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Presented By
Yomna M. Saad
Lecture outline
• 1- Light interaction with objects
• Reflection, absorption and transmission
• Transparency, translucency and opacity
• Scattering, opalescence, fluorescence
• 2- color (hue, chroma, value, metamerism)
• 3- optical properties of ceramics
• Glasses and porcelains
• Glass ceramics
• Polycrystalline ceramics
• 4- recent advances
1- Reflection, Absorption and Transmission
Transparency, translucency and opacity
Small band gap
1.8eV, light
absorption, opaque
Medium band gap 1.8-
3eV, light transmission
and reflection,
translucent
Large band gap
>3eV, light
transmission,
transparent
Enamel: transmits up to 70% of light,
reflected light gives luster
Dentin: less translucent than enamel
and can transmit up to 30%, primary
source of color due to reflection
ADJ: light is reflected to enamel or
refracted into dentin
Translucency is
affected by:
• Thickness (aging)
• Micro-structure
• Hydration
Scattering
• To calculate transmitted
light, the coefficient of
absorption and
coefficient of scattering
must be calculated.
• Scattering anisotropy
factor (-1 dentin and
zirconia, 0 glass, +1
enamel)
2- Opalescence
• Similar to opal
stone
• Blue with
reflected light
and orange with
transmitted light
(light scattering)
• Results from HA crystals (enamel)which
are smaller than the light wavelength
which could be imitated by oxides
3- Fluorescence
• Absorbing non-visible light and
emanating light of different
wavelengths
• Teeth fluoresce under
ultraviolet radiation due to
fluors or proteins in the dentin
giving a blue color
• Gives vitality to the tooth
• Rare earths, such as
europium, terbium,
cerium, and ytterbium,
are currently used as
luminophores to provide
ceramic materials with
fluorescence.
• Luminaries by VITA allow
light reflection to the
overlying structures to
give fluorescence.
Color parameters
Luminosity (brightness) - value
• High value – children
• Medium value – adults
• Low value – elderly
• Viewed better with polarized filters
Metamerism
• The color difference (∆E)
between 2 objects can
be determined by
comparing the
differences between the
respective coordinate
values for each object
• Perceptibility and
acceptability thresholds
• Translucency parameter
• Opalescence parameter
• Non-metallic, inorganic
structures primarily containing
compounds of oxygen with
one or more metallic or semi-
metallic elements
• Amorphous or crystalline
Ceramics
Classification
1- Glasses and
porcelains
• Amorphous structure
• Feldspar (potassium),
quartz (silica) and kaolin
• Metal oxide pigments
• Different fusion
temperatures
• Weak and brittle
• Chromium or chrome-alumina
(pink)
• Iron oxide (black) or platinum
(Grey)
• Cobalt oxide (Blue)
• Titanium oxide (yellow brown)
• Iron/nickel oxide (brown)
• Pure glass is transparent and allows 98% of light to
pass, therefore opaque materials are added to make it
semi-translucent like the tooth.
• Dental porcelains are translucent because there are no
free electrons (transmission > reflection and
absorption)
• Problems arise from the substructure
Porcelain fused to
metal (PFM)
• Increased light reflectivity from the opaque
porcelains that are used to mask the metal
coping
• Opaque porcelain> body porcelain> incisal
porcelain
• Transmission only in the body of the porcelain
• Looks less vital due to low light transmission
Porcelain
veneers

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Optical props of dental ceramics part 1

