2. 2nd law of Thermodynamics
1st law of Thermodynamics
Consists of a series of thermodynamic processes, which take place in a specific order, and the initial conditions are
restored at the end of the processes.
Thermodynamic cycle
Classes of Thermodynamic Cycle:
1. Power cycle
-Convert some heat input into a mechanical work output
2. Heat pump cycles
-transfer heat from low to high temperatures by using mechanical work as the input
3. Class of cycle
/Working Substance
POWER CYCLE HEAT PUMP CYCLE
Ideal Gas - Carnot cycle
- Brayton cycle
- Otto cycle
- Diesel cycle
- Stirling cycle
- Ericson cycle
- Regenerative gas turbine cycle
- Intercooling, reheat regenerative
gas cycles
- Combined brayton-rankine cycle
- Reversed Carnot cycle
- Gas refrigeration cycle
Pure Substance - Rankine cycle
- Reheat cycle
- Supercritical rankine cycle
- Regenerative cycle
- Vapor refrigeration cycle
- Multistage vapor refrigeration
cycle
- Absorption refrigeration cycle
- Heat pump
4. Carnot Cycle: Ideal Power Thermodynamic Cycle
οIs the most efficient thermodynamics cycle
between a high temperature reservoir and a
low temperature reservoir
οAn Ideal cycle that uses reversible processes
to form its cycle operation
1-2 Adiabatic Reversible compression. The completely
insulated cylinder allows no heat transfer during this
reversible process.
2-3 Isothermal Expansion. Heat is transferred reversibly
from the high temperature reservoir at the constant
temperature TH. The piston in the cylinder is withdrawn
and the volume increases.
3-4 Adiabatic Reversible Expansion. The cylinder is
completely insulated so that no heat transfer occurs
during this reversible process. The piston in the cylinder
continues to be withdrawn and the volume increasing.
4-1 Isothermal Compression. Heat is transferred
reversibly to the low temperature reservoir at the
constant temperature The piston continues to compress
the working substance until the original volume,
temperature, and pressure are reached, thereby
completing the cycle.
Carnot Cycle Processes
5. A. ππ΄ = heat added = π2 (π4 - π1)
B. ππ = heat rejected = π1 (π4 - π1)
C. W = net work output = ππ΄ - ππ
W = (π2 - π1) (π4 - π1)
D. Change in entropy
ΞS =
ππ΄
π2
=
ππ
π1
=
π
π2βπ1
E. Cycle Efficiency
e =
π
ππ΄
=
ππ΄βππ
ππ΄
=
π
π+ππ
e =
π2βπ1
π2
= 1 β
π1
π2
= 1 β
ππΏ
ππ»
F. Mean Effective Pressure, Pm
ππ =
π
ππ·
where: ππ· = π1 - π2
Properties of Carnot Cycle
Carnot Cycle: T-S diagram
Isentropic expansion and compression process
Isothermal heat addition and rejection process
6. Learning Exercises
1. A carnot engine requires 35 KJ/sec from the hot source. The engine produces 15kw of power and
temperature of the sink is 26 degree Celsius. What is the temperature of the hot source? Ans. 250.5 Λ C
2. The maximum thermal efficiency possible for a power cycle operating between 1200 ΛF and 225 ΛF
is_____? Ans. 58.7%
3. A carnot engine operating on air accepts 50KJ/Kg of heat and rejects 20KJ/Kg. Calculate the high and low
reservoir temperature if the maximum specific volume is 10m^3/kg and the pressure after isothermal
expansion is 200Kpa. ans. 432.2 and 9.1 Λ C
4. A Carnot engine receives 130Btu of heat from a hot reservoir at 700 ΛF and rejects 49Btu of heat.
Calculate the temperature of the cold reservoir. Ans. -22.77 ΛF
5. A carnot engine operates between two temperature reservoirs maintained at 200 ΛC and 20Λ C,
respectively. If the desired output of the engine is 15KW, determine the heat transfer from the high
temperature reservoir and heat transfer to the low-temperature reservoirs. Ans. 39.41KW, 24.41KW
6. A carnot heat engine produces 10Hp by transferring energy between two reservoirs at 40 Λ F and 212 Λ F.
Calculate the rate of heat transfer from the high temperature reservoir. Ans. 1656.56 Btu/min
7. Internal Combustion Engine
Is a heat engine which converts the heat energy released by the
combustion of the fuel inside the engine cylinder, into mechanical work.
