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Chapter 19
“Acids, Bases, and Salts”

                                    Section 19.1
                                 Acid-Base Theories

Properties of Acids

•   They taste sour (don’t try this at home).
•   They can __________________________________________________.
            – Can be strong or weak electrolytes in aqueous solution
•   ________________________________________________ to form H2 gas.
•   ____________________________________________________ of indicators
    (for example: blue litmus turns to red).
•   _____________________________________________________ (metallic
    hydroxides) to form water and a salt.

•   They have a _________________________________________(more on this concept
    of pH in a later lesson)
•   They react with carbonates and bicarbonates to produce a salt, water, and carbon
    dioxide gas
•   How do you know if a chemical is an acid?
           – It usually starts with ______________________________
           – HCl, H2SO4, HNO3, etc. (but not water!)

Acids Affect Indicators, by changing their color

•   Blue litmus paper turns ________________ in contact with an acid (and red paper
    stays red).

Acids React with Active Metals

•   Acids react with active metals to form salts and hydrogen gas:

HCl(aq) + Mg(s) → MgCl2(aq) + H2(g)

•   This is a _____________________________________________________________

Acids Neutralize Bases

HCl + NaOH → NaCl + H2O

-Neutralization reactions ALWAYS produce a ________________ (which is an ionic
compound) and water.
-Of course, it takes the right proportion of acid and base to produce a neutral salt
Properties of Bases (metallic hydroxides)

•   ____________________________________ to form water and a salt.
•   Taste ______________________.
•   ___________________________ (don’t try this either).
•   Can be strong or weak ___________________________________ in aqueous
    solution
•   _____________________________________________ of indicators (red litmus
    turns blue).

Bases Affect Indicators

•   Red litmus paper turns _____________ in contact with a base (and blue paper stays
    blue).

•   Phenolphthalein turns ____________________ in a base.

Arrhenius Definition – 1887

•   Acids produce hydrogen ions (H1+) in aqueous solution ________________________
•   Bases produce hydroxide ions (OH1-) when dissolved in water.
               • __________________________________________
•   Limited to aqueous solutions.
•   Only one kind of base (hydroxides)
•   NH3 (ammonia) could not be an Arrhenius base: no OH1- produced.
The pH concept – from 0 to 14

   n   pH = pouvoir hydrogene (Fr.)                    “hydrogen power”
   n   definition: pH = -log[H+]
   n   in neutral pH = -log(1 x 10-7) = 7
   n   in acidic solution [H+] > 10-7
   n   pH < -log(10-7)
           – pH < 7 (from 0 to 7 is the acid range)
           – in base, pH > 7 (7 to 14 is base range)

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Chemistry - Chp 19 - Acid, Base, Salt - Notes

  • 1. Chapter 19 “Acids, Bases, and Salts” Section 19.1 Acid-Base Theories Properties of Acids • They taste sour (don’t try this at home). • They can __________________________________________________. – Can be strong or weak electrolytes in aqueous solution • ________________________________________________ to form H2 gas. • ____________________________________________________ of indicators (for example: blue litmus turns to red). • _____________________________________________________ (metallic hydroxides) to form water and a salt. • They have a _________________________________________(more on this concept of pH in a later lesson) • They react with carbonates and bicarbonates to produce a salt, water, and carbon dioxide gas • How do you know if a chemical is an acid? – It usually starts with ______________________________ – HCl, H2SO4, HNO3, etc. (but not water!) Acids Affect Indicators, by changing their color • Blue litmus paper turns ________________ in contact with an acid (and red paper stays red). Acids React with Active Metals • Acids react with active metals to form salts and hydrogen gas: HCl(aq) + Mg(s) → MgCl2(aq) + H2(g) • This is a _____________________________________________________________ Acids Neutralize Bases HCl + NaOH → NaCl + H2O -Neutralization reactions ALWAYS produce a ________________ (which is an ionic compound) and water. -Of course, it takes the right proportion of acid and base to produce a neutral salt
  • 2. Properties of Bases (metallic hydroxides) • ____________________________________ to form water and a salt. • Taste ______________________. • ___________________________ (don’t try this either). • Can be strong or weak ___________________________________ in aqueous solution • _____________________________________________ of indicators (red litmus turns blue). Bases Affect Indicators • Red litmus paper turns _____________ in contact with a base (and blue paper stays blue). • Phenolphthalein turns ____________________ in a base. Arrhenius Definition – 1887 • Acids produce hydrogen ions (H1+) in aqueous solution ________________________ • Bases produce hydroxide ions (OH1-) when dissolved in water. • __________________________________________ • Limited to aqueous solutions. • Only one kind of base (hydroxides) • NH3 (ammonia) could not be an Arrhenius base: no OH1- produced.
  • 3. The pH concept – from 0 to 14 n pH = pouvoir hydrogene (Fr.) “hydrogen power” n definition: pH = -log[H+] n in neutral pH = -log(1 x 10-7) = 7 n in acidic solution [H+] > 10-7 n pH < -log(10-7) – pH < 7 (from 0 to 7 is the acid range) – in base, pH > 7 (7 to 14 is base range)