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KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 2/15/2011 Revision date: 5/4/2016 Supersedes: 12/6/2013 Version: 1.1
5/4/2016 EN (English) 1/10
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : KASKARA EW
Product code : CA701867
Synonyms : 2,4-D EHE 200 g/L + Dicamba 85 g/L ae as DMA salt + Triclopyr BEE 65 g/L EW
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Professional use
Industrial/Professional use spec : Pesticide
Agriculture
Use of the substance/mixture : Herbicide
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Arysta LifeScience Benelux
Rue de Renory 26/1
B-4102 Ougrée - Belgium
T +32 (0)4 385 97 11 - F +32 (0)4 385 97 49
sdsin@arysta.com - http://www.arystalifescience.com
1.4. Emergency telephone number
Emergency number : Europe/Rest of the world (English): +44(0)1235 239670
112 (European Emergency Number)
USA: +1 215 207 0061 or 001866 928 0789
Australia: +61 2801 44558
People's Republic of China: + 86 10 5100 3039
New Zealand: +64 9929 1483
Country Organisation/Company Address Emergency number Comment
WHO http://www.who.int/gho/phe/chemical_saf
ety/poisons_centres/en/index.html
United Kingdom National Poisons Information
Service (Belfast Centre)
Royal Victoria Hospital
Grosvenor Road
BT12 6BA Belfast
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
United Kingdom National Poisons Information
Service (Birmingham Centre)
City Hospital, Guy's & St Thomas'
Hospital Trust
Dudley Road
B18 7QH Birmingham
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
United Kingdom National Poisons Information
Service (Cardiff Centre)
Gwenwyn Ward, Wolfson Unit
Penarth
CF64 2XX Cardiff
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
United Kingdom NPIS Edinburgh (Scottish
Poisons Information Bureau)
Royal Infirmary of Edinburgh, Centre
Hospitalier Universitaire Bab el Oued
51 Little France Crescent
EH16 4SA Edinburgh
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
United Kingdom Guy's & St Thomas' Poisons
Unit
Medical Toxicology Unit, Centre
Hospitalier Universitaire de Constantine
Avonley Road
SE14 5ER London
0870 243 2241
United Kingdom National Poisons Information
Service (Newcastle Centre)
Regional Drugs and Therapeutics Centre
Claremont Place
Newcastle-upon-Tyne
NE1 4LP Newcastle
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830
(REACH Annex II)
Acute toxicity (oral),
Category 4
H302 On basis of test data
Sensitisation — Skin,
Category 1
H317 Calculation method
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 2/10
Hazardous to the aquatic
environment — Acute
Hazard, Category 1
H400 Calculation method
Hazardous to the aquatic
environment — Chronic
Hazard, Category 1
H410 Calculation method
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS07 GHS09
CLP Signal word : Warning
Hazardous ingredients : 1,2-benzisothiazol-3(2H)-one; Triclopyr butoxy ethyl ester; 2,4-D 2-EHE
Hazard statements (CLP) : H302 - Harmful if swallowed
H317 - May cause an allergic skin reaction
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P261 - Avoid breathing spray
P264 - Wash Skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear eye protection, protective clothing, protective gloves
P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or
collection site except for empty clean containers which can be disposed of as non-hazardous
waste
EUH-statements : EUH401 - To avoid risks to human health and the environment, comply with the instructions for
use
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
2,4-D 2-EHE (CAS No) 1928-43-4
(EC no) 217-673-3
(EC index no) 607-308-00-X
28.7 - 31.2 Acute Tox. 4 (Oral), H302
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Dicamba DMA salt (CAS No) 2300-66-5
(EC no) 218-951-7
(EC index no) 607-044-00-5
10.2 - 11.2 Eye Irrit. 2, H319
Aquatic Chronic 3, H412
Triclopyr butoxy ethyl ester (CAS No) 64700-56-7
(EC no) 265-024-8
7.8 - 9.3 Acute Tox. 4 (Oral), H302
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
1,2-benzisothiazol-3(2H)-one (CAS No) 2634-33-5
(EC no) 220-120-9
(EC index no) 613-088-00-6
0.005 - 0.01 Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 3/10
Specific concentration limits:
Name Product identifier Specific concentration limits
1,2-benzisothiazol-3(2H)-one (CAS No) 2634-33-5
(EC no) 220-120-9
(EC index no) 613-088-00-6
(C >= 0.05) Skin Sens. 1, H317
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : If medical advice is needed, have product container or label at hand.
