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PEER-REVIEWED MAINTENANCE
Boilers and other installations operat-
ing at high pressures and tempera-
tures are designed for a finite life [1].This
limitation is due to in-service degradation
(i.e., damage that occurs throughout its
years of operation). For a chemical recov-
ery boiler, the typical, ongoing damage
mechanisms that will limit the unit’s life
are summarized TTaabbllee II.
The design life of a boiler often is not
openly specified.Many designers and spe-
cialists consider 25 to 30 years to be a rea-
sonable estimate for the life of water tube
boilers and for the power plants of which
they are part [2]. Practical experience,
however, shows that the real durability of
such installations, in most cases, is much
greater than this estimation.This is espe-
cially true with the advent of new materi-
als and improved operational and mainte-
nance practices.Thus, a life of 40 years or
more becomes a technically reasonable
expectation for a recovery boiler,which is
obviously very desirable from the eco-
nomic point of view.
To achieve this life extension, a careful
engineering evaluation is carried out to
determine any necessary repairs and
replacements required.The boiler’s oper-
ations, maintenance and inspection histo-
ry, and its current condition, are consid-
ered in projecting its remaining life.
Brazilian regulations (the NR13 safety
standard) specify that every boiler should
undergo a structural integrity evaluation
and remaining life assessment upon com-
BASIC PREMISES FOR
STRUCTURAL INTEGRITY
EVALUATION (SIE)
Basic Requirements
The objective of a structural integrity
evaluation (SIE) is to enable a safe con-
tinuation of the unit’s operating life, gen-
erally beyond the period first intended.
Of course, there is not a single formula
for conducting such investigations.
However, some basic requirements must
be taken into consideration in these pro-
cedures.
Annual inspections do not fully
address such requirements.An SIE differs
from routine inspections in the following
ways:
• It investigates time-dependant
degradation mechanisms that occur
in the mid- and long-term, such as
fatigue, creep, metallurgical
degradation, and water chemistry
effects.These mechanisms must be
clearly differentiated from those
acting “faster” or those more related
to incidents or to accidental and
circumstantial factors.
• It investigates in greater depth the
integrity of parts that do not usually
receive such attention during
periodic inspections due to lack of
time and difficulty in access: headers,
drums, attemperators, main steam
lines, structural elements, etc. (see
FFiiggss.. 11--33).
pleting 25 years in service [3].The NR13,
however, is a general requirement for all
types of steam generators and does not
provide technical guidance. This paper
provides additional information and rec-
ommendations for conducting integrity
assessments, specifically focusing on
chemical recovery boilers, with the aim
to assist pulp mills to fulfill this important
technical and legal requirement.
TIMING FOR STARTING
EVALUATIONS
Under normal conditions, integrity evalu-
ations and remaining life assessments
should occur:
• On completion of 80% of the design
life, or
• On completion of 25 years (the legal
time period in Brazil, which under no
circumstances should be exceeded)
[4].
Evaluations should occur sooner in the
following cases:
• Operation above nominal capacity
• Excessive cycling (stop and start)
and/or variation of load
• History of stops and starts faster than
those anticipated by the design
• Known evidence of accumulated
damages
• History of accumulated damages on
similar units [5].
Guidelines for integrity evaluation and
remaining life assessment of recovery
boilers – CENIBRA’s experience
FLÁVIO A. PAOLIELLO
ABSTRACT: The need for integrity evaluations and remaining life assessments of boilers arises from
technical, economic, and legal reasons.The pulp and paper industry has less experience and tradition in using
this engineering discipline when compared to other industries such as oil, petrochemical, and power gener-
ation.The pertinent Brazilian legal standard (NR-13) is concise in establishing this requirement, without pro-
viding details of applicable technical procedures. Furthermore, recovery boilers are a special type of steam
generator, being very specific as to their inherent in-service degradation mechanisms and inspection needs.
In view of the above scenario, pulp and paper mill engineers often have doubts and encounter diverse inter-
pretations of the official regulations when they need to carry out integrity evaluations of quarter-century old
recovery boilers.This paper relates CENIBRA’s recent experience in evaluating its recovery boiler No. 1.
AApppplliiccaattiioonn:: This paper may serve as a guide for other pulp mills and help answer questions about the
process of integrity evaluation and remaining life assessment of aged recovery boilers.
VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 17
18 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005
MAINTENANCE
• It evaluates the integrity of each
boiler component individually, to
determine the susceptibility of each
one to the corresponding
degradation mechanisms, indicating
those whose useful life will expire
before the others.
• It evaluates metallurgical aspects,
mostly in high temperature parts, to
identify nonvisual damage
mechanisms that may not be
indicated by changes in wall
thickness. Examples of microstructural
degradation include spheroidizing,
graphitization, precipitation of
carbides, and microvoids from creep.
These are illustrated in FFiiggss.. 44--77.
The main concern with corrosion in
recovery boilers may divert the
engineers’ attention from this point.
• It evaluates and documents the
kinetics of damage evolution,
quantifying corrosion rates, wear,
crack growth progress, etc.
• It focuses attention on the
steam and water side,
investigating the unit’s history
in relation to possible
waterside contamination (e.g.,
with liquor) and evaluating
possible consequences.
