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INTRODUCTION TO WET PROCESSING
LECTURE - 1
By Robel L.
Faculty of Textile and Fashion Technology
Aksum University
2020
2/20/2020 1
TEXTILE WET PROCESSING
 There is far more to go after fabric production to make the
substrates suitable for end-use and hence satisfy customer
requirements.
 The substrates lack attractiveness or aesthetics and serviceability or
adequate performance which are required for their effective
utilization.
 Attractiveness and improvement of properties are achieved through
pretreatment, coloration and finishing of the textile materials.
2/20/2020 2
Pretreatment Coloration Finishing
Pretreatment: Removal of impurities for smooth chemical processing
Coloration: Application of color using dyes/pigments for attractiveness
Finishing: Improvement of end use property by applying finishes
2/20/2020 3
PRETREATMENT OF TEXTILE MATERIALS
 Grey goods are contaminated with impurities
 Cellulosic fibers (cotton) contain various impurities: fats, waxes,
protineous matters, etc.
 Wool fiber contains wool wax (grease), inorganic salts and other dirt
matters.
 The serecin gum in silk fiber is also considered as impurity.
 Synthetic fibers such as polyester and nylon are contaminated with
spin finish lubricants.
 Besides inherent fiber impurities textile substrates are contaminated
with added impurities which are used in facilitating the conversion
process from fiber to fabric.
 These include size and lubrication oils.
2/20/2020 4
What is the fiber forming polymer of cotton, wool, silk
polyester and nylon?
5
Pretreatment process of textile material are:
 SINGEING: Burning of protruding fibers
 DESIZING: Removal of size material
 SCOURING: Removal of oil and wax based impurities
 BLEACHING: Removal of coloring matters
 MERCERIZATION: Treatment with caustic soda for value addition
 CARBONIZING: Removal of vegetable matters in wool fiber
 DEGUMMING: Removal of silk gum in silk fiber
cont...
Cotton fiber composition
2/20/2020 6
Composition of cotton
Natural impurities
Constituent %
Cellulose 88
Waxes 0.5
Pectins 0.7
Proteins 1.1
Coloring matter 0.5
Mineral Matter 1.0
Moisture 8.0
2/20/2020 7
Fats and Waxes
Fats are Triglycerides of fatty acids
FATS CAN BE EASILY SAPONIFIED BY NaOH INTO SOAPAND GLYCEROL
Stearic acid
Waxes are (Esters of fatty alcohol)
C17H35COOH + C28H57OH = C17H35COOC28H57
Stearic acid Montanyl alcohol
WAXES ARE DIFFICULT TO SAPONIFY BY ALKALI
2/20/2020 8
FATTYACIDS AND FATTYALCOHOLS FOUND IN COTTON FIBRE
Fatty acids
 Stearic acid
 Palmitic acid
 Oleic acid
Fatty alcohols
 Gossipyl alcohol (C30H61OH)
 Ceryl alcohol (C26H53OH)
 Montanyl alcohol (C28H57OH)
2/20/2020 9
Pectins
 Derivatives of pectic acid
 Polymer of high molecular weight
 Composed of Galactouronic acid
 Some COOH groups are present as Ca and Mg salts
 Free acid and Ca and Mg salts are insoluble in water
2/20/2020 10
Proteins
 Nitrogenous compounds
 Present in primary wall and Lumen
 Some of the amino acids identified are
Leucine
Valine
Proline
Alanine etc.
 Yellowish (Creamish) colour of cotton is related to Proteins and
Coloring matter
2/20/2020 11
Coloring matter
 Color pigments present are
 3,5,7,2’, 4’ Penta hydroxy flavone (Morrin)
 3,5,7,8,3’,4’ Hexa hydroxy flavone (Gossypetine)
2/20/2020 12
Added Impurities
Sizing agents:
 Agents used to give protective coating to warp threads
 Minimize the breaking of warp threads during weaving
 Improve weaving productivity.
 The operation is known as sizing.
