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PHOSPHORUS REMOVAL AND GENERAL
PERFORMANCE ASSESSMENT OF
DOWN-FLOW HANGING SPONGE (DHS)
REACTORS AS A SECONDARY
TREATMENT PROCESS FOR THE
TREATMENT OF DOMESTIC WASTEWATER
STUDENT: ALEXANDROS KONNARIS
SUPERVISOR: PROF. DAVID GRAHAM
DATE: 2ND SEPTEMBER 2016
Overview
 Introduction
 Background
 Aims and Objectives
 Methodology and Design
 Results
 Summary of Results
 Conclusions
Introduction
 Reusing water is vital in conserving it, as well as minimizing
its waste.
 Down-flow hanging sponge (DHS) reactors offer the
option of a low-energy biological system treating
wastewater, which can be applied to decentralised
water supply systems.
 The 91/271/EEC Urban Waste Water Treatment Directive
(EEC Council, 1991), UWWTD in short, provides the
regulatory guidelines for the quality of treated waters,
against which the results of the study were compared to
assess its performance and compliance.
Background
 Decentralised water supply and low energy treatment
techniques are very important for developing countries who do
not possess the funds for advanced technologies and well
planned water supply networks.
 DHS reactors in the past were used as tertiary treatment units,
usually treating effluent from Up-flow Activated Sludge Blanket
(UASB) reactors.
 The DHS performance results in the past showed good potential
for the use of this method as a secondary treatment technique.
Aim
To assess the performance of two DHS reactors as secondary process units in treating
domestic wastewater, focusing on its effectiveness in removing phosphorus from the influent.
Objectives:
 In phase 1, achieve reactor acclimation.
 In phase 2, test the purification efficiency for settled domestic wastewater from a
municipal water treatment plant and its compliance with the UWWTD 91/271/EEC.
 If requirements are not met, modify the reactors and repeat the process of phase 2.
 Test the hypotheses of: - Alternating oxygen regimes achieving phosphorus removal.
- Reactor 2 design is to be more effective than Reactor 1.
- The large Hydraulic Retention Time (HRT) will bring better results.
Methodology
- Activated sludge and wastewater were circulated in the reactors
during phase 1.
- Standard methods were used for the sample analyses, for:
- Total and Volatile Suspended Solids (TSS and VSS)
- Ammonium (NH4-N)
- Total Kjeldahl Nitrogen (TKN)
- Chemical Oxygen Demand (COD)
- Total Dissolved Phosphorus (TDP)
- Dissolved Oxygen (DO)
- Alkalinity
- Bacteria Enumeration
- pH
- VFA
Design
 HRT was calculated to be 93 hours.
 In the anaerobic regions poly-
phosphate is used up by organisms
as energy, releasing phosphorus as
orthophosphate and taking up
carbon.
 In the aerobic regions, carbon is
oxidised to carbon dioxide,
releasing energy and allowing
Phosphorus Accumulating
Organisms (PAO) to uptake the
free orthophosphate.
Results – Phase 1
12.88
14.96
7.00
14.41
16.37
5.88
0.00
2.00
4.00
6.00
8.00
10.00
12.00
14.00
16.00
18.00
02-May 09-May 16-May
TDNconcentration(mg/L)
Sampling Date
2A 2C
108.5 106.5
95.5
108
116.5
62
130
84
58.5
0
20
40
60
80
100
120
140
160
02-May 09-May 16-May
TotalCODconcentration(mg/L)
Sampling Date
1A 1B 1C
Results – Phase 2
60
65
70
75
80
85
90
95
100
105
23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun
PercentageCODRemoved
Sampling Date
UWWTD 2C 1C
0.00
10.00
20.00
30.00
40.00
50.00
60.00
23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun
TotalNitrogen(mgTN/L)
Sampling Date
1C 2C UWWTD (100K) UWWTD (10K-100K)
Results – Phase 2
0
1
2
3
4
5
6
23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun
TDPconcentration(mg/L)
INF 1A 1B 1C UWWTD
0
5
10
15
20
25
30
20-May 25-May 30-May 04-Jun 09-Jun 14-Jun 19-Jun 24-Jun 29-Jun
Solids(mg/L)
Sampling Date
TSS VSS
Design Modifications
 Some of the
sponges in section C
were replaced with
a layer of Granular
Activated Carbon
(GAC).
 The changes were
identical for the two
reactors.
Results – Phase 3
60
65
70
75
80
85
90
95
100
01-Jul 08-Jul 15-Jul 22-Jul
PercentageCODRemoved
Sampling Date
UWWTD 1C 2C
0
5
10
15
20
25
01-Jul 08-Jul 15-Jul 22-Jul
TotalNitrogen(mgTN/L)
Sampling Date
1C 2C UWWTD (10K-100K) UWWTD (100K)
Results – Phase 3
0
1
2
3
4
5
6
29-Jun 04-Jul 09-Jul 14-Jul 19-Jul 24-Jul 29-Jul 03-Aug
TDPconcentration(mg/L)
Sampling Date
1C 2C UWWTD
28.42
31.34
41.03
54.21
30.86
38.68
9.35
0
10
20
30
40
50
60
01-Jul 08-Jul 15-Jul 18-Jul 22-Jul 25-Jul 29-Jul
PercentageTDPremoved
Sampling Date
2C 2C no change
General Results
Date Reactor 1 Reactor 2
06-Jun 99.98 99.99
20-Jun 99.99 99.99
24-Jun 100.00 99.99
08-Jul 99.73 99.66
15-Jul 99.95 99.78
22-Jul 99.99 99.85
Removal rates of Total Coliforms during phases 2 (light blue) and 3 (red).
