APPLIED MINERALS INC.                                                                                                                                        TM
110 Greene Street, Suite 1101
New York, NY 10012
1.800.356.6463
www.appliedminerals.com



                                       Applied Minerals is a leading global producer of Halloysite Clay. Vertically integrated from
                                       mine to market, our niche focus and in-depth application knowledge allow us to offer our
                                       customers commercially consistent product grades, specifically tailored to achieve their
                                       enhanced performance objectives. Applied Mineral’s Halloysite products are offered under
                                       the DragoniteTM brand.
                                       Applied Minerals is proud to introduce Dragonite-XRTM, a drop-in additive specifically suited
                                       for polymer reinforcement. Dragonite-XRTM is naturally exfoliated due to its tubular shape and
                                       uniform surface charge. As a result, Dragonite-XRTM disperses easily in various thermoplastic
                                       and thermoset resins at loading levels up to 40%. This is a major advantage over layered
                                       silicate fillers that must undergo a complex and costly chemical exfoliation process.
                                       Dragonite-XRTM composites exhibit not only high stiffness but also higher tensile and flex
                                       strength, all with a lower density and retained toughness.

                                                                            Dragonite-XRTM
                                                                            in powder form




         5µm
         SEM image of Dragonite-XRTM

                                                                                                        Crude ore of Dragonite-XRTM extracted
                                                                                                        from the Dragon Mine


                                       Advantages of Dragonite-XRTM in Composites
                                         Lower density than conventional fillers results in reduced weight of finished products.
                                         Naturally exfoliated morphology provides ease of dispersion at loadings up to 40% without
                                         a need for organo-treatment. This results in lower raw material, mixing, and quality control
                                         costs compared to organo clays.
                                         Increases both the stiffness (modulus) and strength of composite with minimal changes in
                                         impact strength, weld line strength, and viscosity.
                                         Improves fatigue resistance and drop impact resistance compared to chopped glass fibers.
                                         Acts as a nucleating agent with 8°C increase in crystallization temperature, even at 1-3
                                         wt% level, resulting in faster cooling and cycle time.
                                         Improves thermal stability: 20°C increase in the decomposition temperature in TGA.
                                         Increases time to ignite, reduces peak heat release rate, and improves char density when
                                         added at 5-10 wt% with other conventional flame retardants.
                                         Lower shrinkage than organo clay and lower warpage than chopped glass fiber and mica.
                                         Increases stiffness and toughness of thermoset compounds.
                                         Tubular morphology enables the entrapment of active agents followed by their controlled-
                                         release at predetermined rates.
                                         Halloysite is an inorganic material that is non-toxic and biocompatible.
                                         Lower cost than organo clay.



                                       NOTICE: All statements, information and data given herein are believed to be accurate and reliable, but are pre-
                                       sented without guarantee, warranty or responsibility of any kind, expressed or implied. Statements or suggestions
                                       concerning possible use of our products are made without representation or warranty that any such use is free of
                                       patent infringement, and are not recommendations to infringe any patent. The user should not assume that all safety
                                       measures are indicated, or that measures may not be required. The values presented in this data sheet are typical
                                       values and are not to be interpreted as product specifications.
APPLIED MINERALS INC.
110 Greene Street, Suite 1101                                                                                                                                        TM
New York, NY 10012
1.800.356.6463
www.appliedminerals.com



Comparative Analysis
PROPERTIES OF PP HOMOPOLYMER
                                                                            Flex           Tensile       Flex        Impact
WITH DRAGONITE-XRTM
                                                               Specific     Modulus        Strength     Strength     Strength
% Dragonite-XR  TM
                     (w/w)                                     Gravity      Kpsi             psi          psi       ft-lb/inch

 0                                                             0.905            214         5581         6509        0.66
  3                                                            0.928            258         5913         7360        0.75
     5                                                         0.940            278         6113         7650        0.68
          9                                                    0.961            316         6150         8100        0.62
               20                                              1.038            398         6003         8400        0.66
                      27                                       1.098            423         6177         8500        0.62


PROPERTIES OF NYLON 6
                                                                            Flex           Tensile       Flex        Impact
WITH DRAGONITE-XRTM
                                                               Specific     Modulus        Strength     Strength     Strength
% Dragonite-XR  TM
                     (w/w)                                     Gravity      Kpsi             psi          psi       ft-lb/inch

