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Phytochemistry
S.Y.B.Sc. Botany Paper III
Unit 1
Part 5
Phytochemistry
Volatile Oils or Essential Oils
Menthol – Mentha arvensis
Sandal wood oil
The spice star anise is distilled
to make star anise oil
Davana oil, from the
Artemisia pallens
Volatile Oils or Essential Oils
Volatile oil originates from plants, possess a
unique odour or flavor, mainly used in
perfumes and flavorings.
Volatile Oils or Essential Oils
How to Differentiate Between Volatile Oil and
Fixed Oil?
Volatile Oils or Essential Oils
Volatile oil Fixed Oil
Also called as an essential oil. Also called as natural non-volatile oil.
Volatile oil can evaporate when placed under
room temperature
Fixed oils do not evaporate at room temperature
They can be extracted easily by the distillation
process
They require some specific techniques for
extraction.
There is no spot (no permanent stain) left after
evaporation
Some type of spot (permanent stain) left after
evaporation
They are unable to undergo saponification Fixed oils can be easily saponified.
Mixtures of cleoptenes & stearoptenes are
termed as volatile oils
Esters of higher fatty acids & glycerin are called
as fixed oils.
Posses high refractive index Posses low refractive index
These are optically active. These are optically inactive.
Their primary source is leaves, roots, in petals
and bark.
Their major source is seeds of the plant.
Volatile Oils or Essential Oils
• Odourous principles
• Plant parts – Leaf, bark, Seed, Fruit, Flower etc.
• Evaporates at room temperature
• Colourless initially – on oxidation – resinify – turn
dark in colour
• Stored in amber coloured bottle, tightly
stoppered
• Immiscible with water
Volatile Oils or Essential Oils
Distribution
• Labiatae/ Lamiaceae
• Piperaceae
• Umbelliferae/Apiaceae
• Pinaceae
• Rutaceae
Volatile Oils or Essential Oils
Chemical Composition
• Hydrocarbon + Oxygenated compounds of
Hydrocarbons
• Type I – Hydrocarbon > Oxygenated Compds.
of Hydrocarbons
– Eg. Turpentine
• Type II– Hydrocarbon < Oxygenated Compds.
of Hydrocarbons
– Eg. Clove oil
Volatile Oils or Essential Oils
• Oxygenated Compounds are more soluble in
Alcohol than Water
• Volatile oils differ in chemical composition
• But number of physical properties are common,
like –
– Odour – Characteristic
– Refractive Index – High
– Mostly – Optically active
– Contains – Terpenes, Sesquiterpenes and
Diterpenes, alcohol, aldehyde, ketones,
phenols, ethers and esters
Volatile Oils or Essential Oils
Properties
• Volatises at room temperature
• Does not leave any stain on paper
• On exposure – they oxidise – then resinify
• Do not form soap with alkali
• They can be steam distilled at ordinary
temperature
• Mix freely with Chloroform, Ether and Alcohol
Volatile Oils or Essential Oils
Extraction of Volatile oils
• Distillation
• Cold expression
• Fat Expression
– Enfleurage
– Maceration
• Solvent Extraction
Extraction of Volatile oils
Extraction of Volatile oils
Volatile Oils or Essential Oils
Uses
• As flavouring agent in pharma, food,
beverages, cosmetics etc.
• Perfume industry
• As medicines and Carminative(Camphor,
Pudina etc.)
• Antiseptic, Antihelmintic, Stimulant, local
counter irritant
The global essential oil market is
expected to reach USD 11.67
billion by 2022, according to a new
report by Grand View Research, Inc.
Growing consumer awareness
regarding heath benefits associated
with natural and organic personal
care products is expected to remain
a key driving factor for global
essential oil market over the forecast
period.
Growth of organic product industry
has prompted major manufacturers
to shift their focus from synthetic to
natural additives.
Growing use of essential oil in the
preparation of natural flavors and
fragrances on account of their
increasing demand across key end-
use industries is also expected to fuel
the market growth.
Pharmacognosy part 5
Pharmacognosy part 5

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Pharmacognosy part 5

  • 4. Sandal wood oil The spice star anise is distilled to make star anise oil Davana oil, from the Artemisia pallens
  • 5.
  • 6. Volatile Oils or Essential Oils Volatile oil originates from plants, possess a unique odour or flavor, mainly used in perfumes and flavorings.
  • 7. Volatile Oils or Essential Oils How to Differentiate Between Volatile Oil and Fixed Oil?
  • 8. Volatile Oils or Essential Oils Volatile oil Fixed Oil Also called as an essential oil. Also called as natural non-volatile oil. Volatile oil can evaporate when placed under room temperature Fixed oils do not evaporate at room temperature They can be extracted easily by the distillation process They require some specific techniques for extraction. There is no spot (no permanent stain) left after evaporation Some type of spot (permanent stain) left after evaporation They are unable to undergo saponification Fixed oils can be easily saponified. Mixtures of cleoptenes & stearoptenes are termed as volatile oils Esters of higher fatty acids & glycerin are called as fixed oils. Posses high refractive index Posses low refractive index These are optically active. These are optically inactive. Their primary source is leaves, roots, in petals and bark. Their major source is seeds of the plant.
  • 9. Volatile Oils or Essential Oils • Odourous principles • Plant parts – Leaf, bark, Seed, Fruit, Flower etc. • Evaporates at room temperature • Colourless initially – on oxidation – resinify – turn dark in colour • Stored in amber coloured bottle, tightly stoppered • Immiscible with water
  • 10. Volatile Oils or Essential Oils Distribution • Labiatae/ Lamiaceae • Piperaceae • Umbelliferae/Apiaceae • Pinaceae • Rutaceae
  • 11. Volatile Oils or Essential Oils Chemical Composition • Hydrocarbon + Oxygenated compounds of Hydrocarbons • Type I – Hydrocarbon > Oxygenated Compds. of Hydrocarbons – Eg. Turpentine • Type II– Hydrocarbon < Oxygenated Compds. of Hydrocarbons – Eg. Clove oil
  • 12. Volatile Oils or Essential Oils • Oxygenated Compounds are more soluble in Alcohol than Water • Volatile oils differ in chemical composition • But number of physical properties are common, like – – Odour – Characteristic – Refractive Index – High – Mostly – Optically active – Contains – Terpenes, Sesquiterpenes and Diterpenes, alcohol, aldehyde, ketones, phenols, ethers and esters
  • 13. Volatile Oils or Essential Oils Properties • Volatises at room temperature • Does not leave any stain on paper • On exposure – they oxidise – then resinify • Do not form soap with alkali • They can be steam distilled at ordinary temperature • Mix freely with Chloroform, Ether and Alcohol
  • 14. Volatile Oils or Essential Oils Extraction of Volatile oils • Distillation • Cold expression • Fat Expression – Enfleurage – Maceration • Solvent Extraction
  • 17. Volatile Oils or Essential Oils Uses • As flavouring agent in pharma, food, beverages, cosmetics etc. • Perfume industry • As medicines and Carminative(Camphor, Pudina etc.) • Antiseptic, Antihelmintic, Stimulant, local counter irritant
  • 18. The global essential oil market is expected to reach USD 11.67 billion by 2022, according to a new report by Grand View Research, Inc.
  • 19. Growing consumer awareness regarding heath benefits associated with natural and organic personal care products is expected to remain a key driving factor for global essential oil market over the forecast period.
  • 20. Growth of organic product industry has prompted major manufacturers to shift their focus from synthetic to natural additives.
  • 21. Growing use of essential oil in the preparation of natural flavors and fragrances on account of their increasing demand across key end- use industries is also expected to fuel the market growth.