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A
TECHNICAL SEMINAR REPORT
ON
SUPER CONDUCTORS
Bachelor of Technology
In
Department of Electrical and Electronics Engineering
Submitted by
N.SANTHOSH KUMAR
19705A0244
II-B.TECH, I SEMESTER
Under the esteemed Guidance Of
DR. Pasala Gopi,
Assistant Professor
Department of Electrical and Electronics Engineering
ANNAMACHARYA INSTITUTE OF TECHNOLOGY AND SCIENCES
(An Autonomous Institution)
(Approved by AICTE, Affiliated to JNTUA, Anantapur)
(NAAC & IEI)
New Boyanapalli-516126, Rajampet.
2019-20
TABLE OF CONTANTS
 Introduction
 Types of Fuel Cells
 Major Components of Fuel Cell
 Applications
 Advantages
 Disadvantages
 Conclusion
INTRODUCTION
Technology is increasing our energy needs, but it is also showing in new
way to generate power more effect with less impact on the environment.
One of the most promising options for supplementing future power
supplies in the fuel cells.they only have potential to create much more
reliable power, with lower levels of undesirable emission's and noise and
higher overall efficiency than more traditional power generation systems
with existing and projected applications ranging from space craft to
private automobiles, large stationary power generator systems to small
electronics devices, fuel cells are poised to play an increasingly Critical
role in meeting the worlds blowing demand for clean , reliable power.
Fig1:Fuel Cell car model
What is Fuel Cell ?
Fig 2: Fuel Cell working
A fuel cell is an electrochemical cell that converts the chemical
energy of a fuel (often hydrogen) and an oxidizing agent (often
oxygen) into electricity through a pair of redox reactions. Fuel
cells are different from most batteries in requiring a continuous
source of fuel and oxygen (usually from air) to sustain the
chemical reaction, whereas in a battery the chemical energy
usually comes from metals and their ions or oxides that are
commonly already present in the battery, except in flow batteries.
Fuel cells can produce electricity continuously for as long as fuel
and oxygen are supplied.
TYPES OF FUEL CELLS
 Polymer electrolyte Membrane
Fuel Cell
 Molten Carbonate Fuel Cell
 Solid Oxide Fuel Cell
 Phosphoric Acid Fuel Cell
Fig 3: Types Of Fuel Cells
 Hydrogen Fuel Cells
A Hydrogen Fuel Cell uses Hydrogen as its fuel and oxygen as its oxidant. Other fuels include hydrocarbons and
alcohols. Other oxidants include chlorine and chlorine dioxide
 Polymer Electrolyte Membrane Fuel Cell
Polymer electrolyte membrane (PEM) fuel cells—also called proton exchange membrane fuel cells—deliver high
power density and offer the advantages of low weight and volume compared with other fuel cells. PEM fuel
cells use a solid polymer as an electrolyte and porous carbon electrodes containing a platinum or platinum
alloy catalyst. They need only hydrogen, oxygen from the air, and water to operate. They are typically fueled
with pure hydrogen supplied from storage tanks or reformers’. fuel cells operate at relatively low
temperatures, around 80°C (176°F). Low-temperature operation allows them to start quickly (less warm-up
time) and results in less wear on system components, resulting in better durability. However, it requires that a
noble-metal catalyst (typically platinum) be used to separate the hydrogen's electrons and protons, adding to
system cost. The platinum catalyst is also extremely sensitive to carbon monoxide poisoning, making it
necessary to employ an additional reactor to reduce carbon monoxide in the fuel gas if the hydrogen is derived
from a hydrocarbon fuel. This reactor also adds cost.PEM fuel cells are used primarily for transportation
applications and some stationary applications. Due to their fast startup time and favorable power-to-weight
ratio, PEM fuel cells are particularly suitable for use in passenger vehicles, such as cars and buses.
