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ELECTROCHEMISTRY Chapter 18 SAVE PAPER AND INK!!! When you print out the notes on PowerPoint, print "Handouts" instead of "Slides" in the print setup. Also, turn off the backgrounds (Tools>Options>Print>UNcheck "Background Printing")!
Electron Transfer Reactions ,[object Object],[object Object],[object Object]
Terminology for Redox Reactions ,[object Object],[object Object],[object Object],[object Object]
You can’t have one… without the other! ,[object Object],[object Object],LEO  the lion says  GER ! GER!
Another way to remember ,[object Object]
OXIDATION-REDUCTION REACTIONS ,[object Object],[object Object],[object Object]
OXIDATION-REDUCTION REACTIONS ,[object Object],[object Object]
Why Study Electrochemistry? ,[object Object],[object Object],[object Object],[object Object],The heme group
Electrochemical Cells ,[object Object],[object Object],[object Object],Batteries are voltaic cells
Anode Cathode Basic Concepts  of Electrochemical Cells
CHEMICAL CHANGE ---> ELECTRIC CURRENT ,[object Object],[object Object],With time, Cu plates out onto Zn metal strip, and Zn strip “disappears.”
[object Object],CHEMICAL CHANGE ---> ELECTRIC CURRENT This is accomplished in a  GALVANIC  or  VOLTAIC  cell. A group of such cells is called a  battery . http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/galvan5.swf
[object Object],[object Object],Zn --> Zn 2+  + 2e- Cu 2+  + 2e- --> Cu <--Anions Cations--> Oxidation Anode Negative Red uction Cat hode Positive RED CAT
Terms Used for Voltaic Cells
CELL POTENTIAL, E ,[object Object],[object Object],[object Object]
Calculating Cell Voltage ,[object Object],Zn(s)  --->  Zn 2+ (aq)  +  2e- Cu 2+ (aq)  +  2e-  ---> Cu(s) -------------------------------------------- Cu 2+ (aq)  +  Zn(s) ---> Zn 2+ (aq)  +  Cu(s) If we know E o  for each half-reaction, we could get E o  for net reaction.
TABLE OF STANDARD REDUCTION POTENTIALS 2 To determine an oxidation from a reduction table, just take the opposite sign of the reduction! E o (V) Cu 2+ +  2e-  Cu +0.34 2 H + +  2e-  H 0.00 Zn 2+ +  2e-  Zn -0.76 oxidizing ability of ion reducing ability of element
Zn/Cu Electrochemical Cell ,[object Object],[object Object],[object Object],[object Object],[object Object],Cathode, positive, sink for electrons Anode, negative, source of electrons +
 
E o  for a Voltaic Cell Cd  -->  Cd 2+  + 2e- or Cd 2+  + 2e-  -->  Cd Fe  -->  Fe 2+  + 2e- or Fe 2+  + 2e-  -->  Fe All ingredients are present. Which way does reaction proceed?
[object Object],[object Object],[object Object],E o  for a Voltaic Cell
More About  Calculating Cell Voltage ,[object Object],2 H 2 O  +  2e-  --->  H 2   +  2 OH -  Cathode 2 I -   --->   I 2   +  2e-   Anode ------------------------------------------------- 2 I -   +  2 H 2 O  -->  I 2  +  2 OH -  +  H 2 Assuming reaction occurs as written,  E˚ = E˚ cat + E˚ an = (-0.828 V) - (- +0.535 V) =  -1.363 V Minus E˚ means rxn. occurs in opposite direction (the connection is backwards or you are recharging the battery)
Charging a Battery When you charge a battery, you are forcing the electrons backwards (from the + to the -).  To do this, you will need a higher voltage backwards than forwards.  This is why the ammeter in your car often goes slightly higher while your battery is charging, and then returns to normal. In your car, the battery charger is called an alternator.  If you have a dead battery, it could be the battery needs to be replaced OR the alternator is not charging the battery properly.
Dry Cell Battery ,[object Object],[object Object],[object Object],[object Object]
Alkaline Battery ,[object Object],Anode (-):  Zn + 2 OH -  --->  ZnO + H 2 O +  2e- Cathode (+):  2 MnO 2  + H 2 O  +  2e-  --->  Mn 2 O 3  + 2 OH -
Mercury Battery ,[object Object],[object Object],[object Object],[object Object]
Lead Storage Battery ,[object Object],[object Object],[object Object],[object Object]
Ni-Cad Battery ,[object Object],[object Object],[object Object],[object Object]
H 2  as a Fuel Cars can use electricity generated by H 2 /O 2  fuel cells. H 2  carried in tanks or generated from hydrocarbons
Balancing Equations  for Redox Reactions ,[object Object],[object Object],Mn = +7 Fe = +2 Fe = +3 Mn = +2
Balancing Equations ,[object Object],Cu  +  Ag +   --give-->  Cu 2+   +  Ag
Balancing Equations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Balancing Equations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Balancing Equations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],VO 2 +   --->  VO 2+   +  H 2 O 2 H +   + Add H 2 O on O-deficient side and add H +  on other side for H-balance.
Balancing Equations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Tips on Balancing Equations ,[object Object],[object Object],[object Object],[object Object],[object Object]

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intro to electrochemistry

  • 1. ELECTROCHEMISTRY Chapter 18 SAVE PAPER AND INK!!! When you print out the notes on PowerPoint, print &quot;Handouts&quot; instead of &quot;Slides&quot; in the print setup. Also, turn off the backgrounds (Tools>Options>Print>UNcheck &quot;Background Printing&quot;)!
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  • 10. Anode Cathode Basic Concepts of Electrochemical Cells
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  • 14. Terms Used for Voltaic Cells
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  • 17. TABLE OF STANDARD REDUCTION POTENTIALS 2 To determine an oxidation from a reduction table, just take the opposite sign of the reduction! E o (V) Cu 2+ + 2e- Cu +0.34 2 H + + 2e- H 0.00 Zn 2+ + 2e- Zn -0.76 oxidizing ability of ion reducing ability of element
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  • 20. E o for a Voltaic Cell Cd --> Cd 2+ + 2e- or Cd 2+ + 2e- --> Cd Fe --> Fe 2+ + 2e- or Fe 2+ + 2e- --> Fe All ingredients are present. Which way does reaction proceed?
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  • 23. Charging a Battery When you charge a battery, you are forcing the electrons backwards (from the + to the -). To do this, you will need a higher voltage backwards than forwards. This is why the ammeter in your car often goes slightly higher while your battery is charging, and then returns to normal. In your car, the battery charger is called an alternator. If you have a dead battery, it could be the battery needs to be replaced OR the alternator is not charging the battery properly.
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  • 29. H 2 as a Fuel Cars can use electricity generated by H 2 /O 2 fuel cells. H 2 carried in tanks or generated from hydrocarbons
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Editor's Notes

  1. To play the movies and simulations included, view the presentation in Slide Show Mode.