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ENGINEERING
CHEMSTRY-II
SUB CODE : CY6251
Persented
By
OUT LINE
 History
 About Cement
 Raw materials
 Description
 Manufacturing Process
 Manufacturing Steps
 Process Scheme
 Uses
History
 Cement was first invented by the Egyptians.
 Cement was later reinvented by the Greeks
and the Babylonians who made their mortar
out of lime.
 About ninety-nine percent of all cement used
today is Portland cement.
PORTLAND CEMENTS
 Cement is a material with adhesive and cohesive
properties which make it capable of bonding
minerals fragments into a compact whole.
 It helps to join the materials like
stones,sand,bricks,building stones etc…
 PORTLAND – Island in English
What is Cement?
 Cement is a fine grayish powder which, when mixed with water, forms a thick
paste. When this paste is mixed with sand and gravel and allowed to dry it is called
concrete.
 The term cement is commonly used to refer to powdered materials which develop strong
adhesive qualities when combined with water.
 Gypsum plaster, common lime, hydraulic lime, natural pozzolana, and Portland cements
are the more common hydraulic cements.
RAW MATERIALS :
 Calcareous Material : Such as limestone or chalk ,
as a source of lime .
 Clayey Material : Such as clay or shale(soft clayey
stones), as a source of silica and alumina .
MANUFACTURING METHODS
METHODS
WET
PROCESS
DRY
PROCESS
 WET PROCESS :
Grinding and mixing of the raw materials
the existence of water.
 DRY PROCESS :
Grinding and mixing of the raw materials
their dry state
Manufacturing Process
 The production of cement takes place with several steps:
• Quarrying of limestone and shale
• Dredging the ocean floor for shells
• Digging for clay and marl
• Grinding
• Blending of components
• Fine grinding
• Burning
• Finish grinding
• Packaging and/or shipping
Manufacturing Steps
 The most common way to manufacture Portland cement is through a
dry method.
 The first step is to quarry the principal raw materials, mainly
limestone, clay, and other materials. After quarrying the rock is
crushed. This involves several stages.
 The first crushing reduces the rock to a maximum size of about 6
inches. The rock then goes to secondary crushers or hammer mills for
reduction to about 3 inches or smaller.
Manufacturing Steps
 The crushed rock is combined with other
ingredients such as iron ore or fly ash and ground,
mixed, and fed to a cement kiln.
 The cement kiln heats all the ingredients to about
2,700 degrees Fahrenheit in huge cylindrical steel
rotary kilns lined with special firebrick.
 In its simplest form, the rotary kiln is a tube up to
200 meters long and perhaps 6 meters in
diameter, with a long flame at one end.
Manufacturing Steps
 The material formed in the kiln is described as 'clinker' and is
typically composed of rounded nodules between 1mm and
25mm across.
 After cooling, the clinker may be stored temporarily in a clinker
store, or it may pass directly to the cement mill. The cement
mill grinds the clinker to a fine powder.
 A small amount of gypsum - a form of calcium sulfate - is
normally ground up with the clinker. The gypsum controls the
setting properties of the cement when water is added.
Process
PROCESS OF SETTING
CEMENT + WATER → CEMENT
PASTE → LOSE ITS PLASTICITY
GRADUALLY → WHEN IT LOSE ITS
PLASTICITY → SETTING OCCURS
COMPOSITION OF PORTLAND
CEMENTS
OXIDES PERCENTAGE CONTENT
Cao 60-67
SiO2 17-25
Al2O3 3-8
Fe2O3 0.5-6
Mgo 0.5-4
Alkalis (as Na2O) 0.3-1.2
SO3 2.0-3.5
SETTING AND HARDNING
STAGES OF SETTING
FIRST STAGE :
C3A + 6H2O → C3A.6H2O
SECOND STAGE :
2C3S + 6H2O → C3S.3H2O + 3Ca(OH)2
THIRD STAGE :
2C2S + 4H2O → C3S2.3H2O + C(OH)2
FOURTH STAGE :(Hardening)
C4AF + 7H2O → C3A.6H2O + CF.H2O
FACTORS AFFECTING THE SETTING
WATER/CEMENT RATIO : Setting time increases with
the increase of W/O ratio .
TEMPERATURE AND RELATIVE HUMIDITY : Setting
time decreases with a rise in temperature .
FINENESS OF CEMENT : Setting time decreases with a
rise in fineness of cement .
Uses
 Its modern uses include:
• Building (floors, beams, columns, roofing, piles, bricks, mortar,
panels, plaster).
• Transport (roads, pathways, crossings, bridges, sleepers, viaducts,
tunnels, stabilization, runways, parking).
• Water (pipes, culverts, kerbing, drains, canals, weirs, dams, tanks,
pools).
• Civil (piers, docks, retaining walls, silos, warehousing, poles, pylons,
fencing).