Classification of I.C. Engines
1. Nature of thermodynamic cycles as:
1. Otto cycle engine
2. Diesel cycle engine
3. Dual combustion cycle engine
2. Type of the fuel used:
1. Gas engine
2. Diesel engine.
3. Bi-fuel engine
3. Number of strokes as:
1. Four stroke engine
2. Two stroke engine
4. Method of ignition as:
1. Spark ignition engine, known as SI engine
2. Compression ignition engine, known as C.I. engine
5. Number of cylinder as:
1. Single cylinder engine
2. Multi cylinder engine
6. Position of the cylinder as:
1. Horizontal engine
2. Vertical engine.
3. Vee engine
4. In-line engine.
5. Opposed cylinder engine
7. Method of cooling as:
1. Air cooled engine
2. Water cooled engine
8. οis a spark ignition type engine
οtwo constant volume and two isentropic process
οheat is transferred during the two isentropic (constant volume) process
οmaximum temperature occur after combustion or before expansion
οif compression ratio increases, itβs cycle efficiency will increase
οcycle efficiency depends on compression ratio and itβs specific heat ratio
οtypical compression ratio is 8.0
P-V and T-S
DIAGRAM
Otto Cycle
10. A. πΈπ¨ = heat added = mππ (π3 - π2)
B. πΈπΉ = heat rejected = mππ (π4 - π1)
C. W = work = ππ΄ - ππ
D. e = Cycle Efficiency
e =
π
ππ΄
=
ππ΄βππ
ππ΄
=
π
π+ππ
=
(π3βπ2) β (π4βπ1)
π3βπ2
e =1 -
1
ππΎ
πΎβ1 = 1 -
1
ππ
πΎβ1
πΎ
= 1 -
π1
π2
E. ππΎ =
π1
π2
=
1+πΆ
πΆ
= compression ratio where c- clearance volume
F. ππ =
π
ππ·
=
π
π1βπ2
where: π1 =
ππ π1
π1
π3 = maximum pressure
Formulas: Otto Cycle
11. Learning Exercise:
1. An otto engine has clearance volume of 7%. It produces 300Kw power. What is the
amount of heat rejected in Kw? Ans. 152KW
2. In an air standard Otto Cycle, the clearance volume is 18% of the displacement
volume. Find the compression ratio and thermal efficiency. Ans. 6.556, 53%
3. An otto cycle has an initial condition of 100Kpa and 30 ΛC . The compression ratio is 10
and the maximum temperature is 1400 ΛC. Find the cycle mean effective pressure per
kg of air. Ans. 502.83Kpa
4. An engine operates on the air standard Otto cycle. The cycle work is 900KJ/Kg, the
maximum cycle temperature is 3000ΛC and the temperature at the end of isentropic
compression is 600 ΛC. Determine the engines compression ratio. Ans. 6.388
5. An Otto cycle has an efficiency of 54%. If heat added is 400KJ, Find the work done.
Ans. 216KJ
12. οis a compression-ignition type of engine
οtwo isentropic, one constant pressure and one constant volume process
3. Diesel Cycle
P-V and T-S
DIAGRAM
14. A. πΈπ¨ = heat added = mππ (π3 - π2)
B. πΈπΉ = heat rejected = mππ (π4 - π1)
C. W = work = ππ΄ - ππ
D. e = Cycle Efficiency
e =
π
ππ΄
=
ππ΄βππ
ππ΄
=
π
π+ππ
=
(π3βπ2) β (π4βπ1)
π3βπ2
e =1 -
1
ππΎ
πΎβ1
ππ
πΎβ1
πΎβ ππβ1
E. ππΎ =
π1
π2
=
1+πΆ
πΆ
= compression ratio where c- clearance volume
F. ππ =
π
ππ·
=
π
π1βπ2
where: π1 =
ππ π1
π1
π2= π3 = maximum pressure
Formulas: Diesel Cycle
ππΎ = compression ratio =
π1
π2
ππ = Cut-off ratio =
π3
π2
=
π3
π2
ππ = Expansion ratio =
π4
π3
ππΎ = ππ β ππ
π3 - π2 = Volume of fuel injected
15. Example:
β’ A diesel cycle has a compression ratio of 6 and cut off ratio of 2. If heat added is 1500KJ,
Find the heat rejected. Ans. 857.60KJ
β’ In an air standard diesel cycle, compression starts at 100Kpa and 300 ΛK. The compression
ratio is 12 and the maximum cycle temperature is 2000 ΛK. Determine the cycle efficiency.