 0                                                             1.130            348        10481       13243          1.20
  3                                                            1.149            466        12087       17621          0.72
      7                                                        1.163            495        12997       18100          0.94              S-4800 5.0V 4.5mm x 5.00k SE(U)
          13                                                   1.182            533        13655       18900          0.86              10um
                24                                             1.297            731        14465       22653          0.77
                                                                                                                                   SEM image of PP composite with 20 wt% Dragonite-XRTM


PROPERTIES OF REINFORCED PP HOMOPOLYMER
                                                                            Flex           Tensile       Flex        Impact
WITH 10% FILLER - SPECIFIC VALUES (VALUE/DENSITY)                          Modulus        Strength     Strength     Strength
                                             Specific Gravity                Kpsi             psi          psi       ft-lb/inch            % Δ STRENGTH, PSI * % Δ MODULUS, KPSI
     Polypropylene                                 0.905                        196        5581         6509          0.81                                       0
     Dragonite - XRTM                              0.961                        329        6400         8429          0.73                                                           0.0994
     Chopped Glass Fibers                          0.978                        327        6449         8589          0.61                                                               0.1041
     Micro-Talc                                    0.973                        338        6074         8181          0.84                                                      0.0641
     Wollastonite                                  0.980                        266        5184         6214          0.84                            -0.0255
     Calcium Carbonate                             0.975                        256        4923         6769          1.13                           -0.0363
     Nanoclay - MMT                                0.954                        340        5615         7429          0.63                                           0.0045
More detailed information available upon request


Typical Analysis of Dragonite-XRTM Halloysite Clay
Length                            1.75 µm                      CHEMISTRY (WT %)

Outside Diameter                  50nm                         Si02      Ti02     Al203        Fe203     MnO        MgO          CaO           K2O      Na2O    P205      SO3     Sum       LOI
Inside Diameter                   15nm                         40.5      0.1      35.4         <2.0       0.1        0.7         1.8           0.3       0.4    0.1       0.3     79.4     18.0
True Specific Gravity              2.53
Refractive Index                  1.54
Bulk Density                      15.6 lbs /ft3
% Linear Dry Shrinkage            1.01                                                                                                      0 µm
                                                                                                                                        - 3.
                                                                                                                                  0.5
% Total Shrinkage                 21.4
Initial pH                        6.5-6.9
Cation Exchange Capacity          8 meq /100 grams
Oil Absorption (Linseed Oil)      40 lbs/100lbs                                           7A
BHT Surface Area                  64.66 m2/gm
BHT Pore Volume                   1.2-1.34 ml/gm
Hunter Brightness                 65
Particle Size                     100% < 5 µm
Particle Seize                    90% < 2 µm                                                                      15 nm

                                                                                                                  50 nm
APPLIED MINERALS INC.
110 Greene Street, Suite 1101                                                                                            TM
New York, NY 10012
1.800.356.6463
www.appliedminerals.com



                                                 The Dragon Mine: Applied Mineral’s Wholly Owned Source
                                                 of Halloysite
                                                 The Dragon Mine is located in the Tintic District of Utah stretching over 230 acres of land.
                                                 Applied Minerals retained the world’s leading experts in Halloysite to create a standard
                                                 for the characterization, quantification, and commercialization of this unique mineral. As
                                                 a result of these efforts, the Company is able to deliver commercially consistent product
                                                 grades of the highest quality Halloysite in the world.


PATENTED TECHNOLOGY
US PROVISIONAL PATENT: Process for Polymer
Composite with Inorganic Filler
US PATENT NO: 6,280,759 Method of Controlled
Release and Controlled Release Microstructures
US PATENT NO: 5,492,696 Controlled Release
Microstructures
US PATENT NO: 5,705,191 Sustained Delivery
of Active Compounds From Tubules with Rational
Control
US PATENT NO: 5,651,976 Controlled Release of
Active Agents Using Inorganic Tubules


                                                 Applied Mineral’s Dragon Mine: Utah, USA.



