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Sm-Co Permanent Magnets and Their Applications Jinfang Liu Electron Energy Corporation
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
Sintered  Sm-Co Magnets (Overview) Sm-Co Magnets SmCo 5  type Sm 2 Co 17  type Conventional Sm-Co 2:17 grades High energy Sm-Co 2:17 magnets Sm-Co 2:17  TC  materials Conventional Sm-Co 1:5 grades Sm-Co 1:5  TC  materials High temperature magnets EEC2:17-31 EEC2:17-29 EEC2:17-27 EEC2:17-24 T400, T500, T550 EEC1:5TC-15 EEC1:5-13 EEC1:5TC-9 EEC1:5-18 EEC2:17TC-18 EEC2:17TC-16 EEC2:17TC-15 TC: temperature compensated
Typical Manufacturing Process for  Sintered  Sm-Co Magnets Ball milling or Jet milling  To ~ 2-5   m Sintering, Solution and  Heat treatment Pressing Raw Materials Sm, Co, Fe,Cu, Zr (2:17) Sm, Co (1:5) Crushing to <500   m Induction Melting Magnetizing  &  Testing Grinding, lapping, honing,  Or wire EDM Machining
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Properties of SmCo 5  Magnet Demagnetization Curves of  SmCo 5  Magnet
[object Object],[object Object],[object Object],[object Object],[object Object],Properties of  SmCo 2:17 magnets High Energy SmCo 2:17 magnets
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
Reversible temperature coefficient  ,[object Object],[object Object],[object Object],[object Object],[object Object], Br Br  T 1 X  100%
Temperature compensated Sm-Co 2:17 magnets *RTC: Reversible temperature coefficient RTC of B r  is calculated within the temperature range –50 to +150 o C Sm 2 TM 17 (Sm,Gd) 2 TM 17 Gd 2 TM 17 Grades 2:17-24 (BH) max RTC* of B r Comment 24 MGOe -0.035 %/ o C -0.02 %/ o C -0.001 %/ o C No comp Some comp 2:17TC-18 18 MGOe 2:17TC-16 16 MGOe Full comp H  (kOe)
Temperature compensated RE-Co 1:5 magnets ,[object Object],[object Object],*RTC: Reversible temperature coefficient EEC 1:5TC-15 EEC 1:5TC-13 EEC 1:5TC-9 Grades EEC 1:5-18 (BH) max RTC* of B r Comment 18 MGOe -0.04 %/ o C -0.03 %/ o C -0.02 %/ o C no compensation some compensation 15 MGOe 13 MGOe some compensation 9 MGOe -0.001 %/ o C full compensation
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
High temperature magnets ,[object Object],[object Object],[object Object]
High temperature magnets T M : Maximum operating temperature at which magnets still have a straight-line demagnetization curve   Grades   B r   (kG)   (BH) max  (MGOe)  T M  ( o C) EEC 24-T400  10.2  24  400 EEC 21-T400  9.5  21  400 EEC 20-T500  9.2  20  500 EEC 18-T500  8.7  18  500 EEC 16-T550  8.5  16  550 EEC 15-T550  8.0  15  550
More high temperature magnets with T M  = 400 o C Grade B r H c (BH) max H ci RTC of B r (kG) (kOe) (MGOe) (kOe) % 9500H 9500 9.03 21.3 >25 -0.035 9250H 9250 8.79 20.2 >25 -0.030 9000H 9000 8.55 19.2 >25 -0.025 8750H 8750 8.27 18.0 >25 -0.020 8500H 8500 8.03 17.0 >25 -0.018 8250H 8250 7.80 16.0 >25 -0.015 8000H 8000 7.56 15.1 >25 -0.010 7750H 7750 7.32 14.1 >25 -0.007 7500H 7500 7.05 13.2 >25 -0.003 7250H 7250 6.82 12.3 >25 0.001 7000H 7000 6.58 11.5 >20 0.004 6750H 6750 6.35 10.7 >20 0.008
Demagnetization Curves for High Temp. Magnets T M  = 300 o C T M  = 400 o C T M  = 500 o C T M  = 550 o C
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Important Features of High Temperature Magnets
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
a b    EMD //EMD EMD: Easy magnetization direction Cellular microstructure of Sintered SmCo 2:17 Magnets
Long-term Thermal Stability at 300 ° C in Air Thermal Stability
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Outline
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Applications of Sm-Co magnets
Sm-Co Advantage --- Straight-line Demagnetization Curves Application with load line #1: Both magnets are okay to use Application with load line #2: Only magnet #1 is suitable B d1 Magnet #1: Sm-Co Load line 2 B r H c 0 Knee Load line 1 B d2 H d1 H d2 B r H c Magnet #2: Comparison magnet
Traveling Wave Tube Amplifier (TWTA) Towed Decoys  could improve survivability of current military Aircraft ,[object Object],[object Object],[object Object],0.545 T Axial Field (T) Position  (inch)
Sm-Co Magnet for Ion Propulsion   ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Magnetic Coupling Systems Surface Coupling Systems Concentric Coupling Systems
Magnetizing System Such systems can be used for the magnetization of low intrinsic coercivity materials, such as bonded ferrite
Halbach Structures Halbach Dipole Halbach Quadrupole
Some requirements for magnets: Straight-line demagnetization curve up 300 o C, and the for some up to 500 o C  PM-Biased Radial Bearing Design Details
Sm-Co Magnets for Medical Devices Some medical devices require autoclave sterilization, which makes Sm-Co magnets more attractive
Thanks for your attention Contact Information: Jinfang Liu, Ph.D. Vice President of Technology and Engineering Electron Energy Corporation 924 Links Ave, Landisville, PA 17538 717-898-2294 (Phone)  717-459-1004 (Direct Line) 717-898-0660 (Fax)  E-mail: jfl@electronenergy.com

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Sm-Co Permanent Magnets Properties and High Temperature Applications

  • 1. Sm-Co Permanent Magnets and Their Applications Jinfang Liu Electron Energy Corporation
  • 2.