 Molten Carbonate Fuel Cell
Molten carbonate fuel cells (MCFCs) are currently being developed for natural gas and coal-based power
plants for electrical utility, industrial, and military applications. MCFCs are high-temperature fuel cells
that use an electrolyte composed of a molten carbonate salt mixture suspended in a porous, chemically
inert ceramic lithium aluminum oxide matrix. Because they operate at high temperatures of 650°C
(roughly 1,200°F), non-precious metals can be used as catalysts at the anode and cathode, reducing
costs. Improved efficiency is another reason MCFCs offer significant cost reductions over phosphoric acid
fuel cells. Molten carbonate fuel cells, when coupled with a turbine, can reach efficiencies approaching
65%, considerably higher than the 37%–42% efficiencies of a phosphoric acid fuel cell plant. When the
waste heat is captured and used, overall fuel efficiencies can be over 85%.
Unlike alkaline, phosphoric acid, and PEM fuel cells, MCFCs do not require an external reformer to
convert fuels such as natural gas and biogas to hydrogen. At the high temperatures at which MCFCs
operate, methane and other light hydrocarbons in these fuels are converted to hydrogen within the fuel
cell itself by a process called internal reforming, which also reduces cost.
The primary disadvantage of current MCFC technology is durability. The high temperatures at which these
cells operate and the corrosive electrolyte used accelerate component breakdown and corrosion,
decreasing cell life. Scientists are currently exploring corrosion-resistant materials for components as
well as fuel cell designs that double cell life from the current 40,000 hours (~5 years) without decreasing
performance.
 Solid Oxide Fuel cell
• Solid oxide fuel cells (SOFCs) use a hard, non-porous ceramic compound as the electrolyte. SOFCs are
around 60% efficient at converting fuel to electricity. In applications designed to capture and utilize
the system's waste heat (co-generation), overall fuel use efficiencies could top 85%.
• SOFCs operate at very high temperatures—as high as 1,000°C (1,830°F). High-temperature operation
removes the need for precious-metal catalyst, thereby reducing cost. It also allows SOFCs to reform
fuels internally, which enables the use of a variety of fuels and reduces the cost associated with
adding a reformer to the system.
• SOFCs are also the most sulfur-resistant fuel cell type; they can tolerate several orders of magnitude
more sulfur than other cell types can. In addition, they are not poisoned by carbon monoxide, which
can even be used as fuel. This property allows SOFCs to use natural gas, biogas, and gases made from
coal. High-temperature operation has disadvantages. It results in a slow startup and requires
significant thermal shielding to retain heat and protect personnel, which may be acceptable for
utility applications but not for transportation. The high operating temperatures also place stringent
durability requirements on materials. The development of low-cost materials with high durability at
cell operating temperatures is the key technical challenge facing this technology.
• Scientists are currently exploring the potential for developing lower-temperature SOFCs operating at
or below 700°C that have fewer durability problems and cost less. Lower-temperature SOFCs have not
yet matched the performance of the higher temperature systems, however, and stack materials that
will function in this lower temperature range are still under development.
 Phosphoric Acid Fuel Cell
• Phosphoric acid fuel cells (PAFCs) use liquid phosphoric acid as an electrolyte—the acid is
contained in a Teflon-bonded silicon carbide matrix—and porous carbon electrodes containing a
platinum catalyst. The electro-chemical reactions that take place in the cell are shown in the
diagram to the right.
• The PAFC is considered the "first generation" of modern fuel cells. It is one of the most mature
cell types and the first to be used commercially. This type of fuel cell is typically used for
stationary power generation, but some PAFCs have been used to power large vehicles such as
city buses.
• PAFCs are more tolerant of impurities in fossil fuels that have been reformed into hydrogen
than PEM cells, which are easily "poisoned" by carbon monoxide because carbon monoxide binds
to the platinum catalyst at the anode, decreasing the fuel cell's efficiency. PAFCs are more than
85% efficient when used for the co-generation of electricity and heat but they are less efficient
at generating electricity alone (37%–42%). PAFC efficiency is only slightly more than that of
combustion-based power plants, which typically operate at around 33% efficiency. PAFCs are
also less powerful than other fuel cells, given the same weight and volume. As a result, these
fuel cells are typically large and heavy. PAFCs are also expensive. They require much higher
loadings of expensive platinum catalyst than other types of fuel cells do, which raises the cost.
Major components of Fuel Cells
 A Fuel Stack
 A Processor to extract pares Hydrogen from the fuel source
 A storage and conditioners system to adapt the fuel cells
continues Power supply only out ton fluctuating demand
 A Mechanism for recovering heat from electro chemical
process
Fig4 : Fuel cell stack
 APPLICATIONS
 Fuel cell technology has a wide range of applications. Currently, heavy
research is being conducted in order to manufacture a cost-efficient
automobile which is powered by a fuel cell. A few applications of this
technology are listed below.
• Fuel cell electric vehicles, or FCEVs, use clean fuels and are therefore more
eco-friendly than internal combustion engine-based vehicles.
• They have been used to power many space expeditions including the Appolo
space program.
• The portability of some fuel cells is extremely useful in some military
applications.
• These electrochemical cells can also be used to power several electronic
devices.
• Fuel cells are also used as primary or backup sources of electricity in many
remote areas.
Fig 5 : FUEL CAR Fig6: Fuel cell Module of NASA
 ADVANTAGES
 It offers an effective method of energy storage.
 This technology offers a high level of energy efficiency.
 The emissions from a hydrogen fuel cell are virtually zero.
 Vehicles using a hydrogen fuel cell achieve a better fuel economy rating.
 We receive a greater level of consistency with hydrogen fuel cells.
 You can reduce the risk of chemical exposure by using hydrogen fuel cells.
 You can reduce the risk of chemical exposure by using hydrogen fuel cells.
 You can reduce the risk of chemical exposure by using hydrogen fuel cells.
 Most fuel cell components are recyclable and reusable.
DISADVANTAGES
 You must regulate the temperature of a hydrogen fuel cell to maximize its
use.
 The cost to store hydrogen is expensive enough that it is prohibitive for
most people.
 It costs more to transport hydrogen than it does most other fuels.
 This technology is not widely available right now.
 It is not currently a complete renewable energy resource.
CONCLUSION
 Fuel cells are an attractive technology option for India, because of our
economic, environmental, and energy management advantages. In India
context, we will have the following benfits.
 High efficient, can deliver power per unit of fuel consumption.
 Less pollution.
 Suitable for powering vehicles to reduce urban pollution.
FUEL CELL TECHNOLOGY.pptx
FUEL CELL TECHNOLOGY.pptx

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FUEL CELL TECHNOLOGY.pptx

  • 1. A TECHNICAL SEMINAR REPORT ON SUPER CONDUCTORS Bachelor of Technology In Department of Electrical and Electronics Engineering Submitted by N.SANTHOSH KUMAR 19705A0244 II-B.TECH, I SEMESTER Under the esteemed Guidance Of DR. Pasala Gopi, Assistant Professor Department of Electrical and Electronics Engineering ANNAMACHARYA INSTITUTE OF TECHNOLOGY AND SCIENCES (An Autonomous Institution) (Approved by AICTE, Affiliated to JNTUA, Anantapur) (NAAC & IEI) New Boyanapalli-516126, Rajampet. 2019-20
  • 2. TABLE OF CONTANTS  Introduction  Types of Fuel Cells  Major Components of Fuel Cell  Applications  Advantages  Disadvantages  Conclusion
  • 3. INTRODUCTION Technology is increasing our energy needs, but it is also showing in new way to generate power more effect with less impact on the environment. One of the most promising options for supplementing future power supplies in the fuel cells.they only have potential to create much more reliable power, with lower levels of undesirable emission's and noise and higher overall efficiency than more traditional power generation systems with existing and projected applications ranging from space craft to private automobiles, large stationary power generator systems to small electronics devices, fuel cells are poised to play an increasingly Critical role in meeting the worlds blowing demand for clean , reliable power. Fig1:Fuel Cell car model
  • 4. What is Fuel Cell ? Fig 2: Fuel Cell working A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from metals and their ions or oxides that are commonly already present in the battery, except in flow batteries. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
  • 5. TYPES OF FUEL CELLS  Polymer electrolyte Membrane Fuel Cell  Molten Carbonate Fuel Cell  Solid Oxide Fuel Cell  Phosphoric Acid Fuel Cell Fig 3: Types Of Fuel Cells
  • 6.  Hydrogen Fuel Cells A Hydrogen Fuel Cell uses Hydrogen as its fuel and oxygen as its oxidant. Other fuels include hydrocarbons and alcohols. Other oxidants include chlorine and chlorine dioxide  Polymer Electrolyte Membrane Fuel Cell Polymer electrolyte membrane (PEM) fuel cells—also called proton exchange membrane fuel cells—deliver high power density and offer the advantages of low weight and volume compared with other fuel cells. PEM fuel cells use a solid polymer as an electrolyte and porous carbon electrodes containing a platinum or platinum alloy catalyst. They need only hydrogen, oxygen from the air, and water to operate. They are typically fueled with pure hydrogen supplied from storage tanks or reformers’. fuel cells operate at relatively low temperatures, around 80°C (176°F). Low-temperature operation allows them to start quickly (less warm-up time) and results in less wear on system components, resulting in better durability. However, it requires that a noble-metal catalyst (typically platinum) be used to separate the hydrogen's electrons and protons, adding to system cost. The platinum catalyst is also extremely sensitive to carbon monoxide poisoning, making it necessary to employ an additional reactor to reduce carbon monoxide in the fuel gas if the hydrogen is derived from a hydrocarbon fuel. This reactor also adds cost.PEM fuel cells are used primarily for transportation applications and some stationary applications. Due to their fast startup time and favorable power-to-weight ratio, PEM fuel cells are particularly suitable for use in passenger vehicles, such as cars and buses.
  • 7.  Molten Carbonate Fuel Cell Molten carbonate fuel cells (MCFCs) are currently being developed for natural gas and coal-based power plants for electrical utility, industrial, and military applications. MCFCs are high-temperature fuel cells that use an electrolyte composed of a molten carbonate salt mixture suspended in a porous, chemically inert ceramic lithium aluminum oxide matrix. Because they operate at high temperatures of 650°C (roughly 1,200°F), non-precious metals can be used as catalysts at the anode and cathode, reducing costs. Improved efficiency is another reason MCFCs offer significant cost reductions over phosphoric acid fuel cells. Molten carbonate fuel cells, when coupled with a turbine, can reach efficiencies approaching 65%, considerably higher than the 37%–42% efficiencies of a phosphoric acid fuel cell plant. When the waste heat is captured and used, overall fuel efficiencies can be over 85%. Unlike alkaline, phosphoric acid, and PEM fuel cells, MCFCs do not require an external reformer to convert fuels such as natural gas and biogas to hydrogen. At the high temperatures at which MCFCs operate, methane and other light hydrocarbons in these fuels are converted to hydrogen within the fuel cell itself by a process called internal reforming, which also reduces cost. The primary disadvantage of current MCFC technology is durability. The high temperatures at which these cells operate and the corrosive electrolyte used accelerate component breakdown and corrosion, decreasing cell life. Scientists are currently exploring corrosion-resistant materials for components as well as fuel cell designs that double cell life from the current 40,000 hours (~5 years) without decreasing performance.
  • 8.  Solid Oxide Fuel cell • Solid oxide fuel cells (SOFCs) use a hard, non-porous ceramic compound as the electrolyte. SOFCs are around 60% efficient at converting fuel to electricity. In applications designed to capture and utilize the system's waste heat (co-generation), overall fuel use efficiencies could top 85%. • SOFCs operate at very high temperatures—as high as 1,000°C (1,830°F). High-temperature operation removes the need for precious-metal catalyst, thereby reducing cost. It also allows SOFCs to reform fuels internally, which enables the use of a variety of fuels and reduces the cost associated with adding a reformer to the system. • SOFCs are also the most sulfur-resistant fuel cell type; they can tolerate several orders of magnitude more sulfur than other cell types can. In addition, they are not poisoned by carbon monoxide, which can even be used as fuel. This property allows SOFCs to use natural gas, biogas, and gases made from coal. High-temperature operation has disadvantages. It results in a slow startup and requires significant thermal shielding to retain heat and protect personnel, which may be acceptable for utility applications but not for transportation. The high operating temperatures also place stringent durability requirements on materials. The development of low-cost materials with high durability at cell operating temperatures is the key technical challenge facing this technology. • Scientists are currently exploring the potential for developing lower-temperature SOFCs operating at or below 700°C that have fewer durability problems and cost less. Lower-temperature SOFCs have not yet matched the performance of the higher temperature systems, however, and stack materials that will function in this lower temperature range are still under development.