• It investigates possible
alterations in behavior of
structural elements, such as
increases in hysteresis of
elastic supports of steam
piping.
• It takes operations above rated
capacity and excessive cycling
into consideration.
SIE should encompass more
than the legally required evalua-
tion of the boiler itself. Common sense
and best practices dictate that SIEs
should extend to peripheral and ancillary
elements closely associated with the boil-
er,especially those subjected to high tem-
peratures, such as the main steam line,
headers, and accumulators, up to the tur-
bine’s inlet flange. Additionally, the mill
should evaluate the integrity of the deaer-
ator, feed water tank, feed water line, dis-
solving tank, and other support systems
(see FFiigguurree 88).
SIE conceptual approaches
Mills vary in their approach to conduct-
ing SIEs, their objectives, and the criteria
they may use to assess in-service dam-
ages and degradation. The two main
approaches are as follows:
TThhee ““PPrroojjeecctt CCooddee”” aapppprrooaacchh——The
evaluation of used and degraded equip-
ment, exclusively from a design codes’
point of view (American Society of
Mechanical Engineers, for example) is
the simplest and most traditional
approach. It applies the same design and
manufacturing criteria for evaluating the
boiler’s condition and damages resulting
from service.Through testing and repairs
and replacements, this approach aims to
restore the boiler’s condition and reliabil-
ity to “as good as new.”
TThhee ““FFiittnneessss--ffoorr--SSeerrvviiccee”” aapppprrooaacchh—
This newer approach evaluates the
equipment’s fitness-for-service,in spite of
accumulated damages, in its degraded
condition.Analytical techniques to estab-
lish the possibility to continue operating
with existing defects are applied (taking
into consideration the flaws’ dimensions,
shape, localization, evolution, kinetics,
I. Factors that limit the life of chemical recovery boiler components.
HHiigghh MMiiccrroo--
DDaammaaggee TTeemmpp.. SSttrruuccttuurraall
MMeecchhaanniissmmss CCoorrrroossiioonn FFaattiigguuee EErroossiioonn OOxxiiddaattiioonn CCrreeeepp DDeeggrraaddaattiioonn
Furnace ✔ ✔ ✔ — — —
Drums ✔ ✔ — — — —
Economizer ✔ ✔ ✔ — — —
Boiler bank ✔ ✔ ✔ — — —
Superheaters ✔ ✔ ✔ ✔ ✔ ✔
High temperature — ✔ — ✔ ✔ ✔
headers
Non-refrigerated parts ✔ ✔ ✔ ✔ — ✔
exposed to flue gas
Main steam line — ✔ — — ✔ ✔
Structures ✔ ✔ — — — —
Dissolving tank ✔ ✔ ✔ — — —
Deaerator ✔ ✔ ✔ — — —
1. Inspection and non-destructive
testing of lower waterwall header.
Investigation as to ligament cracking.
2. Steam drum without its insulation
to enable detailed examination and
testing.
3. Access provided for inspection of
elements in the interior of penthouse
and other “cold” chambers in the
recovery boiler.
VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 19
MAINTENANCE
etc.) The evaluation may include stress
analyses, calculations through fracture
mechanics, and use of API 579 and
BS:7910 standards. Among other bene-
fits, this approach seeks to minimize
repairs and replacements, without com-
promising reliability.
The second approach,already consoli-
dated in the power generation, oil, and
chemistry industries, has also gained
increasing recognition and acceptance in
other industries. Both philosophies men-
tioned, and others, are acceptable from
the technical point of view and recog-
nized by legislation. It is up to the boiler
owner to evaluate it and other approach-
es in terms of cost, time, availability of
technical resources, company culture,
and other factors.
PROCEDURES FOR
EVALUATING STRUCTURAL
INTEGRITY AND
REMAINING LIFE
Integrity evaluations involve complex
engineering work that must be carried
out by extremely specialized and quali-
fied professionals. While specific proce-
dures may vary, the evaluation is usually
conducted in three distinct phases:
Phase 1: Preliminary Evaluation
OObbjjeeccttiivveess
• Define physical limits, or the “boiler
island,” within which analyses will be
carried out.
• Collect information on the
equipment (scrutinize the unit’s
operational, maintenance, and
inspection history, and its design data).
• Identify in-service degradation
mechanisms taking place in the
boiler.
• Identify the boiler’s critical parts
or zones, and which damage
mechanisms affect them.
• Analyze the collected information and
determine whether available data are
sufficient to establish the unit’s
structural condition.
• Plan inspection and additional
non-destructive testing (NDT), as
needed.
Phase 2: Non-destructive
Testing
OObbjjeeccttiivvee
• To supplement data collected in Phase
1 (which in extremely rare cases are
sufficient per se), verify through
additional inspections and NDTs the
presence of accumulated in-service
damage, defining its extent and
responsible mechanisms.
TTaabbllee IIII lists resources that are usually
applicable in this phase, with examples,
some of which are illustrated in FFiiggss.. 99--
1122 [6].
Phase 3: complementary
analysis
GGooaallss
• Analyze data collected in the
previous phases.
4. Micro-structural gradient of ferric material subjected to high temperature (typically superheaters). These figures are
merely illustrative.
5. Structure showing microvoids from
creep. Illustrative figure.