Ans. 54.22%
β’ A diesel cycle has a compression ratio of 8 and initial temperature of 34 ΛC. If the
maximum temperature of the cycle is 2000 ΛK, find the Heat rejected. 726.3KJ/Kg
β’ A diesel cycle has a cycle efficiency of 58%. If heat added is 1600KJ/Kg, Find the work. Ans.
928 KJ/Kg
β’ A diesel has a compression ratio of 8 and cut off ratio of 2.5. Find the cycle efficiency. Ans.
45.97 %
17. Usual Component of Steam Power Plant
1. Coal Storage:
It is the place where coal is stored which can be utilised when required.
2. Coal Handling:
Here the coal is converted into the pulverised form before feeding to the furnace. A proper system is
designed to transport the pulverised coal to the boiler furnace.
3. Boiler:
It converts the water into high pressure steam. It contains the furnace inside or outside the boiler shell.
The combustion of coal takes place in the furnace.
4. Air-preheater:
It is used to pre-heat the air before entering into the boiler furnace. The pre heating of air helps in the
burning of fuel to a greater extent. It takes the heat from the burnt gases from the furnace to heat the
air from the atmosphere.
5. Economiser:
As its name indicates it economises the working of the boiler. It heats the feed water to a specified
temperature before it enters into the boiler drum. It takes the heat from the burnt gases from the
furnace to do so.
6. Turbine:
It is the mechanical device which converts the kinetic energy of the steam to the mechanical energy.
18. 7. Generator:
It is coupled with the turbine rotor and converts the mechanical energy of the turbine to the
electrical energy.
8. Ash Storage:
It is used to store the ash after the burning of the coal.
9. Dust Collector:
It collects the dust particle from the burnt gases before it is released to the chimney.
10. Condenser:
It condensate the steam that leaves out turbine. It converts the low pressure steam to water. It is
attached to the cooling tower.
11. Cooling Tower:
It is a tower which contains cold water. Cold water is circulates to the condenser for the cooling of
the residual steam from the turbine.
12. Chimney:
It is used to release the hot burnt gases or smoke from the furnace to the environment at
appropriate height. The height of the tower is very high such that it can easily throw the smoke and
exhaust gases at the appropriate height. And it cannot affect the population living near the steam
power plant.
13. Feed Water Pump:
It is used to transport the feed water to the boiler.
19. Rankine Cycle
is the fundamental operating cycle of all power plants where an operating fluid is continuously evaporated and
condensed.
β’1-2 Isentropic Expansion. The vapor is expanded in the turbine, thus
producing work which may be converted to electricity. In practice, the
expansion is limited by the temperature of the cooling medium and by the
erosion of the turbine blades by liquid entrainment in the vapor stream as
the process moves further into the two-phase region. Exit vapor qualities
should be greater than 90%.
β’2-3 Isobaric Heat Rejection. The vapor-liquid mixture leaving the turbine
is condensed at low pressure, usually in a surface condenser using
cooling water. In well designed and maintained condensers, the pressure
of the vapor is well below atmospheric pressure, approaching the
saturation pressure of the operating fluid at the cooling water temperature.
β’3-4 Isentropic Compression. The pressure of the condensate is raised
in the feed pump. Because of the low specific volume of liquids, the pump
work is relatively small and often neglected in thermodynamic
calculations.