                                                 Other DragoniteTM Applications & Uses
                                                 Controlled Release Technology: As a carrier of active ingredients, the tubular nature
                                                 of DragoniteTM Halloysite clay enables a product to maintain uniform and sustained
                                                 release rates of an active agent, thereby reducing application frequency and initial
                                                 overdosage. Release rates can be controlled through selection of tube diameter, length,
                                                 and encapsulation. This increased efficiency of application reduces the amount of active
                                                 agent needed to achieve desired results, translating into significant cost savings and
                                                 environmental responsibility.
                                                 Applications for Controlled Release: paints/coatings, building materials, agriculture,
                                                 cosmetics, fragrances, pigments, electronics, fabrics, textiles, drug delivery fields and a
                                                 range of other industries.
                                                 Other Areas of Use: catalysts, molecular sieves, environmental remediation, filtration,
                                                 technical ceramics, cosmetics, paint modifiers, tyre composites, proppants, drilling muds.

Dragonite -XR Brochure

  • 1.
    APPLIED MINERALS INC. TM 110 Greene Street, Suite 1101 New York, NY 10012 1.800.356.6463 www.appliedminerals.com Applied Minerals is a leading global producer of Halloysite Clay. Vertically integrated from mine to market, our niche focus and in-depth application knowledge allow us to offer our customers commercially consistent product grades, specifically tailored to achieve their enhanced performance objectives. Applied Mineral’s Halloysite products are offered under the DragoniteTM brand. Applied Minerals is proud to introduce Dragonite-XRTM, a drop-in additive specifically suited for polymer reinforcement. Dragonite-XRTM is naturally exfoliated due to its tubular shape and uniform surface charge. As a result, Dragonite-XRTM disperses easily in various thermoplastic and thermoset resins at loading levels up to 40%. This is a major advantage over layered silicate fillers that must undergo a complex and costly chemical exfoliation process. Dragonite-XRTM composites exhibit not only high stiffness but also higher tensile and flex strength, all with a lower density and retained toughness. Dragonite-XRTM in powder form 5µm SEM image of Dragonite-XRTM Crude ore of Dragonite-XRTM extracted from the Dragon Mine Advantages of Dragonite-XRTM in Composites Lower density than conventional fillers results in reduced weight of finished products. Naturally exfoliated morphology provides ease of dispersion at loadings up to 40% without a need for organo-treatment. This results in lower raw material, mixing, and quality control costs compared to organo clays. Increases both the stiffness (modulus) and strength of composite with minimal changes in impact strength, weld line strength, and viscosity. Improves fatigue resistance and drop impact resistance compared to chopped glass fibers. Acts as a nucleating agent with 8°C increase in crystallization temperature, even at 1-3 wt% level, resulting in faster cooling and cycle time. Improves thermal stability: 20°C increase in the decomposition temperature in TGA. Increases time to ignite, reduces peak heat release rate, and improves char density when added at 5-10 wt% with other conventional flame retardants. Lower shrinkage than organo clay and lower warpage than chopped glass fiber and mica. Increases stiffness and toughness of thermoset compounds. Tubular morphology enables the entrapment of active agents followed by their controlled- release at predetermined rates. Halloysite is an inorganic material that is non-toxic and biocompatible. Lower cost than organo clay. NOTICE: All statements, information and data given herein are believed to be accurate and reliable, but are pre- sented without guarantee, warranty or responsibility of any kind, expressed or implied. Statements or suggestions concerning possible use of our products are made without representation or warranty that any such use is free of patent infringement, and are not recommendations to infringe any patent. The user should not assume that all safety measures are indicated, or that measures may not be required. The values presented in this data sheet are typical values and are not to be interpreted as product specifications.
