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Material Safety Data Sheet
Pigment Yellow 138
1. Identification
Product identifier used on the label
Pigment Yellow 138
Recommended use of the chemical and restriction on use
Recommended use*: colorant(s)
Suitable for use in industrial sector: plastics processing industry
Details of the supplier of the safety data sheet
Dongguan Baoxu Chemical Technology.,ltd.
Caijin Business Bldg DongGuan CN 523071
+86 0769 22821082 Fax 86 0769 22821083
www.additivesforpolymer.com
info@additivesforpolymer.com
Dongguan Baoxu Chemical Technology.,ltd.
Caijin Business Bldg DongGuan CN 523071
+86 0769 22821082 Fax 86 0769 22821083
Website www.additivesforpolymer.com
Email info@additivesforpolymer.com
Emergency telephone number
Other means of identification
Molecular formula: C26H6Cl8N2O4
Chemical family: quinophthalone pigment
Synonyms: Quinophthalone yellow
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200 Classification of the product
Combustible Dust Combustible Dust (1) Combustible Dust
Label elements
Signal Word: Warning
Hazard Statement:
May form combustible dust concentration in air.
Hazards not otherwise classified
The product is under certain conditions capable of dust explosion.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200
This product does not contain any components classified as hazardous under the referenced
regulation.
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part
1910.1200
The product contains:
CAS Number Weight % Chemical name
30125-47-4 100.0 % C.I. Pigment Yellow 138
4. First-Aid Measures
Description of first aid measures
General advice:
Remove contaminated clothing.
If inhaled:
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
If on skin:
Remove contaminated clothing. Wash thoroughly with soap and water. If irritation develops,
seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If
irritation develops, seek medical attention.
If swallowed:
Rinse mouth and then drink plenty of water. Do not induce vomiting. Seek medical attention
if necessary.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling
(see section 2) and/or in section 11.
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media: dry powder, foam
Unsuitable extinguishing media for safety reasons: carbon dioxide
Additional information:
Avoid whirling up the material/product because of the danger of dust explosion.
Special hazards arising from the substance or mixture
Hazards during fire-fighting: harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in
case of fire.
Advice for firefighters
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.
Impact Sensitivity:
Impact Weight: 10 kg
Height of Fall: 0.4 m
Method: Explosive properties
Number of positive 0
reactions:
6. Accidental release measures Personal precautions, protective equipment and
emergency procedures
Avoid dust formation. Use personal protective clothing.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface wate
rs/grou 门 dwate r.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Contain with dust binding material and dispose of.
Avoid raising dust.
7. Handling and Storage
Precautions for safe handling
Breathing must be protected when large quantities are decanted without local exhaust
ventilation.
Closed containers should only be opened in well-ventilated areas.
Protection against fire and explosion:
Avoid dust formation. Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in
a cool place.
8. Exposure Controls/Personal Protection
Advice on system design:
Provide local exhaust ventilation to control dust.
Personal protective equipment Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.
Observe OSHA regulations for respirator use (29 CFR 1910.134).
Hand protection:
Chemical resistant protective gloves
Eye protection:
Safety glasses with side-shields. Wear face shield if splashing hazard exists.
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Due to the
colouring properties of the product closed work clothes should be used, to avoid stains
during manipulation. Eye wash fountains and safety showers must be easily accessible.
Wash soiled clothing immediately.
9. Physical and Chemical Properties
Form:
Odour:
Odour
threshold:
Colour: pH
value:
Melting point:
Boiling point:
Flash point:
Flammability:
Autoignition:
Vapour
pressure:
powder
odourless
No applicable information available.
yellow
3.5 - 6.5
(50 g/l, 20 °C)
(as suspension)
> 200 °C not applicable
not applicable, the product is a
solid not flammable not
applicable
The product has not been tested.
Density:
Bulk density:
Partitioning
coefficient n-
octanol/water (log
Pow): Self-ignition
temperature:
Thermal
decomposition:
Viscosity, dynamic:
Particle size:
Solubility in water:
Evaporation rate:
Other Information:
approx. 1.80 g/cm3
(20 °C)
approx. 310 kg/m3
10.185
not self-igniting
(calculated)
> 400 °C (DTA) not applicable
(134001)
insoluble
The product is a non-volatile solid.