β’4-1 Isobaric Heat Transfer. High pressure liquid enters the boiler from
the feed pump and is heated to the saturation temperature. Further
addition of energy causes evaporation of the liquid until it is fully
converted to saturated steam.
Processes
20. A. Heat added to the boiler
ππ΄ = β1 β β4 , KJ/Kg
ππ΄ =m(β1 β β4), KW
where β1 = βπ @ given boiler pressure or temperature
B. Heat rejected from the condenser
ππ = β2 β β3, KJ/Kg
ππ =m(β2 β β3), KW
where β3 = βπ @ given condenser pressure or temperature
C. Turbine Work
π€π = β1 β β2, KJ/Kg
ππ =m( β1 β β2), KW
Quality and Enthalpy after Turbine Expansion:
π1 = π2 = ππ + π₯πππ x =
π2βππ
πππ
β2 = βπ + π₯βππ
where: ππ, πππ, βπ, βππ saturated properties @ given
condenser pressure or temperature
Properties of Rankine Cycle
D. Pump Work
π€π = β4 β β3, KJ/Kg
ππ =m( β4 β β3), KW
Enthalpy after compression:
β4 = π£3(π4 β π3) + β3, KW
where: π4 = Boiler Pressure
π3 = Condenser Pressure
π£3=π£π @ given condenser pressure or
temperature
Pump Efficiency:
ππ =
ππ
ππ
E. Cycle Efficiency
e =
ππ’πππππ π€πππβππ’ππ π€πππ
π»πππ‘ π΄ππππ
=
ππ‘βππ
ππ΄
=
ππ΄βππ
ππ΄
F. Heat Carried by Cooling Water
Heat receive by cooling water = Heat reject by condenser
ππ = ππ
ππ€ cp π‘2 β π‘1 = ππ (β2 β β3)
ππ€ =
ππ (β2ββ3)
ππ π‘2βπ‘1
, kg
21. Learning Exercises
1. In a rankine cycle, steam enters the turbine saturated at 2.5 Mpa and
condenser at 50Kpa. What is the thermal efficiency of the cycle? Ans. 25.55%
2. In a rankine cycle, the steam throttle condition is 4.10 Mpa and 440 Λ C. If
turbine exhaust is 0.105Mpa, determine: a) Heat added in the
boiler(2878.29KJ/Kg), b) Work of the turbine(797.16KJ/Kg), c)Pump
Work(4.172KJ/Kg), d)System Net Work(792.99KJ/Kg), e)Thermal efficiency of
the cycle(27.55%).
3. A steam power plant is proposed to operate in a Rankine cycle with pressures
between 10Kpa and 2Mpa and a maximum temperature of 400 Λ C . What is
the maximum efficiency possible from the power cycle? Ans. 32.32%.
22. Refrigeration Engineering
β’ is a diverse field and covers a large number of processes ranging from cooling to air conditioning and from food
processes to human comfort by applying refrigeration
Refrigeration
β’ The science of moving heat from low temperature to high temperature
- Food Storage or
preservation
- Food Production
- Drying
- Air Conditioning
Sample Application: Ice Making
- Brine Circuit
- Refrigeration Circuit
- Cooling Water Circuit
Application:
23. a. QR = Heat Rejected in Condenser
=
b. QA = Refrigerating Effect
=
c. W = Net Work
=
d. COP =Coefficient of Performance
=
e. TR = Tons of Refrigeration:
T2(S1 - S4)
T1(S1 - S4)
QR - QA = (T2 - T1)(S1 - S4)
=
π»π
π»π β π»π
=
πΈπ¨
π. πππ
πΈπ¨
πΎπͺ πΊπ β πΊπ
Where: QA- Heat Added or Refrigerating Effect in KW
Reversed Carnot Refrigeration cycle:
Process 1-2 β Isentropic Compression, s1 = s2
Process 2-3 β Isothermal Heat Rejection, T2=T3
Process 3-4 β Isentropic Expansion, s3 = s4
Process 4-1 β Isothermal Heat absorption, T4=T1
Reversed Carnot cycle as a Heat pump:
=
π»π
π»π β π»π
πΈπΉ
πΎπͺ
a. COP=
24. Sample Problem
1. A refrigeration system operates on the reversed Carnot cycle. The minimum and
maximum temperatures are -25 0C and 720C, respectively. The heat rejected to the
condenser is 6,000 kJ/min. Draw the T-S diagram, find power input required, and
Tons of Refrigeration developed. 28.11KW, 20.44TR
2. A refrigerating system operates on the reversed Carnot cycle. The highest
temperature of the refrigerant in the system is 120 0F and the lower temperature is
100F. The capacity is to be 20 tons. Determine the heat rejected from the system in
Btu/min, Net Work in Btu/min and Net work in HP. 4936.17Btu/min, 936.17 Btu/min,
22.07 Hp
3. The power requirement of a carnot refrigerator in maintaining a low temperature
region at 238.9K is 1.1kW per ton.