First-aid measures after inhalation : IF INHALED: if breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing. If breathing is difficult, give oxygen. If breathing stops, give artificial
respiration. In all cases of doubt, or when symptoms persist, seek medical attention.
First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash immediately
with plenty of water and soap. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and
attention.
First-aid measures after ingestion : If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting.
Get immediate medical advice and attention.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : AFFF foam. dry chemical powder. Carbon dioxide (CO2). Water fog.
Unsuitable extinguishing media : High volume water jet.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Non-flammable.
5.3. Advice for firefighters
Precautionary measures fire : No open flames. No smoking.
Firefighting instructions : Evacuate and limit access. Use a water spray to cool exposed surfaces and to protect fire-
fighters.
Protection during firefighting : Wear suitable protective clothing. In case of inadequate ventilation wear respiratory protection.
Other information : Do not allow run-off from fire fighting to enter drains or water courses.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Clean up even minor leaks or spills, if possible, without unnecessary risk.
6.1.1. For non-emergency personnel
Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. In case of insufficient
ventilation, wear suitable respiratory equipment.
Emergency procedures : Evacuate the danger area. Provide adequate ventilation to minimize dust and/or vapour
concentrations. Consult an expert. Eliminate every possible source of ignition.
6.1.2. For emergency responders
Protective equipment : Wear self-contained breathing apparatus, rubber boots and thick rubber gloves.
6.2. Environmental precautions
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Notify authorities if product enters
sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Prevent liquid from entering sewers, watercourses, underground or low areas. Impound and
recover large spill by mixing it with inert granular solids.
Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it.
Other information : Avoid spilling the product, as this might cause falls.
6.4. Reference to other sections
Exposure controls/personal protection. Disposal considerations.
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 4/10
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Handle in accordance with good industrial hygiene and safety procedures. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not allow to
enter into surface water or drains.
Handling temperature : Store at room temperature
Hygiene measures : Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it
before reuse. Wash hands and other exposed areas with mild soap and water before eating,
drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground well. Use explosion-proof equipment.
Storage conditions : Keep out of direct sunlight.
Incompatible products : Strong acids. Strong bases. Strong oxidizing agents.
Maximum storage period : 2 year(s)
Storage area : Keep container tightly closed and in well ventilated place. Provide for retaining containers, eg.
floor pan without outflow.
Packaging materials : Keep only in the original container. Keep locked up and out of reach of children.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
2,4-D 2-EHE (1928-43-4)
Austria MAK (mg/m³) 1 mg/m³ Aerosol
Austria MAK Short time value (mg/m³) 4 mg/m³ Aerosol
Belgium Limit value (mg/m³) 10 mg/m³
Denmark Grænseværdie (langvarig) (mg/m³) 1 mg/m³
Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³
France VME (mg/m³) 10 mg/m³
Germany TRGS 900 Occupational exposure limit value (mg/m³) 1 mg/m³ Aerosol
Germany TRGS 900 Limitation of exposure peaks (mg/m³) 8 mg/m³ Aerosol
Hungary AK-érték 1 mg/m³
Hungary CK-érték 4 mg/m³
Spain VLA-ED (mg/m³) 10 mg/m³
United Kingdom WEL TWA (mg/m³) 10 mg/m³
United Kingdom WEL STEL (mg/m³) 20 mg/m³
Switzerland VME (mg/m³) 1 mg/m³
Switzerland VLE (mg/m³) 8 mg/m³
8.2. Exposure controls
Personal protective equipment : Gloves. Gas mask. Safety glasses.
Hand protection : Wear suitable gloves resistant to chemical penetration. Nitrile rubber gloves. For special
purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves
Eye protection : Face shield. Chemical goggles or safety glasses
Skin and body protection : Skin protection appropriate to the conditions of use should be provided
Respiratory protection : In case of inadequate ventilation wear respiratory protection
Environmental exposure controls : Notify authorities if product enters sewers or public waters.
Other information : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 5/10
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : white.
Odour : No data available
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : > 79 °C
Auto-ignition temperature : 382 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1.093 g/ml
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 173 - 1828 mPa.s (20C°)
Explosive properties : Product is not explosive.
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
When exposed to heat, may decompose liberating hazardous gases.
10.2. Chemical stability
Stable under normal conditions of use.
10.3. Possibility of hazardous reactions
None under normal conditions. For further information, refer to section 10 : "Stability and Reactivity".
10.4. Conditions to avoid
Keep out of direct sunlight. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
10.5. Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.
10.6. Hazardous decomposition products
When heated to decomposition, emits dangerous fumes. Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
KASKARA EW
LD50 oral rat 500 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat (mg/l) > 4.97 mg/l/4h (MATC)
Triclopyr butoxy ethyl ester (64700-56-7)
LD50 oral rat 803 mg/kg
LD50 dermal rat > 2000 mg/kg
LC50 inhalation rat (mg/l) > 4.8 mg/l/4h (MATC)
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 6/10
2,4-D 2-EHE (1928-43-4)
LD50 oral rat 896 mg/kg
LD50 dermal rat > mg/kg
LD50 dermal rabbit > 4000 mg/kg
LC50 inhalation rat (mg/l) > 5.39 mg/l/4h
1,2-benzisothiazol-3(2H)-one (2634-33-5)
LD50 oral 670 mg/kg
Skin corrosion/irritation : Not classified.
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard : Not classified
SECTION 12: Ecological information
12.1. Toxicity
Triclopyr butoxy ethyl ester (64700-56-7)
LC50 fish 1 0.36 mg/l (96h Lepomis macrochirus)
EC50 Daphnia 1 2.9 mg/l (48h Daphnia magna)
ErC50 (algae) > 3 mg/l (96h Pseudokirchneriella subcapitata)
2,4-D 2-EHE (1928-43-4)
LC50 fish 1 > 0.24 mg/l (96h Menidia beryllina)
EC50 Daphnia 1 > 1.91 mg/l (96h Daphnia magna)
ErC50 (algae) 0.23 mg/l (120d Skeletonema constatum)
ErC50 (other aquatic plants) 0.5 mg/l (14d Lemna Gibba)
NOEC chronic crustacea 0.015 mg/l (21d Daphnia magna)
1,2-benzisothiazol-3(2H)-one (2634-33-5)
LC50 fish 1 1.3 mg/l
EC50 Daphnia 1 0.99 mg/l
ErC50 (algae) 0.084 mg/l
NOEC chronic fish 0.74 mg/l
NOEC chronic crustacea 0.7 mg/l
NOEC chronic algae 0.043 mg/l
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Triclopyr butoxy ethyl ester (64700-56-7)
BCF fish 1 100 - 300
Log Pow 4.09 - 4.49
2,4-D 2-EHE (1928-43-4)
BCF fish 1 10
Log Pow 0.83
12.4. Mobility in soil
KASKARA EW
Surface tension 31.2 mN/m (20°C)
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 7/10
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Do not empty into drains, dispose of this material and its container at hazardous or special
waste collection point.