If necessary, information on other physical and
chemical parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Oxidizing properties:
not fire-propagating
Formation of Remarks
flammable gases:
Forms no flammable gases in
the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
In spite of the dedusting carried out for reasons of industrial health a dust explosion hazard
can not be excluded.
Conditions to avoid
No conditions to avoid anticipated.
Incompatible materials
strong oxidizing agents, strong acids, strong bases
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and
handled as prescribed/indicated.
Thermal decomposition:
> 400 °C (DTA)11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or
skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may
be a route of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic
after a single ski 门 contact.
Oral
Type of value: LD50 Species: rat Value: > 5,000 mg/kg
Dermal
Type of value: LD50 Species: rat Value: > 2,000 mg/kg
Assessment other acute effects Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected
after a single exposure.
Irritation / corrosion
Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin.
Skin
Species: rabbit Result: non-irritant Method: BASF-Test
Eye
Species: rabbit Result: non-irritant Method: BASF-Test
Sensitization
Assessment of sensitization: The chemical structure does not suggest a sensitizing effect.
No data available.
Aspiration Hazard No aspiration hazard expected.
Chronic Toxicity/Effects
Repeated dose toxicity
Assessment of repeated dose toxicity: No data available.
Genetic toxicity
Assessment of mutagenicity: No mutagenic effects reported.
Carcinogenicity.
Assessment of carcinogenicity: The whole of the information assessable provides no
indication of a Carcinogenic effect.
None of the components in this product at concentrations greater than 0.1% are listed by 丨
ARC;
NTP, OSHA or ACGIH as a carcinogen.
Reproductive toxicity
Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a
toxic effect on reproduction.
Teratogenicity
Assessment of teratogenicity: No data available.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section
2) and/or in section 11.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
At the present state of knowledge, no negative ecological effects are expected. The
inhibition of the degradation activity of activated sludge is not anticipated when introduced
to biological treatment plants in appropriate low concentrations.
Toxicity to fish
LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, static)
Aquatic invertebrates
EC50 (48 h) > 100 mg/l, Daphnia magna
The product has low solubility in the test medium. An eluate has been tested.
Aquatic plants
EC50 (72 h) > 100 mg/l (biomass), Desmodesmus subspicatus (OECD Guideline 201, static)
Nominal concentration.
No observed effect concentration (72 h) >= 100 mg/l (biomass), Desmodesmus subspicatus
(OECD Guideline 201, static)
Nominal concentration.
Lowest observed effect concentration (72 h) > 100 mg/l (biomass), Desmodesmus
subspicatus (OECD Guideline 201, static)
Nominal concentration.
EC50 (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201,
static) Nominal concentration.
No observed effect concentration (72 h) >= 100 mg/l (growth rate), Desmodesmus
subspicatus (OECD Guideline 201, static)
Nominal concentration.
Lowest observed effect concentration (72 h) > 100 mg/l (growth rate), Desmodesmus
subspicatus (OECD Guideline 201, static)
Nominal concentration.
No data available.
Chronic toxicity to aquatic invertebrates
No data available.
Microorganisms/Effect on activated sludge
Toxicity to microorganisms
Directive 88/302/EEC, part C, p. 118 activated sludge, domestic/EC50 (30 min): >
1,000 mg/l
Nominal concentration.
Persistence and degradability
Assessment biodegradation and elimination (H2O)
The product is not very soluble in water and can thus be removed from water
mechanically in
suitable effluent treatment plants.
Elimination information
Well eliminable from water by adsorption on activated sludge.
Bioaccumulative potential
Assessment bioaccumulation potential
Because of the n-octanol/water distribution coefficient (log Pow) accumulation in
organisms is not to
be expected.
Bioaccumulation potential
Bioconcentration factor: < 3 (OECD Guideline 305 B)
Does not accumulate in organisms.
