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NITROGEN USE EFFICIENCY (NUE)
MANAGEMENT, COATED FERTILIZERS
AND INHIBITORS
Presented By
BIJAYA KHADKA
Agriculture and Forestry University (AFU)
Rampur, Chitwan
Nitrogen Use Efficiency (NUE) is the fraction of applied
nitrogen removed from the field by the crop.
NUE = Nitrogen removed from field in crop product (kg/ha) x100
Fertilizer N applied (kg/ha)
Nitrogen Use Efficiency (NUE)
Soil
N-Fertilizer
•NUE is very low ranging from 30-50%.
•However, conversion of N inputs to products for
arable crops can be 60-70% or even more (Kitchen
and Goulding, 2001).
•The main reason for low NUE is that nitrogen is lost
from soil in different forms at different stages
(Prasad1998).
Nitrogen Loss Mechanisms
1. Ammonium volatilization
2. Nitrate leaching
3. Denitrification
3. Erosion/ Runoff
Methods To Improve Nitrogen Efficiency
Proper management of soil, crop and fertilizer is the key to
enhance NUE.
• N-Fertilizer management (type, amount & timing of
application)
• Crop and soil management (soil drainage, good soil
structure etc.)
• Manure management (e.g. timing and application method)
• Modification of N fertilizers (CRF/SRF, urease and
nitrification inhibitors)
Crop Management
•Sward management (age, species, nutrient balance,
soil and plant analysis)
•The development of crop plants with improved
nitrogen assimilation.
•Identify genes that can increase NUE by crop plants,
which may reduce the rate of N application to crops.
(Genetic engineering for NUE).
Soil Management
• Soil factors that influencing losses are pH, texture,
structure, topography and drainage.
• Improved drainage so, soil is not so wet and prone to
denitrification and leaching losses.
• liming of acid soils (Bhat et al. 2010) and application of
gypsum on sodic soils (Abrol et al. 1988) can considerably
enhance NUE.
• Destruction of soil texture due to puddling in rice may
lower NUE in wheat in the rice-wheat cropping system
(Aulakh et al. 1992).
Fertilizer Management
• Fertilizer source, rate and time of application is
important management factor.
• Avoid application at the time of heavy rainfall.
• Use NH4
+-N instead of NO3-N based fertilizers under
wet conditions (Paddy field).
• Foliar application of N in flooded rice fields where soil
application is not possible.
• Deep placement of Urea to avoid volatilization.
• Spilt application of N in crop grown under irrigation.
Modification of N Fertilizers
A) Slow Release Fertilizers or Controlled Release
Fertilizers (SRF/CRF)
B) Urea Super Granules
C) Urease and Nitrification inhibitors
Slow Release Fertilizers (SRF)
• SRF products reduce the rate of N release to the soil
solution compared to urea or other inorganic sources.
• Fertilizer material that would supply N continuously but
slowly over an extended period
• Two general categories:
1. Uncoated, slow release
2. Coated, slow release
Uncoated Slow Release Fertilizer
Name
Base
Compound
Common Name N
content
(%)
Inhibition
duration
(weeks)
Urea
Formaldehyde
Ureaforms
Methylene
urea
Methylol urea
Nitroform, Folocorn,
Hydrolene, Resi-
grow
35-40 10-30
Isobutylidene
diurea
Isobutyliden
e urea
IBDU 31 10-16
Triazone Triazone /
Urea
N-Sure, Nitamin,
Trisert, Formmlene
28-33 6-10
Contylidene
diurea
Urea /
Contylidene
CDU, Triabon 34 6-12
Coated Slow Release Fertilizers
• Sulfur-coated urea (SCU)
– Coating with sulfur reduces solubility of urea
in water
– Releases N through oxidation of S coating.
– Used for turf fertilization
• Polymer-coated (or Poly-coated) urea (PCU)
– Urea is coated with organic polymer or resin.
– Polymer thickness controls the N release rate.
– Water moves in through coating to dissolve urea.
– N diffuses out through porous polymer membrane.
