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Environmental Studies
Environmental Pollution
 Environment
 Components of Environment
 Air -Atmosphere
 Water - Hydrosphere
 Soil - Lithosphere
Pollution
• Pollutant
• Types of Pollution
Type of Pollution
Air Pollution
Water Pollution
Soil Pollution
Noise Pollution
Other Types of Pollution
Pesticide Pollution
Implication:
• Soil Pollution
• Air Pollution
• Water Pollution
Oil Pollution
Implication:
• Water Pollution
Radioactive Pollution
Implication:
• Soil Pollution
• Air Pollution
• Water Pollution
Thermal Pollution
Implication:
• Water Pollution
Heavy Metal Pollution
Air Pollution
Earth’s Atmosphere
 Envelope of Gases above the Earth’s Surface is termed
as EarthsAtmosphere
Earth’s Atmosphere
Troposphere : 0-11km
Stratosphere: 11-50km
Mesosphere: 50-87km
Thermosphere: 87-500km
Exosphere: 500-1000km
Air Pollution mainly occurs
inTroposphere and
Stratosphere
Role of Earth’s Atmosphere
1. Protects Earths Biosphere from Electromagnetic
Radiations
2. Absorbs Infra Red Radiations and maintainTemperature
on earth’s surface
3. Maintains balance in the bio-chemical cycles (Oxygen,
Nitrogen, Carbon, Hydrological)
Role of Earth’sAtmosphere
1. Protects Earths Biosphere from Electromagnetic
Radiations
2. Absorbs Infra Red Radiations and maintainTemperature
on earth’s surface
3. Maintains balance in the bio-chemical cycles (Oxygen,
Nitrogen, Carbon, Hydrological)
Composition of Clean Air
Gases Avg.
Conc.
(ppm)
Gases Avg.
Conc.
(ppm)
Nitrogen 780900 Krypton 1.0
Oxygen 209400 Hydrogen 0.5
Argon 9300 Carbon Monoxide 0.1
Carbon Dioxide 318 Ozone 0.02
Neon 18 Nitrogen Dioxide 0.001
Helium 5.2 Sulphur 0.0002
Methane 1.3
Metrology and Air Pollution
Primary Metrological Parameter
 Wind Direction and Speed
 Temperature
 Atmospheric Stability
 Mixing Height
Secondary Metrological Parameters
 Precipitation (Rain)
 Humidity
 Solar Radiation
 Visibility
Air Pollutants
 These are compounds causing Air Pollution
 They are Classified as:
 PrimaryAir Pollutants
 Secondary Air Pollutants
Primary Air Pollutants
✓ Oxides of Carbon
✓ Oxides of Nitrogen
✓ Oxides of Sulphur
✓ Volatile Organic Compounds
✓ Hydrocarbons
✓ Particulate Matter
✓ Radioactive Pollutants
Oxides of Carbon – Carbon Monoxide
Sources Ill-Effects
 Incomplete combustion of
materials containing
carbon
 Automobile Exhausts
 Oxidation of Methane by
anaerobic Decomposition
 SmallAmount –Volcanic
Eruption, Forest Fires
 Formation of Carboxyl
Haemoglobin
 Impairment of Central
nervous system
 Changes in cardiac and
pulmonary functions
 Drowsiness, respiratory
failure, coma, fatality
Oxides of Carbon – Carbon Dioxide
Sources Ill-Effects
 318pppm conc. In clean air
 Burning of Fossil Fuels
 Complete combustion of
materials containing
carbon
 No Direct Health Effects
 Conc. more the 10%
activates Green House
Effect (56% of Green
House Gases)
 One of the air pollutant
causingAcid Rain
Oxides of Nitrogen
Sources Ill-Effects
Nitrogen Oxides at normal temperature are harmless but
at high temperature combines with oxygen to produce
nitric oxide
 Automobile Exhaust
(Diesel Engines)
 Electrical Power Plants
 Marine Steamers
 High Conc.– Lung Cancer and
cause suffocation
 Low Conc. – Pneumonia,
Swelling and Irritation to Skin
 MajorAir Pollutant forAcid
Rain
 6% contributing Green House
Gas
Oxides of Sulphur
Sources Ill-Effects
 Burning of fuels
 Volcanic Eruptions (35%
to 65%)
 Industrial Boilers and
Metal Smelter
 Burning of Domestic
Coal
 Forest Fires
 High Conc. – Reduced
Lung Functioning
 Low Conc. – Irritation to
mucous membrane of
Eyes, Nose andThroat
 Major Air Pollutant for
Acid Rain
Amongst the oxides of Sulphur, Sulphur Dioxides is the
dominant Air pollutant and found in traceable concentrations
and has Pungent and unpleasant odour
Volatile Organic Compound
 VOC are categorized as :
 Methane (MVOCs)
 Non Methane (NMVOCs)
 Benzene
 Toulene
VOC - Methane
Sources Ill-Effects
 Natural CleanAir
 Natural gas system and
Manure management
 Landfills
 Coal Mining
 WastewaterTreatment
 Composting
 Odour Nuisance
 Green House
(contributing 18%)
Contributes 1.3ppmv of Natural Clean Air
Its a organic compound composed of 6 carbon atom in a ring
with 1 hydrogen atom attached to each carbon atom
VOC - Benzene
Sources Ill-Effects
 Industries (Rubber,
chemical, tannery,
petroleum)
 Volcanoes, Forest Fires
and crude Oil
Evaporation
 Emission from glues,
adhesives
 Odour Nuisance
 Green House
(contributing 18%)
Its a organic compound with sweet odour with composition
(C7H8, C6H5, CH3)
VOC -Toulene
Sources Ill-Effects
 Emission from Paint
Thinner,Adhesives
 Emission from
evaporation of Gasoline,
Kerosene
 High Conc. – Light-
headness, Dizziness,
Sleepiness, unconsciousness
and even fatality
 Low Conc. –Tiredness,
Confusion, Memory Loss,
Nauseas, Loss of hearing and
colour vision
Its a organic compound entirely consisting of Hydrogen and
CarbonAtoms
Hydrocarbons
Sources Ill-Effects
 Automobile Emissions
 Emission of Isoprene
from trees like
eucalyptus, spruce, oak
 High Conc. (500-
1000ppmv) are carcinogenic
to lungs