 Starch is one of the most important sizing agent for cotton
 Sizing agents and
 Oil stains
2/20/2020 13
 Inhibit penetration of chemicals used in coloration/finishing
 Interfere with coloration/finishing processes
 Reduce the visual appearance of textiles
 Unless the impurities are removed subsequent chemical
processing can not be smoothly accomplished.
 A procedure mainly concerned with the removal of natural
as well as added impurities in fabric to a level necessary
for good absorbency and whiteness by utilizing minimum
time, energy and chemicals as well as water.
Influence of impurity
Chemical Pretreatment
2/20/2020 14
PREPARATION BEFORE PRETREATMENT
Inspection
 The most important point is to obtain fabrics "free from exterior impurities" in
order to achieve smooth and trouble free results in the subsequent finishing
systems
 It is checked whether the grey fabrics are in conformity with standards, and all
weaving faults are marked out.
Mechanical cleaning of fabric
 Brushing to remove the short and loose fibers from the surface of the cloth.
 Shearing is cutting of the loose strands of fibers from fabric with a sharp
edged razor or scissors.
2/20/2020 15
Principles of Brushing
 Fabric moves in contact with Cylinders (2-4) covered with fine
bristles (Brush Roller).
 The loose threads are picked up by the brush rollers.
 Removed by vacuum.
 In this operation only loose threads are removed
 Threads attached to the fabric surface removed by shearing/cropping
operation.
2/20/2020 16
Principles of Cropping
 Achieved by raising the loose thread with the help of brush
roller and cutting it close to the fabric surface with the help of
spiral blades.
2/20/2020 17
Purposes of Preparatory Processes
To remove Natural and added impurities
To impart certain desirable properties (water absorbency)
To improve the appearance of fabric (whiteness)
To make it suitable for subsequent processes like dyeing,
printing finishing
2/20/2020 18
Principle of preparatory processes
 The impurity are insoluble in water
 Conversion of water insoluble impurities to water soluble form.
 Chemical reactions involved (In case of Cotton)
 Hydrolysis
 Oxidation
 The choice of chemicals depends on chemical nature of
impurity.
2/20/2020 19
END
2/20/2020 20

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Introduction lecture 1

  • 1. INTRODUCTION TO WET PROCESSING LECTURE - 1 By Robel L. Faculty of Textile and Fashion Technology Aksum University 2020 2/20/2020 1
  • 2. TEXTILE WET PROCESSING  There is far more to go after fabric production to make the substrates suitable for end-use and hence satisfy customer requirements.  The substrates lack attractiveness or aesthetics and serviceability or adequate performance which are required for their effective utilization.  Attractiveness and improvement of properties are achieved through pretreatment, coloration and finishing of the textile materials. 2/20/2020 2
  • 3. Pretreatment Coloration Finishing Pretreatment: Removal of impurities for smooth chemical processing Coloration: Application of color using dyes/pigments for attractiveness Finishing: Improvement of end use property by applying finishes 2/20/2020 3
  • 4. PRETREATMENT OF TEXTILE MATERIALS  Grey goods are contaminated with impurities  Cellulosic fibers (cotton) contain various impurities: fats, waxes, protineous matters, etc.  Wool fiber contains wool wax (grease), inorganic salts and other dirt matters.  The serecin gum in silk fiber is also considered as impurity.  Synthetic fibers such as polyester and nylon are contaminated with spin finish lubricants.  Besides inherent fiber impurities textile substrates are contaminated with added impurities which are used in facilitating the conversion process from fiber to fabric.  These include size and lubrication oils. 2/20/2020 4 What is the fiber forming polymer of cotton, wool, silk polyester and nylon?
  • 5. 5 Pretreatment process of textile material are:  SINGEING: Burning of protruding fibers  DESIZING: Removal of size material  SCOURING: Removal of oil and wax based impurities  BLEACHING: Removal of coloring matters  MERCERIZATION: Treatment with caustic soda for value addition  CARBONIZING: Removal of vegetable matters in wool fiber  DEGUMMING: Removal of silk gum in silk fiber cont...
