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Urea Formaldehyde
Presented By
Himmat Purohit
Index
 Introduction
 Chemical structure
 Manufacturing Process
 Properties
 Advantages & disadvantages
 Application
Introduction
 UF resin was first produced in 1884 by Holzer, who was working with Bernhard
Tollens.
 Urea-formaldehyde, also known as urea-methanal, so named for its common
synthesis pathway and overall structure, is a non-transparent thermosetting resin
or plastic.
 It is produced from urea and formaldehyde. These resins are used in adhesives,
finishes, particle board, and moulded objects.
 UF glue resins were the most important type of adhesives in the wood industry last
60 years, especially for the production of wood based panels.
 In industrial production, urea resins are made by the condensation of
formaldehyde and urea in an aqueous solution, using ammonia as an
alkaline catalyst .
 The condensation reaction gives a colourless, solution that can be spray-dried
to a powder for later use in coatings or adhesives.
 it can also be mixed with cellulose filler to produce powders for moulding into
solid objects.
 Under the influence of heat and pressure, the resin, at this point made up
largely of low-molecular-weight intermediate polymers or prepolymers, is
cured to its final state,
 which consists of a three-dimensional network of interlinked polymer.
Chemical Structure
UF Condensation Reaction
Manufacturing Process
 Urea and formaldehyde reacted at reflux under acid
conditions to a required viscosity.
 Resin is neutralized and cooled.
 A further amount of urea is added to react with
remaining free formaldehyde.
 Resin is evaporated to obtain the correct viscosity and
solids
Diagram
Process control
 Formaldehyde and urea are weighed into a reactor
from a weigh vessel.
 Precision on formalin weighing is 0.02%.
 Precision on urea weighing is 0.5%.
 Viscometers and pH meters are calibrated daily.
 Thermocouples are calibrated bi-annually
Properties
 It has a very high tensile strength.
 Has the property of flexural modulus.
 Has the property of heat distortion temperature.
 Has the capacity of low water absorption .
 It has the property of mould shrinkage.
 Has a property of high surface hardness.
Advantages
 Higher maximum operating temperature.
 Better dielectric constant.
 Tracking resistance.
 Dimensional stability compared with cellulose filled
urea formaldehyde
 Lower cost
 Good electrical insulator
Disadvantages
 Lower High Density Temperature(HDT).
 Higher water absorption and mould shrinkage.
 Lower surface hardness.
 can have toxic effects
 breathing difficulties,
Application
 Electrical Casings
 Tableware
 Decorative worktop laminates
 Plug & switches Buttons
 Paints
 Surface coating
Urea formaldehyde powder glue is used in many wood practices and its shell life is only 1
month but it can be longer in liquid glues.
Thank You

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Urea formaldehyde

  • 2. Index  Introduction  Chemical structure  Manufacturing Process  Properties  Advantages & disadvantages  Application
  • 3. Introduction  UF resin was first produced in 1884 by Holzer, who was working with Bernhard Tollens.  Urea-formaldehyde, also known as urea-methanal, so named for its common synthesis pathway and overall structure, is a non-transparent thermosetting resin or plastic.  It is produced from urea and formaldehyde. These resins are used in adhesives, finishes, particle board, and moulded objects.  UF glue resins were the most important type of adhesives in the wood industry last 60 years, especially for the production of wood based panels.
  • 4.  In industrial production, urea resins are made by the condensation of formaldehyde and urea in an aqueous solution, using ammonia as an alkaline catalyst .  The condensation reaction gives a colourless, solution that can be spray-dried to a powder for later use in coatings or adhesives.  it can also be mixed with cellulose filler to produce powders for moulding into solid objects.  Under the influence of heat and pressure, the resin, at this point made up largely of low-molecular-weight intermediate polymers or prepolymers, is cured to its final state,  which consists of a three-dimensional network of interlinked polymer.
  • 7. Manufacturing Process  Urea and formaldehyde reacted at reflux under acid conditions to a required viscosity.  Resin is neutralized and cooled.  A further amount of urea is added to react with remaining free formaldehyde.  Resin is evaporated to obtain the correct viscosity and solids
  • 9. Process control  Formaldehyde and urea are weighed into a reactor from a weigh vessel.  Precision on formalin weighing is 0.02%.  Precision on urea weighing is 0.5%.  Viscometers and pH meters are calibrated daily.  Thermocouples are calibrated bi-annually
  • 10. Properties  It has a very high tensile strength.  Has the property of flexural modulus.  Has the property of heat distortion temperature.  Has the capacity of low water absorption .  It has the property of mould shrinkage.  Has a property of high surface hardness.
  • 11. Advantages  Higher maximum operating temperature.  Better dielectric constant.  Tracking resistance.  Dimensional stability compared with cellulose filled urea formaldehyde  Lower cost  Good electrical insulator
  • 12. Disadvantages  Lower High Density Temperature(HDT).  Higher water absorption and mould shrinkage.  Lower surface hardness.  can have toxic effects  breathing difficulties,
  • 13. Application  Electrical Casings  Tableware  Decorative worktop laminates  Plug & switches Buttons  Paints  Surface coating
  • 14. Urea formaldehyde powder glue is used in many wood practices and its shell life is only 1 month but it can be longer in liquid glues.
  • 15.