 Low Conc. – Irritation to
mucous membrane of eyes
and nose, leading to
respiratory disorder
 Plants leaves turning
Yellowish
It is fine particles or tiny particles of solid or liquid
suspended in a gas
Particulate Matter
Sources Ill-Effects
 Volcanoes, Dust-storms,
forest fires, Sea Sprays
 Burning of Fossil Fuels
 High Conc. – Respiratory
disorder,Altered lung
function and may lead lung
cancer
 Low Conc. – visibility
reduction
 Primary Pollutant for
Photochemical Smog
Radioactive Pollutants
Sources Ill-Effects
 Nuclear Power Plants
 Mining and Refining of
Plutonium,Thorium,
Uranium
 NuclearWeapons
(Production and Explosion)
 Transportation of Radioactive
Materials
 Disposal of RadioactiveWaste
 Preparation of Radioactive
Isotopes
 Nuclear Fallout
Secondary Pollutants
The major Secondary Pollutants are:
1. Ground Level Ozone
2. Photochemical Smog
3. PAN (PeroxyAcetyl Nitrate)
4. Acid Mist
5. Chlorofluorocarbons (CFCs)
6. Formaldehyde
7. Persistent Organic Pollutants
Ground Level Ozone
 Formed by Photochemical Reaction between Oxides of
Nitrogen,Volatile organic Compound and Carbon
monoxide.
Presence of
Sunlight
Peroxy Acetyl Nitrate (PAN)
 Formed by Photochemical Reaction between
Hydrocarbons, Nitrogen Oxides and Oxygen.
Hydrocarbons + NOx + O2
Presence of
Sunlight
PAN
Photochemical Smog
 Formed by Photochemical Reaction between
Hydrocarbons, Nitrogen Oxides and oxygen.
Hydrocarbons + NOx + O2
Presence of
Sunlight,Smog
Photochemical
Smog
Acid Mist
 Mist containing a high concentration of acid particles of any
toxic chemicals such as CarbonTetrachlorideand Silicon
Tetrachloride.
Mist + SOx, NOx, Cox + H2O Acid Mist
Chloro-Fluoro-Carbons (CFC’s)
 It is a organic compound of Carbon, Chlorine and
Fluorine produced as a volatile derivation of methane
and ethane
Formaldehyde
 It is a organic compound of with formula CH2O.
 It is simplest Aldehyde and its systematic name is
Methanol
Persistent Organic Pollutants
 These are organic compounds that are resistant to
environmental degradation through biological and
photolytic processes
Zoning for Control of Air Pollution
▪ Definition
▪ Zoning on basis of:
▪ Functional Requirements
▪ Performance Requirements
▪ Industrial Zoning basis:
▪ Bangalore City:
▪ Light
▪ Medium
▪ Large
▪ Mumbai City:
▪ Small Repairing and Light Manufacturing Units
▪ Service Industrial Zone
▪ Special Industrial Zone
▪ General Industrial Zone
Control of Air Pollution
NAMP - Central Pollution Control Board is executing a
nation-wide programme of ambient air quality monitoring
known as National Air Quality Monitoring Programme
(NAMP).
Monitoring of fourAir Pollutants
 Sulphur Dioxide (SO2),
 Oxides of Nitrogen as NO2,
 Suspended Particulate Matter (SPM) and
 Respirable Suspended Particulate Matter (RSPM /
PM10)
Water Pollution
Definition ofWater Pollution
Water Masses on Earth
 Lakes
 Rivers
 Oceans
 Ground Water
Water Pollutants Sources can be,
 Direct Sources
 Indirect Sources
Types ofWater Pollutants
 OrganicWater Pollutants
 InorganicWater Pollutants
Water Cycle
Relation ofWater Cycle and Pollution
Water Pollution
Anthropogenic Activities contributing Water Pollution
 Domestic Activities
 Industrial Activities
 AgriculturalActivities
 Shipping IndustrialActivities
 Thermal Power Plants
 NuclearActivities
 MiningActivities
Sources ofWater Pollution
 Domestic Sewage
 Industrial Effluents
 AgriculturalWaste
Water Pollution
Classification ofWater Pollution
Based on Characteristics ofWater
 PhysicalWater Pollution
• Colour
• Turbidity
• Taste
• Odour
• Foams
• Heat
 ChemicalWater Pollution
• Toxic Compounds
• Inorganic Compounds
• Heavy Metals
 BiologicalWater Pollution
• Pathogenic Micro-organisms
 PhysiologicalWater Pollution
• ChemicalAgents
Water Pollution
Classification ofWater Pollution
Based on Sources and Storage ofWater
 GroundWater Pollution
Factors on which GWP depends are:
 Rain Pattern
 Depth ofWaterTable
 Distance from the source of contaminants
 Soil Properties such as texture , structure and filtration rate
 SurfaceWater Pollution
Factors on which SWP depends are:
 Hydrological Characteristics of diluting biocides and extent of self
purifications
 Vegetation soil type and degree of weatheringrocks
 WasteWater Disposal Systems
 Physical, Chemical and Biological characteristics ofWastewaterentering
surfaceWaters
 Hygiene and Health situation of the communities residing near surface waters
Water Pollution
Classification ofWater Pollution
Based on Sources and Storage ofWater
 SurfaceWater Pollution
 LakeWaterPollution
 RiversWater Pollution
 SeaWater or Marine Pollution
Water Pollution
Classification ofWater Pollution
OverallTypes ofWater Pollution
 Microbiological Pollution
 Oxygen Depletion Pollution
 Nutrients Pollution
 Suspended Matter Pollution
Important Concepts
 Biological Oxygen Demand
 Chemical Oxygen Demand
 Eutrophication
 Dissolved Oxygen
Water Pollution
Water Pollutants (Harmful)
Water Pollution
Zinc Cobalt
Copper Nickel
Barium Boron
Iron Acidity andAlkalinity
Cadmium Phosphatesand Nitrates
Mercury Chlorine
Lead Sulphide
Arsenic Salinity
