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A galvanização e os
investimentos em
portos
by
Frank Goodwin
William Marques

International Zinc
Association
Shipyards in Brazil
January 2012
•47 Shipyards
•11 New yards under
construction
•59,000 workers
directly employed
•6.2 Million DWT order
book
•18 Offshore Oil
Platforms under
construction
The most important ports
•
•
•
•
•
•
•
•
•

Porto
Porto
Porto
Porto
Porto
Porto
Porto
Porto
Porto

de
de
de
de
de
de
de
de
de

Santos – SP
Vitória – ES
Paranaguá – PR
Rio Grande – RS
Rio de Janeiro – RJ
Itajaí – SC
São Sebastião – SP
Itaqui – MA
Aratu – BA

Port of Santos
Brazilian Shipyards
DWT under construction
Brazilian Shipyards
Today’s Order Book and New
Orders as of January 2012
BrasFELS - Angra dos Reis (RJ)
specializes in offshore production
platforms.

Atlantico Sul Shipyard – Suape (PE)
Large crude carriers, offshore platforms
and drill ships
Port Facilities
Portos e Navios
Port of Vancouver, BC

Delta Port- Vancouver’s largest container terminal
Delta Port handles the
largest container ships
afloat and features dualhoist gantry cranes – a
first in the Americas along with super postpanamax cranes, 3 berths
and advanced computer
systems.
Delta Port – galvanized structures
Delta Port – galvanized structures
Dredge “Ned Edwards”
Port of New Orleans, USA

Galvanizing
used for
handrails,
stairs,
walkways,
and
platforms
Dredge “Ned Edwards”
Port of New Orleans, USA
Arbon Marina
Lake Constance, Switzerland
Arbon Marina
Arbon Marina
Bottighofen marina
Lake Constance
Bottighofen Marina
Bottighofen Marina
Galvanized boat trailers at
Bottighofen Marina
Bottighofen marina
Duplex Coating

• The protection of steel by a layer of
zinc which is overcoated by a nonmetallic coating
• The purpose is to provide
additional corrosion resistance,
easy visibility, camouflage or a
pleasing aesthetic appearance
• Corrosion resistance of a
properly applied duplex coating
can provide corrosion protection
outside the pH or Cl- range
normally acceptable for galvanizing.
Why does a Duplex System Work?
• Zinc products of Corrosion far less than RED Rust
• Blistering (corrosion creep) of paint therefore far less
than when it is direct onto steel

• Zinc products of corrosion tend to seal the pours in
the top paint coating
• Results in the “Synergistic effect”, which is:

Duplex Service Life = Factor x (Zn Life + Paint Life)
e.g. Service Life = 1.5 x (9 years + 5 years)
= 21 years to 5% rust
Synergistic factors
• Industrial/Marine
1.8 to 2.0
• Sea water (immersion) 1.5 to 1.6
• Non-aggressive climate 2.0 to 2.7

• Paint is not there to protect the zinc, but
zinc is there to support the paint when it
starts to fail!
Atmospheric corrosive environments
classified in terms of ISO 9223
Galvanized & Painted Weed Bars in a Lock
Location: Delfzijl, The Netherlands

After
17 years,
still
no sign of
rust
Specify type and thickness of paint
in accordance with ISO
12944:1998 Part 5 Table A.9
S te p 3
* S e le c t a n IS O 1 2 9 4 4 c om plia nt s ys te m

E N IS O 1 2 9 4 4 -5 : 1 9 9 8
T a b le A 9 : P a in t s y s te m s c o rro s iv ity c a te g o rie s C 2 to C 5 -I a n d C 5 -M
S u b s tra te : H o t-d ip -g a lv a n iz e d s te e l¹)
Th e p a in t s ys te m s g ive n in th e fo llo w in g ta b le a re o n ly e xa m p le s ,. O th e r p a in t s ys te m s h a vin g th e s a m e p e rfo rm a n c e
a re p o s s ib le .
If th e s e e xa m p le s a re u s e d , it s h a ll b e e n s u re d th a t th e p a in t s ys te m s c h o s e n co m p ly w ith th e in d ic a te d d u ra b ility w h e n e xe c u tio n o f th e p a in t w o