Mobility in soil
Assessment transport between environmental compartments
The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is not expected.
Additional information
Adsorbable organically-bound halogen (AOX): approx. 40,9 %
The product contains according to the formulation, organically bound halogen. It can
increase the
AOX-value in the water purification plants overflow or if it reaches waters.
Other ecotoxicological advice:
The inhibition of the degradation activity of activated sludge is not anticipated when
introduced to
biological treatment plants in appropriate low concentrations.
Do not discharge product into the environment without control.13. Disposal considerations
Waste disposal of substance:
Do not discharge into drains/surface waters/groundwater. Dispose of in accordance with
national, state and local regulations.
Container disposal:
Dispose of in accordance with national, state and local regulations. Recommend crushing,
puncturing or other means to prevent unauthorized use of used containers.
RCRA: None
14. Transport Information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
Federal Regulations Registration status:
Chemical TSCA, US released / listed
EPCRA 311/312 (Hazard categories): Fire (Combustible Dust);
CA Prop. 65:
WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
NFPA Hazard codes:
Health : 1 Fire: 1 Reactivity: 0 Special:
HMIS III rating
Health: 1 Flammability: 1 Physical hazard: 0
16. Other Information
Pigment yellow 138 cas 30125 47-4 safety data sheet msds sds baoxu chemical

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Pigment yellow 138 cas 30125 47-4 safety data sheet msds sds baoxu chemical

  • 1. Material Safety Data Sheet Pigment Yellow 138 1. Identification Product identifier used on the label Pigment Yellow 138 Recommended use of the chemical and restriction on use Recommended use*: colorant(s) Suitable for use in industrial sector: plastics processing industry Details of the supplier of the safety data sheet Dongguan Baoxu Chemical Technology.,ltd. Caijin Business Bldg DongGuan CN 523071 +86 0769 22821082 Fax 86 0769 22821083 www.additivesforpolymer.com info@additivesforpolymer.com Dongguan Baoxu Chemical Technology.,ltd. Caijin Business Bldg DongGuan CN 523071 +86 0769 22821082 Fax 86 0769 22821083 Website www.additivesforpolymer.com Email info@additivesforpolymer.com Emergency telephone number Other means of identification Molecular formula: C26H6Cl8N2O4 Chemical family: quinophthalone pigment Synonyms: Quinophthalone yellow 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Classification of the product Combustible Dust Combustible Dust (1) Combustible Dust Label elements Signal Word: Warning
  • 2. Hazard Statement: May form combustible dust concentration in air. Hazards not otherwise classified The product is under certain conditions capable of dust explosion. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 This product does not contain any components classified as hazardous under the referenced regulation. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 The product contains: CAS Number Weight % Chemical name 30125-47-4 100.0 % C.I. Pigment Yellow 138 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. If on skin: Remove contaminated clothing. Wash thoroughly with soap and water. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting. Seek medical attention if necessary. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Indication of any immediate medical attention and special treatment needed
  • 3. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Advice for firefighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire. Impact Sensitivity: Impact Weight: 10 kg Height of Fall: 0.4 m Method: Explosive properties Number of positive 0 reactions: 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use personal protective clothing. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface wate rs/grou 门 dwate r. Methods and material for containment and cleaning up For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust.
  • 4. 7. Handling and Storage Precautions for safe handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Closed containers should only be opened in well-ventilated areas. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. 8. Exposure Controls/Personal Protection Advice on system design: Provide local exhaust ventilation to control dust. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Observe OSHA regulations for respirator use (29 CFR 1910.134). Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses with side-shields. Wear face shield if splashing hazard exists. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Due to the colouring properties of the product closed work clothes should be used, to avoid stains during manipulation. Eye wash fountains and safety showers must be easily accessible. Wash soiled clothing immediately. 9. Physical and Chemical Properties Form: Odour: Odour threshold: Colour: pH value: Melting point: Boiling point: Flash point: Flammability: Autoignition: Vapour pressure: powder odourless No applicable information available. yellow 3.5 - 6.5 (50 g/l, 20 °C) (as suspension) > 200 °C not applicable not applicable, the product is a solid not flammable not applicable The product has not been tested.