  • 2.
  • 3. Lecture outline • 1- Light interaction with objects • Reflection, absorption and transmission • Transparency, translucency and opacity • Scattering, opalescence, fluorescence • 2- color (hue, chroma, value, metamerism) • 3- optical properties of ceramics • Glasses and porcelains • Glass ceramics • Polycrystalline ceramics • 4- recent advances
  • 4. 1- Reflection, Absorption and Transmission
  • 6. Small band gap 1.8eV, light absorption, opaque Medium band gap 1.8- 3eV, light transmission and reflection, translucent Large band gap >3eV, light transmission, transparent
  • 7. Enamel: transmits up to 70% of light, reflected light gives luster Dentin: less translucent than enamel and can transmit up to 30%, primary source of color due to reflection ADJ: light is reflected to enamel or refracted into dentin
  • 8. Translucency is affected by: • Thickness (aging) • Micro-structure • Hydration
  • 9. Scattering • To calculate transmitted light, the coefficient of absorption and coefficient of scattering must be calculated. • Scattering anisotropy factor (-1 dentin and zirconia, 0 glass, +1 enamel)
  • 10. 2- Opalescence • Similar to opal stone • Blue with reflected light and orange with transmitted light (light scattering)
  • 11. • Results from HA crystals (enamel)which are smaller than the light wavelength which could be imitated by oxides
  • 12.
  • 13. 3- Fluorescence • Absorbing non-visible light and emanating light of different wavelengths • Teeth fluoresce under ultraviolet radiation due to fluors or proteins in the dentin giving a blue color • Gives vitality to the tooth
  • 14. • Rare earths, such as europium, terbium, cerium, and ytterbium, are currently used as luminophores to provide ceramic materials with fluorescence. • Luminaries by VITA allow light reflection to the overlying structures to give fluorescence.
  • 16. Luminosity (brightness) - value • High value – children • Medium value – adults • Low value – elderly • Viewed better with polarized filters
  • 18. • The color difference (∆E) between 2 objects can be determined by comparing the differences between the respective coordinate values for each object • Perceptibility and acceptability thresholds
  • 19. • Translucency parameter • Opalescence parameter
  • 20. • Non-metallic, inorganic structures primarily containing compounds of oxygen with one or more metallic or semi- metallic elements • Amorphous or crystalline Ceramics
  • 22. 1- Glasses and porcelains • Amorphous structure • Feldspar (potassium), quartz (silica) and kaolin • Metal oxide pigments • Different fusion temperatures • Weak and brittle
  • 23. • Chromium or chrome-alumina (pink) • Iron oxide (black) or platinum (Grey) • Cobalt oxide (Blue) • Titanium oxide (yellow brown) • Iron/nickel oxide (brown)
  • 24. • Pure glass is transparent and allows 98% of light to pass, therefore opaque materials are added to make it semi-translucent like the tooth. • Dental porcelains are translucent because there are no free electrons (transmission > reflection and absorption) • Problems arise from the substructure
  • 25. Porcelain fused to metal (PFM) • Increased light reflectivity from the opaque porcelains that are used to mask the metal coping • Opaque porcelain> body porcelain> incisal porcelain • Transmission only in the body of the porcelain • Looks less vital due to low light transmission

Editor's Notes

  1. Color is not a property of the object, but of the light that enters our eyes from it. Electromagnetic wave from 400-700 nm
  2. The light that doesn’t pass is reflected and gives color Transparent transmits, opaque absorbs and translucent does all
  3. Enamel is translucent while dentin is opaque Adj has light due to back reflection
  4. Micro grooves cause diffuse reflection This decrease was due to the increase of the refractive index of enamel caused by the water outflow and air intake on the outskirts of the prisms causing less hydration
  5. Negative is back scatter, positive is forward scatter and zero is no scatter of single crystals
  6. Since HA is destroyed by caries it appears black by trans illumination
  7. Blue light is scattered in all directions by the tiny molecules of air in Earth's atmosphere. Blue is scattered more than other colors because it travels as shorter, smaller waves.
  8. UV light of flash and composite
  9. Hue is the wavelength, chroma is the saturation, value is brightness
  10. In natural teeth, the value is characteristic for the enamel, while the chroma and hue characterize dentine. The younger individuals, less exposed to the wear caused by the acids in the diet and brushing, present enamel thicker than older individuals, and consequently lighter teeth. As wear is accentuated and the thickness of the enamel layer decreases, the translucency of the enamel increase, enabling chroma and hue, characteristics concerning the dentine, become more obvious.
  11. 3.7 is acceptable although color difference is seen 1 is perciptable
  12. Hue, chroma and value are used for colored objects but for dental objects translucency is the fourth parameter spectrophotometer
  13. More crystals therefore better mechanical props
  14. High potassium alumino silicate and low kaolin to give translucency Sodium and potassium are fluxes and opacifiers
  15. Blue for enamel, translucent
  16. No free electrons opposite to metals
  17. A natural tooth diffuses and transmits light, whereas a PFM restoration violates this property. It will only diffuse and reflect the light in the body area. As a result, PFM restorations often look brighter in the mouth