6. Preparation for field metallography
in the main steam line.
7. Preparation for field metallography
in a high pressure steam header.
8. Preparation for inspection and non-
destructive testing in the deaerator
tank saddle. Simultaneously, the ves-
sel itself had been tested internally by
wet fluorescent magnetic particles.
20 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005
MAINTENANCE
• Confirm the hypotheses formulated
during Phase 2, using complementary
tests to samples taken from the
equipment, double-checks, actual
stress analysis, etc.
• Reach final evaluation of the
structural condition and the
remaining life.
A final report must then be issued,
containing all the information regarding
the evaluation: the current structural
condition and remaining life of each boil-
er component; recommended proce-
dures for future similar evaluations; pos-
sible recommendations for repairs or
replacements, re-rating of components,
possible process changes; calculations;
and all applicable planning.
RECOMMENDATIONS FOR
NEW BOILERS
The procedures addressed in this paper
are mainly intended for owners of older
boilers, especially those approaching the
II. Non-destructive tests that may be used as part of system integrity evaluations of recovery boilers.
NNoonn--DDeessttrruuccttiivvee TTeesstt
Dye penetrant
Magnetic particle
Ultrasonic thickness surveys
Ultrasonic for flaw detection
Field metallography (direct or
replication)
Dimensional examinations
Hardness readings
Internal Rotary Inspection System
(I.R.I.S.), near drum inspection
Endoscope inspection
Destructive testing
Digital radiography
Load analysis in pipelines supports
UUssuuaall LLooccaattiioonnss
Composite tube furnaces, structures,
membranes, spacers, welded
attachments
Weld seams of drums and headers
Tubing, headers, drums, deaerator
Weld seams of drums and headers
and other thick-walled elements
High temperature tubing and headers,
furnace tubing
High temperature tubing and headers
High temperature tubing and
headers
Boiler bank
Attemperators (sometimes also called
a de-super heater), economizer, head-
ers, downcomers
As necessary
Superheaters, lower bends
Live steam piping
NNootteewwoorrtthhyy SSIIEE AApppplliiccaattiioonnss
Investigation of cracking on furnace
openings
Investigation of ligament cracking in
headers and drums
Remaining life estimations in the
light of corrosion rates
Investigation of creep, micro-
structural degradation, localized
over-heating, surveillance of known
flaws, etc.
Investigation of creep
Complementary investigation of
microstructural degradation
Investigation of near mud drum
corrosion [7]
Investigation of changes in the
support reactions of the piping [8]
11. Equipment for I.R.I.S. testing, being
used to inspect tubes of the boiler
bank. The corrosion of tubes in the
region near the lower drum (known as
near mud drum corrosion) in a recov-
ery boiler is a typical concern.
9. Non-destructive testing (magnetic
particles) in progress in the water
drum of a recovery boiler.
10. Preparation for non-destructive
testing (ultrasonic and magnetic par-
ticles) of a crossover pipe welding.
VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 21
MAINTENANCE
legally established time for starting the
integrity evaluation. However, the discus-
sion and suggestions also may be useful
to those dealing with new boilers, and
even for projects in the early stages of
specification and procurement for a
future unit.
The following suggestions may be
helpful to owners of newer boilers, or
those specifying or procuring a future
unit:
• Require that the vendor who is
offering a new boiler provide
recommendations or guidelines for
future SIE of the equipment being
supplied.
• Keep samples of all materials of
construction of a newly erected
boiler, as a reference for future
comparison as to micro-structural
degradation and creep.
• Conduct dimensional examinations
of the high temperature tubes before
the initial start-up as a reference for
future comparison as to creep.
• Consider installing instrumentation
to monitor the temperature of the
hottest and most critical parts of the
future boiler.
• Perform an “early start” of the SIE
program, collecting data of interest
and recording relevant information
through the life of the boiler from
the beginning of its operations.
FINAL CONSIDERATIONS
An integrity evaluation is not just an
extensive program of inspections and
testing, or life-time projections, although
elements of those are markedly present.
It is rather an ongoing, multi-disciplinary
program that should be established from
the beginning of the boiler life cycle. It
must be customized for each individual
plant, taking into consideration its actual
status as to accumulated damage. Thus,
the boiler owner should be cautious
about vendors offering a predetermined,
“standardized” program of inspections.
The integrity evaluation also presumes a
close participation and co-operation of
the boiler owner and the professionals
commissioned to do the evaluation.
The following are some of the benefits
afforded by integrity evaluations and
remaining life assessment programs:
• Establishment of a base line of the
boiler’s structural condition
• Increased safety for personnel and
facilities
• Increased availability of the boiler at
maturity
• Economic flexibility, allowing the
mill more time to explore
replacement and repair options, and
possibly postpone investments
• “Good will” through a positive image
of the mill, associated with safety and
proper engineering practices
• Training for the mill’s engineers
• Legal compliance.
AAuutthhoorr’’ss NNoottee:: the information and rec-
ommendations contained in this paper
reflect the author’s best knowledge and
belief at the time of writing. However,
the text should serve only as a general
reference to the reader. No warranties
are offered or responsibilities taken that
the information provided is perfectly
adequate or sufficient for the purpose in
question. TJ
LITERATURE CITED
1. Singer, J.G., Combustion, Fossil
Power. ABB Combustion
Engineering, Windsor,
Connecticut, 1991.
