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WHAT IS GASOLINE?
WHAT IS GASOLINE?
 Gasoline is a term used to describe a
complex mixture of various hydrocarbons
refined from crude petroleum oil for use as
fuel in engines.
 Made up of several hydrocarbon molecules
including the following:
- Methane, Ethane, Propane, Butane,
Pentane, Hexane, & Heptane.
DISTILLATION
 Raw Crude oil is heated
and put into a distillation
column — and different
hydrocarbon
components boil off and
can be recovered as
they condense at
different temperatures.
CRACKING
 The distilled oil is then “Cracked” by a
catalyst or thermal process. Cracking, as the
name suggests, is a process in which large
hydrocarbon molecules are broken down into
smaller and more useful ones.
CRACKING
OCTANE NUMBER?
 The octane rating of gasoline essentially tells
you how much the air-fuel mixture can be
compressed before it will spontaneously
ignite. Gasoline with an optimal octane rating
performs best in an engine designed to run
on that octane level. (so don’t waste your
money)
VOLATILITY
 Describes how easily the gasoline
evaporates (forms a vapor). The definition of
volatility assumes that the vapors will remain
in the fuel tank or fuel line and will cause a
certain pressure based on the temperature of
the fuel.
 Which is measured by;
REID VAPOR PRESSURE
 Reid Vapor Pressure, Or “RVP” is the
pressure of the vapor above the fuel when
the fuel is at 100F. Increased vapor pressure
permits the engine to start in cold weather.
Gasoline must be vaporized to burn.
REID VAPOR PRESSURE
 This is why we have “Winter blend” and
“Summer blend” fuels. In the winter we need
the gas to vaporize easier (higher RVP,
usually 15psi) . In summer we need the
vaporization to decrease (lower RVP, usually
7-9psi).
VOLATILITY-RELATED PROBLEMS
 If we use winter blend in the summer, the fuel
in our vehicles will evaporate easier, creating
higher tank pressures (air pollution) and
vapor locking our fuel lines (tiny bubbles in
fuel) creating a lean condition (higher
exhaust emissions).
VOLATILITY-RELATED PROBLEMS
 If we use summer blend fuels in the winter,
our vehicles will be hard to start and may
stall (fuel will not evaporate easily)
TESTING RVP
 There are “homemade” kits for sale, or you
can make your own, but you may not being
comparing “apples to apples” due to
calibration errors. Commercial testers are
very expensive.
SMELL TEST
 Even though you can’t smell “RVP”, you can
smell if the gas is rancid, which can indicate
if its old, which can indicate if the wrong
volatility is being used.
 When in doubt, drain and refill at local Petrol
station.
QUICK TIPS!
 Keep fuel tank above quarter tank to prolong
fuel pump life! (due to dirt and heat)
 Don’t “top off” your gas tank, when the pump
shuts off, STOP! (may fail smog)
 If you must re-enter your vehicle during
fueling, touch the metal body away from
fueling point (BOOM)
 Don’t fill gasoline containers off the ground
(Truck beds…etc.)
QUICK TIPS!
OXYGENATED FUELS
OXYGENATED FUELS
 By definition are fuels that contain an oxygen
atom in the fuel molecule itself. The oxygen
is used to help fuel burn more efficiently and
reduce exhaust emissions, plus it helps
reduce the amount of nonrenewable fossil
fuels consumed.
 Oxygenated fuels also increase octane and
volatility.
OK BUT WHAT ARE OXYGENATED FUELS!
 Methanol- is an Oxygenated alcohol fuel,
that was originally distilled from wood.
 Methanol (like Ethanol) is volatile, colorless,
tasteless, and flammable.
 Unlike Ethanol, Methanol is HIGHLY toxic.
Only four ounces consumed is fatal.
 Methanol is also toxic through inhalation and
absorption.
OK BUT WHAT ARE OXYGENATED FUELS!
 Ethanol- is an Oxygenated alcohol fuel as
well, but is distilled from;
- Corn, Soybeans, Sorghum, Wheat, Barley,
and Potatoes.
 Used to increase the volatility of winter
blends.
 In quantities higher than 85% (E85) qualifies
as an alternative fuel as defined by the
Energy Policy Act of 1992.
METHANOL ETHANOL
WHAT ARE FLEX FUEL VEHICLES
 Vehicles equipped to be able to run on E85
(85% Ethanol) or Gasoline. (Identified by a
yellow fuel cap)
 Must be able to detect Ethanol content in
gasoline to keep driveability acceptable.
(using either a oxygen sensor or variable
fuel sensor).
FLEX FUEL PROS
 Using E85 reduces pollutants and our
dependence on imported oil.
 E85 is water soluble, non toxic, and
biodegradable.
 Using E85 in a flex-fuel vehicle can result in
a 5% power increase. (over 100% Gasoline)
 Purchase price for flex fuel vehicles are the
same as their gasoline counterparts.
FLEX FUEL CONS
 Using E85 in a flex-fuel vehicle can result in
a 20-30% reduction in fuel economy. (over
Gas)
 Vehicle repairs can cost more, due to
“special” parts in the fuel system to protect
against corrosion of alcohol based fuel, and
special E85 detection components.