  • 7. Composition of cotton Natural impurities Constituent % Cellulose 88 Waxes 0.5 Pectins 0.7 Proteins 1.1 Coloring matter 0.5 Mineral Matter 1.0 Moisture 8.0 2/20/2020 7
  • 8. Fats and Waxes Fats are Triglycerides of fatty acids FATS CAN BE EASILY SAPONIFIED BY NaOH INTO SOAPAND GLYCEROL Stearic acid Waxes are (Esters of fatty alcohol) C17H35COOH + C28H57OH = C17H35COOC28H57 Stearic acid Montanyl alcohol WAXES ARE DIFFICULT TO SAPONIFY BY ALKALI 2/20/2020 8
  • 9. FATTYACIDS AND FATTYALCOHOLS FOUND IN COTTON FIBRE Fatty acids  Stearic acid  Palmitic acid  Oleic acid Fatty alcohols  Gossipyl alcohol (C30H61OH)  Ceryl alcohol (C26H53OH)  Montanyl alcohol (C28H57OH) 2/20/2020 9
  • 10. Pectins  Derivatives of pectic acid  Polymer of high molecular weight  Composed of Galactouronic acid  Some COOH groups are present as Ca and Mg salts  Free acid and Ca and Mg salts are insoluble in water 2/20/2020 10
  • 11. Proteins  Nitrogenous compounds  Present in primary wall and Lumen  Some of the amino acids identified are Leucine Valine Proline Alanine etc.  Yellowish (Creamish) colour of cotton is related to Proteins and Coloring matter 2/20/2020 11
  • 12. Coloring matter  Color pigments present are  3,5,7,2’, 4’ Penta hydroxy flavone (Morrin)  3,5,7,8,3’,4’ Hexa hydroxy flavone (Gossypetine) 2/20/2020 12
  • 13. Added Impurities Sizing agents:  Agents used to give protective coating to warp threads  Minimize the breaking of warp threads during weaving  Improve weaving productivity.  The operation is known as sizing.  Starch is one of the most important sizing agent for cotton  Sizing agents and  Oil stains 2/20/2020 13
  • 14.  Inhibit penetration of chemicals used in coloration/finishing  Interfere with coloration/finishing processes  Reduce the visual appearance of textiles  Unless the impurities are removed subsequent chemical processing can not be smoothly accomplished.  A procedure mainly concerned with the removal of natural as well as added impurities in fabric to a level necessary for good absorbency and whiteness by utilizing minimum time, energy and chemicals as well as water. Influence of impurity Chemical Pretreatment 2/20/2020 14
  • 15. PREPARATION BEFORE PRETREATMENT Inspection  The most important point is to obtain fabrics "free from exterior impurities" in order to achieve smooth and trouble free results in the subsequent finishing systems  It is checked whether the grey fabrics are in conformity with standards, and all weaving faults are marked out. Mechanical cleaning of fabric  Brushing to remove the short and loose fibers from the surface of the cloth.  Shearing is cutting of the loose strands of fibers from fabric with a sharp edged razor or scissors. 2/20/2020 15
  • 16. Principles of Brushing  Fabric moves in contact with Cylinders (2-4) covered with fine bristles (Brush Roller).  The loose threads are picked up by the brush rollers.  Removed by vacuum.  In this operation only loose threads are removed  Threads attached to the fabric surface removed by shearing/cropping operation. 2/20/2020 16
  • 17. Principles of Cropping  Achieved by raising the loose thread with the help of brush roller and cutting it close to the fabric surface with the help of spiral blades. 2/20/2020 17
  • 18. Purposes of Preparatory Processes To remove Natural and added impurities To impart certain desirable properties (water absorbency) To improve the appearance of fabric (whiteness) To make it suitable for subsequent processes like dyeing, printing finishing 2/20/2020 18
  • 19. Principle of preparatory processes  The impurity are insoluble in water  Conversion of water insoluble impurities to water soluble form.  Chemical reactions involved (In case of Cotton)  Hydrolysis  Oxidation  The choice of chemicals depends on chemical nature of impurity. 2/20/2020 19