2. French, D.N., Microstructural
Degradation. The National Board
of Boiler and Pressure Vessel
Inspectors web site, Classic
Articles, available online at
www.nationalboard.org/classics.
3. Manual Técnico de Caldeiras e
Vasos de Pressão, Ministério do
Trabalho, Brasília, 1996.
4. Procedimento Geral de Avaliação
de Vida Restante de Componentes
Estáticos Submetidos a Alta
Temperatura. Instituto de
Soldadura e Qualidade, Lisboa.
5. Prática Recomendada para Análise
de Danos Acumulados em Serviço
por Equipamentos Pressurizados
que Operam a Alta Temperatura,
Recomendação Geral para
Inspeção de Equipamentos que
Operam emTemperaturas
Elevadas, Associação Brasileira de
Ciências Mecânicas, Rio de
Janeiro, 1992.
6. Babcock & Wilcox Condition
Assessment Services. Available at
www.babcock.com.
7. Adams,T.N., Frederick, W.J., Grace,
T.M., et al, Kraft Recovery Boilers,
TAPPI Press, Atlanta, 1997.
8. Caldeira, R. B., Relatório de
Avaliação de Integridade e Vida
Remanescente de Caldeira de
Recuperação 1, CENIBRA. Instituto
de Soldadura e Qualidade - ISQ
Brasil, Belo Horizonte, 2002.
This paper was originally published in the
June, 2004 issue of O Papel, the official
publication of the Brazilian Technical
Association of Pulp and Paper (ABTCP). It is
being reprinted by TAPPI JOURNAL
through a cooperative agreement between
TAPPI and ABTCP.
This paper is also published on TAPPI’s
web site <www.tappi.org> and
summarized in the February Solutions!
for People, Processes and Paper
magazine (Vol. 88 No. 2).
12. Ultrasonic thickness survey on a
studded tube of a recovery furnace.
13. CENIBRA’s recovery boiler No. 1.
This unit had its first start-up in 1977,
and underwent an integrity evalua-
tion program in 2002, according to
the guidelines described in this paper.
22 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005
MAINTENANCE
INSIGHTS FROM THE AUTHORS
Facing the need to conduct an integrity evaluation and
remaining life assessment program to a recovery boil-
er in the mill I work for, I soon realized there was limit-
ed information available about this subject within the
Brazilian pulp industry, in spite of its importance. Also,
I found diverse interpretations (by previous users and
inspection services suppliers) of the official require-
ments, and no written guidelines with a specific focus
on recovery boilers.That prompted me to write this arti-
cle.
Brazilian official standards require that boilers under-
go an integrity evaluation at 25 years. But they give no
technical guidance and do not highlight the special
needs and risks associated with recovery boilers. This
paper is therefore intended to help provide mill engi-
neers with some complementary support when they
carry out such programs.
The most difficult aspect of preparing for an integrity
evaluation, and in writing this paper, is the lack of ref-
erences and successful past experiences in Brazilian
mills. I searched the procedures used in other indus-
tries, and by pulp mills abroad, then adapted them to
our reality.
Through my research, I was particularly impressed
by the wide array of available engineering disciplines
and testing techniques that now can help engineers
evaluate the conditions of a used recovery boiler, giv-
ing an excellent level of confidence in the results of
such evaluations.
Some Brazilian mills are systematizing and improv-
ing their procedures in evaluating the integrity of aged
recovery boilers.This paper, while not intended to be a
complete or definitive guide, could be a first step
towards this improvement.
With time, more recommendations and aspects per-
taining specifically to recovery boiler
in-service evaluations should be added
to the contents of this paper, making it
more and more comprehensive.
— Flávio A. Paoliello
Paoliello is a maintenance engineer with
CENIBRA, Belo Oriente, MG, Brazil. Email
Paoliello at flavio.paoliello@cenibra.com.br. Paoliello
COMING NEXT MONTH IN TAPPI JOURNAL:
Prediction of dust composition and amount in kraft recovery boilers
by Barry Malmberg, Lou Edwards, Sten Lundborg, Mikael Ahlroth, and Björn Warnqvist A modular, steady-state model for the recovery furnace has
been extended to predict dust compositions and amounts accurately. Validated with industrial boiler data from three recovery boilers, this mathe-
matical model can help engineers predict what the effects will be when a mill upgrades a recovery boiler.
Novel method to improve wet strength of paper
by Tsuguyuki Saito and Akira Isogai Working to meet the industry's need for more environmentally-friendly wet strength additives as alternatives
to PAE, researchers found that the combination of TEMPO-mediated oxidation of bleached kraft pulp under suitable conditions and alum addition
can give sufficient wet strength to paper without any additions of the conventional wet strength agents.
Monitoring particulate material formation in a kraft furnace recovery boiler
by Andréa O. S. Costa, Maurício B. de Souza Jr., Evaristo C. Biscaia Jr., and Enrique L. Lima This study proposes the use of neural networks to mon-
itoring particulate material formation during a recovery boiler furnace operation. Using discrete radial basis function networks to classify the
amount of particles in size intervals, the authors show that the proposed methodology can satisfactorily describe the particulate material forma-
tion, mainly as a monitoring tool for plant operation.
