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SECTION 1
Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name : Sodium lauryl ether sulfate
Other Names : Sodium Fatty Alcohol Ether Sulfate, Sodium laureth sulphate, Sodium
Polyoxyethylene, Fatty Alcohol Sulfate
CAS-No. : 68585-34-2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Shampoo, soap, foam compositions, detergent raw materials.
1.3 Details of the supplier of the safety datasheet
Company Address : Prakash Chemicals International Pvt Ltd.
"Prakash House", 39/40-
Krishna Estate, Opp BIDC,
Gorwa, Vadodara, India.
1.4 Emergency telephone number
Emergency Phone # : +91 265 3926000
SECTION 2
Hazards identification
2.1 Classification of the substance or mixture
Hazard Class & Category Code(s) Hazard Statement Code(s) Hazard Statement Phrase(s)
Skin corrosion Category 1C H315 Causes skin irritation
Eye damage Category 1 H319 Causes serious eye irritation
Acute aquatic toxicity Category 2 H402 Toxic to aquatic life
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 Label elements
Labeling according to CLP/GHS
Pictogram Signal Word Code(s) Hazard Statement Code(s) Suppl. Hazard Statement
Code(s)
GHS07 H302
Harmful if swallowed
Precautionary statement(s)
P264 : Wash hands thoroughly after handling.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection
Response Precautionary Statement(s)
P264 : Wash hands thoroughly after handling.
P302 + P352 : IF ON SKIN: Wash with plenty water.
P332 + P313 : If skin irritation occurs: Get medical advice/attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P337 + P313 : If eye irritation persists: Get medical advice/attention
Storage precautionary statements
No special requirement.
Disposal precautionary statements
P501 : Dispose of contents/container according to relevant local and national
regulations.
2.3 Physical and Chemical hazards
It is white or light yellow gelatinous paste without peculiar smell.The product is not flammable, no
special danger.
2.4 Health hazards
Causes skin irritation. Causes serious eye irritation.
2.5 Environment hazards
Harmful to aquatic life.
2.6 Other hazards
No information available.
SECTION 3
Composition/information on ingredients
Component Name CAS Number %(w/w)
Sodium lauryl ether sulfate 68585-34-2 70 % min
Water 7732-18-5 29% max
Others - 1%
SECTION 4
First aid measures
Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses,if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
Skin contact: In case of contact with melts, immediately flush with cold water. If irritation
persists,get medical advice/attention. Take off contaminated clothing and
wash it before reuse.
Inhalation: If discomfort occurs after inhaling vapours from processing or thermal
decomposition, remove to a place where air is fresh.
Ingestion: Rinse mouth. Do not induce vomiting without professional instruction. Get
medical attention if discomfort.
Acute and delayed effect: Acute effect: Causes skin irritation. Causes serious eye irritation.
Delayed effect: Not found.
Personal protective Recommend wearing protective gloves (e.g. rubber gloves).
Equipment: Wear safety goggles when exposure limits are exceeded or liquid may splash.
Further medical: No special requirements
SECTION 5
Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
In case of a fire, use dry chemical for small fire; water fog, foam or CO2 for large fire. Do NOT use water jet
which may make molten material splash. Seek advice from local fire-fighting authority.
5.2 Special hazards arising from chemical
The product is not flammable. No special danger is found. It may release smoke, carbon monoxide, carbon
dioxide, hydrogen sulphide and other hazardous gas from burning.
5.3 Special fire fighting Method
Remove all ignition sources when this can be done without any risk.
Extinguish fire from upwind, and the fire extinguishing method should be appropriate to the situation in
the surroundings. Cool surrounding facilities, etc. with water spray. Remove containers from fire area if it
can be done without risk.
5.4 Special protective actions for fire-fighters
Wear self contained breathing apparatus and protective gear.
SECTION 6
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective gloves, clothing, safety glasses and mask. Workers should be well trained before handling.
The leakage may cause slipping hazard, so recommend wearing antiskid shoes.
6.2 Emergency procedures
Due to the nature of this product, there is no special requirement.
6.3 Environmental precautions
Keep collected waste out of municipal sewers and open bodies of water. Comply with local and
national laws and regulations.
6.4 Measures for cleaning/ Collection
Small Spill
Mop up or absorb with an inert dry material (e.g. sand) and place in an appropriately
labeled waste disposal container.
Large Spill
Isolate contaminated area and set up a warning board. The persons handling emergency are
recommended wearing protective gloves, clothing, safety glasses and antiskid shoes. Make sure all the
present persons safe. Avoid slipping. Containers should be clearly marked for recycling or disposed as
waste
6.5 Precautions for secondary hazards
Keep collected waste out of municipal sewers and open bodies of water.