• Neem or ‘nimin’ coated urea (NCU)
–Primarily based on the nitrification inhibiting
properties of neem (Thomas and Prasad 1983)
– Although some slow release property was provided by
the carbon in the neem cake
Advantages of SRF
 Reducing split application in sand soils/ potato (Wilson
et.al., 2009)
Greater utilization of N in corn, barley and potato (Shoji
et.al.,2001)
 Reducing N leaching loss on sandy soil (Pack et. al., 2006)
PCU increase corn yield in low-lying areas (subject to
denitrification losses) (Noellsch et. al., 2009)
Urea Super Granule (USG)
•Super granules are conventional soluble fertilizers
formulated in a compacted form, with a relatively
small surface-to-volume ratio.
•Slow or relatively slow release of nutrients into the
soil solution.
•Particularly in tropical and subtropical regions.
•In tropical regions, their preferred use is in irrigated
rice.
Urease Inhibitors
•Inhibit the hydrolysis of urea by reducing the activity of
enzyme urease.
•Reducing the rate of conversion of urea to NH4
+
(NH2) 2 CO+H2O (NH4)2 CO3 2NH3 + H2O+CO2
Urease
Hydrolysis
Volatilization
Urease Inhibitor Products
•N-(n-butyl) triophosphoric triamide (NBPT)
– Agrotain ®(Agrotain, Inc., LLC, Corydon, KY)
– Urease enzyme inhibitor
– Fertilizer additive that increases the
efficiency of Urea/UAN fertilizer
•Thiosulfate
•Hydroquinone
•Thiophosphosphoryl triamides
Nitrification Inhibitors
• Inhibit nitrification process by direct toxicity to Nitrosomonas
bacteria.
• Delay conversion of NH4
+ to NO3
-
• Thereby reduce the loss of NO3 by leaching and denitrification.
NH4
+ NO2
- NO3
-
Denitrification
Leaching loss
Plant uptake
Nitrobacter
Nitrosomonas
Nitrification Inhibitor Products
• Nitrapyrin or N-serve [2-chloro-6-(trichloromethyl)-piridine)]
– N-Serve® (Dow AgroSciences LLC, Indianapolis, IN)
only labeled for corn, sorghum, and wheat.
• Dicyandiamide (DCD)
• SuperU® (Agrotain)
– contatins Agrotain and DCD
Results of adding a urease and
nitrification inhibitor to Nitrogen
Minimize losses from:
• Immobilization
• Volatilization
• Leaching
• Denitrification
Enhances ammonium (NH4
+ ) nutrition.
Nitrogen Use Efficiency

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Nitrogen Use Efficiency

  • 1. NITROGEN USE EFFICIENCY (NUE) MANAGEMENT, COATED FERTILIZERS AND INHIBITORS Presented By BIJAYA KHADKA Agriculture and Forestry University (AFU) Rampur, Chitwan
  • 2. Nitrogen Use Efficiency (NUE) is the fraction of applied nitrogen removed from the field by the crop. NUE = Nitrogen removed from field in crop product (kg/ha) x100 Fertilizer N applied (kg/ha) Nitrogen Use Efficiency (NUE) Soil N-Fertilizer
  • 3. •NUE is very low ranging from 30-50%. •However, conversion of N inputs to products for arable crops can be 60-70% or even more (Kitchen and Goulding, 2001). •The main reason for low NUE is that nitrogen is lost from soil in different forms at different stages (Prasad1998).
  • 4. Nitrogen Loss Mechanisms 1. Ammonium volatilization 2. Nitrate leaching 3. Denitrification 3. Erosion/ Runoff
  • 5.
  • 6. Methods To Improve Nitrogen Efficiency Proper management of soil, crop and fertilizer is the key to enhance NUE. • N-Fertilizer management (type, amount & timing of application) • Crop and soil management (soil drainage, good soil structure etc.) • Manure management (e.g. timing and application method) • Modification of N fertilizers (CRF/SRF, urease and nitrification inhibitors)
  • 7. Crop Management •Sward management (age, species, nutrient balance, soil and plant analysis) •The development of crop plants with improved nitrogen assimilation. •Identify genes that can increase NUE by crop plants, which may reduce the rate of N application to crops. (Genetic engineering for NUE).
  • 8. Soil Management • Soil factors that influencing losses are pH, texture, structure, topography and drainage. • Improved drainage so, soil is not so wet and prone to denitrification and leaching losses. • liming of acid soils (Bhat et al. 2010) and application of gypsum on sodic soils (Abrol et al. 1988) can considerably enhance NUE. • Destruction of soil texture due to puddling in rice may lower NUE in wheat in the rice-wheat cropping system (Aulakh et al. 1992).