Energy reduction at a kraft mill: The effects of process integration, benchmarking, and water reduction
By Michael Towers, Pulp and Paper Research Institute of Canada This work studies a western Canadian market kraft mill to examine issues and
opportunities with respect to energy cost reduction and water reduction. The first phase of the work identifies energy reduction opportunities using
pinch analysis and benchmarking of some operations. The second phase examines further energy savings through implementing water reduction
measures in addition to process integration.

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Guidelines for evaluating structural integrity and remaining life of recovery boilers

  • 1. PEER-REVIEWED MAINTENANCE Boilers and other installations operat- ing at high pressures and tempera- tures are designed for a finite life [1].This limitation is due to in-service degradation (i.e., damage that occurs throughout its years of operation). For a chemical recov- ery boiler, the typical, ongoing damage mechanisms that will limit the unit’s life are summarized TTaabbllee II. The design life of a boiler often is not openly specified.Many designers and spe- cialists consider 25 to 30 years to be a rea- sonable estimate for the life of water tube boilers and for the power plants of which they are part [2]. Practical experience, however, shows that the real durability of such installations, in most cases, is much greater than this estimation.This is espe- cially true with the advent of new materi- als and improved operational and mainte- nance practices.Thus, a life of 40 years or more becomes a technically reasonable expectation for a recovery boiler,which is obviously very desirable from the eco- nomic point of view. To achieve this life extension, a careful engineering evaluation is carried out to determine any necessary repairs and replacements required.The boiler’s oper- ations, maintenance and inspection histo- ry, and its current condition, are consid- ered in projecting its remaining life. Brazilian regulations (the NR13 safety standard) specify that every boiler should undergo a structural integrity evaluation and remaining life assessment upon com- BASIC PREMISES FOR STRUCTURAL INTEGRITY EVALUATION (SIE) Basic Requirements The objective of a structural integrity evaluation (SIE) is to enable a safe con- tinuation of the unit’s operating life, gen- erally beyond the period first intended. Of course, there is not a single formula for conducting such investigations. However, some basic requirements must be taken into consideration in these pro- cedures. Annual inspections do not fully address such requirements.An SIE differs from routine inspections in the following ways: • It investigates time-dependant degradation mechanisms that occur in the mid- and long-term, such as fatigue, creep, metallurgical degradation, and water chemistry effects.These mechanisms must be clearly differentiated from those acting “faster” or those more related to incidents or to accidental and circumstantial factors. • It investigates in greater depth the integrity of parts that do not usually receive such attention during periodic inspections due to lack of time and difficulty in access: headers, drums, attemperators, main steam lines, structural elements, etc. (see FFiiggss.. 11--33). pleting 25 years in service [3].The NR13, however, is a general requirement for all types of steam generators and does not provide technical guidance. This paper provides additional information and rec- ommendations for conducting integrity assessments, specifically focusing on chemical recovery boilers, with the aim to assist pulp mills to fulfill this important technical and legal requirement. TIMING FOR STARTING EVALUATIONS Under normal conditions, integrity evalu- ations and remaining life assessments should occur: • On completion of 80% of the design life, or • On completion of 25 years (the legal time period in Brazil, which under no circumstances should be exceeded) [4]. Evaluations should occur sooner in the following cases: • Operation above nominal capacity • Excessive cycling (stop and start) and/or variation of load • History of stops and starts faster than those anticipated by the design • Known evidence of accumulated damages • History of accumulated damages on similar units [5]. Guidelines for integrity evaluation and remaining life assessment of recovery boilers – CENIBRA’s experience FLÁVIO A. PAOLIELLO ABSTRACT: The need for integrity evaluations and remaining life assessments of boilers arises from technical, economic, and legal reasons.The pulp and paper industry has less experience and tradition in using this engineering discipline when compared to other industries such as oil, petrochemical, and power gener- ation.The pertinent Brazilian legal standard (NR-13) is concise in establishing this requirement, without pro- viding details of applicable technical procedures. Furthermore, recovery boilers are a special type of steam generator, being very specific as to their inherent in-service degradation mechanisms and inspection needs. In view of the above scenario, pulp and paper mill engineers often have doubts and encounter diverse inter- pretations of the official regulations when they need to carry out integrity evaluations of quarter-century old recovery boilers.This paper relates CENIBRA’s recent experience in evaluating its recovery boiler No. 1. AApppplliiccaattiioonn:: This paper may serve as a guide for other pulp mills and help answer questions about the process of integrity evaluation and remaining life assessment of aged recovery boilers. VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 17