SECTION 7
Handling and storage
7.1 Precautions for safe handling
Wash hands thoroughly after handling. Avoid release to the environment. Wear gloves, safety
glasses/mask/antiskid shoes.
7.2 Conditions for safe storage
Requirements to be met by storerooms: Store it in a well-ventilated, cool and dry store room.
Storage temperature should not exceed 50
o
C.
7.3 Incompatible materials
No special requirement.
7.4 Packaging material
Plastic Additional Information: The storeroom should be equipped with proper facilities for accidental
leakage and fire.
SECTION 8
Exposure controls/personal protection
8.1 Occupational Exposure Limits
Monitoring Method: The hazardous substances should be monitored per GBZ 159 “Sampling code for
monitoring of hazardous substances in workplace air ". The well-accepted monitoring methods of other
countries are also can be adopted.
Biological limit: No data available
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. Install washer eyes and safety showers near to
the handling and storage area.
8.2 Personal Protective Equipment (for workers)
Individual protection measures:
Respiratory protection: Use vapor respirator
Eye protection: Use goggles.
Wash eyes before breaks and at the end of work.
Protective gloves: Protective gloves
Skin protection: Protective work clothing
SECTION 9
Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance White or light yellow
Physical state Gelatinous paste
Odor No peculiar smell
Odor threshold N/A
pH 6.5~9.5
Melting point/freezing point No data available
Initial boiling and boiling range
>100℃
Flash point >100°C
Evaporation rate N/A
Flammability This product is not classified as flammable
liquid.
Upper/lower flammability N/A
Vapor pressure N/A
Solubility Soluble in water and ethanol
Vapor density N/A
Relative density N/A
Partition coefficient: n-octanol /water N/A
Auto-ignition temperature N/A
Decomposition temperature N/A
Viscosity N/A
Molecular weight N/A
SECTION 10
Stability and reactivity
10.1 Chemical stability & Possibility of hazardous reactions
Stable under normal temperatures and pressures. The product is not flammable. No special danger is
found.
10.2 Conditions to avoid
High temperature
10.3 Incompatible materials
No special requirement
10.4 Hazardous decomposition products
It may release smoke, carbon monoxide, Sulfur dioxide and other hazardous gas from burning.
In the event of fire: see section 5.
SECTION 11
Toxicological information
11.1 Product Toxicity Data
Ingredient (s)/Product CAS# LD50/LC50 (median lethal dose)
Classification of the whole
product
-- Acute toxicity (Oral) LD50: 1,700mg/kg-5,000
mg/kg (rat)
Data source: Data from the manufacturer:
Brown, Muir (1970), Tusing (1962), Walker
(1967), Continental Oil company, P&G, Stepan
company.
Classification of the whole product Not classified
Skin corrosion/irritation
This product is classified as Category 2. This product contains Sodium lauryl ether sulfate (CAS: 68585-34-
2) which is classified as Category 2 (Data source: CCID). Considering the total percentage of this
ingredient exceeds the classification criteria, the whole product is classified as Category 2.
Serious eye damage/eye irritation
This product is classified as Category 2A. This product contains Sodium lauryl ether sulfate (CAS: 68585-
34-2) which is classified as Category 2A (Data source: CCID). Considering the total percentage of this
ingredient exceeds the classification criteria, the whole product is classified as Category 2A.
Respiratory /Skin sensitizer
No classification for this product
Germ cell mutagenicity
No classification for this product
Carcinogenicity
No classification for this product.
Reproductive Toxicity
No classification for this product.
STOT SE/RE
No classification for this product.
Aspiration hazard
No classification for this product.
Effects on or via lactation
No classification for this product.
Toxic kinetics, metabolism and distribution of information:
No relevant information.
Other health hazards
No relevant information
SECTION 12
Ecological information
12.1 Eco Toxicity
Sodium lauryl ether sulfate (CAS: 68585-34-2): 48h-EC50: 3.43mg/L Crustaceans
Data source: CCID
Whole product: LC50:1-450mg/L Fish
Data source: Data from the manufacturer: Brown, Muir (1970), Tusing (1962), Walker (1967), Continental
Oil company, P&G, Stepan company.
Classification of the whole product: Hazardous to the aquatic environment, acute hazard-3h
12.2 Persistence and degradability
Whole product: biodegradability:>95%
Data source: Data from the manufacturer
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
As it is in liquid status, it can move in soil
SECTION 13
Disposal considerations
13.1 Disposal methods
Dispose of contents and container in accordance with Waste Control Regulation.
