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June 2014
Klaus S. Lackner
Columbia University
Closing the Carbon Cycle
Technology for Stopping
Climate Change
2
Carbon Management
• Not about stabilizing emissions
…but about eliminating all emissions
• The concept of a single CO2 lifetime
in air is misleading
• CO2 is extremely persistent
… thermal effects linger even longer
The “drain in the bathtub” clogs up
as the tub is filling
3
200
300
400
500
600
700
800
1900 2000 2100 2200
Continued
Exponential
Growth
Constant
Emissions
after 2010
100%
of 2010 rate
33%
10%
0%
Preindustrial Level
280 ppm
Hazardous Level
450 ppm
Hazardous Level
450 ppm
CO2 TrajectoriesCO2(ppm)
year
4
Without carbon capture and storage fossil
fuels will have to be phased out

For every ton of fossil carbon
extracted from the ground
another ton will have to be returned

All carbon dioxide emitted to the air will
need to be recaptured
5
The personal carbon allowance
Picture from emercedes online blog: http://www.emercedesbenz.com/Aug08/08_001327_Mercedes_Benz_Econic_Semi_Trailer_Tanker_Trucks_Enter_Service_At_London_Farnborough_Airport.html
~ 30 tons C for every person will lead to 450 ppm
Total permanent allotment
6
IPCC: Need for Negative Emissions
• Negative emissions require carbon storage
○ Safe, permanent, and extremely large capacity
○ Needs more than natural processes
○ Needs more than biomass growth
• Negative emissions require capture from air
○ Needs more than biomass capture
○ Cannot be solved with power plant capture
• Need for storage capacity is potentially large
○ 100 ppm reduction requires 1500 Gt of CO2 storage
○ Ocean will largely return what it absorbed
Question of when – not if
7
Zero emission is a tall order
• Orders of magnitude matter
○ More CO2 than all oil, gas and coal combined
○ The added oxygen weighs 2.7 times as much as the
carbon
• Stuck in a paradigm of incrementalism
○ Reduce emissions from power plants
○ Utilize carbon
○ Wait for renewables to come on line
○ Leave the transportation sector alone
Lacking a sense of urgency
8
Technology solutions for climate
• Need to push the technological envelope in
carbon management
○ Closing the carbon cycle is a necessity
○ Shrinking the carbon cycle is an option
○ Committed to 1500 Gt of CO2 disposal
• Need to go beyond conventional solutions
○ More than retrofits
○ More than one storage option
○ More than energy alternatives
○ More than energy efficiency
• Need to operate at a formidable scale
9
Adressing climate change
is about risk management
• Reducing atmospheric CO2 minimizes climate risk
○ Air capture allows for a return to safe CO2 concentrations
○ It does not entirely eliminate the climate damage risk
• Point source storage minimizes economic risk
○ Access to fossil carbon reduces risk of energy shortages
• Multiple options for storage minimizes all risks
○ Geological storage may fall short
• Physical limitations
• Public perception and acceptance
• Liability issues
Navigating between climate catastrophe and economic collapse
10
Power plant capture is not enough
• A 70% reduction of a 30% contributor
cannot achieve a 90 to 100% reduction
○ Point sources only cover half of all emissions
• Geological storage is important
… but not enough
○ Problems with local availability
○ Uncertainty of long term storage
○ Public acceptance issues
○ Need for alternatives to cover unquantified risks
11
Biomass is not enough
• Agriculture satisfies human metabolism
○ About 100 Watt per person
• Can it provide primary energy demand?
○ US: 10,000 Watt per person
• Three way collision between
○ Food supply
○ Energy demand
○ Environmental impact
12
Net Zero Carbon Economy
CO2
extraction
from air
Permanent &
safe
disposal
CO2 from
concentrated
sources
Capture from power
plants, cement, steel,
refineries, etc.
Geological Storage
Mineral carbonate disposal
+ many others
13
Carbon Storage/Disposal is the biggest
part of the problem

