4. HISTORY OF DALTON’S
ATOMIC THEORY
ALTHOUGHTHECONCEPTOFTHEATOMDATESBACKTOTHEIDEASOFDEMOCRITUS,THEENGLISH
METEOROLOGISTANDCHEMISTJOHNDALTONFORMULATEDTHEFIRSTMODERNDESCRIPTIONOF
ITASTHEFUNDAMENTALBUILDINGBLOCKOFCHEMICALSTRUCTURES.DALTONDEVELOPEDTHE
LAWOFMULTIPLEPROPORTIONS(FIRSTPRESENTEDIN1803)BYSTUDYINGANDEXPANDINGUPON
THEWORKSOFANTOINELAVOISIERANDJOSEPHPROUST.
PROUSTHADSTUDIEDTINOXIDESANDFOUNDTHATTHEIRMASSESWEREEITHER88.1%TINAND
11.9%OXYGENOR78.7%TINAND21.3%OXYGEN(THESEWERETIN(II)OXIDEANDTINDIOXIDE
RESPECTIVELY).DALTONNOTEDFROMTHESEPERCENTAGESTHAT100GOFTINWILLCOMBINE
EITHERWITH13.5GOR27GOFOXYGEN;13.5AND27FORMARATIOOF1:2.DALTONFOUNDANATOMIC
THEORYOFMATTERCOULDELEGANTLYEXPLAINTHISCOMMONPATTERNINCHEMISTRY– INTHE
CASEOFPROUST’STINOXIDES,ONETINATOMWILLCOMBINEWITHEITHERONEORTWOOXYGEN
ATOMS.
5. Dalton also believedatomic theory couldexplainwhywaterabsorbed different gasesin different
proportions: for example, he found that water absorbed carbondioxide far better than it absorbed
nitrogen. Daltonhypothesizedthis was due to the differences in the mass and complexityof the gases’
respective particles. Indeed, carbondioxide molecules (CO2) are heavier and larger thannitrogen
molecules (N2).
Dalton proposed that each chemical element is composed of atoms of a single, unique type, and though
theycannot be alteredor destroyed by chemical means, theycan combineto form more complex
structures (chemical compounds). Since Dalton reachedhis conclusionsby experimentation and
examination of the results in an empirical fashion, this marked the first trulyscientific theoryof the
atom.