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Material Safety Data Sheet
HALS 292
1. Identification
Product identifier used on the label
HALS 292
Recommended use of the chemical and restriction on use
Recommended use*: stabilizer; polyurethane component
Unsuitable for use: This material is not intended for use in products for which prolonged
contact with mucous membranes, body fluids or abraded skin, or implantation within the
human body, is specifically intended, unless the finished product has been tested in
accordance with nationally and internationally applicable safety testing requirements. Because
of the wide range of such potential uses, we are not able to recommend this material as safe
and effective for such uses and assume no liability for such uses.
Suitable for use in industrial sector: Polymers industry; chemical industry
Details of the supplier of the safety data sheet
Dongguan Baoxu Chemical Technology.,ltd.
Caijin Business Bldg DongGuan CN 523071
+86 0769 22821082 Fax 86 0769 22821083
www.additivesforpolymer.com
info@additivesforpolymer.com
Emergency telephone number
Other means of identification
Chemical family: Sterically hindered amine light stabilizer
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Classification of the product
Skin Sens.
Aquatic
Acute
1A
1
Skin sensitization
Hazardous to the aquatic environment - acute
P280 Wear protective gloves.
P 273 Avoid release to the environment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplac
e.
Aquatic Chronic
Label elements Hazardous to the aquatic environment - chronic
Pictogram:
Signal Word:
Warning
Hazard Statement:
H317
H400
H410
May cause an allergic skin reaction
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Precautionary Statements (Prevention):
1
Precautionary Statements (Response):
P333+ P311 If skin irritation or rash occurs: Call a POISON CENTER or
doctor/physician.
P303 + P352 IF ON SKIN (on hair): Wash with plenty of soap and
water.P391 Collect spillage.
P362 + P364 Take off contaminated clothing and wash before reuse.
Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazards not otherwise classified
If applicable information is provided in this section on other hazards which do not
result in classification but which may contribute to the overall hazards of the
substance or mixture.
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200
Emergency overview
CAUTION:
Skin sensitizer.
Avoid contact with the substance.
Use NIOSH approved respirator as needed to mitigate exposure.
Wear protective clothing.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200 CAS Number Content (W/W) Chemical name
41556-26-7 50.0 - 100.0 % bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate
82919-37-7 20.0 - 50.0 % Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200 CAS Number Content (W/W) Chemical name
41556-26-7 50.0 - 100.0 % bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate
82919-37-7 20.0 - 50.0 % Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
4. First-Aid Measures Description of
first aid measures General advice:
Immediately remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek
medical attention.
If on skin:
Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes.
If irritation develops, seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
If irritation develops, seek medical attention.
If swallowed:
Rinse mouth immediately with water. Never induce vomiting or give anything by mouth if the
victim is unconscious or having convulsions. Do not induce vomiting due to aspiration hazard.
Seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the
labelling (see section 2) and/or in section 11.
Further important symptoms and effects are so far not known.
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing
media: water spray, dry
powder, foam
Unsuitable extinguishing media for safety
reasons: water jet
Special hazards arising from the substance or mixture
Hazards during fire-fighting: harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in
case of fire.
Advice for fire-fighters
Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Keep people away and stay on the upwind side. Breathing
protection required.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in
accordance with regulations.
7. Handling and Storage
Precautions for safe handling
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
No special precautions necessary.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a
cool place.
The packed product is not damaged by low temperatures or by frost.
8. Exposure Controls/Persona 丨 Protection
Personal protective equipment Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent)
organic vapour/particulate respirator.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Safety glasses with side-shields.
Body protection:
Impermeable protective clothing
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Handle in accordance with
good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Form: liquid
Odour: ester-like
Odour threshold: No applicable information available.
Colour: light yellow
pH value: 8.4 (1 %(m), 20 - 25 °C) (as suspension)
glass transition -57.8 °C (1,013 hPa) (Directive 92/69/EEC, A.1)
temperature:
boiling temperature: > 300 °C (Directive 92/69/EEC, A.2)
Sublimation point: No applicable information available.
Flash point: 209.5 °C (Directive 92/69/EEC, A.9)
Flammability: not applicable
Lower explosion limit: For liquids not relevant for classification
and labelling. The lower explosion point
may be 5 - 15 °C below the flash point.
Upper explosion limit: For liquids not relevant for classification
and labelling.
Autoignition: 380 °C (DIN 51794)
Vapour pressure: 0.000001 hPa (20 °C) (OECD Guideline 104)
Density: 0.993 g/cm3 (20 °C) (OECD Guideline 109)
Relative density: 0.99 (OECD Guideline 109)
Vapour density: No applicable information available.