Additional information : Do not contaminate water with the product or its container. Do not clean application equipment
near surface water. Notify authorities if product enters sewers or public waters.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
3082 3082 3082 3082 3082
14.2. UN proper shipping name
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE)
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE)
Environmentally
hazardous substance,
liquid, n.o.s. (2,4-D EHE,
Dicamba, Triclopyr BEE)
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE)
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE)
Transport document description
UN 3082
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE),
9, III, (E)
UN 3082
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE),
9, III, MARINE
POLLUTANT/ENVIRONM
ENTALLY HAZARDOUS
UN 3082 Environmentally
hazardous substance,
liquid, n.o.s. (2,4-D EHE,
Dicamba, Triclopyr BEE),
9, III,
ENVIRONMENTALLY
HAZARDOUS
UN 3082
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE),
9, III,
ENVIRONMENTALLY
HAZARDOUS
UN 3082
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (2,4-D EHE,
Dicamba, Triclopyr BEE),
9, III,
ENVIRONMENTALLY
HAZARDOUS
14.3. Transport hazard class(es)
9 9 9 9 9
14.4. Packing group
III III III III III
14.5. Environmental hazards
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
Marine pollutant : Yes
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M6
Special provisions (ADR) : 274, 335, 601
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Special packing provisions (ADR) : PP1
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions
(ADR)
: T4
Portable tank and bulk container special
provisions (ADR)
: TP1, TP29
Tank code (ADR) : LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V12
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 8/10
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code : E
EAC code : •3Z
- Transport by sea
Special provisions (IMDG) : 274, 335
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
Special packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP2, TP29
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
CAO max net quantity (IATA) : 450L
Special provisions (IATA) : A97, A158
ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M6
Special provisions (ADN) : 274, 335, 61
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : M6
Special provisions (RID) : 274, 335, 601
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Special packing provisions (RID) : PP1
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions
(RID)
: T4
Portable tank and bulk container special
provisions (RID)
: TP1, TP29
Tank codes for RID tanks (RID) : LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W12
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW31
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 9/10
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
No additional information available
SECTION 16: Other information
Indication of changes:
PCA packing
instructions (IATA)
Added
PCA max net quantity
(IATA)
Added
PCA limited quantity
max net quantity (IATA)
Added
PCA Limited quantities
(IATA)
Added
CAO max net quantity
(IATA)
Added
CAO packing
instructions (IATA)
Added
PCA Excepted
quantities (IATA)
Added
EmS-No. (Spillage) Removed
EmS-No. (Fire) Removed
1.2 Use of the
substance/mixture
Added
1.2 Main use category Removed
1.2 Industrial/Professional
use spec
Modified
2.1 Classification according
to Regulation (EC) No.
1272/2008 [CLP]
Modified
2.1 Classification according
to Directive
67/548/EEC [DSD] or
1999/45/EC [DPD]
Added
2.2 EUH-statements Added
2.2 Precautionary
statements (CLP)
Modified
3 Composition/informatio
n on ingredients
Modified
6.1 Emergency procedures Modified
7.2 Maximum storage
period
Modified
8.2 Eye protection Modified
11.1 ATE CLP (oral) Modified
14.4 Packing group (ADR) Added
14.6 Instruction "passenger"
- Limited quantities
(ICAO)
Removed
KASKARA EW
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
5/4/2016 EN (English) 10/10
14.6 Instruction "passenger"
(ICAO)
Removed
14.6 Instruction "cargo"
(ICAO)
Removed
14.6 Hazard identification
number (Kemler No.)
Added
14.6 Classification code
(ADR)
Added
Full text of H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Sensitisation — Skin, Category 1
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH401 To avoid risks to human health and the environment, comply with the instructions for use
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Acute Tox. 4 (Oral) H302 On basis of test data
Skin Sens. 1 H317 Calculation method
Aquatic Acute 1 H400 Calculation method
Aquatic Chronic 1 H410 Calculation method
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

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Kaskara msds