Total VFA to Total Alkalinity ratio was on average 1.976 and 0.355 for reactors
1 and 2 respectively, where values greater than 1 show poor reactor stability.
Summary of Results Parameter
UWWTD
Limit / Min
reduction
Reactor 1 Reactor 2
Phase 2 Phase 3 Phase 2 Phase 3
COD concentration 125 mg/L 37.5 mg/L 28.9 mg/L 46.9 mg/L 26 mg/L
COD removal rate 75 % 89.5 % 90.5 % 86.9 % 91.4 %
Total Nitrogen
concentration
10 mg/L 16.4 mg/L 11.7 mg/L 11.8 mg/L 5.1 mg/L
Total Nitrogen
removal rate
70-80 % 64.1 % 69.5 % 75.3 % 85.2 %
TDP concentration 1 mg/L 4.4 mg/L
2.7 mg/L
(Min: 1.95 mg/L)
3.6 mg/L
2.6 mg/L
(Min: 2.3 mg/L)
TDP removal rate 80 % -20.7 %
36.4 %
(Max: 54.2 %)
-2.2 %
38.8 %
(Max: 54.2 %)
Solids concentration 35 mg/L 7.5 mg/L 6.8 mg/L 5.7 mg/L 5.5 mg/L
Solids removal rate 90 % 93 % 94.9 % 94.6 % 92.8 %
 Reactor 2 was found to
be superior to reactor 1
throughout phase 3
 Reactor 2 was also
better than reactor 1
during phase 2, with the
exception of COD
removal
Conclusions
 Reactor 2 design was proven to be more effective than
Reactor 1 in all parameter comparisons.
 Neither the alternating oxygen regimes, nor the very long
HRT presented any potential in removing phosphorus.
 The GAC technique managed to achieve significant
phosphorus reduction, yet it had a short lifetime.
 The growth of PAO proved to be harder than expected.
 Further research on other absorbing material and on
PAO growth could be useful in improving DHS reactors.
Any Questions?
?

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Konnaris - CEG8110

  • 1. PHOSPHORUS REMOVAL AND GENERAL PERFORMANCE ASSESSMENT OF DOWN-FLOW HANGING SPONGE (DHS) REACTORS AS A SECONDARY TREATMENT PROCESS FOR THE TREATMENT OF DOMESTIC WASTEWATER STUDENT: ALEXANDROS KONNARIS SUPERVISOR: PROF. DAVID GRAHAM DATE: 2ND SEPTEMBER 2016
  • 2. Overview  Introduction  Background  Aims and Objectives  Methodology and Design  Results  Summary of Results  Conclusions
  • 3. Introduction  Reusing water is vital in conserving it, as well as minimizing its waste.  Down-flow hanging sponge (DHS) reactors offer the option of a low-energy biological system treating wastewater, which can be applied to decentralised water supply systems.  The 91/271/EEC Urban Waste Water Treatment Directive (EEC Council, 1991), UWWTD in short, provides the regulatory guidelines for the quality of treated waters, against which the results of the study were compared to assess its performance and compliance.
  • 4. Background  Decentralised water supply and low energy treatment techniques are very important for developing countries who do not possess the funds for advanced technologies and well planned water supply networks.  DHS reactors in the past were used as tertiary treatment units, usually treating effluent from Up-flow Activated Sludge Blanket (UASB) reactors.  The DHS performance results in the past showed good potential for the use of this method as a secondary treatment technique.
  • 5. Aim To assess the performance of two DHS reactors as secondary process units in treating domestic wastewater, focusing on its effectiveness in removing phosphorus from the influent. Objectives:  In phase 1, achieve reactor acclimation.  In phase 2, test the purification efficiency for settled domestic wastewater from a municipal water treatment plant and its compliance with the UWWTD 91/271/EEC.  If requirements are not met, modify the reactors and repeat the process of phase 2.  Test the hypotheses of: - Alternating oxygen regimes achieving phosphorus removal. - Reactor 2 design is to be more effective than Reactor 1. - The large Hydraulic Retention Time (HRT) will bring better results.