Find a. COP (3.19)
b. T2 (586.64)
c. heat rejected (4.609)
25.
26. Basic Components
Compressor
1. It circulates the refrigerant within the system.
2. It compresses the low pressure gas to high pressure
gas
Expansion Valve
1. Expands the high pressure liquid to a
mixture of low pressure liquid gas particles.
2. Controls the amount of refrigerant in the
evaporator.
Evaporator
1. Acts as heat exchanger between the product and the
refrigerant.
2. Completely vaporize the refrigerant
Condenser
1.Convert the refrigerant from vapor(gas) state to liquid
state.
2.Removes the heat of compression
27. Schematic Diagram
P-h Diagram
Processes:
1 to 2 β Is isentropic compression process(s1=s2)
2 to 3 β Is constant pressure process (P2=P3)
3 to 4 β Is throttling process (H3 = H4)
4 to 1 β Is constant Pressure process (P4 = P1)
28. Components Performance and Formulas
wc = h2 - h1 , kJ/kg
Wc = m(h2 - h1), kW
For cooling water:
qR = h2 - h3 , kJ/kg
QR = m(h2 - h3), kW
where: m = mass of refrigerant circulated
The Vapor Compression Cycle
1. Compressor Power (Wc) - is the power needed to
compress the refrigerant.
2. Heat Rejected (QR) - is the amount of heat
rejected to the cooling medium.
3. Expansion Valve Process (h3 = h4)
h3 = h4 = hf4 + xhfg4
π =
ππ β πππ
πππ β πππ
hfg4 = hg4 - hf4
where:
X= Quality after expansion
4. Refrigerating Effect (RE) - is the amount of heat gained
from the load.
RE = mw cP (t1 β t2), kW
RE = m(h1 - h4), kW
For chilling water:
QR = mw cP (t2 β t1), kW
RE = h1 - h4, kJ/kg
29. TR =
π(ππ β ππ)
π. πππ
COP =
ππ β ππ
ππ βππ
COP =
πΉππππππππππππ π¬πππππ
πͺπππππππππ π·ππππ
5. Tons of refrigeration (TR)
TR =
πΉππππππππππππ π¬πππππ
π.πππ
where:
1 ton of refrigeration
Performance of Refrigeration System
1. Coefficient of Performance (COP) - is
the ratio of refrigerating effect and
compression work
= 3.516 kW
= 200 Btu/min
= 12,000 Btu/hr
πΎπ
π»πΉ
=
πͺπππππππππ π·ππππ
π»ππ ππ πππππππππππ
, π²πΎ/π»ππ
π―π·
π»ππ
=
π. ππ
πͺπΆπ·
π²πΎ
π»ππ
=
π. πππ
πͺπΆπ·
2. Power Per Ton :
EER =
πΉππππππππππππ (π²πΎ)
π¬ππππππππππ πͺππππππππππ π²πΎ
= π. πππ π πͺπΆπ·
3. Energy Efficiency Ratio (EER) β the ratio of energy
removed at the evaporator (refrigerating effects) to the
electrical energy consumed. This shall conform with the
standards set by the Department of energy
4. Volume Flow at Suction (V1)
V1 = mv1 , m3/sec
π½π·π» =
π½π
π»πππ ππ πΉππππππππππ
5. Volume Flow Per Ton :
30. A. Chilling and Cooling Load
1. Refrigerating effect = m(h1 - h4)
2. Heat loss from water =mL cp (t1 β t2)
Note: Refrigerating Effect = Product Load
Product load = Heat to be removed from a product
=Sensible load + Latent load
Chilled liquid in the evaporator:
3. Mass of liquid circulated (mL ):
mL =
π(ππβππ)
πͺπ(ππβππ)
where:
m = mass flow of refrigerant
mL = mass of liquid circulated
CP = specific heat of liquid= 4.187 kJ/kg-K for water
t1 = initial temperature of liquid
t2 = final temperature of liquid
Evaporator
mw =
π(ππβππ)
πͺπ(ππβππ)
VW =
ππΎ
ππ―ππ
B. Cooling water in the condenser:
1. Heat Rejected in the condenser (QR)