Scale dwarfs all other industrial scales with
the exception of water

15
Mineral Sequestration
Mg3Si2O5(OH)4 + 3CO2(g) → 3MgCO3 + 2SiO2 +2H2O(l)
+63kJ/mol CO2
•Safe and permanent storage option
•High storage capacity
•Permanence on a geological time scale
•Closure of the natural carbon cycle
16
Energy States of Carbon
Carbon
Carbon Dioxide
Carbonate
400 kJ/mole
60...180 kJ/mole
The ground state of carbon
is a mineral carbonate
17
CO2 N2
H2O
SOx, NOx and
other
Pollutants
Carbon
Air
Zero Emission
Principle …
Solid WastePower Plant
… leads to
advanced power
plant designs
18
Boudouard Reaction
Air extraction can
compensate for CO2
emissions anywhere
Art courtesy Stonehaven CCS, Montreal
Separate sources from sinks
• CO2 capture
• combined with remote storage
• part of closed carbon fuel cycles
• commercial source of CO2
20
Air capture
• Air capture for access to fossil fuels
○ Air capture as part of CCS
○ Focus on dispersed and mobile sources
○ Complementing power plant capture
• Air capture with non-fossil energy
○ Allowing liquid fuels in the transportation sector
○ Synthetic fuel production from CO2 and H2O
○ Requires cheap non-fossil energy
• Air capture for drawing down CO2
○ First emissions must be stopped or canceled out
○ No excuse for procrastinationn – already too late
○ Ocean will return much of its CO2
• (count past fossil fuel emissions not ppm in the air)
21
Stabilizing climate with small machines
Many one-ton-per-day units
100 million units would
eliminate world emissions
With 10 year life time,
production must be
10 million units per
year
K S Lackner has co-founded GRT LLC, a company started to explore the feasibility of air capture. He is an advisor to
its successor organization Kilimanjaro Energy, Inc. He has an ownership stake in the company
22
Air capture is the capture of last resort
• can handle emissions from any and all sources
• sets upper limit on cost of carbon management
• assures feasibility of zero carbon scenarios
• provides a solution to the risk of leaky storage
• encourages point source capture
Wikipedia picture
23
For new technologies, low cost comes with experience
price dropped fortyfold
price dropped hundredfold
cost of lighting fell
7000 fold in the 20th
century
Wikipedia pictures
Ingredient costs are already small – small units: low startup cost
$600
$500
$400
$300
$200
$100
$0
APS (low tech)
GRT (first of a kind)
Current estimates
CO2 enriched air
Per ton CO2
Raw material and energy limit (frictionless cost)
The
power
of the
learning
curve
24
Technology for abating climate change
• Storage and capture from all sources
• Provide alternatives to geological storage
• Create negative emissions by air capture
• Access remote storage sites by air capture
• Removal from air is a necessity
Think big – there is no alternative

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Closing the Carbon Cycle: Technology for Stopping Climate Change - Klaus Lackner at the Alternative CCS Pathways Workshop, Oxford Martin School, 26 June 2014