13.2 Contaminated packaging
Do not throw away the used containers and wash thoroughly before recycling. The waste water should
be treated as to be not hazardous.
13.3 Cautions for disposal
Do not allow product to reach sewage system. Do not throw it into any open bodies of water.
SECTION 14
Transportation information
14.1 Proper Shipping Name
Not regulated
14.2 Hazard Class
Not classified
14.3 UN Code
Not regulated
14.4 Packaging group
Not classified
14.5 Packaging Group Symbol
Not classified
14.6 Marine pollutants (Yes/ No)
No data available
14.7 EMS No
Not regulated
Note:
Check whether the package is completed or sealed before transporting; make sure there are no damage
and no falling down of packages during transporting; the transport vehicle should be equipped with fire-
fighting equipments and emergency facilities for handling with release; do NOT transport this product
together with incompatible substances
SECTION 15
Regulatory information
15.1 Laws and Regulations of China
General rule for classification and hazard communication of chemicals (GB 13690-2009):
Physical hazards: Not classified.
Health hazards: Skin corrosion/irritation-2, Serious eye damage/eye irritation-2A. Environmental hazards:
Hazardous to the aquatic environment, acute hazard-3
The Principle of Classification of Transport Packaging Groups of Dangerous Goods (GB/T 15098-
2008):
Not applicable
Dangerous Chemicals List (GB 12268-2012)
Not listed.
Dangerous chemicals directory (2015)
Not applicable
Production Safety Law of the People's Republic of China
As for safe production and management, emergency handling and legal liability, comply with relevant
provisions of this law.
Occupation Disease Prevention Law the People's Republic of China
As for precautions, prevention, management and occupational disease diagnosis, comply with relevant
provisions of this law.
The Environment Protection Law of the People's Republic of China
As for the prevention of environment pollution and environment protection, comply with relevant
provisions of this law
15.2 International Laws and Regulations
TSCA (Toxic Substance Control Act)
Sodium lauryl ether sulfate (CAS: 68585-34-2) is listed in the U.S. Toxic Substances Control Act Chemicals
Substance Inventory List (EC) 1272/2008 Annex VI Table 3.1:
Ingredient(s) EC No. 1272/2008 Classification
CLASS. CODE HAZARD CODE
Not applicable Not applicable Not applicable
15.3 Carcinogenicity categories
Not listed by EPA, NTP, ACGIH and IARC
15.4 Clear Water Act
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

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Sodium Laureth Sulfate Manufacturers - Prakash Chemicals International

  • 1. SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Sodium lauryl ether sulfate Other Names : Sodium Fatty Alcohol Ether Sulfate, Sodium laureth sulphate, Sodium Polyoxyethylene, Fatty Alcohol Sulfate CAS-No. : 68585-34-2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Shampoo, soap, foam compositions, detergent raw materials. 1.3 Details of the supplier of the safety datasheet Company Address : Prakash Chemicals International Pvt Ltd. "Prakash House", 39/40- Krishna Estate, Opp BIDC, Gorwa, Vadodara, India. 1.4 Emergency telephone number Emergency Phone # : +91 265 3926000 SECTION 2 Hazards identification 2.1 Classification of the substance or mixture Hazard Class & Category Code(s) Hazard Statement Code(s) Hazard Statement Phrase(s) Skin corrosion Category 1C H315 Causes skin irritation Eye damage Category 1 H319 Causes serious eye irritation Acute aquatic toxicity Category 2 H402 Toxic to aquatic life For the full text of the H-Statements mentioned in this Section, see Section 16.
  • 2. 2.2 Label elements Labeling according to CLP/GHS Pictogram Signal Word Code(s) Hazard Statement Code(s) Suppl. Hazard Statement Code(s) GHS07 H302 Harmful if swallowed Precautionary statement(s) P264 : Wash hands thoroughly after handling. P273 : Avoid release to the environment. P280 : Wear protective gloves/protective clothing/eye protection/face protection Response Precautionary Statement(s) P264 : Wash hands thoroughly after handling. P302 + P352 : IF ON SKIN: Wash with plenty water. P332 + P313 : If skin irritation occurs: Get medical advice/attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 : If eye irritation persists: Get medical advice/attention Storage precautionary statements No special requirement. Disposal precautionary statements P501 : Dispose of contents/container according to relevant local and national regulations. 2.3 Physical and Chemical hazards It is white or light yellow gelatinous paste without peculiar smell.The product is not flammable, no special danger. 2.4 Health hazards Causes skin irritation. Causes serious eye irritation.