P a int
S yst em
No

P r i mi ng c o a t ( s )

B ind er 5)

N umb er o f
co at s

T o p c o a t ( s ) ) i nc l ud i ng
i nt e r me d i a t e c o a t ( s ) )

NDFT

-

S9 .0 1

3)

B ind er 5)

-

N umb er o f
co at s

NDFT 3)

T o t al N D F T 3 )

µm

µm

1

µm

80

1

80
12 0

C2
L

1

40

1

80

2

S9 .0 3

1

80

1

80

2

1

80

2

16 0

3

S9 .0 5

-

-

1

80

1

40

1

80

2

12 0

S9 .0 7

1

80

1

80

2

1

80

2

16 0

3

-

-

1

80

1

40

1

80

2

L

M

C 5- I
H

L

M

C 5- M
H

H

L

80

1

C4
H

240

S9 .0 9

M

16 0

S9 .0 8

L

80

1

C3
H

240

S9 .0 6

M

16 0

S9 .0 4

12 0

S9 .0 2

S9 .10

PV C

AY

EP
or
PU R

PV C

AY

1

80

S9 .12

1

80

S9 .13

1

EP
or
PU R 4 )

80

S9 .11

B i nd e r s f o r p r imi ng c o a t ( s )

1

80

2

16 0

3

240

2 -3

240

3 -4

1- p ack

2 - p ack

W at er
b o r ne
p o ssib le

x

AY

= A crylic

x

EP

= Ep o xy

x

PU R

= Po lyur et hane

x

P a i nt s ( l i q ui d )
N o . o f co mp o nent s
1- p ack

PV C

= Po lyvinyl chlo rid e

320
B i nd e r s f o r t o p c o a t ( s )

P a int s ( l iq ui d )

PV C

-

16 0

2

N o o f co mp o nent s

1)
2)
3)
4)
5)
6)

E xp ect e d d ur ab ilit y 2 ) 6 )
( s e e 5 . 5 a n d I S O 12 9 4 4 - 1)

P a i nt s y s t e m

= Po lyvinyl chlo r id e

x

AY

= A cr ylic

x

EP

= Po lyur et hane

x

= Ep o xy

PU R

2 - p ack

W at er
b o r ne
p o ssib le

x

x
x
x

x

x

Th e m e ch a n ic a l o r ch e m ica l s u rfa ce p re p a ra tio n re rq u ire d is d e s c rib e d in IS O 1 2 9 4 4 -4 .
Th e d u ra b ility is in th is c a s e re la te d to th e p a in t s ys te m a d h e s io n to th e h o t-d ip -g a lva n ize d s u rfa c e .
N D FT = N o m in a l D ry Film Th ic kn e s s . S e e 5 .4 fo r fu rth e r d e ta ils .
If c o lo u r a n d g lo s s re te n tio n is re q u ire d , it is re c o m m e n d e d th a t th e la s t co a t s h o u ld b e b a s e d o n a lip h a tic P U R .
Fo r e xp la n a tio n o f a b b re via tio n s , s e e fo o t o f ta b le
L ig h t g re y s h a d in g in d ica te s th a t th e p a in t s ys te m s c o n c e rn e d w o u ld n o t n o rm a lly b e u s e d fo r th e s e c o rro s ivity c a te g o rie s .
Th e y a re n o t lis te d in ta b le A.2 a n d /o r A.3 .

H
When to paint the
galvanized structure
• Apply the paint system as soon as possible after
galvanizing, after correct pre-treatment
• Weathered galvanizing, which is suitably cleaned, can
provide a satisfactory surface on which to apply paint but
this should only be considered if material is situated on a
site where corrosion is relatively mild and a stable
weathered zinc surface has developed.
• Painting of freshly galvanized structures should never be
deferred in a marine environment where the need to
remove unstable zinc corrosion products, prior to painting,
could render the system less effective.
• Or, apply a suitable primer at this stage, followed by a
compatible top coat on site.
Conclusions
• Galvanized steel is not well known, or
much used, in Brazilian ports
• Case studies show this could be an
important market for the galvanizer
• Severe marine climates suggest duplex
coatings may be required to give 20 years
before significant maintenance is required.

