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“The Tale Of Ozone Hole”
IDC-601
ABHISHEK MISHRA
PH14047
CONTENTS
• Motivation
• Ozone Chemistry [Stratosphere]
• Historical Timeline
• TOMS dataset / observations
• Lessons Learned
DISCRETE LAYERS OF ATMOSPHERE Z[P,T]
IMAGE SOURCE: Howstuffworks
IMAGE SOURCE: Wiki commons
‘SELECTIVE ABSORPTION’ by gases in
Atmosphere
99%[Fix],H2O,
Trace species
Dry, ozone, [m+d]
oxygen, etc.
Difficult to quantify
Any object, Temperature > 0 emits Electromagnetic/Thermal Radiation:
[WIDE SPECTRUM OF ENERGIES]
SOLAR ELECTROMAGNETIC SPECTRUM
High Energy Waves Low Energy waves
TROPOSPHERE
STRATOSPHERE
MESOSPHERE
OZONE LAYER
“HIGH ENERGY UV
[λ<300nm]
RADIATIONS NEVER
MAKE IT TO THE
EARTH’S SURFACE”
Image Source: Google images
Discovered by
Schoenbien in 1839
PHOTODISSOCITION
M: Any Air molecule
This ozone absorbs the harmful UV radiation!!
Although photo dissociation of O2
[Must be Replenished]
CHAPMAN
PROPOSED
COUPLE OF
REACTIONS
[SOURCE]
CHAPMAN’S MECHANISM [1930]
Ozone sounding [Source: NOAA Antarctica]
SOURCE
“MISSING SINK”
OVERESTIMATION
25 km
KM
NET
The Missing Sinks were identified in the last three decades of research work!!
CATALYTIC
LOSS CYCLES
“PRE-HUMAN
INFLUENCE”
RESERVOIR
MUTUAL
DESTRUCTION
They proposed that CFC’s due to their inertness could make it to the Stratosphere and
interact with the catalytic cycles. [Transport Concept]
Dr. Joseph Farman
Farman’s Research group and NASA
satellites showed a Expanding
depleted region of ozone in
Antarctica!! [1985]
A Rising Concern at that time [Anderson et al., 1989]
It was figured out in a couple of years that the reason was CFC!!
PUTTING THE PIECES TOGETHER
RESERVOIR
LOSS OF OZONE
NEW
CATALYTIC
CYCLE
A result of both experimental and Lab results
Image courtesy NASA (Mark Schoenberg, GSFC).
PSC’s [Polar Stratospheric Clouds] Jeopardise the Reservoirs
-80 degree centigrade
LESSONS LEARNT Source: Prof.V.Sinha
2010
AURA OBSERVATION
The Power of Science and Technology!!
Source: Paul Newman Ted talk
Hailey Station [1956]
We need to Trust our Data and Work [Honesty]
Dr. Shigeru Chubachi, Meteorological
Research Institute, Japan, measured low
ozone and an ozone hole over Syowa,
Antarctica (reported at Ozone
Commission meeting in Halkidiki, Greece
in Sept 1984)
Source: Paul Newman Ted talk
The Significance of Human Beings!!
Source: Wiki Commons
Our Strength lies in “UNITY”
The Montreal Protocol
Source: Paul Newman Ted talk
Vasudhaiva Kutumbakam
{Rig VEDA}
“THE WORLD IS ONE FAMILY”
THANK YOU
References
• Paul Newman Ted talk
• Wallace and Hobbs
• The Ozone Observatory/ the earth observatory [NASA]
• J c Farman, B G Gardiner and J.D Shanklin, [Large losses of ozone in stratosphere {nature 315 -207 (16 May 1985)}
• Mario Molina and Roland [Stratospheric Sinks for CFC’s]
• Johnson et al 1989

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IDC_601

  • 1. “The Tale Of Ozone Hole” IDC-601 ABHISHEK MISHRA PH14047
  • 2. CONTENTS • Motivation • Ozone Chemistry [Stratosphere] • Historical Timeline • TOMS dataset / observations • Lessons Learned
  • 3. DISCRETE LAYERS OF ATMOSPHERE Z[P,T] IMAGE SOURCE: Howstuffworks IMAGE SOURCE: Wiki commons ‘SELECTIVE ABSORPTION’ by gases in Atmosphere 99%[Fix],H2O, Trace species Dry, ozone, [m+d] oxygen, etc. Difficult to quantify
  • 4. Any object, Temperature > 0 emits Electromagnetic/Thermal Radiation: [WIDE SPECTRUM OF ENERGIES] SOLAR ELECTROMAGNETIC SPECTRUM High Energy Waves Low Energy waves
  • 5. TROPOSPHERE STRATOSPHERE MESOSPHERE OZONE LAYER “HIGH ENERGY UV [λ<300nm] RADIATIONS NEVER MAKE IT TO THE EARTH’S SURFACE” Image Source: Google images Discovered by Schoenbien in 1839
  • 6. PHOTODISSOCITION M: Any Air molecule This ozone absorbs the harmful UV radiation!! Although photo dissociation of O2 [Must be Replenished] CHAPMAN PROPOSED COUPLE OF REACTIONS [SOURCE] CHAPMAN’S MECHANISM [1930]
  • 7. Ozone sounding [Source: NOAA Antarctica] SOURCE “MISSING SINK” OVERESTIMATION 25 km KM
  • 8. NET The Missing Sinks were identified in the last three decades of research work!! CATALYTIC LOSS CYCLES “PRE-HUMAN INFLUENCE” RESERVOIR MUTUAL DESTRUCTION
  • 9. They proposed that CFC’s due to their inertness could make it to the Stratosphere and interact with the catalytic cycles. [Transport Concept]
  • 10.
  • 11. Dr. Joseph Farman Farman’s Research group and NASA satellites showed a Expanding depleted region of ozone in Antarctica!! [1985]
  • 12. A Rising Concern at that time [Anderson et al., 1989] It was figured out in a couple of years that the reason was CFC!!
  • 13. PUTTING THE PIECES TOGETHER RESERVOIR LOSS OF OZONE NEW CATALYTIC CYCLE A result of both experimental and Lab results
  • 14. Image courtesy NASA (Mark Schoenberg, GSFC). PSC’s [Polar Stratospheric Clouds] Jeopardise the Reservoirs -80 degree centigrade
  • 15. LESSONS LEARNT Source: Prof.V.Sinha 2010 AURA OBSERVATION
  • 16. The Power of Science and Technology!! Source: Paul Newman Ted talk
  • 17. Hailey Station [1956] We need to Trust our Data and Work [Honesty] Dr. Shigeru Chubachi, Meteorological Research Institute, Japan, measured low ozone and an ozone hole over Syowa, Antarctica (reported at Ozone Commission meeting in Halkidiki, Greece in Sept 1984) Source: Paul Newman Ted talk
  • 18. The Significance of Human Beings!! Source: Wiki Commons
  • 19. Our Strength lies in “UNITY” The Montreal Protocol Source: Paul Newman Ted talk
  • 20. Vasudhaiva Kutumbakam {Rig VEDA} “THE WORLD IS ONE FAMILY” THANK YOU
  • 21. References • Paul Newman Ted talk • Wallace and Hobbs • The Ozone Observatory/ the earth observatory [NASA] • J c Farman, B G Gardiner and J.D Shanklin, [Large losses of ozone in stratosphere {nature 315 -207 (16 May 1985)} • Mario Molina and Roland [Stratospheric Sinks for CFC’s] • Johnson et al 1989

Editor's Notes

  1. Hartley in 1881 observed a cut in radiation around 0.30nm and attributed it to Ozone.