Vanadium Oil/Grease/OilSludge
Silver Aluminium
Radioactive Materials/Substances Pesticides/Insecticides
Fluoride Phenols
Selenium Cyanides
Chromium Salinity
Manganese
Adverse Effects ofWater Pollution
 Effect of Infectious Agents
 Effect of Pesticides
 Effect of Heavy Metals
 Effect of Acid Mine Drainage
 Effect of Inorganic Pollutants
 Effects of Sediments
 Effect of Detergents
 Effect of Plant Nutrients
 Effect of Radioactivity Pollutants
 Effect ofThermal Pollution
Water Pollution
Soil Pollution Noise Pollution
Definition of Soil Pollution
Causes of Soil Pollution
- Agricultural Activities
- Mining and Quarrying Activities
- Sewage Sludge Deposition
- Dumping of Dredged Soil
- Dumping of Solid Wastes
- Deforestation
- Pollution Due to Urbanisation
- IndustrialActivities
Ill Effects of Soil Pollution
- Due to Agricultural Activities
- Due to Mining and Quarrying Activities
- Due to Sewage Sludge Deposition
- Due to Dumping of Dredged Soil
- Due to Dumping of Solid Wastes
- Due to Deforestation
- Due to Urbanisation Pollution
- Due to IndustrialActivities
Control of Soil Pollution
- Reduce, Reuse,Recycleand Recovery
of Solid Waste
- Solid waste treatment
- Reducingchemical fertilizer and
pesticide use
- Reforesting
Noise Pollution
Definition of Noise Pollution
Causes of NoisePollution
- Road Traffic
- Air Traffic
- Rail Traffic
- Domestic Noise
- IndustrialNoise
Norms for Noise Pollution as per CPCB
Solutions for Noise Pollution
 Planting of trees at the point of source
 Regular maintenance of automobiles and machines
 Use of sound absorbing materials
 Restriction on usage of loudspeakers
 Zoning – by landuse
 Social awareness programs
Thermal Pollution Marine Pollution
Definitionof ThermalPollution
Sources/Causesof ThermalPollution
- Waste Water from Cooling Agents in Industrial Facilities
- Deforestation of Shorelines
- Soil Erosion
- Agricultural Sources
Ill-Effects of Thermal Pollution
- Decrease in Dissolved Oxygen in Water
- Affecting Ecosystem Composition
Definitionof Marine Pollution
Sources/Causes of Marine Pollution
- Land Based Discharge
- Oil Exploration and Production
- Dumping of Solid Waste
- Marine Transport
- Atmospheric Inputs
Ill-Effects of Marine Pollution
- Increase in Toxicity of Water
- Leads to Microbiological Pollution
- Leads to Oxygen Depletion Pollution
- Leads to Nutrient Pollution
- Leads to Oil Pollution
Radioactive Pollution
Pesticide Pollution
Radioactive Pollution
Definition
Radioactive pollution can be defined as the emission of high
energy particles or radioactive substance into air, water or
land due to human activities in the form of radioactive
waste. Radioactive waste is usually the product of a nuclear
process such as nuclear fission, which is extensively used in
nuclear reactors, nuclear weapons and other nuclear fuel-
cycles.
Radioactive Pollution
Radioactive Pollution
Sources
 Production of nuclear weapons
 Decommissioning of nuclear weapons
 Mining of radioactive ore (uranium,phosphate etc.)
 Coal ash
 Medical waste
 Nuclear power plants
Radioactive Pollution
 Continuous pollution: This type of condition exists in uranium mines,
nuclear reactors, test labs etc. where the humans are under
continuous exposure to radioactive contaminants and protective
clothing is required to avoid radiation exposure.
 Accidental Pollution: This type of condition exists during accidental
exposure to radiations by virtue of equipment failure, radiation leak,
faulty protective equipment etc.
 Occasional Pollution:This condition exists during isolated
experiment or test of nuclear substance.
Radioactive Pollution
RadioactiveWaste Management
 Geological disposal– this is, effectively, the burying of radioactive material.
Large geologic formations are located and tunnels as deep as 1000m
underground are drilled. Rooms are then excavated at the bottom of these
and radioactive material is stored here until it has decayed enough to not be
dangerous any more. Radioactive waste has also previously been dumped
into the world’s oceans but following the sixteenth meeting of the LDC
(London Dumping Convention) in 1993, the dumping of radioactive waste
into the sea is banned, permanently.
Radioactive Pollution
RadioactiveWaste Management
 Transmutation – transmutation of radioactive waste is the process of
consuming this radioactive waste and turning it into less harmful
waste.This is currently not used very often due to high costs,
however, research is being done to make the process more efficient
and more economically viable.This currently is our most
environmentally friendly radioactive waste management technique
and, as such, when perfected will effectively solve the problem of
radioactive waste.
Radioactive Pollution
RadioactiveWaste Management
 Re-use of radioactive waste – some radioactive isotopes, such as
strontium-90 and caesium-137 are able to be extracted for use in
other industries such as food irradiation.The re-use of radioactive
waste means that the quantity of waste produced is reduced, so this
serves as another good environmentally friendly management
scheme.