QR = m(h2 - h3)
QR = mw cP (t2 - t1)
2. Mass of cooling water required (mw):
3. Volume flow of cooling water required, Q:
Condenser
where:
m = mass flow of refrigerant
mW = mass of water circulated
CP = specific heat of water
= 4.187 kJ/kg-K for water
t1 = initial temperature of water
t2 = final temperature of water
π H20 = density of water
31. d. Overβall efficiency =
π·ππ
π·ππ
c. Efficiency of compressor =
π·ππ
π·ππ
b. Efficiency of coupling =
π·ππ
π·ππ
a. Efficiency of motor =
π·ππ
π·ππ
C. Motor and Compressor Performance
where: Pim = power input of motor
Pom = power output of motor
Pic = power input of compressor
Poc = power output of compressor
32. Sample problem.
1. A refrigeration system using refrigerant 22 has the evaporator entrance h = 252.4 KJ/kg exit h = 401.6
KJ/kg. If mass flow of refrigerant is 1.2 kg/s and a coefficient of performance of 2.98, find the compressor
power and heat rejected from the condenser.
2. The heat required to remove from beef 110kg is 36437 KJ which will be cooled from 20 ΛC to -18 ΛC. The
specific heat above freezing is 3.23 KJ/kg-ΛK and latent heat of fusion is 233 KJ/kg. If specific heat below
freezing is 1.68 KJ/kg-ΛK, find the freezing temperature.
3. A belt driven compressor is used in a refrigeration system that will cool 10 li/sec of water from 130C to
10C. The belt efficiency is 98%, motor efficiency is 85%, and the input of the compressor is 0.7 kW/ton of
refrigeration. Find the mass flow rate of condenser cooling water warmed from 210C to 320C if overall
efficiency is 65%.
4. A standard vapor compression cycle developing 50 kW of refrigeration using refrigerant 22 operates with
a condensing temperature of 350C and an evaporating temperature of -100C. Calculate:
β’ The refrigerating effect in kJ/kg
β’ The circulation rate of refrigerant in kg/s
β’ The power required by the compressor in kW
β’ Coefficient of performance
β’ The volume flow rate measure at the compressor suction
β’ The power per kW of refrigeration
β’ The compressor discharge temperature4
33. 1. An air conditioning system of a high rise building has a capacity of 350KW of refrigeration using R-22. The
evaporator and condenser temperature are 0ΛC and 35 ΛC, respectively. Determine work of compression in KW.
2. The change of enthalpy between the inlet and outlet of evaporator is 1000KJ/Kg and mass flow of refrigerant is
12Kg/min. What is the capacity of plant in Tons of refrigeration.
3. An industrial plant requires to cool 120 gal/min of water from 20 ΛC to 5 ΛC. Determine the Tons of refrigeration
required.
4. A refrigeration system using Freon 12 has a capacity of 320 kw of refrigeration. The evaporating
temperature is -10 degrees C and the condensing temperature is 40ο°C. Calculate the fraction of vapor in
the mixture before the evaporator.
5. Milk must be received and cooled from 80 ΛF to 38 ΛF in 5 hrs. If 4000 gallons of fresh milk received having SG of
1.03 and πΆπ = 0.935 Btu per lb- ΛF, find the refrigeration capacity.
Exercises