  • 2. 18 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005 MAINTENANCE • It evaluates the integrity of each boiler component individually, to determine the susceptibility of each one to the corresponding degradation mechanisms, indicating those whose useful life will expire before the others. • It evaluates metallurgical aspects, mostly in high temperature parts, to identify nonvisual damage mechanisms that may not be indicated by changes in wall thickness. Examples of microstructural degradation include spheroidizing, graphitization, precipitation of carbides, and microvoids from creep. These are illustrated in FFiiggss.. 44--77. The main concern with corrosion in recovery boilers may divert the engineers’ attention from this point. • It evaluates and documents the kinetics of damage evolution, quantifying corrosion rates, wear, crack growth progress, etc. • It focuses attention on the steam and water side, investigating the unit’s history in relation to possible waterside contamination (e.g., with liquor) and evaluating possible consequences. • It investigates possible alterations in behavior of structural elements, such as increases in hysteresis of elastic supports of steam piping. • It takes operations above rated capacity and excessive cycling into consideration. SIE should encompass more than the legally required evalua- tion of the boiler itself. Common sense and best practices dictate that SIEs should extend to peripheral and ancillary elements closely associated with the boil- er,especially those subjected to high tem- peratures, such as the main steam line, headers, and accumulators, up to the tur- bine’s inlet flange. Additionally, the mill should evaluate the integrity of the deaer- ator, feed water tank, feed water line, dis- solving tank, and other support systems (see FFiigguurree 88). SIE conceptual approaches Mills vary in their approach to conduct- ing SIEs, their objectives, and the criteria they may use to assess in-service dam- ages and degradation. The two main approaches are as follows: TThhee ““PPrroojjeecctt CCooddee”” aapppprrooaacchh——The evaluation of used and degraded equip- ment, exclusively from a design codes’ point of view (American Society of Mechanical Engineers, for example) is the simplest and most traditional approach. It applies the same design and manufacturing criteria for evaluating the boiler’s condition and damages resulting from service.Through testing and repairs and replacements, this approach aims to restore the boiler’s condition and reliabil- ity to “as good as new.” TThhee ““FFiittnneessss--ffoorr--SSeerrvviiccee”” aapppprrooaacchh— This newer approach evaluates the equipment’s fitness-for-service,in spite of accumulated damages, in its degraded condition.Analytical techniques to estab- lish the possibility to continue operating with existing defects are applied (taking into consideration the flaws’ dimensions, shape, localization, evolution, kinetics, I. Factors that limit the life of chemical recovery boiler components. HHiigghh MMiiccrroo-- DDaammaaggee TTeemmpp.. SSttrruuccttuurraall MMeecchhaanniissmmss CCoorrrroossiioonn FFaattiigguuee EErroossiioonn OOxxiiddaattiioonn CCrreeeepp DDeeggrraaddaattiioonn Furnace ✔ ✔ ✔ — — — Drums ✔ ✔ — — — — Economizer ✔ ✔ ✔ — — — Boiler bank ✔ ✔ ✔ — — — Superheaters ✔ ✔ ✔ ✔ ✔ ✔ High temperature — ✔ — ✔ ✔ ✔ headers Non-refrigerated parts ✔ ✔ ✔ ✔ — ✔ exposed to flue gas Main steam line — ✔ — — ✔ ✔ Structures ✔ ✔ — — — — Dissolving tank ✔ ✔ ✔ — — — Deaerator ✔ ✔ ✔ — — — 1. Inspection and non-destructive testing of lower waterwall header. Investigation as to ligament cracking. 2. Steam drum without its insulation to enable detailed examination and testing. 3. Access provided for inspection of elements in the interior of penthouse and other “cold” chambers in the recovery boiler.
  • 3. VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 19 MAINTENANCE etc.) The evaluation may include stress analyses, calculations through fracture mechanics, and use of API 579 and BS:7910 standards. Among other bene- fits, this approach seeks to minimize repairs and replacements, without com- promising reliability. The second approach,already consoli- dated in the power generation, oil, and chemistry industries, has also gained increasing recognition and acceptance in other industries. Both philosophies men- tioned, and others, are acceptable from the technical point of view and recog- nized by legislation. It is up to the boiler owner to evaluate it and other approach- es in terms of cost, time, availability of technical resources, company culture, and other factors. PROCEDURES FOR EVALUATING STRUCTURAL INTEGRITY AND REMAINING LIFE Integrity evaluations involve complex engineering work that must be carried out by extremely specialized and quali- fied professionals. While specific proce- dures may vary, the evaluation is usually conducted in three distinct phases: Phase 1: Preliminary Evaluation OObbjjeeccttiivveess • Define physical limits, or the “boiler island,” within which analyses will be carried out. • Collect information on the equipment (scrutinize the unit’s operational, maintenance, and inspection history, and its design data). • Identify in-service degradation mechanisms taking place in the boiler. • Identify the boiler’s critical parts or zones, and which damage mechanisms affect them. • Analyze the collected information and determine whether available data are sufficient to establish the unit’s structural condition. • Plan inspection and additional non-destructive testing (NDT), as needed. Phase 2: Non-destructive Testing OObbjjeeccttiivvee • To supplement data collected in Phase 1 (which in extremely rare cases are sufficient per se), verify through additional inspections and NDTs the presence of accumulated in-service damage, defining its extent and responsible mechanisms. TTaabbllee IIII lists resources that are usually applicable in this phase, with examples, some of which are illustrated in FFiiggss.. 99-- 1122 [6]. Phase 3: complementary analysis GGooaallss • Analyze data collected in the previous phases. 4. Micro-structural gradient of ferric material subjected to high temperature (typically superheaters). These figures are merely illustrative. 5. Structure showing microvoids from creep. Illustrative figure. 6. Preparation for field metallography in the main steam line. 7. Preparation for field metallography in a high pressure steam header. 8. Preparation for inspection and non- destructive testing in the deaerator tank saddle. Simultaneously, the ves- sel itself had been tested internally by wet fluorescent magnetic particles.
