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Topic: PESTICIDE POLLUTANTS
Name Of Scholar: FAROOQUE AHMED JANJHI
Assigned by: Prof: Dr. AAMNA BALOUCH
2
NATIONAL CENTER OF EXCELLENCE IN
ANALYTICAL CHEMISTRY
UNIVERSITY OF SINDH JAMSHORO
CONTENTS
01 Iintroduction
02 Classification
03
What are pollutant?
04
Effects
05 Green Method (Biological Method)
3
PESTICIDES
Pesticides are chemical compounds that are
used to kill pests, including insects, rodents,
fungi and unwanted plants (weeds).
 Pesticides are used in public health to kill
vectors of disease, such as mosquitoes, and in
agriculture, to kill pests that damage crops.
 The term pesticide also treated as synonymous
with plant protection product.
4
COMPOSITION OF PESTICIDES
Pesticide includes two types of ingredients
Active ingredients: These are used to kill, control or repel the pest.
Other ingredients: These are used to attract the pest, spreading the active
ingredient arounds
5
CLASSIFICATION OF PESTICIDE
Its based on targeted organism;
PESTICIDES
Herbicides
Nematicides
Rodenticides
MolluscicideInsecticide
Algaecides
Fungicides
Piscicides Bactericides
6
HERBICIDES
Herbicides, also commonly known as weed killers, are chemical
substances used to control unwanted plants. Selective herbicides
control specific weed species, while leaving the
desired crop relatively unharmed, while non-selective
herbicides (sometimes called total weed killers in commercial
products) can be used to clear waste ground, industrial and
construction sites, railways and railway embankments as they kill
all plant materials with which they come into contact.
e.g. Borax, Nitrofen.
7
INSECTICIDE
Insecticides are substances used to kill insects. They include
ovicides and larvicides used against insect eggs and larvae,
respectively.
Insecticides are used in agriculture, medicine, industry and
by consumers. Insecticides are claimed to be a major factor
behind the increase in the 20th-century's agricultural
productivity. Nearly all insecticides have the potential to
significantly alter ecosystems; many are toxic to humans
and/or animals; some become concentrated as they spread
along the food chain.
e.g. DDT, BHC.
8
RODENTICIDE
• Rodenticides are pesticides that kill rodents. Rodents include
not only rats and mice, but also squirrels, woodchucks,
chipmunks, porcupines, nutria, and beavers. Although rodents
play important roles in nature, they may sometimes require
control. They can damage crops, violate housing codes,
transmit disease, and in some cases cause ecological damage.
• e.g. Warfarin, Zinc phosphide.
9
NEMATICIDE
• A nematicide is a type of chemical pesticide used
to kill plant-parasitic nematodes. Nematicides have
tended to be broad-spectrum toxicants possessing
high volatility or other properties promoting
migration through the soil.
• e.g. DBCP, Phorate
10
MOLLUSICIDE
• Molluscicides, also known as snail baits and snail pellets,
are pesticides against molluscs, which are usually used in
agriculture or gardening, in order to control gastropod pests
specifically slugs and snails which damage crops or other
valued plants by feeding on them.
• e.g.: Sodium pentachloride phenate
11
FUNGICIDE
• Fungicides are biocidal chemical compounds or
biological organisms used to kill parasitic fungi or
their spores. A fungistatic inhibits their growth. Fungi
can cause serious damage in agriculture, resulting in
critical losses of yield, quality, and profit. Fungicides
are used both in agriculture and to fight fungal
infections in animals.
• e.g. Bordeaux mixture
12
BACTERICIDE
• A bactericide or bacteriocide, sometimes
abbreviated Bcidal, is a substance that kills
bacteria. Bactericides are disinfectants,
antiseptics, or antibiotics.
• e.g. Dichlorophen,Oxolinic acid
13
ALGICIDE
• Algaecide or algicide is a biocide used for
killing and preventing the growth of algae.
• e.g. Copper sulphate, Endothal
14
PISCICIDES
• A piscicide is a chemical substance which is poisonous
to fish. The primary use for piscicides is to eliminate a
dominant species of fish in a body of water, as the first
step in attempting to populate the body of water with a
different fish.
• e.g. Trifluoro methyl nitrophenol(TFM)
15
WHAT IS POLLUTANT?
 A pollutant is a substance introduced into the environment that has
undesired effects, or adversely affects the usefulness of a resource.
 A pollutant may cause long- or short-term damage by changing the
growth rate of plant or animal species, or by interfering with human
amenities, comfort, health, or property values.
16
WHY PESTICIDES CAN BE HARMFUL
Pesticides contain ingredients such as oxygen, chlorine, sulfur, phosphorus,
nitrogen, and bromine as well as heavy metals such as arsenic, copper
sulfates, lead, and mercury. Pesticides, being toxic chemicals, can interfere
with the environment and cause harms in several ways.
17
HOW DOES IT POLLUTE THE ENVIRONMENT?
This normally occurs when heavy wind or rain falls on the aforementioned
lands. The spreading of the pesticides into unintended areas, coming in
contact with natural resources such clean air, water, land, plants, and
animals, there by contaminating or harming them.
18
WHAT HAPPENS AFTER CONTAMINATION?19
After contamination of pesticide can cause wide range of human health hazards,
ranging from short-term to long-term impacts such as
 headaches
 Cancer
 Endocrine disruption.
 Blood disorders
 Kidney & liver problems
 Reproductive problems
 Breathing problems
 Vomiting
 Nausea
 Skin irritation
DEGRADATION PROCESS OF PESTICIDES
There are Four major process of degradation of pesticides;
Microbial breakdown: It’s the breakdown of pesticides by microorganism
such as fungi and bacteria.
Chemical breakdown: It’s the breakdown of pesticides by chemical
reactions in soils.
Photodegradation or photolysis: It’s the breakdown of pesticides by
sunlight.
Hydrolysis: it’s the breakdown of pesticides by water into smaller ones.
20
PESTICIDE CYCLE21
ENVIRONMENTAL EFFECTS
Environment is living things and what is around you. It includes physical,
chemical and other natural forces.
22
AIR POLLUTION BY PESTICIDE23
• Pesticides can spread by volatilization and may be blown by
winds into nearby areas.
• Following factors affect to the spreading of pesticide in the air
 Weather conditions
 Temperature
 Relative humidity
CONT:24
 Ground spraying produces less spread than aerial spraying.
 To minimize this air pollution farmers can establish a buffer zone around
their crop fields.
 Such windbreaks are legally required in the Netherlands.
 plants such as evergreen trees to serve as windbreaks and absorb the
pesticides.
 It prevent drift in to other areas.
WATER POLLUTION25
 There are some major routes through which pesticides reach the water, like
Soil eroding, As a water runoff, Hydrolysis of pesticides
 After contaminate the water it makes lot of problems
 Reduce the quality of drinking water.
 Insecticides are typically more toxic to aquatic life than herbicides and
fungicides.
 Ex. Rice cultivation – it may be leach through the soil.
SOIL POLLUTION26
 The use of pesticides decreases the general biodiversity in the soil.
 Also affect to the soil micro-organisms & decrease the soil fertility.
 Effect on growth of the plants.
 Residual effect of the pesticide in the soil.
 Enter to the food chain & bio magnification.
PESTICIDES EFFECT ON PLANTS
Root nodule formation in plants saves the world economy $10 billion in
synthetic nitrogen fertilizer every year.
specially pentachlorophenol interfere with legume rhizobium chemical.
Reduction of this symbiotic chemical results in reduced nitrogen fixation.
Pesticides can kill bees and decline the pollinators.
US farmers lose at least $200 million a year from reduced crop pollination
because pesticides applied to fields.
27
PESTICIDES EFFECTS ON ANIMALS
Pesticides can eliminate some animals' essential food sources.
Residues can travel up the food chain.
Example: Earthworms digest organic matter and increase nutrient content in
the top layer of soil. Pesticides have harmful effects on growth and
reproduction on earthworms.
28
PESTICIDES EFFECTS ON BIRDS
The US estimates that 72 million birds are killed by pesticides in the
United States each year.
DDT-induced egg shell thinning has especially affected European and
North American bird populations.
some types of fungicides slightly toxic to birds and mammals, but may kill
earthworms, which can in turn reduce populations of the birds.