  • 1. June 2014 Klaus S. Lackner Columbia University Closing the Carbon Cycle Technology for Stopping Climate Change
  • 2. 2 Carbon Management • Not about stabilizing emissions …but about eliminating all emissions • The concept of a single CO2 lifetime in air is misleading • CO2 is extremely persistent … thermal effects linger even longer The “drain in the bathtub” clogs up as the tub is filling
  • 3. 3 200 300 400 500 600 700 800 1900 2000 2100 2200 Continued Exponential Growth Constant Emissions after 2010 100% of 2010 rate 33% 10% 0% Preindustrial Level 280 ppm Hazardous Level 450 ppm Hazardous Level 450 ppm CO2 TrajectoriesCO2(ppm) year
  • 4. 4 Without carbon capture and storage fossil fuels will have to be phased out  For every ton of fossil carbon extracted from the ground another ton will have to be returned  All carbon dioxide emitted to the air will need to be recaptured
  • 5. 5 The personal carbon allowance Picture from emercedes online blog: http://www.emercedesbenz.com/Aug08/08_001327_Mercedes_Benz_Econic_Semi_Trailer_Tanker_Trucks_Enter_Service_At_London_Farnborough_Airport.html ~ 30 tons C for every person will lead to 450 ppm Total permanent allotment
  • 6. 6 IPCC: Need for Negative Emissions • Negative emissions require carbon storage ○ Safe, permanent, and extremely large capacity ○ Needs more than natural processes ○ Needs more than biomass growth • Negative emissions require capture from air ○ Needs more than biomass capture ○ Cannot be solved with power plant capture • Need for storage capacity is potentially large ○ 100 ppm reduction requires 1500 Gt of CO2 storage ○ Ocean will largely return what it absorbed Question of when – not if
  • 7. 7 Zero emission is a tall order • Orders of magnitude matter ○ More CO2 than all oil, gas and coal combined ○ The added oxygen weighs 2.7 times as much as the carbon • Stuck in a paradigm of incrementalism ○ Reduce emissions from power plants ○ Utilize carbon ○ Wait for renewables to come on line ○ Leave the transportation sector alone Lacking a sense of urgency
  • 8. 8 Technology solutions for climate • Need to push the technological envelope in carbon management ○ Closing the carbon cycle is a necessity ○ Shrinking the carbon cycle is an option ○ Committed to 1500 Gt of CO2 disposal • Need to go beyond conventional solutions ○ More than retrofits ○ More than one storage option ○ More than energy alternatives ○ More than energy efficiency • Need to operate at a formidable scale
  • 9. 9 Adressing climate change is about risk management • Reducing atmospheric CO2 minimizes climate risk ○ Air capture allows for a return to safe CO2 concentrations ○ It does not entirely eliminate the climate damage risk • Point source storage minimizes economic risk ○ Access to fossil carbon reduces risk of energy shortages • Multiple options for storage minimizes all risks ○ Geological storage may fall short • Physical limitations • Public perception and acceptance • Liability issues Navigating between climate catastrophe and economic collapse
  • 10. 10 Power plant capture is not enough • A 70% reduction of a 30% contributor cannot achieve a 90 to 100% reduction ○ Point sources only cover half of all emissions • Geological storage is important … but not enough ○ Problems with local availability ○ Uncertainty of long term storage ○ Public acceptance issues ○ Need for alternatives to cover unquantified risks
  • 11. 11 Biomass is not enough • Agriculture satisfies human metabolism ○ About 100 Watt per person • Can it provide primary energy demand? ○ US: 10,000 Watt per person • Three way collision between ○ Food supply ○ Energy demand ○ Environmental impact
  • 12. 12 Net Zero Carbon Economy CO2 extraction from air Permanent & safe disposal CO2 from concentrated sources Capture from power plants, cement, steel, refineries, etc. Geological Storage Mineral carbonate disposal + many others
  • 13. 13 Carbon Storage/Disposal is the biggest part of the problem  Scale dwarfs all other industrial scales with the exception of water 
  • 14.
  • 15. 15 Mineral Sequestration Mg3Si2O5(OH)4 + 3CO2(g) → 3MgCO3 + 2SiO2 +2H2O(l) +63kJ/mol CO2 •Safe and permanent storage option •High storage capacity •Permanence on a geological time scale •Closure of the natural carbon cycle
  • 16. 16 Energy States of Carbon Carbon Carbon Dioxide Carbonate 400 kJ/mole 60...180 kJ/mole The ground state of carbon is a mineral carbonate
  • 17. 17 CO2 N2 H2O SOx, NOx and other Pollutants Carbon Air Zero Emission Principle … Solid WastePower Plant … leads to advanced power plant designs
  • 19. Air extraction can compensate for CO2 emissions anywhere Art courtesy Stonehaven CCS, Montreal Separate sources from sinks • CO2 capture • combined with remote storage • part of closed carbon fuel cycles • commercial source of CO2
  • 20. 20 Air capture • Air capture for access to fossil fuels ○ Air capture as part of CCS ○ Focus on dispersed and mobile sources ○ Complementing power plant capture • Air capture with non-fossil energy ○ Allowing liquid fuels in the transportation sector ○ Synthetic fuel production from CO2 and H2O ○ Requires cheap non-fossil energy • Air capture for drawing down CO2 ○ First emissions must be stopped or canceled out ○ No excuse for procrastinationn – already too late ○ Ocean will return much of its CO2 • (count past fossil fuel emissions not ppm in the air)
  • 21. 21 Stabilizing climate with small machines Many one-ton-per-day units 100 million units would eliminate world emissions With 10 year life time, production must be 10 million units per year K S Lackner has co-founded GRT LLC, a company started to explore the feasibility of air capture. He is an advisor to its successor organization Kilimanjaro Energy, Inc. He has an ownership stake in the company
  • 22. 22 Air capture is the capture of last resort • can handle emissions from any and all sources • sets upper limit on cost of carbon management • assures feasibility of zero carbon scenarios • provides a solution to the risk of leaky storage • encourages point source capture Wikipedia picture
  • 23. 23 For new technologies, low cost comes with experience price dropped fortyfold price dropped hundredfold cost of lighting fell 7000 fold in the 20th century Wikipedia pictures Ingredient costs are already small – small units: low startup cost $600 $500 $400 $300 $200 $100 $0 APS (low tech) GRT (first of a kind) Current estimates CO2 enriched air Per ton CO2 Raw material and energy limit (frictionless cost) The power of the learning curve
  • 24. 24 Technology for abating climate change • Storage and capture from all sources • Provide alternatives to geological storage • Create negative emissions by air capture • Access remote storage sites by air capture • Removal from air is a necessity Think big – there is no alternative