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http://dx.doi.org/10.1111/j.1863-2378.2012.01522.x
http://dx.doi.org/10.1007/s00253-013-4939-1

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ManganesehasbeenobservedonMarsbytheNASACuriosityroverinavarietyofcontextsand isanimportantindicatorofredoxprocessesinhydrologicsystemsonEarth.WithintheMurrayformation,an ancientprimarilyfine‐grainedlacustrinesedimentarydeposit inGalecrater,Mars,haveobservedupto45× enrichmentinmanganeseandupto1.5×enrichmentinironwithincoarsergrainedbedrocktargetscomparedto themeanMurraysedimentcomposition.Thisenrichment inmanganesecoincideswiththetransitionbetween twostratigraphicunitswithintheMurray:SuttonIsland, interpretedasalakemarginenvironment,andBlunts Point,interpretedasalakeenvironment.OnEarth,lacustrineenvironmentsarecommonlocationsofmanganese precipitationduetohighlyoxidizingconditionsinthelakes.Here,weexplorethreemechanismsfor ferromanganeseoxideprecipitationatthislocation:authigenicprecipitationfromlakewateralongalakeshore, authigenicprecipitationfromreducedgroundwaterdischargingthroughporoussandsalongalakeshore,and earlydiageneticprecipitationfromgroundwaterthroughporoussands.All threescenariosrequirehighly oxidizingconditionsandwediscussoxidantsthatmayberesponsiblefortheoxidationandprecipitationof manganeseoxides.Thisworkhasimportant implicationsforthehabitabilityofMarstomicrobesthatcould haveusedMnredoxreactions,owingtoitsmultipleredoxstates,asanenergysourceformetabolism.

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11. http://dx.doi.org/10.1111/j.1863-2378.2012.01522.x http://dx.doi.org/10.1007/s00253-013-4939-1

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