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Msds magnesium lignosulfonate
1. SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Identification of the substance/mixture: Calcium lignosulfonate
CAS Number: 8061 51 6
EC number: /
REACH Registration number: Exempt
1.2. Relevant identified uses of the substance or mixture and uses advised against
Laboratory chemicals, Manufacture of substances
1.3. Details of the supplier of the safety data sheet
Manufacturer/Supplier: GREEN AGROCHEM
Address: Address:Lizeyayuan Apartment,South West Station Road,Fengtai
District,Beijing,China
Zip code:100072
Branch Address.WestXinluo St. High-tech Dist, Jinan, Shandong ,China.
Email:info@greenagrochem.com
Http://www.greenagrochem.com
E-mail info@greenagrochem.com
1.4. Emergency telephone number (+86)-10-63388399
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
2.2. Label Elements
Caution - substance not yet tested completely.
2.3. Other hazards
none
Page: 1/9
Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
2. SECTION 3: Composition/information on ingredients
3.1. Substance/preparation
Name Calcium Lignosulfonate
Product Code GAC-CALS
Appearance Yellow Brown Powder
pH 4-7
Dry maters 95%min
Water-insoluble 1.0%max
Total calcium and
calcium
8%min
Lignosulfonate 55%min
Sulfate 2%min
Total reducing matter 7%min
Density 0.55g/cm3
Moisture 7%Max
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
3. SECTION 4: First aid measures
4.1. Description of necessary first aid measures
In case of inhalation : If breathed in, move person into fresh air. If not breathing, giv
e artificial respiration.
In case of contact with skin : Wash off with soap and plenty of water.
IF IN EYES: Flush eyes with water as a precaution.
In case of ingestion: Never give anything by mouth to an unconscious person. Rins
e mouth with water.
Individual protection of the person providing first
aid :
No information available.
4.2. Most important symptoms and effects, both acute and delayed
no data available
4.3. Indication of any immediate medical attention and special treatment needed
Indication of any immediate medical attention and
special treatment needed :
No information available.
SECTION 5: Firefighting measures
5.1. Extinguishing Media
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media: Carbon oxides, Sulphur oxides
5.2. Special hazards arising from the substance or mixture
Special hazards arising from the substance or
mixture:
None special
5.3. Advice for firefighters
Wear self contained breathing apparatus for fire
fighting if necessary.
No special requirements.
Do not allow spillage of fire will be poured into drains or watercourses.
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
4. SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: Avoid dust formation
Avoid breathing dust and contact with eyes
Use respiratory protection if high dust conditions, chemical resistant gloves
and safety glasses
For emergency responders: None special
6.2. Environmental precautions
Environmental precautions: Do not discharge into any drains, surface waters or groundwaters.
6.3. Methods and material for containment and cleaning up
Methods and material for containment and
cleaning up:
Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4. Reference to other sections
Reference to other sections : No information available.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Recommendations: Avoid contact with the eyes, skin and clothing. Wear protective clothing and
use glasses.
Advice on general occupational hygiene: Provide suitable air extraction ventilation in the work areas.
Observe the rules of hygiene and safety at work.
Other information: Store in cool place. Keep container tightly closed in a dry and well-ventilated pl
ace.
7.2. Conditions for safe storage, including any incompatibilities
Conditions for safe storage, including any
incompatibilities:
Store in cool place. Keep container tightly closed in a dry and well-ventilated pl
ace.
7.3. Specific end use(s)
Specific end use(s): None.
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
5. SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Components with workplace control parameters
8.2. Exposure controls
Appropriate engineering controls : General industrial hygiene practice.
Individual protection measures, such as personal
protective equipment :
Eye/face protection: Use equipment for eye protection tested and approved under appropriate gover
nment standards
such as NIOSH (US) or EN 166(EU).
Skin protection : Light protective clothing recommended. Wash contaminated clothing before
reuse.
Avoid inhalation and contact with skin and eyes.
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove r
emoval technique
(without touching glove's outer surface) to avoid skin contact with this product.
Dispose of
contaminated gloves after use in accordance with applicable laws and good la
boratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directiv
e 89/686/EEC and
the standard EN 374 derived from it.
Other: Choose body protection in relation to its type, to the concentration and amount
of dangerous
substances, and to the specific work-place., The type of protective equipment
must be selected
according to the concentration and amount of the dangerous substance at the
specific workplace.
.
Respiratory protection: Respiratory protection is not required. Where protection from nuisance levels o
f dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and comp
onents tested and
approved under appropriate government standards such as NIOSH (US) or CE
N (EU).