Partitioning coefficient n- 2.37 - 2.77 (25 °C) (OECD Guideline 107)
octanol/water (log Pow):
Self-ignition Based on its structural properties the
temperature: product is not classified as self-igniting.
Thermal decomposition: 325 °C
No decomposition if stored and handled as
prescribed/indicate
d.Viscosity, dynamic: 400 mPa.s ( 20 °C)
Viscosity, kinematic: 478 mm2/s ( 20 °C) (Capilliary viscometer)
Particle size:
The substance / product is marketed or
used in a non solid or granular form.
% volatiles: 0.5 %
Solubility in water: 21.5 - 29.8 mg/l ( 21 °C)
Solubility (qualitative): miscible
solve 门 t(s): organic solvents,
Molar mass: 508.79 g/mol
Evaporation rate: Value can be approximated from Henry's
Law Constant or vapor pressure.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Oxidizing properties:
Based on its structural properties the product is not classified as
oxidizing. Minimum ignition energy:
No data
available.
Reactions with
water/air:
Formation of
flammable
gases:
Reaction with: water
Flammable gases: no
Toxic gases: no
Corrosive gases: no
Smoke or fog: no
Peroxides: no
Reaction with: air
Flammable gases: no
Toxic gases: no
Corrosive gases: no
Smoke or fog: no
Peroxides: no
Remarks: Form
spresence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
The product is chemically stable.
Conditions to avoid
No special precautions other than good housekeeping of chemicals.
Incompatible materials
strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and
handled as prescribed/indicated.
Thermal decomposition:
325 °C
No decomposition if stored and handled as prescribed/indicated.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a
route of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Of low toxicity after single ingestion.
Oral
Type of value: LD50 Species: rat
Value: 3,230 mg/kg (Conventional method)
Inhalation not determined
Dermal
not determined
Assessment other acute effects Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected
after a single exposure.
Irritation / corrosion
Assessment of irritating effects: Not irritating to eyes and skin. Skin
Species: rabbit
Result: non-irritant
Method: OPP 81-5 (EPA-Guideline)
Eye
Species: rabbit Result: non-irritant
Sensitization Species: guinea pig Result: sensitizing Method: OECD Guideline 406
Aspiration Hazard No aspiration hazard expected.
Chronic Toxicity/Effects
Repeated dose toxicity
Assessment of repeated dose toxicity: No known chronic effects. Genetic toxicity
Genetic toxicity in vitro: Ames-test negative
Carcinogenicity
Assessment of carcinogenicity: None of the components in this product at concentrations
greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen.
The whole of the information assessable provides no indication of a carcinogenic effect.
Reproductive toxicity
Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic
effect on reproduction.
Experiences in humans Sensitizing effects by skin contact.
Other Information Tested as a preparation.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11.
Further important symptoms and effects are so far not known.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
May cause long-term adverse effects in the aquatic environment.
Very toxic (acute effect) to aquatic organisms. The inhibition of the degradation activity of
activated sludge is not anticipated when introduced to biological treatment plants in
appropriate low concentrations.
Toxicity to fish
LC50 (96 h) 0.97 mg/l, Lepomis macrochirus (OECD Guideline 203)
LC50 (96 h) 7.9 mg/l, Oncorhynchus mykiss (OECD Guideline 203)
LC50 (96 h) 0.9 mg/l, Brachydanio rerio (OECD Guideline 203, semistatic)
The details of the toxic effect relate to the nominal concentration. The product has low
solubility in the test medium. An aqueous solution prepared with solubilizers has been tested.
Aquatic invertebrates
EC50 (24 h) 20 mg/l, Daphnia magna (OECD Guideline 202, part 1)
Aquatic plants
EC50 (72 h) 1.68 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)
The details of the toxic effect relate to the nominal concentration. The product has low
solubility in the test medium. An aqueous solution prepared with solubilizers has been tested.
Chronic toxicity to aquatic invertebrates
No observed effect concentration (21 d) 1 mg/l, Daphnia magna (OECD Guideline 211,
semistatic) The details of the toxic effect relate to the nominal concentration. The product has
low solubility in the test medium. An aqueous solution prepared with solubilizers has been
Microorganisms/Effect on activated sludge
Toxicity to microorganisms
OECD Guideline 209 aerobic
activated sludge, domestic/EC50 (3 h): > 100 mg/l
Persistence and degradability
Assessment biodegradation and elimination (H2O)
Not readily biodegradable (by OECD criteria). Moderately/partially biodegradable.