The paraquat, when sprayed onto bird eggs, causes growth abnormalities
in embryos and reduces the number of chicks that hatch successfully
29
RESISTANCE DEVELOPMENT30
 When pesticide use long period of time, some pest
become resistance to the pesticide.
 Because of resistance development pest can not be
control.
 Farmer have to increase the concentration or change the
pesticide.
GREEN METHOD FOR CONTROLLING PESTICIDE
POLLUTANT
 It include the use of living beneficial organisms, called natural enemies to
control pests.
 Biological control is an important part of any integrated pest management
programme. All insect and mites have some natural enemies. Managing
these enemies can effectively control many pest.
 There are three component of biological control- Importation,
Conservation, Augmentation
31
BIO-PESTICIDES
 These are most effective, important and commercially viable because
these are inexpensive, cause no pollution and no threat to human health.
 It include naturally available agents in nature e.g.-
Bacteria-Bacillus thuringiensis, Fungi-Metarhizium, Beauveria.
 It also includes the use of natural extracts obtained from plants and
microbes e.g. Azadiractin from neem, Nicotine from tobacco.
32
BIOMAGNIFICATIONS
It’s the increasing of concentration of substance, such as a toxic
chemical in the tissues of tolerant organism at successively
higher level in a food chain.
Biomagnification also called bio amplification or biological
magnification.
This is danger expose to human because they are also in top of
the food chains.
33
34
CONCLUSION
• The pesticides are the chemical compounds that can kill pest, weeds etc.
• EPA recommended value of pesticides is beneficial for our economic
growth but above this value can cause environmental pollution..
• Green methods are the key replacement for the pesticides pollutant.
35
ACKNOWLEDGEMENT
First of all we are thankful to Almighty ALLAH for his great blessing.
We are also thankful to Prof: Dr. Amana Baloch to give us such an
opportunity.
We are also thankful to our fellows and friends, who encouraged as well as
support us.
36
REFERENCES
• www.slideshare.com
• www.Wikipedia.com
• www.sciencedirect.com
• www.quora.com
• www.greenscience.com
37
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Pesticides by Farooque Janjhi

  • 1. 1
  • 2. Topic: PESTICIDE POLLUTANTS Name Of Scholar: FAROOQUE AHMED JANJHI Assigned by: Prof: Dr. AAMNA BALOUCH 2 NATIONAL CENTER OF EXCELLENCE IN ANALYTICAL CHEMISTRY UNIVERSITY OF SINDH JAMSHORO
  • 3. CONTENTS 01 Iintroduction 02 Classification 03 What are pollutant? 04 Effects 05 Green Method (Biological Method) 3
  • 4. PESTICIDES Pesticides are chemical compounds that are used to kill pests, including insects, rodents, fungi and unwanted plants (weeds).  Pesticides are used in public health to kill vectors of disease, such as mosquitoes, and in agriculture, to kill pests that damage crops.  The term pesticide also treated as synonymous with plant protection product. 4
  • 5. COMPOSITION OF PESTICIDES Pesticide includes two types of ingredients Active ingredients: These are used to kill, control or repel the pest. Other ingredients: These are used to attract the pest, spreading the active ingredient arounds 5
  • 6. CLASSIFICATION OF PESTICIDE Its based on targeted organism; PESTICIDES Herbicides Nematicides Rodenticides MolluscicideInsecticide Algaecides Fungicides Piscicides Bactericides 6
  • 7. HERBICIDES Herbicides, also commonly known as weed killers, are chemical substances used to control unwanted plants. Selective herbicides control specific weed species, while leaving the desired crop relatively unharmed, while non-selective herbicides (sometimes called total weed killers in commercial products) can be used to clear waste ground, industrial and construction sites, railways and railway embankments as they kill all plant materials with which they come into contact. e.g. Borax, Nitrofen. 7
  • 8. INSECTICIDE Insecticides are substances used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. Insecticides are used in agriculture, medicine, industry and by consumers. Insecticides are claimed to be a major factor behind the increase in the 20th-century's agricultural productivity. Nearly all insecticides have the potential to significantly alter ecosystems; many are toxic to humans and/or animals; some become concentrated as they spread along the food chain. e.g. DDT, BHC. 8