  • 3. 2.5 Environment hazards Harmful to aquatic life. 2.6 Other hazards No information available. SECTION 3 Composition/information on ingredients Component Name CAS Number %(w/w) Sodium lauryl ether sulfate 68585-34-2 70 % min Water 7732-18-5 29% max Others - 1% SECTION 4 First aid measures Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Skin contact: In case of contact with melts, immediately flush with cold water. If irritation persists,get medical advice/attention. Take off contaminated clothing and wash it before reuse. Inhalation: If discomfort occurs after inhaling vapours from processing or thermal decomposition, remove to a place where air is fresh. Ingestion: Rinse mouth. Do not induce vomiting without professional instruction. Get medical attention if discomfort. Acute and delayed effect: Acute effect: Causes skin irritation. Causes serious eye irritation. Delayed effect: Not found. Personal protective Recommend wearing protective gloves (e.g. rubber gloves). Equipment: Wear safety goggles when exposure limits are exceeded or liquid may splash. Further medical: No special requirements
  • 4. SECTION 5 Firefighting measures 5.1 Extinguishing media Suitable extinguishing media In case of a fire, use dry chemical for small fire; water fog, foam or CO2 for large fire. Do NOT use water jet which may make molten material splash. Seek advice from local fire-fighting authority. 5.2 Special hazards arising from chemical The product is not flammable. No special danger is found. It may release smoke, carbon monoxide, carbon dioxide, hydrogen sulphide and other hazardous gas from burning. 5.3 Special fire fighting Method Remove all ignition sources when this can be done without any risk. Extinguish fire from upwind, and the fire extinguishing method should be appropriate to the situation in the surroundings. Cool surrounding facilities, etc. with water spray. Remove containers from fire area if it can be done without risk. 5.4 Special protective actions for fire-fighters Wear self contained breathing apparatus and protective gear. SECTION 6 Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear protective gloves, clothing, safety glasses and mask. Workers should be well trained before handling. The leakage may cause slipping hazard, so recommend wearing antiskid shoes. 6.2 Emergency procedures Due to the nature of this product, there is no special requirement. 6.3 Environmental precautions Keep collected waste out of municipal sewers and open bodies of water. Comply with local and national laws and regulations. 6.4 Measures for cleaning/ Collection Small Spill Mop up or absorb with an inert dry material (e.g. sand) and place in an appropriately labeled waste disposal container.
  • 5. Large Spill Isolate contaminated area and set up a warning board. The persons handling emergency are recommended wearing protective gloves, clothing, safety glasses and antiskid shoes. Make sure all the present persons safe. Avoid slipping. Containers should be clearly marked for recycling or disposed as waste 6.5 Precautions for secondary hazards Keep collected waste out of municipal sewers and open bodies of water. SECTION 7 Handling and storage 7.1 Precautions for safe handling Wash hands thoroughly after handling. Avoid release to the environment. Wear gloves, safety glasses/mask/antiskid shoes. 7.2 Conditions for safe storage Requirements to be met by storerooms: Store it in a well-ventilated, cool and dry store room. Storage temperature should not exceed 50 o C. 7.3 Incompatible materials No special requirement. 7.4 Packaging material Plastic Additional Information: The storeroom should be equipped with proper facilities for accidental leakage and fire. SECTION 8 Exposure controls/personal protection 8.1 Occupational Exposure Limits Monitoring Method: The hazardous substances should be monitored per GBZ 159 “Sampling code for monitoring of hazardous substances in workplace air ". The well-accepted monitoring methods of other countries are also can be adopted. Biological limit: No data available Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Install washer eyes and safety showers near to the handling and storage area.
  • 6. 8.2 Personal Protective Equipment (for workers) Individual protection measures: Respiratory protection: Use vapor respirator Eye protection: Use goggles. Wash eyes before breaks and at the end of work. Protective gloves: Protective gloves Skin protection: Protective work clothing SECTION 9 Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance White or light yellow Physical state Gelatinous paste Odor No peculiar smell Odor threshold N/A pH 6.5~9.5 Melting point/freezing point No data available Initial boiling and boiling range >100℃ Flash point >100°C Evaporation rate N/A Flammability This product is not classified as flammable liquid. Upper/lower flammability N/A Vapor pressure N/A Solubility Soluble in water and ethanol Vapor density N/A Relative density N/A Partition coefficient: n-octanol /water N/A Auto-ignition temperature N/A Decomposition temperature N/A Viscosity N/A Molecular weight N/A
  • 7. SECTION 10 Stability and reactivity 10.1 Chemical stability & Possibility of hazardous reactions Stable under normal temperatures and pressures. The product is not flammable. No special danger is found. 10.2 Conditions to avoid High temperature 10.3 Incompatible materials No special requirement 10.4 Hazardous decomposition products It may release smoke, carbon monoxide, Sulfur dioxide and other hazardous gas from burning. In the event of fire: see section 5. SECTION 11 Toxicological information 11.1 Product Toxicity Data Ingredient (s)/Product CAS# LD50/LC50 (median lethal dose) Classification of the whole product -- Acute toxicity (Oral) LD50: 1,700mg/kg-5,000 mg/kg (rat) Data source: Data from the manufacturer: Brown, Muir (1970), Tusing (1962), Walker (1967), Continental Oil company, P&G, Stepan company. Classification of the whole product Not classified Skin corrosion/irritation This product is classified as Category 2. This product contains Sodium lauryl ether sulfate (CAS: 68585-34- 2) which is classified as Category 2 (Data source: CCID). Considering the total percentage of this ingredient exceeds the classification criteria, the whole product is classified as Category 2.