  • 9. Fertilizer Management • Fertilizer source, rate and time of application is important management factor. • Avoid application at the time of heavy rainfall. • Use NH4 +-N instead of NO3-N based fertilizers under wet conditions (Paddy field). • Foliar application of N in flooded rice fields where soil application is not possible. • Deep placement of Urea to avoid volatilization. • Spilt application of N in crop grown under irrigation.
  • 10. Modification of N Fertilizers A) Slow Release Fertilizers or Controlled Release Fertilizers (SRF/CRF) B) Urea Super Granules C) Urease and Nitrification inhibitors
  • 11. Slow Release Fertilizers (SRF) • SRF products reduce the rate of N release to the soil solution compared to urea or other inorganic sources. • Fertilizer material that would supply N continuously but slowly over an extended period • Two general categories: 1. Uncoated, slow release 2. Coated, slow release
  • 12. Uncoated Slow Release Fertilizer Name Base Compound Common Name N content (%) Inhibition duration (weeks) Urea Formaldehyde Ureaforms Methylene urea Methylol urea Nitroform, Folocorn, Hydrolene, Resi- grow 35-40 10-30 Isobutylidene diurea Isobutyliden e urea IBDU 31 10-16 Triazone Triazone / Urea N-Sure, Nitamin, Trisert, Formmlene 28-33 6-10 Contylidene diurea Urea / Contylidene CDU, Triabon 34 6-12
  • 13. Coated Slow Release Fertilizers • Sulfur-coated urea (SCU) – Coating with sulfur reduces solubility of urea in water – Releases N through oxidation of S coating. – Used for turf fertilization • Polymer-coated (or Poly-coated) urea (PCU) – Urea is coated with organic polymer or resin. – Polymer thickness controls the N release rate. – Water moves in through coating to dissolve urea. – N diffuses out through porous polymer membrane.
  • 14. • Neem or ‘nimin’ coated urea (NCU) –Primarily based on the nitrification inhibiting properties of neem (Thomas and Prasad 1983) – Although some slow release property was provided by the carbon in the neem cake
  • 15. Advantages of SRF  Reducing split application in sand soils/ potato (Wilson et.al., 2009) Greater utilization of N in corn, barley and potato (Shoji et.al.,2001)  Reducing N leaching loss on sandy soil (Pack et. al., 2006) PCU increase corn yield in low-lying areas (subject to denitrification losses) (Noellsch et. al., 2009)
  • 16. Urea Super Granule (USG) •Super granules are conventional soluble fertilizers formulated in a compacted form, with a relatively small surface-to-volume ratio. •Slow or relatively slow release of nutrients into the soil solution. •Particularly in tropical and subtropical regions. •In tropical regions, their preferred use is in irrigated rice.
  • 17. Urease Inhibitors •Inhibit the hydrolysis of urea by reducing the activity of enzyme urease. •Reducing the rate of conversion of urea to NH4 + (NH2) 2 CO+H2O (NH4)2 CO3 2NH3 + H2O+CO2 Urease Hydrolysis Volatilization
  • 18. Urease Inhibitor Products •N-(n-butyl) triophosphoric triamide (NBPT) – Agrotain ®(Agrotain, Inc., LLC, Corydon, KY) – Urease enzyme inhibitor – Fertilizer additive that increases the efficiency of Urea/UAN fertilizer •Thiosulfate •Hydroquinone •Thiophosphosphoryl triamides
  • 19. Nitrification Inhibitors • Inhibit nitrification process by direct toxicity to Nitrosomonas bacteria. • Delay conversion of NH4 + to NO3 - • Thereby reduce the loss of NO3 by leaching and denitrification. NH4 + NO2 - NO3 - Denitrification Leaching loss Plant uptake Nitrobacter Nitrosomonas
  • 20. Nitrification Inhibitor Products • Nitrapyrin or N-serve [2-chloro-6-(trichloromethyl)-piridine)] – N-Serve® (Dow AgroSciences LLC, Indianapolis, IN) only labeled for corn, sorghum, and wheat. • Dicyandiamide (DCD) • SuperU® (Agrotain) – contatins Agrotain and DCD
  • 21. Results of adding a urease and nitrification inhibitor to Nitrogen Minimize losses from: • Immobilization • Volatilization • Leaching • Denitrification Enhances ammonium (NH4 + ) nutrition.