  • 3. Sintered Sm-Co Magnets (Overview) Sm-Co Magnets SmCo 5 type Sm 2 Co 17 type Conventional Sm-Co 2:17 grades High energy Sm-Co 2:17 magnets Sm-Co 2:17 TC materials Conventional Sm-Co 1:5 grades Sm-Co 1:5 TC materials High temperature magnets EEC2:17-31 EEC2:17-29 EEC2:17-27 EEC2:17-24 T400, T500, T550 EEC1:5TC-15 EEC1:5-13 EEC1:5TC-9 EEC1:5-18 EEC2:17TC-18 EEC2:17TC-16 EEC2:17TC-15 TC: temperature compensated
  • 4. Typical Manufacturing Process for Sintered Sm-Co Magnets Ball milling or Jet milling To ~ 2-5  m Sintering, Solution and Heat treatment Pressing Raw Materials Sm, Co, Fe,Cu, Zr (2:17) Sm, Co (1:5) Crushing to <500  m Induction Melting Magnetizing & Testing Grinding, lapping, honing, Or wire EDM Machining
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10. Temperature compensated Sm-Co 2:17 magnets *RTC: Reversible temperature coefficient RTC of B r is calculated within the temperature range –50 to +150 o C Sm 2 TM 17 (Sm,Gd) 2 TM 17 Gd 2 TM 17 Grades 2:17-24 (BH) max RTC* of B r Comment 24 MGOe -0.035 %/ o C -0.02 %/ o C -0.001 %/ o C No comp Some comp 2:17TC-18 18 MGOe 2:17TC-16 16 MGOe Full comp H (kOe)
  • 11.
  • 12.
  • 13.
  • 14. High temperature magnets T M : Maximum operating temperature at which magnets still have a straight-line demagnetization curve Grades B r (kG) (BH) max (MGOe) T M ( o C) EEC 24-T400 10.2 24 400 EEC 21-T400 9.5 21 400 EEC 20-T500 9.2 20 500 EEC 18-T500 8.7 18 500 EEC 16-T550 8.5 16 550 EEC 15-T550 8.0 15 550
  • 15. More high temperature magnets with T M = 400 o C Grade B r H c (BH) max H ci RTC of B r (kG) (kOe) (MGOe) (kOe) % 9500H 9500 9.03 21.3 >25 -0.035 9250H 9250 8.79 20.2 >25 -0.030 9000H 9000 8.55 19.2 >25 -0.025 8750H 8750 8.27 18.0 >25 -0.020 8500H 8500 8.03 17.0 >25 -0.018 8250H 8250 7.80 16.0 >25 -0.015 8000H 8000 7.56 15.1 >25 -0.010 7750H 7750 7.32 14.1 >25 -0.007 7500H 7500 7.05 13.2 >25 -0.003 7250H 7250 6.82 12.3 >25 0.001 7000H 7000 6.58 11.5 >20 0.004 6750H 6750 6.35 10.7 >20 0.008
  • 16. Demagnetization Curves for High Temp. Magnets T M = 300 o C T M = 400 o C T M = 500 o C T M = 550 o C
  • 17.
  • 18.
  • 19. a b  EMD //EMD EMD: Easy magnetization direction Cellular microstructure of Sintered SmCo 2:17 Magnets
  • 20. Long-term Thermal Stability at 300 ° C in Air Thermal Stability
  • 21.
  • 22.
  • 23. Sm-Co Advantage --- Straight-line Demagnetization Curves Application with load line #1: Both magnets are okay to use Application with load line #2: Only magnet #1 is suitable B d1 Magnet #1: Sm-Co Load line 2 B r H c 0 Knee Load line 1 B d2 H d1 H d2 B r H c Magnet #2: Comparison magnet
  • 24.
  • 25.
  • 26.
  • 27. Magnetizing System Such systems can be used for the magnetization of low intrinsic coercivity materials, such as bonded ferrite
  • 28. Halbach Structures Halbach Dipole Halbach Quadrupole
  • 29. Some requirements for magnets: Straight-line demagnetization curve up 300 o C, and the for some up to 500 o C PM-Biased Radial Bearing Design Details
  • 30. Sm-Co Magnets for Medical Devices Some medical devices require autoclave sterilization, which makes Sm-Co magnets more attractive
  • 31. Thanks for your attention Contact Information: Jinfang Liu, Ph.D. Vice President of Technology and Engineering Electron Energy Corporation 924 Links Ave, Landisville, PA 17538 717-898-2294 (Phone) 717-459-1004 (Direct Line) 717-898-0660 (Fax) E-mail: jfl@electronenergy.com