense, clockwise or
counterclockwise. Molecules that do this are said to be optically active. Characteristically,
different enantiomers of chiral compounds often taste and smell differently and have different
effects as drugs – see below. These effects reflect the chirality inherent in biological systems.
One chiral \'object\' that interacts differently with the two enantiomers of a chiral compound is
circularly polarised light: An enantiomer will absorb left- and right-circularly polarised light to
differing degrees. This is the basis of circular dichroism (CD) spectroscopy. Usually the
difference in absorptivity is relatively small (parts per thousand). CD spectroscopy [12] is a
powerful analytical technique for investigating the secondary structure of proteins and for
determining the absolute configurations of chiral compounds, in particular, transition metal
complexes. CD spectroscopy is replacing polarimetry as a method for characterising chiral
compounds, although the latter is still popular with sugar chemists.
Solution
Properties of enantiomers?: Their NMR and IR spectra are identical. However,
enantiomers behave differently in the presence of other chiral molecules or objects. For example,
enantiomers do not migrate identically on chiral chromatographic media, such as quartz or
standard media that have been chirally modified. The NMR spectra of enantiomers are affected
differently by single-enantiomer chiral additives such as Eufod. Chiral compounds rotate plane
polarized light. Each enantiomer will rotate the light in a different sense, clockwise or
counterclockwise. Molecules that do this are said to be optically active. Characteristically,
different enantiomers of chiral compounds often taste and smell differently and have different
effects as drugs – see below. These effects reflect the chirality inherent in biological systems.
One chiral \'object\' that interacts differently with the two enantiomers of a chiral compound is
circularly polarised light: An enantiomer will absorb left- and right-circularly polarised light to
differing degrees. This is the basis of circular dichroism (CD) spectroscopy. Usually the
difference in absorptivity is relatively small (parts per thousand). CD spectroscopy [12] is a
powerful analytical technique for investigating the secondary structure of proteins and for
determining the absolute configurations of chiral compounds, in particular, transition metal
complexes. CD spectroscopy is re.
Properties of enantiomers Their NMR and IR spec.pdf
1. Properties of enantiomers?: Their NMR and IR spectra are identical. However,
enantiomers behave differently in the presence of other chiral molecules or objects. For example,
enantiomers do not migrate identically on chiral chromatographic media, such as quartz or
standard media that have been chirally modified. The NMR spectra of enantiomers are affected
differently by single-enantiomer chiral additives such as Eufod. Chiral compounds rotate plane
polarized light. Each enantiomer will rotate the light in a different sense, clockwise or
counterclockwise. Molecules that do this are said to be optically active. Characteristically,
different enantiomers of chiral compounds often taste and smell differently and have different
effects as drugs – see below. These effects reflect the chirality inherent in biological systems.
One chiral 'object' that interacts differently with the two enantiomers of a chiral compound is
circularly polarised light: An enantiomer will absorb left- and right-circularly polarised light to
differing degrees. This is the basis of circular dichroism (CD) spectroscopy. Usually the
difference in absorptivity is relatively small (parts per thousand). CD spectroscopy [12] is a
powerful analytical technique for investigating the secondary structure of proteins and for
determining the absolute configurations of chiral compounds, in particular, transition metal
complexes. CD spectroscopy is replacing polarimetry as a method for characterising chiral
compounds, although the latter is still popular with sugar chemists.
Solution
Properties of enantiomers?: Their NMR and IR spectra are identical. However,
enantiomers behave differently in the presence of other chiral molecules or objects. For example,
enantiomers do not migrate identically on chiral chromatographic media, such as quartz or
standard media that have been chirally modified. The NMR spectra of enantiomers are affected
differently by single-enantiomer chiral additives such as Eufod. Chiral compounds rotate plane
polarized light. Each enantiomer will rotate the light in a different sense, clockwise or
counterclockwise. Molecules that do this are said to be optically active. Characteristically,
different enantiomers of chiral compounds often taste and smell differently and have different
effects as drugs – see below. These effects reflect the chirality inherent in biological systems.
One chiral 'object' that interacts differently with the two enantiomers of a chiral compound is
circularly polarised light: An enantiomer will absorb left- and right-circularly polarised light to
differing degrees. This is the basis of circular dichroism (CD) spectroscopy. Usually the
difference in absorptivity is relatively small (parts per thousand). CD spectroscopy [12] is a
powerful analytical technique for investigating the secondary structure of proteins and for
determining the absolute configurations of chiral compounds, in particular, transition metal
complexes. CD spectroscopy is replacing polarimetry as a method for characterising chiral
compounds, although the latter is still popular with sugar chemists.