KCl is salt and having ionic forces between ions.So, its boiling point is more and ranked first compare to remaining two. CH2O is liquid in solution and its having intermolcular hydrogen bonding.So, its boiling point is more compare to CO2 and ranked second. CO2 is gas at room temperature due to vandarval forces between molecules.So, its boiling point is less compare to remaining two and ranked three. Hence, the decreasing order of boiling points of given molecules is, KCl > CH2O > CO2 Solution KCl is salt and having ionic forces between ions.So, its boiling point is more and ranked first compare to remaining two. CH2O is liquid in solution and its having intermolcular hydrogen bonding.So, its boiling point is more compare to CO2 and ranked second. CO2 is gas at room temperature due to vandarval forces between molecules.So, its boiling point is less compare to remaining two and ranked three. Hence, the decreasing order of boiling points of given molecules is, KCl > CH2O > CO2.