  • 4. 20 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005 MAINTENANCE • Confirm the hypotheses formulated during Phase 2, using complementary tests to samples taken from the equipment, double-checks, actual stress analysis, etc. • Reach final evaluation of the structural condition and the remaining life. A final report must then be issued, containing all the information regarding the evaluation: the current structural condition and remaining life of each boil- er component; recommended proce- dures for future similar evaluations; pos- sible recommendations for repairs or replacements, re-rating of components, possible process changes; calculations; and all applicable planning. RECOMMENDATIONS FOR NEW BOILERS The procedures addressed in this paper are mainly intended for owners of older boilers, especially those approaching the II. Non-destructive tests that may be used as part of system integrity evaluations of recovery boilers. NNoonn--DDeessttrruuccttiivvee TTeesstt Dye penetrant Magnetic particle Ultrasonic thickness surveys Ultrasonic for flaw detection Field metallography (direct or replication) Dimensional examinations Hardness readings Internal Rotary Inspection System (I.R.I.S.), near drum inspection Endoscope inspection Destructive testing Digital radiography Load analysis in pipelines supports UUssuuaall LLooccaattiioonnss Composite tube furnaces, structures, membranes, spacers, welded attachments Weld seams of drums and headers Tubing, headers, drums, deaerator Weld seams of drums and headers and other thick-walled elements High temperature tubing and headers, furnace tubing High temperature tubing and headers High temperature tubing and headers Boiler bank Attemperators (sometimes also called a de-super heater), economizer, head- ers, downcomers As necessary Superheaters, lower bends Live steam piping NNootteewwoorrtthhyy SSIIEE AApppplliiccaattiioonnss Investigation of cracking on furnace openings Investigation of ligament cracking in headers and drums Remaining life estimations in the light of corrosion rates Investigation of creep, micro- structural degradation, localized over-heating, surveillance of known flaws, etc. Investigation of creep Complementary investigation of microstructural degradation Investigation of near mud drum corrosion [7] Investigation of changes in the support reactions of the piping [8] 11. Equipment for I.R.I.S. testing, being used to inspect tubes of the boiler bank. The corrosion of tubes in the region near the lower drum (known as near mud drum corrosion) in a recov- ery boiler is a typical concern. 9. Non-destructive testing (magnetic particles) in progress in the water drum of a recovery boiler. 10. Preparation for non-destructive testing (ultrasonic and magnetic par- ticles) of a crossover pipe welding.
  • 5. VOL. 4: NO. 2 TTAAPPPPII JJOOUURRNNAALL 21 MAINTENANCE legally established time for starting the integrity evaluation. However, the discus- sion and suggestions also may be useful to those dealing with new boilers, and even for projects in the early stages of specification and procurement for a future unit. The following suggestions may be helpful to owners of newer boilers, or those specifying or procuring a future unit: • Require that the vendor who is offering a new boiler provide recommendations or guidelines for future SIE of the equipment being supplied. • Keep samples of all materials of construction of a newly erected boiler, as a reference for future comparison as to micro-structural degradation and creep. • Conduct dimensional examinations of the high temperature tubes before the initial start-up as a reference for future comparison as to creep. • Consider installing instrumentation to monitor the temperature of the hottest and most critical parts of the future boiler. • Perform an “early start” of the SIE program, collecting data of interest and recording relevant information through the life of the boiler from the beginning of its operations. FINAL CONSIDERATIONS An integrity evaluation is not just an extensive program of inspections and testing, or life-time projections, although elements of those are markedly present. It is rather an ongoing, multi-disciplinary program that should be established from the beginning of the boiler life cycle. It must be customized for each individual plant, taking into consideration its actual status as to accumulated damage. Thus, the boiler owner should be cautious about vendors offering a predetermined, “standardized” program of inspections. The integrity evaluation also presumes a close participation and co-operation of the boiler owner and the professionals commissioned to do the evaluation. The following are some of the benefits afforded by integrity evaluations and remaining life assessment programs: • Establishment of a base line of the boiler’s structural condition • Increased safety for personnel and facilities • Increased availability of the boiler at maturity • Economic flexibility, allowing the mill more time to explore replacement and repair options, and possibly postpone investments • “Good will” through a positive image of the mill, associated with safety and proper engineering practices • Training for the mill’s engineers • Legal compliance. AAuutthhoorr’’ss NNoottee:: the information and rec- ommendations contained in this paper reflect the author’s best knowledge and belief at the time of writing. However, the text should serve only as a general reference to the reader. No warranties are offered or responsibilities taken that the information provided is perfectly adequate or sufficient for the purpose in question. TJ LITERATURE CITED 1. Singer, J.G., Combustion, Fossil Power. ABB Combustion Engineering, Windsor, Connecticut, 1991. 2. French, D.N., Microstructural Degradation. The National Board of Boiler and Pressure Vessel Inspectors web site, Classic Articles, available online at www.nationalboard.org/classics. 