  • 1. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 2/15/2011 Revision date: 5/4/2016 Supersedes: 12/6/2013 Version: 1.1 5/4/2016 EN (English) 1/10 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : KASKARA EW Product code : CA701867 Synonyms : 2,4-D EHE 200 g/L + Dicamba 85 g/L ae as DMA salt + Triclopyr BEE 65 g/L EW 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Professional use Industrial/Professional use spec : Pesticide Agriculture Use of the substance/mixture : Herbicide 1.2.2. Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Arysta LifeScience Benelux Rue de Renory 26/1 B-4102 Ougrée - Belgium T +32 (0)4 385 97 11 - F +32 (0)4 385 97 49 sdsin@arysta.com - http://www.arystalifescience.com 1.4. Emergency telephone number Emergency number : Europe/Rest of the world (English): +44(0)1235 239670 112 (European Emergency Number) USA: +1 215 207 0061 or 001866 928 0789 Australia: +61 2801 44558 People's Republic of China: + 86 10 5100 3039 New Zealand: +64 9929 1483 Country Organisation/Company Address Emergency number Comment WHO http://www.who.int/gho/phe/chemical_saf ety/poisons_centres/en/index.html United Kingdom National Poisons Information Service (Belfast Centre) Royal Victoria Hospital Grosvenor Road BT12 6BA Belfast 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours) United Kingdom National Poisons Information Service (Birmingham Centre) City Hospital, Guy's & St Thomas' Hospital Trust Dudley Road B18 7QH Birmingham 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours) United Kingdom National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Wolfson Unit Penarth CF64 2XX Cardiff 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours) United Kingdom NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh, Centre Hospitalier Universitaire Bab el Oued 51 Little France Crescent EH16 4SA Edinburgh 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours) United Kingdom Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Centre Hospitalier Universitaire de Constantine Avonley Road SE14 5ER London 0870 243 2241 United Kingdom National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 4 H302 On basis of test data Sensitisation — Skin, Category 1 H317 Calculation method
  • 2. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 2/10 Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 Calculation method Hazardous to the aquatic environment — Chronic Hazard, Category 1 H410 Calculation method Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS07 GHS09 CLP Signal word : Warning Hazardous ingredients : 1,2-benzisothiazol-3(2H)-one; Triclopyr butoxy ethyl ester; 2,4-D 2-EHE Hazard statements (CLP) : H302 - Harmful if swallowed H317 - May cause an allergic skin reaction H410 - Very toxic to aquatic life with long lasting effects Precautionary statements (CLP) : P261 - Avoid breathing spray P264 - Wash Skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear eye protection, protective clothing, protective gloves P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste EUH-statements : EUH401 - To avoid risks to human health and the environment, comply with the instructions for use 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2,4-D 2-EHE (CAS No) 1928-43-4 (EC no) 217-673-3 (EC index no) 607-308-00-X 28.7 - 31.2 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Dicamba DMA salt (CAS No) 2300-66-5 (EC no) 218-951-7 (EC index no) 607-044-00-5 10.2 - 11.2 Eye Irrit. 2, H319 Aquatic Chronic 3, H412 Triclopyr butoxy ethyl ester (CAS No) 64700-56-7 (EC no) 265-024-8 7.8 - 9.3 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 1,2-benzisothiazol-3(2H)-one (CAS No) 2634-33-5 (EC no) 220-120-9 (EC index no) 613-088-00-6 0.005 - 0.01 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=10) Aquatic Chronic 1, H410
  • 3. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 3/10 Specific concentration limits: Name Product identifier Specific concentration limits 1,2-benzisothiazol-3(2H)-one (CAS No) 2634-33-5 (EC no) 220-120-9 (EC index no) 613-088-00-6 (C >= 0.05) Skin Sens. 1, H317 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If medical advice is needed, have product container or label at hand. First-aid measures after inhalation : IF INHALED: if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. If breathing stops, give artificial respiration. In all cases of doubt, or when symptoms persist, seek medical attention. First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water and soap. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion : If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting. Get immediate medical advice and attention. 4.2. Most important symptoms and effects, both acute and delayed No additional information available 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : AFFF foam. dry chemical powder. Carbon dioxide (CO2). Water fog. Unsuitable extinguishing media : High volume water jet. 5.2. Special hazards arising from the substance or mixture Fire hazard : Non-flammable. 5.3. Advice for firefighters Precautionary measures fire : No open flames. No smoking. Firefighting instructions : Evacuate and limit access. Use a water spray to cool exposed surfaces and to protect fire- fighters. Protection during firefighting : Wear suitable protective clothing. In case of inadequate ventilation wear respiratory protection. Other information : Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Clean up even minor leaks or spills, if possible, without unnecessary risk. 6.1.1. For non-emergency personnel Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. In case of insufficient ventilation, wear suitable respiratory equipment. Emergency procedures : Evacuate the danger area. Provide adequate ventilation to minimize dust and/or vapour concentrations. Consult an expert. Eliminate every possible source of ignition. 6.1.2. For emergency responders Protective equipment : Wear self-contained breathing apparatus, rubber boots and thick rubber gloves. 6.2. Environmental precautions Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Prevent liquid from entering sewers, watercourses, underground or low areas. Impound and recover large spill by mixing it with inert granular solids. Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it. Other information : Avoid spilling the product, as this might cause falls. 6.4. Reference to other sections Exposure controls/personal protection. Disposal considerations.