  • 5. Density: Bulk density: Partitioning coefficient n- octanol/water (log Pow): Self-ignition temperature: Thermal decomposition: Viscosity, dynamic: Particle size: Solubility in water: Evaporation rate: Other Information: approx. 1.80 g/cm3 (20 °C) approx. 310 kg/m3 10.185 not self-igniting (calculated) > 400 °C (DTA) not applicable (134001) insoluble The product is a non-volatile solid. If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: No corrosive effect on metal. Oxidizing properties: not fire-propagating Formation of Remarks flammable gases: Forms no flammable gases in the presence of water. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions In spite of the dedusting carried out for reasons of industrial health a dust explosion hazard can not be excluded. Conditions to avoid No conditions to avoid anticipated. Incompatible materials strong oxidizing agents, strong acids, strong bases Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: > 400 °C (DTA)11. Toxicological information Primary routes of exposure
  • 6. Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single ski 门 contact. Oral Type of value: LD50 Species: rat Value: > 5,000 mg/kg Dermal Type of value: LD50 Species: rat Value: > 2,000 mg/kg Assessment other acute effects Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Irritation / corrosion Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. Skin Species: rabbit Result: non-irritant Method: BASF-Test Eye Species: rabbit Result: non-irritant Method: BASF-Test Sensitization Assessment of sensitization: The chemical structure does not suggest a sensitizing effect. No data available. Aspiration Hazard No aspiration hazard expected. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No data available. Genetic toxicity Assessment of mutagenicity: No mutagenic effects reported. Carcinogenicity. Assessment of carcinogenicity: The whole of the information assessable provides no indication of a Carcinogenic effect.
  • 7. None of the components in this product at concentrations greater than 0.1% are listed by 丨 ARC; NTP, OSHA or ACGIH as a carcinogen. Reproductive toxicity Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effect on reproduction. Teratogenicity Assessment of teratogenicity: No data available. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: At the present state of knowledge, no negative ecological effects are expected. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, static) Aquatic invertebrates EC50 (48 h) > 100 mg/l, Daphnia magna The product has low solubility in the test medium. An eluate has been tested. Aquatic plants EC50 (72 h) > 100 mg/l (biomass), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration. No observed effect concentration (72 h) >= 100 mg/l (biomass), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration. Lowest observed effect concentration (72 h) > 100 mg/l (biomass), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration. EC50 (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration. No observed effect concentration (72 h) >= 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration. Lowest observed effect concentration (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) Nominal concentration.
  • 8. No data available. Chronic toxicity to aquatic invertebrates No data available. Microorganisms/Effect on activated sludge Toxicity to microorganisms Directive 88/302/EEC, part C, p. 118 activated sludge, domestic/EC50 (30 min): > 1,000 mg/l Nominal concentration. Persistence and degradability Assessment biodegradation and elimination (H2O) The product is not very soluble in water and can thus be removed from water mechanically in suitable effluent treatment plants. Elimination information Well eliminable from water by adsorption on activated sludge. Bioaccumulative potential Assessment bioaccumulation potential Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Bioaccumulation potential Bioconcentration factor: < 3 (OECD Guideline 305 B) Does not accumulate in organisms. Mobility in soil Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is not expected. Additional information Adsorbable organically-bound halogen (AOX): approx. 40,9 % The product contains according to the formulation, organically bound halogen. It can increase the AOX-value in the water purification plants overflow or if it reaches waters. Other ecotoxicological advice: The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Do not discharge product into the environment without control.13. Disposal considerations Waste disposal of substance: Do not discharge into drains/surface waters/groundwater. Dispose of in accordance with national, state and local regulations.
  • 9. Container disposal: Dispose of in accordance with national, state and local regulations. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA: None 14. Transport Information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Fire (Combustible Dust); CA Prop. 65: WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 0 Special: HMIS III rating Health: 1 Flammability: 1 Physical hazard: 0 16. Other Information