 Farmland usage is shifting to grow corn for
fuel. (which changes nitrogen levels and soil
erosion).
FLEX FUEL CONS
 In 2001 U.S. corn production was 90% food
and 10% fuel.
 Today only 60% of Corn production is applied
to food. (U.S. supplies 40% of the worlds
corn)
 E85 fueling stations are few and far between,
and the cost per gallon is on the rise. (supply
and demand)
NO PERFECT SOLUTION
 Just like any other alternative fuel option,
there are no perfect solutions or “one size fits
all”. Ethanol and E85 may be the solution in
the corn belt, but not in other parts of the
country.
FIRST FLEX FUEL VEHICLE?
Pop quiz! What was the first flex fuel vehicle?
Henry Ford created the Model T to run on
Ethanol! His vision was to create less dependency
on oil and support our own economy (farmers)
FIRST FLEX FUEL VEHICLE!
E85 IN A NON FLEX FUEL
 It is important to know the characteristics of
using Ethanol or E85 fuel. (due to fuel
contamination in a non flex fuel vehicle)
 E85 is corrosive (due to water and oxygen in
the fuel)
 E85 reaches stoichiometry at 9.7:1
BUT HOW DO WE KNOW IF ITS E85 FOR
SURE!
TESTING FOR ALCOHOL IN GASOLINE
 It is important to be able to test for the
presence of alcohol in Gasoline to help
diagnose and eliminate some driveability
problems.
 You will need the following;
- 100ml Graduated Cylinder
- Sample of Gasoline
- Water
TESTING FOR ALCOHOL IN GASOLINE
 Pour suspect Gasoline into a graduated
cylinder.
 Carefully fill the graduated cylinder to the
90ml mark.
 Add 10ml of water to the graduated cylinder.
TESTING FOR ALCOHOL IN GASOLINE
 Put the stopper in the cylinder and give it a
“scientific shake” for one minute. Relieve
built up pressure by occasionally removing
the stopper. Alcohol dissolves in water and
will drop to the bottom of the cylinder.
(Gasoline is lighter than water).
TESTING FOR ALCOHOL IN GASOLINE
 Place the cylinder on a flat surface and let it
stand for five minutes.
 Take a reading near the bottom of the
cylinder at the boundary between the two
liquids.
TESTING FOR ALCOHOL IN GASOLINE
 For percent of alcohol in gasoline follow this
formula;
%=(Difference/fuel added)x100
For example; (10/90)x100=11.1%
DOES OIL VISCOSITY MATTER?
Yes! And here’s why……………

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What is gasoline

  • 2. WHAT IS GASOLINE?  Gasoline is a term used to describe a complex mixture of various hydrocarbons refined from crude petroleum oil for use as fuel in engines.  Made up of several hydrocarbon molecules including the following: - Methane, Ethane, Propane, Butane, Pentane, Hexane, & Heptane.
  • 3. DISTILLATION  Raw Crude oil is heated and put into a distillation column — and different hydrocarbon components boil off and can be recovered as they condense at different temperatures.
  • 4. CRACKING  The distilled oil is then “Cracked” by a catalyst or thermal process. Cracking, as the name suggests, is a process in which large hydrocarbon molecules are broken down into smaller and more useful ones.
  • 6. OCTANE NUMBER?  The octane rating of gasoline essentially tells you how much the air-fuel mixture can be compressed before it will spontaneously ignite. Gasoline with an optimal octane rating performs best in an engine designed to run on that octane level. (so don’t waste your money)
  • 7. VOLATILITY  Describes how easily the gasoline evaporates (forms a vapor). The definition of volatility assumes that the vapors will remain in the fuel tank or fuel line and will cause a certain pressure based on the temperature of the fuel.  Which is measured by;
  • 8. REID VAPOR PRESSURE  Reid Vapor Pressure, Or “RVP” is the pressure of the vapor above the fuel when the fuel is at 100F. Increased vapor pressure permits the engine to start in cold weather. Gasoline must be vaporized to burn.
  • 9. REID VAPOR PRESSURE  This is why we have “Winter blend” and “Summer blend” fuels. In the winter we need the gas to vaporize easier (higher RVP, usually 15psi) . In summer we need the vaporization to decrease (lower RVP, usually 7-9psi).
  • 10. VOLATILITY-RELATED PROBLEMS  If we use winter blend in the summer, the fuel in our vehicles will evaporate easier, creating higher tank pressures (air pollution) and vapor locking our fuel lines (tiny bubbles in fuel) creating a lean condition (higher exhaust emissions).
  • 11. VOLATILITY-RELATED PROBLEMS  If we use summer blend fuels in the winter, our vehicles will be hard to start and may stall (fuel will not evaporate easily)
  • 12. TESTING RVP  There are “homemade” kits for sale, or you can make your own, but you may not being comparing “apples to apples” due to calibration errors. Commercial testers are very expensive.