Radioactive Pollution
RadioactiveWaste Management
 Space disposal – space disposal is not currently used to reduce
radioactive pollution, due to the potential problems which could
occur when attempting to carry out the procedure. If, for example, a
rocket used to launch the waste fails (and bear in mind that many
rockets would have to be used due to the large amount of radioactive
waste) then huge amounts of radioactive material would be released
into the atmosphere, causing significant health risks to people within
thousands of miles of the launch. Sometime in the future this may be
possible, however, for now, it is best for us to avoid space disposal.
Pesticide Pollution
Pesticide Pollution
Definition
 Pollution caused due to use of pesticide for agricultural
activities causing spraying in the atmosphere or deposition
on soil leading to water and soil pollution is called as
pesticide pollution
Pesticide Pollution
Caused by
 Skin contact: handling of pesticide products
 Inhalation: breathing of dust or spray
 Ingestion:pesticides consumed as a contaminant on/in
food or in water.
Pesticide Pollution
Effects of Pesticide Pollution
 Death of the organism.
 Cancers,tumours and lesions on fish and animals.
 Reproductive inhibition or failure.
 Suppression of immune system.
 Disruption of endocrine (hormonal) system.
 Cellular and DNA damage.
 Teratogenic effects (physical deformities such as hooked
beaks on birds).
Pesticide Pollution
 Effects of Pesticide Pollution
 Poor fish health marked by low red to white blood cell
ratio, excessive slime on fish scales and gills, etc.
 Intergenerational effects (effects are not apparent until
subsequent generations of the organism).
 Other physiological effects such as egg shell thinning.
Green House Effect
Environmental Engineering - I
Atmosphere
Green House Gases
The Green House Gases are:
Methane ,Carbon Dioxide, Nitrous Oxide, Ozone,
Chlorofluorocarbons
Average Composition of Clean Air
Components Average
Concen.
(ppm)
Components Average
Concen.
(ppm)
Nitrogen 780900 Krypton 1.0
Oxygen 209400 Hydrogen 0.5
Argon 9300 Carbon Monoxide 0.1
Carbon Dioxide 318 Ozone 0.02
Neon 18 Nitrogen Dioxide 0.001
Helium 5.2 Sulphur 0.0002
Methane 1.3
Adverse Effect of Greenhouse Gases
1. GlobalWarming
2. Effect on Hydrological Cycle
3. Rise in HTL of Sea
Acid Rain
Environmental Engineering
Acid Rain:
- Acid Rain Can be
- Dry Deposition
- Wet Deposition
- Precipitationwith a pH lower than 5.6 is considered
acidic
Air Pollutants Causing Acid Rain:
The major Air Pollutants causing Acid Rain are:
1. Sulphur Dioxide
2. Nitrogen Oxides
3. Carbon Dioxide
Chemical Reactions of Air Pollutants andWater:
Sulphur Dioxide:
Sulfur dioxide andWater form SulfurousAcid (H2SO3)
SO2(g) + H2O(l) ➔ H2SO3
1. Sulfur Dioxide (SO2) oxidizes to SulfurTrioxide
(SO3)
2SO2(g) + O2(g) ➔ 2SO3
2. SulfurTrioxide (SO3) then combines with water
forming SulfuricAcid (H2SO4)
SO3(g) + H2O(l) ➔ H2SO4
Chemical Reactions of Air Pollutants andWater:
Nitrogen Oxides:
Oxides of Nitrogen like nitrogen dioxide (NO2) react
with water to form nitrous acid (HNO2) and nitric acid
(HNO3)
2NO2(g) + H2O(l) ➔ HNO2 + HNO3
Carbon Dioxide:
Carbon dixide combined with water and forms Carbonic
Acid (Minor Element)
CO2 + H2O ➔ H2CO3
Effects of Acid Rains
- Plant Life
- Aquatic Life
- Property
- Human andAnimal Life
Ozone Depletion
Environmental Engineering
Ozone Depletion:
Ozone depletion have two distinct interrelated phenomena
1. a steady decline of about 4% per decade in the total volume of ozone in Earth's
Stratosphere (the ozone layer), and
2. a much larger springtime decrease in stratospheric ozone over Earth's polar
regions.
This phenomenon is referred as the ozone hole or Ozone Depletion.
Chemical Reactions of Ozone Depletion:
Ozone Depletion mainly occurs due to Stratospheric Chlorine
Thus the element of major concern for Ozone depletion is CFCs which is 60%
(28+23+3+6) of Stratospheric Chlorine
Chemical Reactions in Ozone and CFCs:
1 2
3 4
5 6
Chemical Reactions of Ozone Depletion:
Chemical Reaction with CFCs with Ozone are as follows:
CFCl3 + electromagnetic radiation → CFCl2 + Cl
Cl + O3 → ClO + O2
The chlorine atom changes an ozone molecule to ordinary oxygen
ClO + O3 → Cl + 2 O2
The ClO from the previous reaction destroys a second ozone molecule
This reaction is cyclic. Cl again reacts with ozone and release again Cl +2O2
This release of Oxygen to atmosphere leads to reduction in ozone molecules and
termed as ozone depletion.
Steps in Ozone Depletion
Nuclear Fallout
Environmental Engineering
Nuclear Fallout:
- Definition of Nuclear Fallout
Nuclear fallout is the particles of matter in the air made radioactive from a nuclear
explosion. Some of these particles fall in the immediate area and some get blown by
upper winds many thousands of miles. Eventually they fall to the earth.This is
called fallout
Nuclear Fallout:
- Causes of Nuclear Fallout
 Nuclear Explosion
- Measurement of Nuclear Fallout
Nuclear Fallout is measured as rem – (Roentgen Equivalent Mammal/Man)
Nuclear Fallout:
- Effects on Human Health
Below 100rems Fluctuation in Blood Cell Count
100-200rems Blood FormingTissues affected, Mild Nausea and vomiting, Loss of
appetite lasting for 4 weeks
200-400rems Illness becomes severe, Hair loss, Hemorrhage of mouth and kidney
400-600rems Increase in the severity of all above effects
600-1000rems Bone marrow is completely destroyed
Above
1000rems
Severe intestinal and metabolic problems – diarrhea,intestinal
bleeding, loss of fluid, followed by death in few hours from
circulatory collapse.