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Gb2013 frank goodwin_ international zinc association

  • 1. A galvanização e os investimentos em portos by Frank Goodwin William Marques International Zinc Association
  • 2. Shipyards in Brazil January 2012 •47 Shipyards •11 New yards under construction •59,000 workers directly employed •6.2 Million DWT order book •18 Offshore Oil Platforms under construction
  • 3. The most important ports • • • • • • • • • Porto Porto Porto Porto Porto Porto Porto Porto Porto de de de de de de de de de Santos – SP Vitória – ES Paranaguá – PR Rio Grande – RS Rio de Janeiro – RJ Itajaí – SC São Sebastião – SP Itaqui – MA Aratu – BA Port of Santos
  • 5. Brazilian Shipyards Today’s Order Book and New Orders as of January 2012
  • 6. BrasFELS - Angra dos Reis (RJ) specializes in offshore production platforms. Atlantico Sul Shipyard – Suape (PE) Large crude carriers, offshore platforms and drill ships
  • 9. Port of Vancouver, BC Delta Port- Vancouver’s largest container terminal
  • 10. Delta Port handles the largest container ships afloat and features dualhoist gantry cranes – a first in the Americas along with super postpanamax cranes, 3 berths and advanced computer systems.
  • 11. Delta Port – galvanized structures
  • 12. Delta Port – galvanized structures
  • 13.
  • 14.
  • 15. Dredge “Ned Edwards” Port of New Orleans, USA Galvanizing used for handrails, stairs, walkways, and platforms
  • 16. Dredge “Ned Edwards” Port of New Orleans, USA
  • 23. Galvanized boat trailers at Bottighofen Marina
  • 25. Duplex Coating • The protection of steel by a layer of zinc which is overcoated by a nonmetallic coating • The purpose is to provide additional corrosion resistance, easy visibility, camouflage or a pleasing aesthetic appearance • Corrosion resistance of a properly applied duplex coating can provide corrosion protection outside the pH or Cl- range normally acceptable for galvanizing.
  • 26. Why does a Duplex System Work? • Zinc products of Corrosion far less than RED Rust • Blistering (corrosion creep) of paint therefore far less than when it is direct onto steel • Zinc products of corrosion tend to seal the pours in the top paint coating • Results in the “Synergistic effect”, which is: Duplex Service Life = Factor x (Zn Life + Paint Life) e.g. Service Life = 1.5 x (9 years + 5 years) = 21 years to 5% rust
  • 27. Synergistic factors • Industrial/Marine 1.8 to 2.0 • Sea water (immersion) 1.5 to 1.6 • Non-aggressive climate 2.0 to 2.7 • Paint is not there to protect the zinc, but zinc is there to support the paint when it starts to fail!
  • 29. Galvanized & Painted Weed Bars in a Lock Location: Delfzijl, The Netherlands After 17 years, still no sign of rust
  • 30. Specify type and thickness of paint in accordance with ISO 12944:1998 Part 5 Table A.9