• Agriculture (buildings, processing, housing, feedlots, irrigation).
Engineering Chemistry-II: Cement Manufacturing Process

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Engineering Chemistry-II: Cement Manufacturing Process

  • 3. OUT LINE  History  About Cement  Raw materials  Description  Manufacturing Process  Manufacturing Steps  Process Scheme  Uses
  • 4. History  Cement was first invented by the Egyptians.  Cement was later reinvented by the Greeks and the Babylonians who made their mortar out of lime.  About ninety-nine percent of all cement used today is Portland cement.
  • 5. PORTLAND CEMENTS  Cement is a material with adhesive and cohesive properties which make it capable of bonding minerals fragments into a compact whole.  It helps to join the materials like stones,sand,bricks,building stones etc…  PORTLAND – Island in English
  • 6. What is Cement?  Cement is a fine grayish powder which, when mixed with water, forms a thick paste. When this paste is mixed with sand and gravel and allowed to dry it is called concrete.  The term cement is commonly used to refer to powdered materials which develop strong adhesive qualities when combined with water.  Gypsum plaster, common lime, hydraulic lime, natural pozzolana, and Portland cements are the more common hydraulic cements.
  • 7. RAW MATERIALS :  Calcareous Material : Such as limestone or chalk , as a source of lime .  Clayey Material : Such as clay or shale(soft clayey stones), as a source of silica and alumina .
  • 9.  WET PROCESS : Grinding and mixing of the raw materials the existence of water.  DRY PROCESS : Grinding and mixing of the raw materials their dry state
  • 10. Manufacturing Process  The production of cement takes place with several steps: • Quarrying of limestone and shale • Dredging the ocean floor for shells • Digging for clay and marl • Grinding • Blending of components • Fine grinding • Burning • Finish grinding • Packaging and/or shipping
  • 11. Manufacturing Steps  The most common way to manufacture Portland cement is through a dry method.  The first step is to quarry the principal raw materials, mainly limestone, clay, and other materials. After quarrying the rock is crushed. This involves several stages.  The first crushing reduces the rock to a maximum size of about 6 inches. The rock then goes to secondary crushers or hammer mills for reduction to about 3 inches or smaller.
  • 12. Manufacturing Steps  The crushed rock is combined with other ingredients such as iron ore or fly ash and ground, mixed, and fed to a cement kiln.  The cement kiln heats all the ingredients to about 2,700 degrees Fahrenheit in huge cylindrical steel rotary kilns lined with special firebrick.  In its simplest form, the rotary kiln is a tube up to 200 meters long and perhaps 6 meters in diameter, with a long flame at one end.
  • 13. Manufacturing Steps  The material formed in the kiln is described as 'clinker' and is typically composed of rounded nodules between 1mm and 25mm across.  After cooling, the clinker may be stored temporarily in a clinker store, or it may pass directly to the cement mill. The cement mill grinds the clinker to a fine powder.  A small amount of gypsum - a form of calcium sulfate - is normally ground up with the clinker. The gypsum controls the setting properties of the cement when water is added.
  • 15. PROCESS OF SETTING CEMENT + WATER → CEMENT PASTE → LOSE ITS PLASTICITY GRADUALLY → WHEN IT LOSE ITS PLASTICITY → SETTING OCCURS
  • 16. COMPOSITION OF PORTLAND CEMENTS OXIDES PERCENTAGE CONTENT Cao 60-67 SiO2 17-25 Al2O3 3-8 Fe2O3 0.5-6 Mgo 0.5-4 Alkalis (as Na2O) 0.3-1.2 SO3 2.0-3.5
  • 17. SETTING AND HARDNING STAGES OF SETTING FIRST STAGE : C3A + 6H2O → C3A.6H2O SECOND STAGE : 2C3S + 6H2O → C3S.3H2O + 3Ca(OH)2 THIRD STAGE : 2C2S + 4H2O → C3S2.3H2O + C(OH)2 FOURTH STAGE :(Hardening) C4AF + 7H2O → C3A.6H2O + CF.H2O
  • 18. FACTORS AFFECTING THE SETTING WATER/CEMENT RATIO : Setting time increases with the increase of W/O ratio . TEMPERATURE AND RELATIVE HUMIDITY : Setting time decreases with a rise in temperature . FINENESS OF CEMENT : Setting time decreases with a rise in fineness of cement .
  • 19. Uses  Its modern uses include: • Building (floors, beams, columns, roofing, piles, bricks, mortar, panels, plaster). • Transport (roads, pathways, crossings, bridges, sleepers, viaducts, tunnels, stabilization, runways, parking). • Water (pipes, culverts, kerbing, drains, canals, weirs, dams, tanks, pools). • Civil (piers, docks, retaining walls, silos, warehousing, poles, pylons, fencing). • Agriculture (buildings, processing, housing, feedlots, irrigation).