Nuclear Fallout:
- Effects on Aquatic Life
- Radiations 11 rems a day cause evidence of mutation in metabolisms and
life shortening as notices in case of fishes.

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01 Environmental Pollution 2020.pdf

  • 2.  Environment  Components of Environment  Air -Atmosphere  Water - Hydrosphere  Soil - Lithosphere Pollution • Pollutant • Types of Pollution
  • 3. Type of Pollution Air Pollution Water Pollution Soil Pollution Noise Pollution
  • 4. Other Types of Pollution Pesticide Pollution Implication: • Soil Pollution • Air Pollution • Water Pollution
  • 6. Radioactive Pollution Implication: • Soil Pollution • Air Pollution • Water Pollution
  • 10. Earth’s Atmosphere  Envelope of Gases above the Earth’s Surface is termed as EarthsAtmosphere
  • 11. Earth’s Atmosphere Troposphere : 0-11km Stratosphere: 11-50km Mesosphere: 50-87km Thermosphere: 87-500km Exosphere: 500-1000km Air Pollution mainly occurs inTroposphere and Stratosphere
  • 12. Role of Earth’s Atmosphere 1. Protects Earths Biosphere from Electromagnetic Radiations 2. Absorbs Infra Red Radiations and maintainTemperature on earth’s surface 3. Maintains balance in the bio-chemical cycles (Oxygen, Nitrogen, Carbon, Hydrological)
  • 13.
  • 14.
  • 15. Role of Earth’sAtmosphere 1. Protects Earths Biosphere from Electromagnetic Radiations 2. Absorbs Infra Red Radiations and maintainTemperature on earth’s surface 3. Maintains balance in the bio-chemical cycles (Oxygen, Nitrogen, Carbon, Hydrological)
  • 16. Composition of Clean Air Gases Avg. Conc. (ppm) Gases Avg. Conc. (ppm) Nitrogen 780900 Krypton 1.0 Oxygen 209400 Hydrogen 0.5 Argon 9300 Carbon Monoxide 0.1 Carbon Dioxide 318 Ozone 0.02 Neon 18 Nitrogen Dioxide 0.001 Helium 5.2 Sulphur 0.0002 Methane 1.3
  • 17. Metrology and Air Pollution Primary Metrological Parameter  Wind Direction and Speed  Temperature  Atmospheric Stability  Mixing Height Secondary Metrological Parameters  Precipitation (Rain)  Humidity  Solar Radiation  Visibility
  • 18. Air Pollutants  These are compounds causing Air Pollution  They are Classified as:  PrimaryAir Pollutants  Secondary Air Pollutants
  • 19. Primary Air Pollutants ✓ Oxides of Carbon ✓ Oxides of Nitrogen ✓ Oxides of Sulphur ✓ Volatile Organic Compounds ✓ Hydrocarbons ✓ Particulate Matter ✓ Radioactive Pollutants
  • 20. Oxides of Carbon – Carbon Monoxide Sources Ill-Effects  Incomplete combustion of materials containing carbon  Automobile Exhausts  Oxidation of Methane by anaerobic Decomposition  SmallAmount –Volcanic Eruption, Forest Fires  Formation of Carboxyl Haemoglobin  Impairment of Central nervous system  Changes in cardiac and pulmonary functions  Drowsiness, respiratory failure, coma, fatality
  • 21. Oxides of Carbon – Carbon Dioxide Sources Ill-Effects  318pppm conc. In clean air  Burning of Fossil Fuels  Complete combustion of materials containing carbon  No Direct Health Effects  Conc. more the 10% activates Green House Effect (56% of Green House Gases)  One of the air pollutant causingAcid Rain
  • 22. Oxides of Nitrogen Sources Ill-Effects Nitrogen Oxides at normal temperature are harmless but at high temperature combines with oxygen to produce nitric oxide  Automobile Exhaust (Diesel Engines)  Electrical Power Plants  Marine Steamers  High Conc.– Lung Cancer and cause suffocation  Low Conc. – Pneumonia, Swelling and Irritation to Skin  MajorAir Pollutant forAcid Rain  6% contributing Green House Gas
  • 23. Oxides of Sulphur Sources Ill-Effects  Burning of fuels  Volcanic Eruptions (35% to 65%)  Industrial Boilers and Metal Smelter  Burning of Domestic Coal  Forest Fires  High Conc. – Reduced Lung Functioning  Low Conc. – Irritation to mucous membrane of Eyes, Nose andThroat  Major Air Pollutant for Acid Rain Amongst the oxides of Sulphur, Sulphur Dioxides is the dominant Air pollutant and found in traceable concentrations and has Pungent and unpleasant odour
  • 24. Volatile Organic Compound  VOC are categorized as :  Methane (MVOCs)  Non Methane (NMVOCs)  Benzene  Toulene
  • 25. VOC - Methane Sources Ill-Effects  Natural CleanAir  Natural gas system and Manure management  Landfills  Coal Mining  WastewaterTreatment  Composting  Odour Nuisance  Green House (contributing 18%) Contributes 1.3ppmv of Natural Clean Air
  • 26. Its a organic compound composed of 6 carbon atom in a ring with 1 hydrogen atom attached to each carbon atom VOC - Benzene Sources Ill-Effects  Industries (Rubber, chemical, tannery, petroleum)  Volcanoes, Forest Fires and crude Oil Evaporation  Emission from glues, adhesives  Odour Nuisance  Green House (contributing 18%)
  • 27. Its a organic compound with sweet odour with composition (C7H8, C6H5, CH3) VOC -Toulene Sources Ill-Effects  Emission from Paint Thinner,Adhesives  Emission from evaporation of Gasoline, Kerosene  High Conc. – Light- headness, Dizziness, Sleepiness, unconsciousness and even fatality  Low Conc. –Tiredness, Confusion, Memory Loss, Nauseas, Loss of hearing and colour vision
  • 28. Its a organic compound entirely consisting of Hydrogen and CarbonAtoms Hydrocarbons Sources Ill-Effects  Automobile Emissions  Emission of Isoprene from trees like eucalyptus, spruce, oak  High Conc. (500- 1000ppmv) are carcinogenic to lungs  Low Conc. – Irritation to mucous membrane of eyes and nose, leading to respiratory disorder  Plants leaves turning Yellowish
