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SURE SUCCESS
                                                Class Test-1                                        Time-1hrs
                                                CBSE Class XII                                       F.M-35
1. What are fluids? Give examples.                                                                            [1]
2. Solids are rigid why?                                                                                      [1]
3. What are the characteristics of rate constant?                                                             [1]
4. Define the term: Crystal lattice                                                                           [1]
5. Give one example of each โ€“ Tetragonal and hexagonal crystal system.                                        [1]
6. A chemical reaction 2A ๏Ÿ4B+C in gas phase occurs in a closed vessel. The concentration of B is found to
    be increased by 5 X 10-3 mole L-1 in 10 second. Calculate (i) the rate of appearance of B (ii) the rate of
    disappearance of A?                                                                                        [2]
7. Differentiate Schottky defect and Frankel defect. Name the compound which exhibits both.                   [2]
8. Define pseudo-first order reaction. Give an example of pseudo โ€“ first order reaction?                      [2]
9. What is a Zeroโ€™th-order reaction?                                                                          [2]
10. For the following reactions, write the rate of reaction expression in terms of reactants and products?[2]
            i)       4NH3 (g) + 5O2 (g) ๏€ข4NO (g) + 6H2O (g)
            ii)      2N2O5 ๏€ข2NO2 + O2
11. How many atoms are there in a unit cell of a metal crystallizing in a:                                     [2]
            (a) FCC structure
            (b) BCC structure
12. Derive the expression establishing the relationship between radius and edge length in a body
    centered cubic structure.                                                                                 [3]
13. Differentiate between amorphous and crystalline solids with reference to                                  [3]
            (1) Melting point
            (2) Cleavage property
            (3) Nature
14. In general it is observed that the rate of a chemical reaction doubles with every 10หš rise in
    temperature. If this generalization holds for a reaction in the temperature range295K to 305K, what
    would be the activation energy for this reaction? (R=8.314Jk-1 mol-1)                                     [3]
15. The compound CuCl has ZnS structure and the edge length of the unit cell in 500pm. Calculate the
    density. (Atomic masses: Cu = 63, Cl = 35.5, Avogadro no = 6.02ยด1023 mol-1)                               [3]
16. The rate of a particular reaction quadruples when the temperature changes from 293 K to 313 K.
    Calculate activation energy for such a reaction.                                                          [2]
17. What is the contribution of an atom per unit cell if the atom is:                                         [3]
            (a) At the corner of the cube.
            (b) On the face of the cube.
            (c) In the centre of the cube.

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Solid state & chemical kinetics

  • 1. SURE SUCCESS Class Test-1 Time-1hrs CBSE Class XII F.M-35 1. What are fluids? Give examples. [1] 2. Solids are rigid why? [1] 3. What are the characteristics of rate constant? [1] 4. Define the term: Crystal lattice [1] 5. Give one example of each โ€“ Tetragonal and hexagonal crystal system. [1] 6. A chemical reaction 2A ๏Ÿ4B+C in gas phase occurs in a closed vessel. The concentration of B is found to be increased by 5 X 10-3 mole L-1 in 10 second. Calculate (i) the rate of appearance of B (ii) the rate of disappearance of A? [2] 7. Differentiate Schottky defect and Frankel defect. Name the compound which exhibits both. [2] 8. Define pseudo-first order reaction. Give an example of pseudo โ€“ first order reaction? [2] 9. What is a Zeroโ€™th-order reaction? [2] 10. For the following reactions, write the rate of reaction expression in terms of reactants and products?[2] i) 4NH3 (g) + 5O2 (g) ๏€ข4NO (g) + 6H2O (g) ii) 2N2O5 ๏€ข2NO2 + O2 11. How many atoms are there in a unit cell of a metal crystallizing in a: [2] (a) FCC structure (b) BCC structure 12. Derive the expression establishing the relationship between radius and edge length in a body centered cubic structure. [3] 13. Differentiate between amorphous and crystalline solids with reference to [3] (1) Melting point (2) Cleavage property (3) Nature 14. In general it is observed that the rate of a chemical reaction doubles with every 10หš rise in temperature. If this generalization holds for a reaction in the temperature range295K to 305K, what would be the activation energy for this reaction? (R=8.314Jk-1 mol-1) [3] 15. The compound CuCl has ZnS structure and the edge length of the unit cell in 500pm. Calculate the density. (Atomic masses: Cu = 63, Cl = 35.5, Avogadro no = 6.02ยด1023 mol-1) [3] 16. The rate of a particular reaction quadruples when the temperature changes from 293 K to 313 K. Calculate activation energy for such a reaction. [2] 17. What is the contribution of an atom per unit cell if the atom is: [3] (a) At the corner of the cube. (b) On the face of the cube. (c) In the centre of the cube.