  • 13. SMELL TEST  Even though you can’t smell “RVP”, you can smell if the gas is rancid, which can indicate if its old, which can indicate if the wrong volatility is being used.  When in doubt, drain and refill at local Petrol station.
  • 14. QUICK TIPS!  Keep fuel tank above quarter tank to prolong fuel pump life! (due to dirt and heat)  Don’t “top off” your gas tank, when the pump shuts off, STOP! (may fail smog)  If you must re-enter your vehicle during fueling, touch the metal body away from fueling point (BOOM)  Don’t fill gasoline containers off the ground (Truck beds…etc.)
  • 17. OXYGENATED FUELS  By definition are fuels that contain an oxygen atom in the fuel molecule itself. The oxygen is used to help fuel burn more efficiently and reduce exhaust emissions, plus it helps reduce the amount of nonrenewable fossil fuels consumed.  Oxygenated fuels also increase octane and volatility.
  • 18. OK BUT WHAT ARE OXYGENATED FUELS!  Methanol- is an Oxygenated alcohol fuel, that was originally distilled from wood.  Methanol (like Ethanol) is volatile, colorless, tasteless, and flammable.  Unlike Ethanol, Methanol is HIGHLY toxic. Only four ounces consumed is fatal.  Methanol is also toxic through inhalation and absorption.
  • 19. OK BUT WHAT ARE OXYGENATED FUELS!  Ethanol- is an Oxygenated alcohol fuel as well, but is distilled from; - Corn, Soybeans, Sorghum, Wheat, Barley, and Potatoes.  Used to increase the volatility of winter blends.  In quantities higher than 85% (E85) qualifies as an alternative fuel as defined by the Energy Policy Act of 1992.
  • 21. WHAT ARE FLEX FUEL VEHICLES  Vehicles equipped to be able to run on E85 (85% Ethanol) or Gasoline. (Identified by a yellow fuel cap)  Must be able to detect Ethanol content in gasoline to keep driveability acceptable. (using either a oxygen sensor or variable fuel sensor).
  • 22. FLEX FUEL PROS  Using E85 reduces pollutants and our dependence on imported oil.  E85 is water soluble, non toxic, and biodegradable.  Using E85 in a flex-fuel vehicle can result in a 5% power increase. (over 100% Gasoline)  Purchase price for flex fuel vehicles are the same as their gasoline counterparts.
  • 23. FLEX FUEL CONS  Using E85 in a flex-fuel vehicle can result in a 20-30% reduction in fuel economy. (over Gas)  Vehicle repairs can cost more, due to “special” parts in the fuel system to protect against corrosion of alcohol based fuel, and special E85 detection components.  Farmland usage is shifting to grow corn for fuel. (which changes nitrogen levels and soil erosion).
  • 24. FLEX FUEL CONS  In 2001 U.S. corn production was 90% food and 10% fuel.  Today only 60% of Corn production is applied to food. (U.S. supplies 40% of the worlds corn)  E85 fueling stations are few and far between, and the cost per gallon is on the rise. (supply and demand)
  • 25. NO PERFECT SOLUTION  Just like any other alternative fuel option, there are no perfect solutions or “one size fits all”. Ethanol and E85 may be the solution in the corn belt, but not in other parts of the country.
  • 26. FIRST FLEX FUEL VEHICLE? Pop quiz! What was the first flex fuel vehicle? Henry Ford created the Model T to run on Ethanol! His vision was to create less dependency on oil and support our own economy (farmers)
  • 27. FIRST FLEX FUEL VEHICLE!
  • 28. E85 IN A NON FLEX FUEL  It is important to know the characteristics of using Ethanol or E85 fuel. (due to fuel contamination in a non flex fuel vehicle)  E85 is corrosive (due to water and oxygen in the fuel)  E85 reaches stoichiometry at 9.7:1 BUT HOW DO WE KNOW IF ITS E85 FOR SURE!
  • 29. TESTING FOR ALCOHOL IN GASOLINE  It is important to be able to test for the presence of alcohol in Gasoline to help diagnose and eliminate some driveability problems.  You will need the following; - 100ml Graduated Cylinder - Sample of Gasoline - Water
  • 30. TESTING FOR ALCOHOL IN GASOLINE  Pour suspect Gasoline into a graduated cylinder.  Carefully fill the graduated cylinder to the 90ml mark.  Add 10ml of water to the graduated cylinder.
  • 31. TESTING FOR ALCOHOL IN GASOLINE  Put the stopper in the cylinder and give it a “scientific shake” for one minute. Relieve built up pressure by occasionally removing the stopper. Alcohol dissolves in water and will drop to the bottom of the cylinder. (Gasoline is lighter than water).
  • 32. TESTING FOR ALCOHOL IN GASOLINE  Place the cylinder on a flat surface and let it stand for five minutes.  Take a reading near the bottom of the cylinder at the boundary between the two liquids.
  • 33. TESTING FOR ALCOHOL IN GASOLINE  For percent of alcohol in gasoline follow this formula; %=(Difference/fuel added)x100 For example; (10/90)x100=11.1%
  • 34. DOES OIL VISCOSITY MATTER? Yes! And here’s why……………