Thermal hazards : No information available.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance: Yellow brown powder
Odour: Odourless
pH : 4-7
Melting point: No information available.
Boiling Point : No information available.
Flash Point: Not applicable
Evaporation Rate : No information available.
Flammability (solid, gas) : No information available.
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
6. Upper/lower flammability or explosive limits : No information available
Lower and upper explosive (flammable) limits : No information available
Vapor pressure at 20ยบC : No information available.
Vapor density : No information available.
Relative density: 0.55g/cm3
Solubility(ies) : soluble in water
Partition coefficient: n-octanol/water : No information available.
Auto-ignition temperature : No information available.
Decomposition temperature : No information available.
Viscosity : No information available.
9.2. Other information
Other information : No information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity : None hazardous reactions are expected
10.2. Chemical stability
Chemical stability : This product is stable in normal conditions.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions : None hazardous reactions are expected
10.4. Conditions to Avoid
Conditions to Avoid: No special requirements.
10.5. Incompatible materials
Incompatible materials: None known
10.6. Hazardous decomposition products
Hazardous decomposition products: None hazardous reactions or by-products are expected
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Non-Human Toxicity Excerpts when given to rats in drinking-water at 10 g/100 ml for 16 wk decr wt gain,
caused skin lesions at base of tail & incr leukocyte counts & wt of liver, kidneys
& spleen. changes were consistent with reticulo-endothelial activation in liver &
proximal tubules degeneration.
when supplied in drinking fluid in high concn, sodium lignosulfonate caused
gastric ulceration in 8 of 10 guinea pigs within 2 wk. when supplied in low
concn for 5 wk it caused no damage to stomach but produced ulceration in
colon in 4 of 10 animals.
admin of 1% in drinking fluid to guinea pigs & rabbits over 2- to 6-wk period
caused ulcerative disease of colon in high proportion of animals. clinical
morphological features were very similar to ulcerative disease of colon induced
by carrageenan.
Non-Human Toxicity Values Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May
cause eye irritation. Inhalation: May cause respiratory tract irritation. Ingestion:
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
7. May cause gastrointestinal tract irritation. May affect behavior/central nervous
system (somnolence, muscle weakness, coma, excitement). Chronic Potential
Health Effects: Inhalation: Prolonged or repeated inhalation may affect
respiration, liver, and blood. Ingestion: Prolonged or repeated ingestion may
cause ulceration of stomach and colon, and skin leisons. It may also affect the
liver (impaired liver function tests), kidneys, and blood.
Other relevant information : No specific information is available in our database regarding the other toxic
effects of this material for humans.
There is body of evidence supporting the fact that increased
cancer risk would be limited to people already suffering
from silicosis. According to the current state of the art,
worker protection against silicosis can be consistently
assured by respecting the existing regulatory
occupational exposure limits.
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Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
8. SECTION 12: Ecological information
12.1. Toxicity
Toxicity : Toxicity to fish
LC0 - Phoxinus phoxinus - > 1.000 mg/l - 48 h
LC50 - Oncorhynchus mykiss (rainbow trout) - 7.300 mg/l - 48 h
12.2. Persistence and degradability
Persistence and degradability : no data available
12.3. Bioaccumulative potential
Bioaccumulative potential : no data available
12.4. Soil mobility
Soil mobility : no data available
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : no data available
12.6. Other adverse effects
Other adverse effects: See also Sections 6, 7, 13 and 15
Avoid contamination of soil, groundwater and surface water.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment containers : Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Appropiate methods of waste treatment of both
substance or mixtures :
Dispose in a safe manner in accordance with local/national regulations
Appropiate methods of waste treatment of
contaminated packaging :
Dispose of as unused product.
Wastewater discharge : No information available.
Community/national/regional provisiones relating
to waste :
No information available.
SECTION 14: Transport information
14.1. Land Transport (ADR/RID)
Not dangerous goods
14.2. Sea Transport (IMDG)
Not dangerous goods
14.3. Air Transport (IATA)
Not dangerous goods
Page: 8/9
Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
9. SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Other : No information available.
Authorisations : No information available.
Usage: : No information available.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : No information available.
SECTION 16: Other information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. GREEN AGROCHEM shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions .
Page: 9/9
Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010
10. SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Other : No information available.
Authorisations : No information available.
Usage: : No information available.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : No information available.
SECTION 16: Other information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. GREEN AGROCHEM shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions .
Page: 9/9
Version: 20170118
Revision date: 18.JAN.2017
calcium LIGNOSULFONATE
Sample Safety Data Sheet
According to Regulation (EC) 1907/2006 and Regulation (EC) 453/2010