3. Manual Técnico de Caldeiras e Vasos de Pressão, Ministério do Trabalho, Brasília, 1996. 4. Procedimento Geral de Avaliação de Vida Restante de Componentes Estáticos Submetidos a Alta Temperatura. Instituto de Soldadura e Qualidade, Lisboa. 5. Prática Recomendada para Análise de Danos Acumulados em Serviço por Equipamentos Pressurizados que Operam a Alta Temperatura, Recomendação Geral para Inspeção de Equipamentos que Operam emTemperaturas Elevadas, Associação Brasileira de Ciências Mecânicas, Rio de Janeiro, 1992. 6. Babcock & Wilcox Condition Assessment Services. Available at www.babcock.com. 7. Adams,T.N., Frederick, W.J., Grace, T.M., et al, Kraft Recovery Boilers, TAPPI Press, Atlanta, 1997. 8. Caldeira, R. B., Relatório de Avaliação de Integridade e Vida Remanescente de Caldeira de Recuperação 1, CENIBRA. Instituto de Soldadura e Qualidade - ISQ Brasil, Belo Horizonte, 2002. This paper was originally published in the June, 2004 issue of O Papel, the official publication of the Brazilian Technical Association of Pulp and Paper (ABTCP). It is being reprinted by TAPPI JOURNAL through a cooperative agreement between TAPPI and ABTCP. This paper is also published on TAPPI’s web site <www.tappi.org> and summarized in the February Solutions! for People, Processes and Paper magazine (Vol. 88 No. 2). 12. Ultrasonic thickness survey on a studded tube of a recovery furnace. 13. CENIBRA’s recovery boiler No. 1. This unit had its first start-up in 1977, and underwent an integrity evalua- tion program in 2002, according to the guidelines described in this paper.
  • 6. 22 TTAAPPPPII JJOOUURRNNAALL FEBRUARY 2005 MAINTENANCE INSIGHTS FROM THE AUTHORS Facing the need to conduct an integrity evaluation and remaining life assessment program to a recovery boil- er in the mill I work for, I soon realized there was limit- ed information available about this subject within the Brazilian pulp industry, in spite of its importance. Also, I found diverse interpretations (by previous users and inspection services suppliers) of the official require- ments, and no written guidelines with a specific focus on recovery boilers.That prompted me to write this arti- cle. Brazilian official standards require that boilers under- go an integrity evaluation at 25 years. But they give no technical guidance and do not highlight the special needs and risks associated with recovery boilers. This paper is therefore intended to help provide mill engi- neers with some complementary support when they carry out such programs. The most difficult aspect of preparing for an integrity evaluation, and in writing this paper, is the lack of ref- erences and successful past experiences in Brazilian mills. I searched the procedures used in other indus- tries, and by pulp mills abroad, then adapted them to our reality. Through my research, I was particularly impressed by the wide array of available engineering disciplines and testing techniques that now can help engineers evaluate the conditions of a used recovery boiler, giv- ing an excellent level of confidence in the results of such evaluations. Some Brazilian mills are systematizing and improv- ing their procedures in evaluating the integrity of aged recovery boilers.This paper, while not intended to be a complete or definitive guide, could be a first step towards this improvement. With time, more recommendations and aspects per- taining specifically to recovery boiler in-service evaluations should be added to the contents of this paper, making it more and more comprehensive. — Flávio A. Paoliello Paoliello is a maintenance engineer with CENIBRA, Belo Oriente, MG, Brazil. Email Paoliello at flavio.paoliello@cenibra.com.br. Paoliello COMING NEXT MONTH IN TAPPI JOURNAL: Prediction of dust composition and amount in kraft recovery boilers by Barry Malmberg, Lou Edwards, Sten Lundborg, Mikael Ahlroth, and Björn Warnqvist A modular, steady-state model for the recovery furnace has been extended to predict dust compositions and amounts accurately. Validated with industrial boiler data from three recovery boilers, this mathe- matical model can help engineers predict what the effects will be when a mill upgrades a recovery boiler. Novel method to improve wet strength of paper by Tsuguyuki Saito and Akira Isogai Working to meet the industry's need for more environmentally-friendly wet strength additives as alternatives to PAE, researchers found that the combination of TEMPO-mediated oxidation of bleached kraft pulp under suitable conditions and alum addition can give sufficient wet strength to paper without any additions of the conventional wet strength agents. Monitoring particulate material formation in a kraft furnace recovery boiler by Andréa O. S. Costa, Maurício B. de Souza Jr., Evaristo C. Biscaia Jr., and Enrique L. Lima This study proposes the use of neural networks to mon- itoring particulate material formation during a recovery boiler furnace operation. Using discrete radial basis function networks to classify the amount of particles in size intervals, the authors show that the proposed methodology can satisfactorily describe the particulate material forma- tion, mainly as a monitoring tool for plant operation. Energy reduction at a kraft mill: The effects of process integration, benchmarking, and water reduction By Michael Towers, Pulp and Paper Research Institute of Canada This work studies a western Canadian market kraft mill to examine issues and opportunities with respect to energy cost reduction and water reduction. The first phase of the work identifies energy reduction opportunities using pinch analysis and benchmarking of some operations. The second phase examines further energy savings through implementing water reduction measures in addition to process integration.