Elimination information
38 % DOC reduction (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic,
aerobic microorganisms)
Assessment of stability in water
In contact with water the substance will hydrolyse slowly.
Bioaccumulative potential
Assessment bioaccumulation potential Accumulation in organisms is not to be
expected.
Mobility in soil
Assessment transport between environmental compartments
The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is expected.
Additional information
Other ecotoxicological advice:
Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity
in activated sludge is not to be anticipated during correct introduction of low concentrations.
13. Disposal considerations Waste disposal of substance:
Dispose of in accordance with national, state and local regulations. Do not discharge into
drain/surface waters/groundwater
It is the waste generator's responsibility to determine if a particular waste is hazardous under
RCRA. Container disposal:
Recommend crushing, puncturing or other means to prevent unauthorized use of used
containers. Dispose of in accordance with national, state and local regulations.
14. Transport Information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-
PIPERIDYL)SEBACATE)
Air transport
IATA/ICAO
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4-
PIPERIDYL)SEBACATE)
15. Regulatory Information
Federal Regulations
Registration status:
Chemical TSCA, US released / listed
EPCRA 311/312 (Hazard categories): Acute;
NFPA Hazard codes:
Health : 2 Fire: 1 Reactivity: 0 Special:
HMIS III rating
Health: 2 Flammability: 1 Physical hazard:0 (Essentially no hazard )
16. Other Information
SDS Prepared by:
Hals 292 tinuvin 292 cas 41556 26-7 cas 82919-37-7 safety data sheet msds sds baoxu chemical

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Hals 292 tinuvin 292 cas 41556 26-7 cas 82919-37-7 safety data sheet msds sds baoxu chemical

  • 1. Material Safety Data Sheet HALS 292 1. Identification Product identifier used on the label HALS 292 Recommended use of the chemical and restriction on use Recommended use*: stabilizer; polyurethane component Unsuitable for use: This material is not intended for use in products for which prolonged contact with mucous membranes, body fluids or abraded skin, or implantation within the human body, is specifically intended, unless the finished product has been tested in accordance with nationally and internationally applicable safety testing requirements. Because of the wide range of such potential uses, we are not able to recommend this material as safe and effective for such uses and assume no liability for such uses. Suitable for use in industrial sector: Polymers industry; chemical industry Details of the supplier of the safety data sheet Dongguan Baoxu Chemical Technology.,ltd. Caijin Business Bldg DongGuan CN 523071 +86 0769 22821082 Fax 86 0769 22821083 www.additivesforpolymer.com info@additivesforpolymer.com Emergency telephone number Other means of identification Chemical family: Sterically hindered amine light stabilizer 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Classification of the product Skin Sens. Aquatic Acute 1A 1 Skin sensitization Hazardous to the aquatic environment - acute
  • 2. P280 Wear protective gloves. P 273 Avoid release to the environment. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplac e. Aquatic Chronic Label elements Hazardous to the aquatic environment - chronic Pictogram: Signal Word: Warning Hazard Statement: H317 H400 H410 May cause an allergic skin reaction Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): 1 Precautionary Statements (Response): P333+ P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P303 + P352 IF ON SKIN (on hair): Wash with plenty of soap and water.P391 Collect spillage. P362 + P364 Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: Skin sensitizer. Avoid contact with the substance. Use NIOSH approved respirator as needed to mitigate exposure. Wear protective clothing. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 41556-26-7 50.0 - 100.0 % bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate 82919-37-7 20.0 - 50.0 % Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
  • 3. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 41556-26-7 50.0 - 100.0 % bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate 82919-37-7 20.0 - 50.0 % Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention. If swallowed: Rinse mouth immediately with water. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting due to aspiration hazard. Seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam Unsuitable extinguishing media for safety reasons: water jet
  • 4. Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Keep people away and stay on the upwind side. Breathing protection required. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Precautions for safe handling No special measures necessary provided product is used correctly. Protection against fire and explosion: No special precautions necessary. Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. The packed product is not damaged by low temperatures or by frost. 8. Exposure Controls/Persona 丨 Protection Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.