  • 4. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 4/10 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Handle in accordance with good industrial hygiene and safety procedures. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not allow to enter into surface water or drains. Handling temperature : Store at room temperature Hygiene measures : Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground well. Use explosion-proof equipment. Storage conditions : Keep out of direct sunlight. Incompatible products : Strong acids. Strong bases. Strong oxidizing agents. Maximum storage period : 2 year(s) Storage area : Keep container tightly closed and in well ventilated place. Provide for retaining containers, eg. floor pan without outflow. Packaging materials : Keep only in the original container. Keep locked up and out of reach of children. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2,4-D 2-EHE (1928-43-4) Austria MAK (mg/m³) 1 mg/m³ Aerosol Austria MAK Short time value (mg/m³) 4 mg/m³ Aerosol Belgium Limit value (mg/m³) 10 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 1 mg/m³ Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³ France VME (mg/m³) 10 mg/m³ Germany TRGS 900 Occupational exposure limit value (mg/m³) 1 mg/m³ Aerosol Germany TRGS 900 Limitation of exposure peaks (mg/m³) 8 mg/m³ Aerosol Hungary AK-érték 1 mg/m³ Hungary CK-érték 4 mg/m³ Spain VLA-ED (mg/m³) 10 mg/m³ United Kingdom WEL TWA (mg/m³) 10 mg/m³ United Kingdom WEL STEL (mg/m³) 20 mg/m³ Switzerland VME (mg/m³) 1 mg/m³ Switzerland VLE (mg/m³) 8 mg/m³ 8.2. Exposure controls Personal protective equipment : Gloves. Gas mask. Safety glasses. Hand protection : Wear suitable gloves resistant to chemical penetration. Nitrile rubber gloves. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves Eye protection : Face shield. Chemical goggles or safety glasses Skin and body protection : Skin protection appropriate to the conditions of use should be provided Respiratory protection : In case of inadequate ventilation wear respiratory protection Environmental exposure controls : Notify authorities if product enters sewers or public waters. Other information : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
  • 5. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 5/10 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : white. Odour : No data available Odour threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : > 79 °C Auto-ignition temperature : 382 °C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 °C : No data available Relative density : No data available Density : 1.093 g/ml Solubility : No data available Log Pow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 173 - 1828 mPa.s (20C°) Explosive properties : Product is not explosive. Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity When exposed to heat, may decompose liberating hazardous gases. 10.2. Chemical stability Stable under normal conditions of use. 10.3. Possibility of hazardous reactions None under normal conditions. For further information, refer to section 10 : "Stability and Reactivity". 10.4. Conditions to avoid Keep out of direct sunlight. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. 10.6. Hazardous decomposition products When heated to decomposition, emits dangerous fumes. Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. KASKARA EW LD50 oral rat 500 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 4.97 mg/l/4h (MATC) Triclopyr butoxy ethyl ester (64700-56-7) LD50 oral rat 803 mg/kg LD50 dermal rat > 2000 mg/kg LC50 inhalation rat (mg/l) > 4.8 mg/l/4h (MATC)
  • 6. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 6/10 2,4-D 2-EHE (1928-43-4) LD50 oral rat 896 mg/kg LD50 dermal rat > mg/kg LD50 dermal rabbit > 4000 mg/kg LC50 inhalation rat (mg/l) > 5.39 mg/l/4h 1,2-benzisothiazol-3(2H)-one (2634-33-5) LD50 oral 670 mg/kg Skin corrosion/irritation : Not classified. Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified SECTION 12: Ecological information 12.1. Toxicity Triclopyr butoxy ethyl ester (64700-56-7) LC50 fish 1 0.36 mg/l (96h Lepomis macrochirus) EC50 Daphnia 1 2.9 mg/l (48h Daphnia magna) ErC50 (algae) > 3 mg/l (96h Pseudokirchneriella subcapitata) 2,4-D 2-EHE (1928-43-4) LC50 fish 1 > 0.24 mg/l (96h Menidia beryllina) EC50 Daphnia 1 > 1.91 mg/l (96h Daphnia magna) ErC50 (algae) 0.23 mg/l (120d Skeletonema constatum) ErC50 (other aquatic plants) 0.5 mg/l (14d Lemna Gibba) NOEC chronic crustacea 0.015 mg/l (21d Daphnia magna) 1,2-benzisothiazol-3(2H)-one (2634-33-5) LC50 fish 1 1.3 mg/l EC50 Daphnia 1 0.99 mg/l ErC50 (algae) 0.084 mg/l NOEC chronic fish 0.74 mg/l NOEC chronic crustacea 0.7 mg/l NOEC chronic algae 0.043 mg/l 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential Triclopyr butoxy ethyl ester (64700-56-7) BCF fish 1 100 - 300 Log Pow 4.09 - 4.49 2,4-D 2-EHE (1928-43-4) BCF fish 1 10 Log Pow 0.83 12.4. Mobility in soil KASKARA EW Surface tension 31.2 mN/m (20°C) 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Other adverse effects No additional information available
  • 7. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 7/10 SECTION 13: Disposal considerations 13.1. Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Additional information : Do not contaminate water with the product or its container. Do not clean application equipment near surface water. Notify authorities if product enters sewers or public waters. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID 14.1. UN number 3082 3082 3082 3082 3082 14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE) Environmentally hazardous substance, liquid, n.o.s. (2,4-D EHE, Dicamba, Triclopyr BEE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE) Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE), 9, III, (E) UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE), 9, III, MARINE POLLUTANT/ENVIRONM ENTALLY HAZARDOUS UN 3082 Environmentally hazardous substance, liquid, n.o.s. (2,4-D EHE, Dicamba, Triclopyr BEE), 9, III, ENVIRONMENTALLY HAZARDOUS UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE), 9, III, ENVIRONMENTALLY HAZARDOUS UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D EHE, Dicamba, Triclopyr BEE), 9, III, ENVIRONMENTALLY HAZARDOUS 14.3. Transport hazard class(es) 9 9 9 9 9 14.4. Packing group III III III III III 14.5. Environmental hazards Dangerous for the environment : Yes Dangerous for the environment : Yes Marine pollutant : Yes Dangerous for the environment : Yes Dangerous for the environment : Yes Dangerous for the environment : Yes No supplementary information available 14.6. Special precautions for user - Overland transport Classification code (ADR) : M6 Special provisions (ADR) : 274, 335, 601 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : PP1 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12
  • 8. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 8/10 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code : E EAC code : •3Z - Transport by sea Special provisions (IMDG) : 274, 335 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP2, TP29 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A - Air transport PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y964 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) : 450L Special provisions (IATA) : A97, A158 ERG code (IATA) : 9L - Inland waterway transport Classification code (ADN) : M6 Special provisions (ADN) : 274, 335, 61 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : M6 Special provisions (RID) : 274, 335, 601 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : PP1 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW31
  • 9. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 9/10 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 90 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations No additional information available 15.2. Chemical safety assessment No additional information available SECTION 16: Other information Indication of changes: PCA packing instructions (IATA) Added PCA max net quantity (IATA) Added PCA limited quantity max net quantity (IATA) Added PCA Limited quantities (IATA) Added CAO max net quantity (IATA) Added CAO packing instructions (IATA) Added PCA Excepted quantities (IATA) Added EmS-No. (Spillage) Removed EmS-No. (Fire) Removed 1.2 Use of the substance/mixture Added 1.2 Main use category Removed 1.2 Industrial/Professional use spec Modified 2.1 Classification according to Regulation (EC) No. 1272/2008 [CLP] Modified 2.1 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Added 2.2 EUH-statements Added 2.2 Precautionary statements (CLP) Modified 3 Composition/informatio n on ingredients Modified 6.1 Emergency procedures Modified 7.2 Maximum storage period Modified 8.2 Eye protection Modified 11.1 ATE CLP (oral) Modified 14.4 Packing group (ADR) Added 14.6 Instruction "passenger" - Limited quantities (ICAO) Removed
  • 10. KASKARA EW Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 5/4/2016 EN (English) 10/10 14.6 Instruction "passenger" (ICAO) Removed 14.6 Instruction "cargo" (ICAO) Removed 14.6 Hazard identification number (Kemler No.) Added 14.6 Classification code (ADR) Added Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, Category 1 H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects EUH401 To avoid risks to human health and the environment, comply with the instructions for use Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Acute Tox. 4 (Oral) H302 On basis of test data Skin Sens. 1 H317 Calculation method Aquatic Acute 1 H400 Calculation method Aquatic Chronic 1 H410 Calculation method SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product