  • 2.
    APPLIED MINERALS INC. 110Greene Street, Suite 1101 TM New York, NY 10012 1.800.356.6463 www.appliedminerals.com Comparative Analysis PROPERTIES OF PP HOMOPOLYMER Flex Tensile Flex Impact WITH DRAGONITE-XRTM Specific Modulus Strength Strength Strength % Dragonite-XR TM (w/w) Gravity Kpsi psi psi ft-lb/inch 0 0.905 214 5581 6509 0.66 3 0.928 258 5913 7360 0.75 5 0.940 278 6113 7650 0.68 9 0.961 316 6150 8100 0.62 20 1.038 398 6003 8400 0.66 27 1.098 423 6177 8500 0.62 PROPERTIES OF NYLON 6 Flex Tensile Flex Impact WITH DRAGONITE-XRTM Specific Modulus Strength Strength Strength % Dragonite-XR TM (w/w) Gravity Kpsi psi psi ft-lb/inch 0 1.130 348 10481 13243 1.20 3 1.149 466 12087 17621 0.72 7 1.163 495 12997 18100 0.94 S-4800 5.0V 4.5mm x 5.00k SE(U) 13 1.182 533 13655 18900 0.86 10um 24 1.297 731 14465 22653 0.77 SEM image of PP composite with 20 wt% Dragonite-XRTM PROPERTIES OF REINFORCED PP HOMOPOLYMER Flex Tensile Flex Impact WITH 10% FILLER - SPECIFIC VALUES (VALUE/DENSITY) Modulus Strength Strength Strength Specific Gravity Kpsi psi psi ft-lb/inch % Δ STRENGTH, PSI * % Δ MODULUS, KPSI Polypropylene 0.905 196 5581 6509 0.81 0 Dragonite - XRTM 0.961 329 6400 8429 0.73 0.0994 Chopped Glass Fibers 0.978 327 6449 8589 0.61 0.1041 Micro-Talc 0.973 338 6074 8181 0.84 0.0641 Wollastonite 0.980 266 5184 6214 0.84 -0.0255 Calcium Carbonate 0.975 256 4923 6769 1.13 -0.0363 Nanoclay - MMT 0.954 340 5615 7429 0.63 0.0045 More detailed information available upon request Typical Analysis of Dragonite-XRTM Halloysite Clay Length 1.75 µm CHEMISTRY (WT %) Outside Diameter 50nm Si02 Ti02 Al203 Fe203 MnO MgO CaO K2O Na2O P205 SO3 Sum LOI Inside Diameter 15nm 40.5 0.1 35.4 <2.0 0.1 0.7 1.8 0.3 0.4 0.1 0.3 79.4 18.0 True Specific Gravity 2.53 Refractive Index 1.54 Bulk Density 15.6 lbs /ft3 % Linear Dry Shrinkage 1.01 0 µm - 3. 0.5 % Total Shrinkage 21.4 Initial pH 6.5-6.9 Cation Exchange Capacity 8 meq /100 grams Oil Absorption (Linseed Oil) 40 lbs/100lbs 7A BHT Surface Area 64.66 m2/gm BHT Pore Volume 1.2-1.34 ml/gm Hunter Brightness 65 Particle Size 100% < 5 µm Particle Seize 90% < 2 µm 15 nm 50 nm
  • 3.
    APPLIED MINERALS INC. 110Greene Street, Suite 1101 TM New York, NY 10012 1.800.356.6463 www.appliedminerals.com The Dragon Mine: Applied Mineral’s Wholly Owned Source of Halloysite The Dragon Mine is located in the Tintic District of Utah stretching over 230 acres of land. Applied Minerals retained the world’s leading experts in Halloysite to create a standard for the characterization, quantification, and commercialization of this unique mineral. As a result of these efforts, the Company is able to deliver commercially consistent product grades of the highest quality Halloysite in the world. PATENTED TECHNOLOGY US PROVISIONAL PATENT: Process for Polymer Composite with Inorganic Filler US PATENT NO: 6,280,759 Method of Controlled Release and Controlled Release Microstructures US PATENT NO: 5,492,696 Controlled Release Microstructures US PATENT NO: 5,705,191 Sustained Delivery of Active Compounds From Tubules with Rational Control US PATENT NO: 5,651,976 Controlled Release of Active Agents Using Inorganic Tubules Applied Mineral’s Dragon Mine: Utah, USA. Other DragoniteTM Applications & Uses Controlled Release Technology: As a carrier of active ingredients, the tubular nature of DragoniteTM Halloysite clay enables a product to maintain uniform and sustained release rates of an active agent, thereby reducing application frequency and initial overdosage. Release rates can be controlled through selection of tube diameter, length, and encapsulation. This increased efficiency of application reduces the amount of active agent needed to achieve desired results, translating into significant cost savings and environmental responsibility. Applications for Controlled Release: paints/coatings, building materials, agriculture, cosmetics, fragrances, pigments, electronics, fabrics, textiles, drug delivery fields and a range of other industries. Other Areas of Use: catalysts, molecular sieves, environmental remediation, filtration, technical ceramics, cosmetics, paint modifiers, tyre composites, proppants, drilling muds.