  • 5. Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses with side-shields. Body protection: Impermeable protective clothing General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: liquid Odour: ester-like Odour threshold: No applicable information available. Colour: light yellow pH value: 8.4 (1 %(m), 20 - 25 °C) (as suspension) glass transition -57.8 °C (1,013 hPa) (Directive 92/69/EEC, A.1) temperature: boiling temperature: > 300 °C (Directive 92/69/EEC, A.2) Sublimation point: No applicable information available. Flash point: 209.5 °C (Directive 92/69/EEC, A.9) Flammability: not applicable Lower explosion limit: For liquids not relevant for classification and labelling. The lower explosion point may be 5 - 15 °C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Autoignition: 380 °C (DIN 51794) Vapour pressure: 0.000001 hPa (20 °C) (OECD Guideline 104) Density: 0.993 g/cm3 (20 °C) (OECD Guideline 109) Relative density: 0.99 (OECD Guideline 109) Vapour density: No applicable information available. Partitioning coefficient n- 2.37 - 2.77 (25 °C) (OECD Guideline 107) octanol/water (log Pow): Self-ignition Based on its structural properties the temperature: product is not classified as self-igniting. Thermal decomposition: 325 °C No decomposition if stored and handled as prescribed/indicate d.Viscosity, dynamic: 400 mPa.s ( 20 °C) Viscosity, kinematic: 478 mm2/s ( 20 °C) (Capilliary viscometer) Particle size: The substance / product is marketed or used in a non solid or granular form. % volatiles: 0.5 % Solubility in water: 21.5 - 29.8 mg/l ( 21 °C) Solubility (qualitative): miscible solve 门 t(s): organic solvents, Molar mass: 508.79 g/mol Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section.
  • 6. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: No corrosive effect on metal. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Minimum ignition energy: No data available. Reactions with water/air: Formation of flammable gases: Reaction with: water Flammable gases: no Toxic gases: no Corrosive gases: no Smoke or fog: no Peroxides: no Reaction with: air Flammable gases: no Toxic gases: no Corrosive gases: no Smoke or fog: no Peroxides: no Remarks: Form spresence of water. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions. The product is chemically stable. Conditions to avoid No special precautions other than good housekeeping of chemicals. Incompatible materials strong acids, strong bases, strong oxidizing agents Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: 325 °C No decomposition if stored and handled as prescribed/indicated.
  • 7. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Of low toxicity after single ingestion. Oral Type of value: LD50 Species: rat Value: 3,230 mg/kg (Conventional method) Inhalation not determined Dermal not determined Assessment other acute effects Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Irritation / corrosion Assessment of irritating effects: Not irritating to eyes and skin. Skin Species: rabbit Result: non-irritant Method: OPP 81-5 (EPA-Guideline) Eye Species: rabbit Result: non-irritant Sensitization Species: guinea pig Result: sensitizing Method: OECD Guideline 406 Aspiration Hazard No aspiration hazard expected. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No known chronic effects. Genetic toxicity
  • 8. Genetic toxicity in vitro: Ames-test negative Carcinogenicity Assessment of carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. The whole of the information assessable provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effect on reproduction. Experiences in humans Sensitizing effects by skin contact. Other Information Tested as a preparation. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: May cause long-term adverse effects in the aquatic environment. Very toxic (acute effect) to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish LC50 (96 h) 0.97 mg/l, Lepomis macrochirus (OECD Guideline 203) LC50 (96 h) 7.9 mg/l, Oncorhynchus mykiss (OECD Guideline 203) LC50 (96 h) 0.9 mg/l, Brachydanio rerio (OECD Guideline 203, semistatic) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Aquatic invertebrates EC50 (24 h) 20 mg/l, Daphnia magna (OECD Guideline 202, part 1) Aquatic plants EC50 (72 h) 1.68 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Chronic toxicity to aquatic invertebrates No observed effect concentration (21 d) 1 mg/l, Daphnia magna (OECD Guideline 211, semistatic) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been
  • 9. Microorganisms/Effect on activated sludge Toxicity to microorganisms OECD Guideline 209 aerobic activated sludge, domestic/EC50 (3 h): > 100 mg/l Persistence and degradability Assessment biodegradation and elimination (H2O) Not readily biodegradable (by OECD criteria). Moderately/partially biodegradable. Elimination information 38 % DOC reduction (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, aerobic microorganisms) Assessment of stability in water In contact with water the substance will hydrolyse slowly. Bioaccumulative potential Assessment bioaccumulation potential Accumulation in organisms is not to be expected. Mobility in soil Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected. Additional information Other ecotoxicological advice: Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Do not discharge into drain/surface waters/groundwater It is the waste generator's responsibility to determine if a particular waste is hazardous under RCRA. Container disposal: Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. Dispose of in accordance with national, state and local regulations. 14. Transport Information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport
  • 10. IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4- PIPERIDYL)SEBACATE) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains BIS-(1,2,2,6,6-PENTAMETHYL-4- PIPERIDYL)SEBACATE) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Acute; NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 0 Special: HMIS III rating Health: 2 Flammability: 1 Physical hazard:0 (Essentially no hazard ) 16. Other Information SDS Prepared by: