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MIGRATION REPORT FOR ORGANIC COMPOUNDS IN WATER
This report only affects the sample. You can only partially
reproduce with the written permission of the laboratory.
Date: 23-04-2013 Date: 23-04-2013
Elaborated by: Revised by:
Jorge Agulló Carpena Julio Llorca Porcel
Technician Head of Chromatography Department
LABAQUA S.A. / C/ Dracma, 16-18 • Polígono Industrial Las Atalayas / 03114 Alicante / Tel. +34 965 106 070 / www.labaqua.com
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
INDEX
1. INTRODUCTION AND GENERAL INFORMATION ............................................... 3
2. ELEMENTS OF STUDY DESCRIPTION .........................................................4
3. EXPERIMENTAL PROCEDURE ......................................................................5
4. RESULTS...............................................................................................................7
5. CONCLUSIONS...................................................................................................11
6. RESULTS INTERPRETATION ........................................................................15
Page 2 of 16
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
1. INTRODUCTION AND GENERAL INFORMATION
Komsol Hispania has required a migration study of a liquid material used to be applied in
drinking water facilities.
LABORATORY DATA:
LABAQUA S.A.
Address:
C/ Dracma, 16-18
Polígono Industrial Las Atalayas
03114 – Alicante
España
Phone: 965 10 60 70
Fax: 965 10 60 80
info@labaqua.com
COSTUMER DATA:
Company name:
Komsol Hispaña,
S.L. Address:
Avenida Escandinavia 63, Buzon 122
03130 Santa Pola España
Phone: 693 792 968 Fax: 966 698 158
Web: www.komsol.es E-mail: ea@komsol.es
Page 3 of 16
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
2. ELEMENTS OF STUDY DESCRIPTION
Material pieces. The pieces consist in ceramics sheets covers with the product. The
samples have been identified as 1889760 (Sample) and 1922401 (Blank)
Application: The material has been indicated to be used in water installations.
Commercial name: 11775 CONTROLL INNERSEAL.
Reception data in AQUALOGY LABAQUA on 28th-February 2013.
Manufactured: MAYNOR AS
NORUEGA. Sample remitted by: KOMSOL
HISPAÑA, S.L. Samples prepared by : KOMSOL
HISPAÑA, S.L..
Essay pieces preparation: The sample consist in 10 ceramics sheets cover with the
product. KOMSOL HISPAÑA applied the product on the sheets according with the manual
instructions of the product.
● Pieces characteristics and dimensions:
Dimensions:
10.5 cm × 3.1cm each piece.
S = 0.326dm2
× 2 faces = 0.652dm2
Total pieces = 10
STotal = 6.52dm2
Ratio S/V = 6.52 / 1 litter = 6.52dm-1
Page 4 of 16
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
Figure 1. Essay pieces picture.
Page 5 of 16
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
3. EXPERMENTAL PROCEDURE
The present study is based on UNE-EN ISO 12873-2: 2005 Influence of materials on water
intended for human consumption, Influence of migration. Part 2: Test method applied in situ
materials, excluding metallic materials and cement-based materials.
When the migration water was obtained, the water sample was analyzed, indicated in the
Annex I, in order to calculate the migration rate.
According with the UNE-EN ISO 12873-2: 2005 and with CEN/CENELEC regulations, all
the European countries are required to reach the specifications indicated.
Table 1. General information about the migration test:
Parameter Information
Total number of sheets 10 sheets
Final water volume 1 L
Disinfection process Do not proceed
Water essay characteristics
Water: Milli-q originating in a
Millipore A10 Equipment (CODE A-
052.)
Essay water and temperature
Milli-q water at 70 ± 2 ºC during 24±1h
3 migration periods
Test deviations No deviations have been observed
Incidences No incidences have been observed
Start date : 08/April/2013
Final date: 12/April/2013
Page 6 of 16
MEDIO AMBIENTE
AQUALOGY ENAC
ENSAYOS
Informe migración Nº 109/ L E 285 22/03/2013
Reagents used:
- Tap water from the laboratory.
- Essay water, Milli-q from Millipore A10 equipment (Internal Laboratory Code = A-052)
- Chronometer ID Plan 1873, ID Calibration 25126. (Laboratory code G-154) Ultratermostater
+ refrigeration unit ID Plan 701. ID Calibration 9732. Laboratory Code
(AG – 145)
Migration steps:
- Sampling, shipment and preservation. The sample was provided by the company KOMSOL
HISPAÑA, S.L No special preservation condition was required.
- Sample preparation. The client covered the ceramics sheets on LABAQUA facilities. After
the product applications process, the sheets was stand 28 days in the dark. According with
UNE-EN 12873-1: 2005 only the surface in contact with the water must be into
consideration for the migration. All the sheets faces was cover with the product.
- Pieces treatment. The previous treatment consist on a washing step with a continuous water
flow (rate between 1 to 3 m/min) during 60±5 minutes.
- Static contact period. The sheets were complete immersed in one (1) litter of water during
24±1 hours. No disinfection process has been required.
- Migration essay. The sheets were immersed in 1L of water at 70±2 ºC. Three cycles (24
hour each) was carried out at the indicated temperature. At the same time, a blank without
samples pieces, have been also carried out in the same conditions than the samples. This report
includes the results obtained for the performed cycle of each sample
- Analysis. The final concentration of the organic compounds was determined by means of the
analytical methods indicated in the Annex I.
Page 7 of 16

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#Controllinnerseal :MIGRATION REPORT FOR ORGANIC COMPOUNDS IN WATER

  • 1. MIGRATION REPORT FOR ORGANIC COMPOUNDS IN WATER This report only affects the sample. You can only partially reproduce with the written permission of the laboratory. Date: 23-04-2013 Date: 23-04-2013 Elaborated by: Revised by: Jorge Agulló Carpena Julio Llorca Porcel Technician Head of Chromatography Department LABAQUA S.A. / C/ Dracma, 16-18 • Polígono Industrial Las Atalayas / 03114 Alicante / Tel. +34 965 106 070 / www.labaqua.com
  • 2. MEDIO AMBIENTE AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 INDEX 1. INTRODUCTION AND GENERAL INFORMATION ............................................... 3 2. ELEMENTS OF STUDY DESCRIPTION .........................................................4 3. EXPERIMENTAL PROCEDURE ......................................................................5 4. RESULTS...............................................................................................................7 5. CONCLUSIONS...................................................................................................11 6. RESULTS INTERPRETATION ........................................................................15 Page 2 of 16 MEDIO AMBIENTE
  • 3. AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 1. INTRODUCTION AND GENERAL INFORMATION Komsol Hispania has required a migration study of a liquid material used to be applied in drinking water facilities. LABORATORY DATA: LABAQUA S.A. Address: C/ Dracma, 16-18 Polígono Industrial Las Atalayas 03114 – Alicante España Phone: 965 10 60 70 Fax: 965 10 60 80 info@labaqua.com COSTUMER DATA: Company name: Komsol Hispaña, S.L. Address: Avenida Escandinavia 63, Buzon 122 03130 Santa Pola España Phone: 693 792 968 Fax: 966 698 158 Web: www.komsol.es E-mail: ea@komsol.es Page 3 of 16
  • 4. MEDIO AMBIENTE AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 2. ELEMENTS OF STUDY DESCRIPTION Material pieces. The pieces consist in ceramics sheets covers with the product. The samples have been identified as 1889760 (Sample) and 1922401 (Blank) Application: The material has been indicated to be used in water installations. Commercial name: 11775 CONTROLL INNERSEAL. Reception data in AQUALOGY LABAQUA on 28th-February 2013. Manufactured: MAYNOR AS NORUEGA. Sample remitted by: KOMSOL HISPAÑA, S.L. Samples prepared by : KOMSOL HISPAÑA, S.L.. Essay pieces preparation: The sample consist in 10 ceramics sheets cover with the product. KOMSOL HISPAÑA applied the product on the sheets according with the manual instructions of the product. ● Pieces characteristics and dimensions: Dimensions: 10.5 cm × 3.1cm each piece. S = 0.326dm2 × 2 faces = 0.652dm2 Total pieces = 10 STotal = 6.52dm2 Ratio S/V = 6.52 / 1 litter = 6.52dm-1
  • 5. Page 4 of 16 MEDIO AMBIENTE AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 Figure 1. Essay pieces picture.
  • 6. Page 5 of 16 MEDIO AMBIENTE AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 3. EXPERMENTAL PROCEDURE The present study is based on UNE-EN ISO 12873-2: 2005 Influence of materials on water intended for human consumption, Influence of migration. Part 2: Test method applied in situ materials, excluding metallic materials and cement-based materials. When the migration water was obtained, the water sample was analyzed, indicated in the Annex I, in order to calculate the migration rate. According with the UNE-EN ISO 12873-2: 2005 and with CEN/CENELEC regulations, all the European countries are required to reach the specifications indicated. Table 1. General information about the migration test: Parameter Information Total number of sheets 10 sheets Final water volume 1 L Disinfection process Do not proceed Water essay characteristics Water: Milli-q originating in a Millipore A10 Equipment (CODE A- 052.) Essay water and temperature Milli-q water at 70 ± 2 ºC during 24±1h 3 migration periods Test deviations No deviations have been observed Incidences No incidences have been observed Start date : 08/April/2013 Final date: 12/April/2013
  • 7. Page 6 of 16 MEDIO AMBIENTE AQUALOGY ENAC ENSAYOS Informe migración Nº 109/ L E 285 22/03/2013 Reagents used: - Tap water from the laboratory. - Essay water, Milli-q from Millipore A10 equipment (Internal Laboratory Code = A-052) - Chronometer ID Plan 1873, ID Calibration 25126. (Laboratory code G-154) Ultratermostater + refrigeration unit ID Plan 701. ID Calibration 9732. Laboratory Code (AG – 145) Migration steps: - Sampling, shipment and preservation. The sample was provided by the company KOMSOL HISPAÑA, S.L No special preservation condition was required. - Sample preparation. The client covered the ceramics sheets on LABAQUA facilities. After the product applications process, the sheets was stand 28 days in the dark. According with UNE-EN 12873-1: 2005 only the surface in contact with the water must be into consideration for the migration. All the sheets faces was cover with the product. - Pieces treatment. The previous treatment consist on a washing step with a continuous water flow (rate between 1 to 3 m/min) during 60±5 minutes. - Static contact period. The sheets were complete immersed in one (1) litter of water during 24±1 hours. No disinfection process has been required. - Migration essay. The sheets were immersed in 1L of water at 70±2 ºC. Three cycles (24 hour each) was carried out at the indicated temperature. At the same time, a blank without samples pieces, have been also carried out in the same conditions than the samples. This report includes the results obtained for the performed cycle of each sample - Analysis. The final concentration of the organic compounds was determined by means of the analytical methods indicated in the Annex I.