  • 29. It is fine particles or tiny particles of solid or liquid suspended in a gas Particulate Matter Sources Ill-Effects  Volcanoes, Dust-storms, forest fires, Sea Sprays  Burning of Fossil Fuels  High Conc. – Respiratory disorder,Altered lung function and may lead lung cancer  Low Conc. – visibility reduction  Primary Pollutant for Photochemical Smog
  • 30. Radioactive Pollutants Sources Ill-Effects  Nuclear Power Plants  Mining and Refining of Plutonium,Thorium, Uranium  NuclearWeapons (Production and Explosion)  Transportation of Radioactive Materials  Disposal of RadioactiveWaste  Preparation of Radioactive Isotopes  Nuclear Fallout
  • 31. Secondary Pollutants The major Secondary Pollutants are: 1. Ground Level Ozone 2. Photochemical Smog 3. PAN (PeroxyAcetyl Nitrate) 4. Acid Mist 5. Chlorofluorocarbons (CFCs) 6. Formaldehyde 7. Persistent Organic Pollutants
  • 32. Ground Level Ozone  Formed by Photochemical Reaction between Oxides of Nitrogen,Volatile organic Compound and Carbon monoxide. Presence of Sunlight
  • 33. Peroxy Acetyl Nitrate (PAN)  Formed by Photochemical Reaction between Hydrocarbons, Nitrogen Oxides and Oxygen. Hydrocarbons + NOx + O2 Presence of Sunlight PAN
  • 34. Photochemical Smog  Formed by Photochemical Reaction between Hydrocarbons, Nitrogen Oxides and oxygen. Hydrocarbons + NOx + O2 Presence of Sunlight,Smog Photochemical Smog
  • 35. Acid Mist  Mist containing a high concentration of acid particles of any toxic chemicals such as CarbonTetrachlorideand Silicon Tetrachloride. Mist + SOx, NOx, Cox + H2O Acid Mist
  • 36. Chloro-Fluoro-Carbons (CFC’s)  It is a organic compound of Carbon, Chlorine and Fluorine produced as a volatile derivation of methane and ethane
  • 37. Formaldehyde  It is a organic compound of with formula CH2O.  It is simplest Aldehyde and its systematic name is Methanol
  • 38. Persistent Organic Pollutants  These are organic compounds that are resistant to environmental degradation through biological and photolytic processes
  • 39. Zoning for Control of Air Pollution ▪ Definition ▪ Zoning on basis of: ▪ Functional Requirements ▪ Performance Requirements ▪ Industrial Zoning basis: ▪ Bangalore City: ▪ Light ▪ Medium ▪ Large ▪ Mumbai City: ▪ Small Repairing and Light Manufacturing Units ▪ Service Industrial Zone ▪ Special Industrial Zone ▪ General Industrial Zone
  • 40. Control of Air Pollution NAMP - Central Pollution Control Board is executing a nation-wide programme of ambient air quality monitoring known as National Air Quality Monitoring Programme (NAMP). Monitoring of fourAir Pollutants  Sulphur Dioxide (SO2),  Oxides of Nitrogen as NO2,  Suspended Particulate Matter (SPM) and  Respirable Suspended Particulate Matter (RSPM / PM10)
  • 42. Definition ofWater Pollution Water Masses on Earth  Lakes  Rivers  Oceans  Ground Water Water Pollutants Sources can be,  Direct Sources  Indirect Sources Types ofWater Pollutants  OrganicWater Pollutants  InorganicWater Pollutants Water Cycle Relation ofWater Cycle and Pollution Water Pollution
  • 43. Anthropogenic Activities contributing Water Pollution  Domestic Activities  Industrial Activities  AgriculturalActivities  Shipping IndustrialActivities  Thermal Power Plants  NuclearActivities  MiningActivities Sources ofWater Pollution  Domestic Sewage  Industrial Effluents  AgriculturalWaste Water Pollution
  • 44. Classification ofWater Pollution Based on Characteristics ofWater  PhysicalWater Pollution • Colour • Turbidity • Taste • Odour • Foams • Heat  ChemicalWater Pollution • Toxic Compounds • Inorganic Compounds • Heavy Metals  BiologicalWater Pollution • Pathogenic Micro-organisms  PhysiologicalWater Pollution • ChemicalAgents Water Pollution
  • 45. Classification ofWater Pollution Based on Sources and Storage ofWater  GroundWater Pollution Factors on which GWP depends are:  Rain Pattern  Depth ofWaterTable  Distance from the source of contaminants  Soil Properties such as texture , structure and filtration rate  SurfaceWater Pollution Factors on which SWP depends are:  Hydrological Characteristics of diluting biocides and extent of self purifications  Vegetation soil type and degree of weatheringrocks  WasteWater Disposal Systems  Physical, Chemical and Biological characteristics ofWastewaterentering surfaceWaters  Hygiene and Health situation of the communities residing near surface waters Water Pollution
  • 46. Classification ofWater Pollution Based on Sources and Storage ofWater  SurfaceWater Pollution  LakeWaterPollution  RiversWater Pollution  SeaWater or Marine Pollution Water Pollution
  • 47. Classification ofWater Pollution OverallTypes ofWater Pollution  Microbiological Pollution  Oxygen Depletion Pollution  Nutrients Pollution  Suspended Matter Pollution Important Concepts  Biological Oxygen Demand  Chemical Oxygen Demand  Eutrophication  Dissolved Oxygen Water Pollution
  • 48. Water Pollutants (Harmful) Water Pollution Zinc Cobalt Copper Nickel Barium Boron Iron Acidity andAlkalinity Cadmium Phosphatesand Nitrates Mercury Chlorine Lead Sulphide Arsenic Salinity Vanadium Oil/Grease/OilSludge Silver Aluminium Radioactive Materials/Substances Pesticides/Insecticides Fluoride Phenols Selenium Cyanides Chromium Salinity Manganese
  • 49. Adverse Effects ofWater Pollution  Effect of Infectious Agents  Effect of Pesticides  Effect of Heavy Metals  Effect of Acid Mine Drainage  Effect of Inorganic Pollutants  Effects of Sediments  Effect of Detergents  Effect of Plant Nutrients  Effect of Radioactivity Pollutants  Effect ofThermal Pollution Water Pollution