  • 9. RODENTICIDE • Rodenticides are pesticides that kill rodents. Rodents include not only rats and mice, but also squirrels, woodchucks, chipmunks, porcupines, nutria, and beavers. Although rodents play important roles in nature, they may sometimes require control. They can damage crops, violate housing codes, transmit disease, and in some cases cause ecological damage. • e.g. Warfarin, Zinc phosphide. 9
  • 10. NEMATICIDE • A nematicide is a type of chemical pesticide used to kill plant-parasitic nematodes. Nematicides have tended to be broad-spectrum toxicants possessing high volatility or other properties promoting migration through the soil. • e.g. DBCP, Phorate 10
  • 11. MOLLUSICIDE • Molluscicides, also known as snail baits and snail pellets, are pesticides against molluscs, which are usually used in agriculture or gardening, in order to control gastropod pests specifically slugs and snails which damage crops or other valued plants by feeding on them. • e.g.: Sodium pentachloride phenate 11
  • 12. FUNGICIDE • Fungicides are biocidal chemical compounds or biological organisms used to kill parasitic fungi or their spores. A fungistatic inhibits their growth. Fungi can cause serious damage in agriculture, resulting in critical losses of yield, quality, and profit. Fungicides are used both in agriculture and to fight fungal infections in animals. • e.g. Bordeaux mixture 12
  • 13. BACTERICIDE • A bactericide or bacteriocide, sometimes abbreviated Bcidal, is a substance that kills bacteria. Bactericides are disinfectants, antiseptics, or antibiotics. • e.g. Dichlorophen,Oxolinic acid 13
  • 14. ALGICIDE • Algaecide or algicide is a biocide used for killing and preventing the growth of algae. • e.g. Copper sulphate, Endothal 14
  • 15. PISCICIDES • A piscicide is a chemical substance which is poisonous to fish. The primary use for piscicides is to eliminate a dominant species of fish in a body of water, as the first step in attempting to populate the body of water with a different fish. • e.g. Trifluoro methyl nitrophenol(TFM) 15
  • 16. WHAT IS POLLUTANT?  A pollutant is a substance introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource.  A pollutant may cause long- or short-term damage by changing the growth rate of plant or animal species, or by interfering with human amenities, comfort, health, or property values. 16
  • 17. WHY PESTICIDES CAN BE HARMFUL Pesticides contain ingredients such as oxygen, chlorine, sulfur, phosphorus, nitrogen, and bromine as well as heavy metals such as arsenic, copper sulfates, lead, and mercury. Pesticides, being toxic chemicals, can interfere with the environment and cause harms in several ways. 17
  • 18. HOW DOES IT POLLUTE THE ENVIRONMENT? This normally occurs when heavy wind or rain falls on the aforementioned lands. The spreading of the pesticides into unintended areas, coming in contact with natural resources such clean air, water, land, plants, and animals, there by contaminating or harming them. 18
  • 19. WHAT HAPPENS AFTER CONTAMINATION?19 After contamination of pesticide can cause wide range of human health hazards, ranging from short-term to long-term impacts such as  headaches  Cancer  Endocrine disruption.  Blood disorders  Kidney & liver problems  Reproductive problems  Breathing problems  Vomiting  Nausea  Skin irritation
  • 20. DEGRADATION PROCESS OF PESTICIDES There are Four major process of degradation of pesticides; Microbial breakdown: It’s the breakdown of pesticides by microorganism such as fungi and bacteria. Chemical breakdown: It’s the breakdown of pesticides by chemical reactions in soils. Photodegradation or photolysis: It’s the breakdown of pesticides by sunlight. Hydrolysis: it’s the breakdown of pesticides by water into smaller ones. 20
  • 22. ENVIRONMENTAL EFFECTS Environment is living things and what is around you. It includes physical, chemical and other natural forces. 22
  • 23. AIR POLLUTION BY PESTICIDE23 • Pesticides can spread by volatilization and may be blown by winds into nearby areas. • Following factors affect to the spreading of pesticide in the air  Weather conditions  Temperature  Relative humidity
  • 24. CONT:24  Ground spraying produces less spread than aerial spraying.  To minimize this air pollution farmers can establish a buffer zone around their crop fields.  Such windbreaks are legally required in the Netherlands.  plants such as evergreen trees to serve as windbreaks and absorb the pesticides.  It prevent drift in to other areas.