  • 6. Methodology - Activated sludge and wastewater were circulated in the reactors during phase 1. - Standard methods were used for the sample analyses, for: - Total and Volatile Suspended Solids (TSS and VSS) - Ammonium (NH4-N) - Total Kjeldahl Nitrogen (TKN) - Chemical Oxygen Demand (COD) - Total Dissolved Phosphorus (TDP) - Dissolved Oxygen (DO) - Alkalinity - Bacteria Enumeration - pH - VFA
  • 7. Design  HRT was calculated to be 93 hours.  In the anaerobic regions poly- phosphate is used up by organisms as energy, releasing phosphorus as orthophosphate and taking up carbon.  In the aerobic regions, carbon is oxidised to carbon dioxide, releasing energy and allowing Phosphorus Accumulating Organisms (PAO) to uptake the free orthophosphate.
  • 8. Results – Phase 1 12.88 14.96 7.00 14.41 16.37 5.88 0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 02-May 09-May 16-May TDNconcentration(mg/L) Sampling Date 2A 2C 108.5 106.5 95.5 108 116.5 62 130 84 58.5 0 20 40 60 80 100 120 140 160 02-May 09-May 16-May TotalCODconcentration(mg/L) Sampling Date 1A 1B 1C
  • 9. Results – Phase 2 60 65 70 75 80 85 90 95 100 105 23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun PercentageCODRemoved Sampling Date UWWTD 2C 1C 0.00 10.00 20.00 30.00 40.00 50.00 60.00 23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun TotalNitrogen(mgTN/L) Sampling Date 1C 2C UWWTD (100K) UWWTD (10K-100K)
  • 10. Results – Phase 2 0 1 2 3 4 5 6 23-May 31-May 06-Jun 14-Jun 20-Jun 24-Jun TDPconcentration(mg/L) INF 1A 1B 1C UWWTD 0 5 10 15 20 25 30 20-May 25-May 30-May 04-Jun 09-Jun 14-Jun 19-Jun 24-Jun 29-Jun Solids(mg/L) Sampling Date TSS VSS
  • 11. Design Modifications  Some of the sponges in section C were replaced with a layer of Granular Activated Carbon (GAC).  The changes were identical for the two reactors.
  • 12. Results – Phase 3 60 65 70 75 80 85 90 95 100 01-Jul 08-Jul 15-Jul 22-Jul PercentageCODRemoved Sampling Date UWWTD 1C 2C 0 5 10 15 20 25 01-Jul 08-Jul 15-Jul 22-Jul TotalNitrogen(mgTN/L) Sampling Date 1C 2C UWWTD (10K-100K) UWWTD (100K)
  • 13. Results – Phase 3 0 1 2 3 4 5 6 29-Jun 04-Jul 09-Jul 14-Jul 19-Jul 24-Jul 29-Jul 03-Aug TDPconcentration(mg/L) Sampling Date 1C 2C UWWTD 28.42 31.34 41.03 54.21 30.86 38.68 9.35 0 10 20 30 40 50 60 01-Jul 08-Jul 15-Jul 18-Jul 22-Jul 25-Jul 29-Jul PercentageTDPremoved Sampling Date 2C 2C no change
  • 14. General Results Date Reactor 1 Reactor 2 06-Jun 99.98 99.99 20-Jun 99.99 99.99 24-Jun 100.00 99.99 08-Jul 99.73 99.66 15-Jul 99.95 99.78 22-Jul 99.99 99.85 Removal rates of Total Coliforms during phases 2 (light blue) and 3 (red). Total VFA to Total Alkalinity ratio was on average 1.976 and 0.355 for reactors 1 and 2 respectively, where values greater than 1 show poor reactor stability.
  • 15. Summary of Results Parameter UWWTD Limit / Min reduction Reactor 1 Reactor 2 Phase 2 Phase 3 Phase 2 Phase 3 COD concentration 125 mg/L 37.5 mg/L 28.9 mg/L 46.9 mg/L 26 mg/L COD removal rate 75 % 89.5 % 90.5 % 86.9 % 91.4 % Total Nitrogen concentration 10 mg/L 16.4 mg/L 11.7 mg/L 11.8 mg/L 5.1 mg/L Total Nitrogen removal rate 70-80 % 64.1 % 69.5 % 75.3 % 85.2 % TDP concentration 1 mg/L 4.4 mg/L 2.7 mg/L (Min: 1.95 mg/L) 3.6 mg/L 2.6 mg/L (Min: 2.3 mg/L) TDP removal rate 80 % -20.7 % 36.4 % (Max: 54.2 %) -2.2 % 38.8 % (Max: 54.2 %) Solids concentration 35 mg/L 7.5 mg/L 6.8 mg/L 5.7 mg/L 5.5 mg/L Solids removal rate 90 % 93 % 94.9 % 94.6 % 92.8 %  Reactor 2 was found to be superior to reactor 1 throughout phase 3  Reactor 2 was also better than reactor 1 during phase 2, with the exception of COD removal
  • 16. Conclusions  Reactor 2 design was proven to be more effective than Reactor 1 in all parameter comparisons.  Neither the alternating oxygen regimes, nor the very long HRT presented any potential in removing phosphorus.  The GAC technique managed to achieve significant phosphorus reduction, yet it had a short lifetime.  The growth of PAO proved to be harder than expected.  Further research on other absorbing material and on PAO growth could be useful in improving DHS reactors.