  • 8. Serious eye damage/eye irritation This product is classified as Category 2A. This product contains Sodium lauryl ether sulfate (CAS: 68585- 34-2) which is classified as Category 2A (Data source: CCID). Considering the total percentage of this ingredient exceeds the classification criteria, the whole product is classified as Category 2A. Respiratory /Skin sensitizer No classification for this product Germ cell mutagenicity No classification for this product Carcinogenicity No classification for this product. Reproductive Toxicity No classification for this product. STOT SE/RE No classification for this product. Aspiration hazard No classification for this product. Effects on or via lactation No classification for this product. Toxic kinetics, metabolism and distribution of information: No relevant information. Other health hazards No relevant information SECTION 12 Ecological information 12.1 Eco Toxicity Sodium lauryl ether sulfate (CAS: 68585-34-2): 48h-EC50: 3.43mg/L Crustaceans Data source: CCID Whole product: LC50:1-450mg/L Fish Data source: Data from the manufacturer: Brown, Muir (1970), Tusing (1962), Walker (1967), Continental Oil company, P&G, Stepan company. Classification of the whole product: Hazardous to the aquatic environment, acute hazard-3h 12.2 Persistence and degradability Whole product: biodegradability:>95% Data source: Data from the manufacturer
  • 9. 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil As it is in liquid status, it can move in soil SECTION 13 Disposal considerations 13.1 Disposal methods Dispose of contents and container in accordance with Waste Control Regulation. 13.2 Contaminated packaging Do not throw away the used containers and wash thoroughly before recycling. The waste water should be treated as to be not hazardous. 13.3 Cautions for disposal Do not allow product to reach sewage system. Do not throw it into any open bodies of water. SECTION 14 Transportation information 14.1 Proper Shipping Name Not regulated 14.2 Hazard Class Not classified 14.3 UN Code Not regulated 14.4 Packaging group Not classified 14.5 Packaging Group Symbol Not classified
  • 10. 14.6 Marine pollutants (Yes/ No) No data available 14.7 EMS No Not regulated Note: Check whether the package is completed or sealed before transporting; make sure there are no damage and no falling down of packages during transporting; the transport vehicle should be equipped with fire- fighting equipments and emergency facilities for handling with release; do NOT transport this product together with incompatible substances SECTION 15 Regulatory information 15.1 Laws and Regulations of China General rule for classification and hazard communication of chemicals (GB 13690-2009): Physical hazards: Not classified. Health hazards: Skin corrosion/irritation-2, Serious eye damage/eye irritation-2A. Environmental hazards: Hazardous to the aquatic environment, acute hazard-3 The Principle of Classification of Transport Packaging Groups of Dangerous Goods (GB/T 15098- 2008): Not applicable Dangerous Chemicals List (GB 12268-2012) Not listed. Dangerous chemicals directory (2015) Not applicable Production Safety Law of the People's Republic of China As for safe production and management, emergency handling and legal liability, comply with relevant provisions of this law. Occupation Disease Prevention Law the People's Republic of China As for precautions, prevention, management and occupational disease diagnosis, comply with relevant provisions of this law. The Environment Protection Law of the People's Republic of China As for the prevention of environment pollution and environment protection, comply with relevant provisions of this law
  • 11. 15.2 International Laws and Regulations TSCA (Toxic Substance Control Act) Sodium lauryl ether sulfate (CAS: 68585-34-2) is listed in the U.S. Toxic Substances Control Act Chemicals Substance Inventory List (EC) 1272/2008 Annex VI Table 3.1: Ingredient(s) EC No. 1272/2008 Classification CLASS. CODE HAZARD CODE Not applicable Not applicable Not applicable 15.3 Carcinogenicity categories Not listed by EPA, NTP, ACGIH and IARC 15.4 Clear Water Act None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.