  • 31. S te p 3 * S e le c t a n IS O 1 2 9 4 4 c om plia nt s ys te m E N IS O 1 2 9 4 4 -5 : 1 9 9 8 T a b le A 9 : P a in t s y s te m s c o rro s iv ity c a te g o rie s C 2 to C 5 -I a n d C 5 -M S u b s tra te : H o t-d ip -g a lv a n iz e d s te e l¹) Th e p a in t s ys te m s g ive n in th e fo llo w in g ta b le a re o n ly e xa m p le s ,. O th e r p a in t s ys te m s h a vin g th e s a m e p e rfo rm a n c e a re p o s s ib le . If th e s e e xa m p le s a re u s e d , it s h a ll b e e n s u re d th a t th e p a in t s ys te m s c h o s e n co m p ly w ith th e in d ic a te d d u ra b ility w h e n e xe c u tio n o f th e p a in t w o P a int S yst em No P r i mi ng c o a t ( s ) B ind er 5) N umb er o f co at s T o p c o a t ( s ) ) i nc l ud i ng i nt e r me d i a t e c o a t ( s ) ) NDFT - S9 .0 1 3) B ind er 5) - N umb er o f co at s NDFT 3) T o t al N D F T 3 ) µm µm 1 µm 80 1 80 12 0 C2 L 1 40 1 80 2 S9 .0 3 1 80 1 80 2 1 80 2 16 0 3 S9 .0 5 - - 1 80 1 40 1 80 2 12 0 S9 .0 7 1 80 1 80 2 1 80 2 16 0 3 - - 1 80 1 40 1 80 2 L M C 5- I H L M C 5- M H H L 80 1 C4 H 240 S9 .0 9 M 16 0 S9 .0 8 L 80 1 C3 H 240 S9 .0 6 M 16 0 S9 .0 4 12 0 S9 .0 2 S9 .10 PV C AY EP or PU R PV C AY 1 80 S9 .12 1 80 S9 .13 1 EP or PU R 4 ) 80 S9 .11 B i nd e r s f o r p r imi ng c o a t ( s ) 1 80 2 16 0 3 240 2 -3 240 3 -4 1- p ack 2 - p ack W at er b o r ne p o ssib le x AY = A crylic x EP = Ep o xy x PU R = Po lyur et hane x P a i nt s ( l i q ui d ) N o . o f co mp o nent s 1- p ack PV C = Po lyvinyl chlo rid e 320 B i nd e r s f o r t o p c o a t ( s ) P a int s ( l iq ui d ) PV C - 16 0 2 N o o f co mp o nent s 1) 2) 3) 4) 5) 6) E xp ect e d d ur ab ilit y 2 ) 6 ) ( s e e 5 . 5 a n d I S O 12 9 4 4 - 1) P a i nt s y s t e m = Po lyvinyl chlo r id e x AY = A cr ylic x EP = Po lyur et hane x = Ep o xy PU R 2 - p ack W at er b o r ne p o ssib le x x x x x x Th e m e ch a n ic a l o r ch e m ica l s u rfa ce p re p a ra tio n re rq u ire d is d e s c rib e d in IS O 1 2 9 4 4 -4 . Th e d u ra b ility is in th is c a s e re la te d to th e p a in t s ys te m a d h e s io n to th e h o t-d ip -g a lva n ize d s u rfa c e . N D FT = N o m in a l D ry Film Th ic kn e s s . S e e 5 .4 fo r fu rth e r d e ta ils . If c o lo u r a n d g lo s s re te n tio n is re q u ire d , it is re c o m m e n d e d th a t th e la s t co a t s h o u ld b e b a s e d o n a lip h a tic P U R . Fo r e xp la n a tio n o f a b b re via tio n s , s e e fo o t o f ta b le L ig h t g re y s h a d in g in d ica te s th a t th e p a in t s ys te m s c o n c e rn e d w o u ld n o t n o rm a lly b e u s e d fo r th e s e c o rro s ivity c a te g o rie s . Th e y a re n o t lis te d in ta b le A.2 a n d /o r A.3 . H
  • 32. When to paint the galvanized structure • Apply the paint system as soon as possible after galvanizing, after correct pre-treatment • Weathered galvanizing, which is suitably cleaned, can provide a satisfactory surface on which to apply paint but this should only be considered if material is situated on a site where corrosion is relatively mild and a stable weathered zinc surface has developed. • Painting of freshly galvanized structures should never be deferred in a marine environment where the need to remove unstable zinc corrosion products, prior to painting, could render the system less effective. • Or, apply a suitable primer at this stage, followed by a compatible top coat on site.
  • 33. Conclusions • Galvanized steel is not well known, or much used, in Brazilian ports • Case studies show this could be an important market for the galvanizer • Severe marine climates suggest duplex coatings may be required to give 20 years before significant maintenance is required.