  • 50. Soil Pollution Noise Pollution
  • 51. Definition of Soil Pollution Causes of Soil Pollution - Agricultural Activities - Mining and Quarrying Activities - Sewage Sludge Deposition - Dumping of Dredged Soil - Dumping of Solid Wastes - Deforestation - Pollution Due to Urbanisation - IndustrialActivities
  • 52. Ill Effects of Soil Pollution - Due to Agricultural Activities - Due to Mining and Quarrying Activities - Due to Sewage Sludge Deposition - Due to Dumping of Dredged Soil - Due to Dumping of Solid Wastes - Due to Deforestation - Due to Urbanisation Pollution - Due to IndustrialActivities
  • 53. Control of Soil Pollution - Reduce, Reuse,Recycleand Recovery of Solid Waste - Solid waste treatment - Reducingchemical fertilizer and pesticide use - Reforesting
  • 55. Definition of Noise Pollution Causes of NoisePollution - Road Traffic - Air Traffic - Rail Traffic - Domestic Noise - IndustrialNoise
  • 56.
  • 57. Norms for Noise Pollution as per CPCB
  • 58.
  • 59. Solutions for Noise Pollution  Planting of trees at the point of source  Regular maintenance of automobiles and machines  Use of sound absorbing materials  Restriction on usage of loudspeakers  Zoning – by landuse  Social awareness programs
  • 61. Definitionof ThermalPollution Sources/Causesof ThermalPollution - Waste Water from Cooling Agents in Industrial Facilities - Deforestation of Shorelines - Soil Erosion - Agricultural Sources Ill-Effects of Thermal Pollution - Decrease in Dissolved Oxygen in Water - Affecting Ecosystem Composition
  • 62. Definitionof Marine Pollution Sources/Causes of Marine Pollution - Land Based Discharge - Oil Exploration and Production - Dumping of Solid Waste - Marine Transport - Atmospheric Inputs
  • 63. Ill-Effects of Marine Pollution - Increase in Toxicity of Water - Leads to Microbiological Pollution - Leads to Oxygen Depletion Pollution - Leads to Nutrient Pollution - Leads to Oil Pollution
  • 65. Radioactive Pollution Definition Radioactive pollution can be defined as the emission of high energy particles or radioactive substance into air, water or land due to human activities in the form of radioactive waste. Radioactive waste is usually the product of a nuclear process such as nuclear fission, which is extensively used in nuclear reactors, nuclear weapons and other nuclear fuel- cycles.
  • 67. Radioactive Pollution Sources  Production of nuclear weapons  Decommissioning of nuclear weapons  Mining of radioactive ore (uranium,phosphate etc.)  Coal ash  Medical waste  Nuclear power plants
  • 68. Radioactive Pollution  Continuous pollution: This type of condition exists in uranium mines, nuclear reactors, test labs etc. where the humans are under continuous exposure to radioactive contaminants and protective clothing is required to avoid radiation exposure.  Accidental Pollution: This type of condition exists during accidental exposure to radiations by virtue of equipment failure, radiation leak, faulty protective equipment etc.  Occasional Pollution:This condition exists during isolated experiment or test of nuclear substance.
  • 69. Radioactive Pollution RadioactiveWaste Management  Geological disposal– this is, effectively, the burying of radioactive material. Large geologic formations are located and tunnels as deep as 1000m underground are drilled. Rooms are then excavated at the bottom of these and radioactive material is stored here until it has decayed enough to not be dangerous any more. Radioactive waste has also previously been dumped into the world’s oceans but following the sixteenth meeting of the LDC (London Dumping Convention) in 1993, the dumping of radioactive waste into the sea is banned, permanently.
  • 70. Radioactive Pollution RadioactiveWaste Management  Transmutation – transmutation of radioactive waste is the process of consuming this radioactive waste and turning it into less harmful waste.This is currently not used very often due to high costs, however, research is being done to make the process more efficient and more economically viable.This currently is our most environmentally friendly radioactive waste management technique and, as such, when perfected will effectively solve the problem of radioactive waste.
  • 71. Radioactive Pollution RadioactiveWaste Management  Re-use of radioactive waste – some radioactive isotopes, such as strontium-90 and caesium-137 are able to be extracted for use in other industries such as food irradiation.The re-use of radioactive waste means that the quantity of waste produced is reduced, so this serves as another good environmentally friendly management scheme.
  • 72. Radioactive Pollution RadioactiveWaste Management  Space disposal – space disposal is not currently used to reduce radioactive pollution, due to the potential problems which could occur when attempting to carry out the procedure. If, for example, a rocket used to launch the waste fails (and bear in mind that many rockets would have to be used due to the large amount of radioactive waste) then huge amounts of radioactive material would be released into the atmosphere, causing significant health risks to people within thousands of miles of the launch. Sometime in the future this may be possible, however, for now, it is best for us to avoid space disposal.