  • 25. WATER POLLUTION25  There are some major routes through which pesticides reach the water, like Soil eroding, As a water runoff, Hydrolysis of pesticides  After contaminate the water it makes lot of problems  Reduce the quality of drinking water.  Insecticides are typically more toxic to aquatic life than herbicides and fungicides.  Ex. Rice cultivation – it may be leach through the soil.
  • 26. SOIL POLLUTION26  The use of pesticides decreases the general biodiversity in the soil.  Also affect to the soil micro-organisms & decrease the soil fertility.  Effect on growth of the plants.  Residual effect of the pesticide in the soil.  Enter to the food chain & bio magnification.
  • 27. PESTICIDES EFFECT ON PLANTS Root nodule formation in plants saves the world economy $10 billion in synthetic nitrogen fertilizer every year. specially pentachlorophenol interfere with legume rhizobium chemical. Reduction of this symbiotic chemical results in reduced nitrogen fixation. Pesticides can kill bees and decline the pollinators. US farmers lose at least $200 million a year from reduced crop pollination because pesticides applied to fields. 27
  • 28. PESTICIDES EFFECTS ON ANIMALS Pesticides can eliminate some animals' essential food sources. Residues can travel up the food chain. Example: Earthworms digest organic matter and increase nutrient content in the top layer of soil. Pesticides have harmful effects on growth and reproduction on earthworms. 28
  • 29. PESTICIDES EFFECTS ON BIRDS The US estimates that 72 million birds are killed by pesticides in the United States each year. DDT-induced egg shell thinning has especially affected European and North American bird populations. some types of fungicides slightly toxic to birds and mammals, but may kill earthworms, which can in turn reduce populations of the birds. The paraquat, when sprayed onto bird eggs, causes growth abnormalities in embryos and reduces the number of chicks that hatch successfully 29
  • 30. RESISTANCE DEVELOPMENT30  When pesticide use long period of time, some pest become resistance to the pesticide.  Because of resistance development pest can not be control.  Farmer have to increase the concentration or change the pesticide.
  • 31. GREEN METHOD FOR CONTROLLING PESTICIDE POLLUTANT  It include the use of living beneficial organisms, called natural enemies to control pests.  Biological control is an important part of any integrated pest management programme. All insect and mites have some natural enemies. Managing these enemies can effectively control many pest.  There are three component of biological control- Importation, Conservation, Augmentation 31
  • 32. BIO-PESTICIDES  These are most effective, important and commercially viable because these are inexpensive, cause no pollution and no threat to human health.  It include naturally available agents in nature e.g.- Bacteria-Bacillus thuringiensis, Fungi-Metarhizium, Beauveria.  It also includes the use of natural extracts obtained from plants and microbes e.g. Azadiractin from neem, Nicotine from tobacco. 32
  • 33. BIOMAGNIFICATIONS It’s the increasing of concentration of substance, such as a toxic chemical in the tissues of tolerant organism at successively higher level in a food chain. Biomagnification also called bio amplification or biological magnification. This is danger expose to human because they are also in top of the food chains. 33
  • 34. 34
  • 35. CONCLUSION • The pesticides are the chemical compounds that can kill pest, weeds etc. • EPA recommended value of pesticides is beneficial for our economic growth but above this value can cause environmental pollution.. • Green methods are the key replacement for the pesticides pollutant. 35
  • 36. ACKNOWLEDGEMENT First of all we are thankful to Almighty ALLAH for his great blessing. We are also thankful to Prof: Dr. Amana Baloch to give us such an opportunity. We are also thankful to our fellows and friends, who encouraged as well as support us. 36
  • 37. REFERENCES • www.slideshare.com • www.Wikipedia.com • www.sciencedirect.com • www.quora.com • www.greenscience.com 37
  • 38. 38