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Uso de polímero condutor na produção
de Tinta Inteligente Poliuretana
Anticorrosiva
UNIVERSIDADE FEDERAL DE ALAGOAS
PROGRAMA DE PÓS-GRADUAÇÃO EM MATÉRIAIS
CIÊNCIAS DOS MATERIAIS II
ALUNOS: Diego
Libel Pereira daFonseca
Rafael da Silva Oliveira de Holanda
O ARTIGO...
INTRODUÇÃO
ENSAIOS ELETROQUÍMICOS
Voltametria Cíclica (VC)
A análise de VC em AISI 1010 sem
revestimento busca identificar os valores
de potencial de início e fim da zona de
passivação do metal ao ser exposto à
solução aquosa de H2 SO4 2 mol/L.
Este ensaio ocorreu a partir da varredura de potencial de -1,00 a +2,00 𝑽Ag/AgCl.
ENSAIOS ELETROQUÍMICOS
Potencial de Circuito Aberto (OCP)
Os ensaios foram realizados em amostras de
aço AISI 1010 sem revestimento e com
revestimentos de TCP e a TIP, em período pré-
determinado de 18.000 s.
O aço sem revestimento encontra se em um processo de corrosão instalado.
ENSAIOS ELETROQUÍMICOS
Espectroscopia de Impedância Eletroquímica (EIE)
Figura 7 mostra o diagrama de Nyquist do
ensaio de EIE do aço AISI 1010 sem
revestimento para um período de 0,25 h de
exposição a solução aquosa de H2 SO4 2
mol/L, onde foi verificado um arco com valor
de resistência na ordem de 1400 Ω.cm2.
PAni EB contida nas TIP não sofre alterações significativas de sua capacidade eletroquímica em formar para
redox no sistema metal/revestimento/ eletrólito.
CONCLUSÃO
 Produção de PAni EP e sua passagem pelo processo de desdopagem para a PAni EB,
permitiu realizar a produção de um binder de PAni EB pelo uso do solvente CH2 Cl2;
 O uso do plastificante CMF, que não possui propriedades eletroquímicas que podem
interferir nas características desejadas do PIC.;
 Os filmes formados no binder não teve grandes alterações eletroquímicas;
 A TIP pode ser uma alternativa de revestimento anticorrosivo ativo, por determinado
período.

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Polimeros condutores

  • 1. Uso de polímero condutor na produção de Tinta Inteligente Poliuretana Anticorrosiva UNIVERSIDADE FEDERAL DE ALAGOAS PROGRAMA DE PÓS-GRADUAÇÃO EM MATÉRIAIS CIÊNCIAS DOS MATERIAIS II ALUNOS: Diego Libel Pereira daFonseca Rafael da Silva Oliveira de Holanda
  • 4. ENSAIOS ELETROQUÍMICOS Voltametria Cíclica (VC) A análise de VC em AISI 1010 sem revestimento busca identificar os valores de potencial de início e fim da zona de passivação do metal ao ser exposto à solução aquosa de H2 SO4 2 mol/L. Este ensaio ocorreu a partir da varredura de potencial de -1,00 a +2,00 𝑽Ag/AgCl.
  • 5. ENSAIOS ELETROQUÍMICOS Potencial de Circuito Aberto (OCP) Os ensaios foram realizados em amostras de aço AISI 1010 sem revestimento e com revestimentos de TCP e a TIP, em período pré- determinado de 18.000 s. O aço sem revestimento encontra se em um processo de corrosão instalado.
  • 6. ENSAIOS ELETROQUÍMICOS Espectroscopia de Impedância Eletroquímica (EIE) Figura 7 mostra o diagrama de Nyquist do ensaio de EIE do aço AISI 1010 sem revestimento para um período de 0,25 h de exposição a solução aquosa de H2 SO4 2 mol/L, onde foi verificado um arco com valor de resistência na ordem de 1400 Ω.cm2. PAni EB contida nas TIP não sofre alterações significativas de sua capacidade eletroquímica em formar para redox no sistema metal/revestimento/ eletrólito.
  • 7. CONCLUSÃO  Produção de PAni EP e sua passagem pelo processo de desdopagem para a PAni EB, permitiu realizar a produção de um binder de PAni EB pelo uso do solvente CH2 Cl2;  O uso do plastificante CMF, que não possui propriedades eletroquímicas que podem interferir nas características desejadas do PIC.;  Os filmes formados no binder não teve grandes alterações eletroquímicas;  A TIP pode ser uma alternativa de revestimento anticorrosivo ativo, por determinado período.