  • 74. Pesticide Pollution Definition  Pollution caused due to use of pesticide for agricultural activities causing spraying in the atmosphere or deposition on soil leading to water and soil pollution is called as pesticide pollution
  • 75. Pesticide Pollution Caused by  Skin contact: handling of pesticide products  Inhalation: breathing of dust or spray  Ingestion:pesticides consumed as a contaminant on/in food or in water.
  • 76. Pesticide Pollution Effects of Pesticide Pollution  Death of the organism.  Cancers,tumours and lesions on fish and animals.  Reproductive inhibition or failure.  Suppression of immune system.  Disruption of endocrine (hormonal) system.  Cellular and DNA damage.  Teratogenic effects (physical deformities such as hooked beaks on birds).
  • 77. Pesticide Pollution  Effects of Pesticide Pollution  Poor fish health marked by low red to white blood cell ratio, excessive slime on fish scales and gills, etc.  Intergenerational effects (effects are not apparent until subsequent generations of the organism).  Other physiological effects such as egg shell thinning.
  • 81. The Green House Gases are: Methane ,Carbon Dioxide, Nitrous Oxide, Ozone, Chlorofluorocarbons
  • 82. Average Composition of Clean Air Components Average Concen. (ppm) Components Average Concen. (ppm) Nitrogen 780900 Krypton 1.0 Oxygen 209400 Hydrogen 0.5 Argon 9300 Carbon Monoxide 0.1 Carbon Dioxide 318 Ozone 0.02 Neon 18 Nitrogen Dioxide 0.001 Helium 5.2 Sulphur 0.0002 Methane 1.3
  • 83. Adverse Effect of Greenhouse Gases 1. GlobalWarming 2. Effect on Hydrological Cycle 3. Rise in HTL of Sea
  • 85. Acid Rain: - Acid Rain Can be - Dry Deposition - Wet Deposition - Precipitationwith a pH lower than 5.6 is considered acidic
  • 86. Air Pollutants Causing Acid Rain: The major Air Pollutants causing Acid Rain are: 1. Sulphur Dioxide 2. Nitrogen Oxides 3. Carbon Dioxide
  • 87.
  • 88. Chemical Reactions of Air Pollutants andWater: Sulphur Dioxide: Sulfur dioxide andWater form SulfurousAcid (H2SO3) SO2(g) + H2O(l) ➔ H2SO3 1. Sulfur Dioxide (SO2) oxidizes to SulfurTrioxide (SO3) 2SO2(g) + O2(g) ➔ 2SO3 2. SulfurTrioxide (SO3) then combines with water forming SulfuricAcid (H2SO4) SO3(g) + H2O(l) ➔ H2SO4
  • 89. Chemical Reactions of Air Pollutants andWater: Nitrogen Oxides: Oxides of Nitrogen like nitrogen dioxide (NO2) react with water to form nitrous acid (HNO2) and nitric acid (HNO3) 2NO2(g) + H2O(l) ➔ HNO2 + HNO3 Carbon Dioxide: Carbon dixide combined with water and forms Carbonic Acid (Minor Element) CO2 + H2O ➔ H2CO3
  • 90. Effects of Acid Rains - Plant Life - Aquatic Life - Property - Human andAnimal Life
  • 92. Ozone Depletion: Ozone depletion have two distinct interrelated phenomena 1. a steady decline of about 4% per decade in the total volume of ozone in Earth's Stratosphere (the ozone layer), and 2. a much larger springtime decrease in stratospheric ozone over Earth's polar regions. This phenomenon is referred as the ozone hole or Ozone Depletion.
  • 93. Chemical Reactions of Ozone Depletion: Ozone Depletion mainly occurs due to Stratospheric Chlorine Thus the element of major concern for Ozone depletion is CFCs which is 60% (28+23+3+6) of Stratospheric Chlorine
  • 94. Chemical Reactions in Ozone and CFCs: 1 2 3 4 5 6
  • 95. Chemical Reactions of Ozone Depletion: Chemical Reaction with CFCs with Ozone are as follows: CFCl3 + electromagnetic radiation → CFCl2 + Cl Cl + O3 → ClO + O2 The chlorine atom changes an ozone molecule to ordinary oxygen ClO + O3 → Cl + 2 O2 The ClO from the previous reaction destroys a second ozone molecule This reaction is cyclic. Cl again reacts with ozone and release again Cl +2O2 This release of Oxygen to atmosphere leads to reduction in ozone molecules and termed as ozone depletion.
  • 96. Steps in Ozone Depletion
  • 98. Nuclear Fallout: - Definition of Nuclear Fallout Nuclear fallout is the particles of matter in the air made radioactive from a nuclear explosion. Some of these particles fall in the immediate area and some get blown by upper winds many thousands of miles. Eventually they fall to the earth.This is called fallout
  • 99. Nuclear Fallout: - Causes of Nuclear Fallout  Nuclear Explosion - Measurement of Nuclear Fallout Nuclear Fallout is measured as rem – (Roentgen Equivalent Mammal/Man)
  • 100. Nuclear Fallout: - Effects on Human Health Below 100rems Fluctuation in Blood Cell Count 100-200rems Blood FormingTissues affected, Mild Nausea and vomiting, Loss of appetite lasting for 4 weeks 200-400rems Illness becomes severe, Hair loss, Hemorrhage of mouth and kidney 400-600rems Increase in the severity of all above effects 600-1000rems Bone marrow is completely destroyed Above 1000rems Severe intestinal and metabolic problems – diarrhea,intestinal bleeding, loss of fluid, followed by death in few hours from circulatory collapse.
  • 101. Nuclear Fallout: - Effects on Aquatic Life - Radiations 11 rems a day cause evidence of mutation in metabolisms and life shortening as notices in case of fishes.