  • 9.  Phosphoric Acid Fuel Cell • Phosphoric acid fuel cells (PAFCs) use liquid phosphoric acid as an electrolyte—the acid is contained in a Teflon-bonded silicon carbide matrix—and porous carbon electrodes containing a platinum catalyst. The electro-chemical reactions that take place in the cell are shown in the diagram to the right. • The PAFC is considered the "first generation" of modern fuel cells. It is one of the most mature cell types and the first to be used commercially. This type of fuel cell is typically used for stationary power generation, but some PAFCs have been used to power large vehicles such as city buses. • PAFCs are more tolerant of impurities in fossil fuels that have been reformed into hydrogen than PEM cells, which are easily "poisoned" by carbon monoxide because carbon monoxide binds to the platinum catalyst at the anode, decreasing the fuel cell's efficiency. PAFCs are more than 85% efficient when used for the co-generation of electricity and heat but they are less efficient at generating electricity alone (37%–42%). PAFC efficiency is only slightly more than that of combustion-based power plants, which typically operate at around 33% efficiency. PAFCs are also less powerful than other fuel cells, given the same weight and volume. As a result, these fuel cells are typically large and heavy. PAFCs are also expensive. They require much higher loadings of expensive platinum catalyst than other types of fuel cells do, which raises the cost.
  • 10. Major components of Fuel Cells  A Fuel Stack  A Processor to extract pares Hydrogen from the fuel source  A storage and conditioners system to adapt the fuel cells continues Power supply only out ton fluctuating demand  A Mechanism for recovering heat from electro chemical process Fig4 : Fuel cell stack
  • 11.  APPLICATIONS  Fuel cell technology has a wide range of applications. Currently, heavy research is being conducted in order to manufacture a cost-efficient automobile which is powered by a fuel cell. A few applications of this technology are listed below. • Fuel cell electric vehicles, or FCEVs, use clean fuels and are therefore more eco-friendly than internal combustion engine-based vehicles. • They have been used to power many space expeditions including the Appolo space program. • The portability of some fuel cells is extremely useful in some military applications. • These electrochemical cells can also be used to power several electronic devices. • Fuel cells are also used as primary or backup sources of electricity in many remote areas.
  • 12. Fig 5 : FUEL CAR Fig6: Fuel cell Module of NASA
  • 13.  ADVANTAGES  It offers an effective method of energy storage.  This technology offers a high level of energy efficiency.  The emissions from a hydrogen fuel cell are virtually zero.  Vehicles using a hydrogen fuel cell achieve a better fuel economy rating.  We receive a greater level of consistency with hydrogen fuel cells.  You can reduce the risk of chemical exposure by using hydrogen fuel cells.  You can reduce the risk of chemical exposure by using hydrogen fuel cells.  You can reduce the risk of chemical exposure by using hydrogen fuel cells.  Most fuel cell components are recyclable and reusable.
  • 14. DISADVANTAGES  You must regulate the temperature of a hydrogen fuel cell to maximize its use.  The cost to store hydrogen is expensive enough that it is prohibitive for most people.  It costs more to transport hydrogen than it does most other fuels.  This technology is not widely available right now.  It is not currently a complete renewable energy resource.
  • 15. CONCLUSION  Fuel cells are an attractive technology option for India, because of our economic, environmental, and energy management advantages. In India context, we will have the following benfits.  High efficient, can deliver power per unit of fuel consumption.  Less pollution.  Suitable for powering vehicles to reduce urban pollution.