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Electron
Affinity
is defined as the energy
process in which an
electron is acquired by the
atom in the gas phase
Electron affinity...
More info...
• The larger the affinity of an atom
for an electron, the more negative
the value
• Electron affinity trends are related
to the trends of ionization energy
because both represent the energy
involved in the gain or loss of an
electron by an atom, respectively
The trend down the column...
Electron affinity
decreases as it
goes down a column
This is because...
• Electrons are added increasingly
farther from the nucleus, so the
attractive force between the nucleus
and electrons decreases
• The outer electrons experience less
of a positive charge as you go up the
periodic table (effective nuclear
charge)
The trend across a period...
Electron affinity
increases as it
goes across a period
This is because...
• The octet rule states that atoms
with close to full valence shells will
tend to gain electrons. When they
gain the electrons, they use energy,
which allows the ion to become more
stable
• The outer electrons experience less
of a positive charge as you go across
a period (effective nuclear charge)
Units of EA
KJ/Mol
** electron affinity is negative
Exceptions...
• Nitrogen atoms have no affinity
- in N-
ions, electron-electron repulsion
makes these ions unstable
• Beryllium anion has no affinity
- Be-
is not stable, because the added
electron is assigned to a higher energy
subshell (2p) than the valence electrons
(2s)
More Exceptions...
• Noble gases have no affinity
- they have full valence shells and by
adding or taking away electrons, they
become unstable
• Fluorine has a low affinity
- because it has a small amount of
shells and when you add another
electron, electron-electron repulsion
happens, creating an unstable ion
Electron affinity chemistry engineering ppt

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Electron affinity chemistry engineering ppt

  • 2. is defined as the energy process in which an electron is acquired by the atom in the gas phase Electron affinity...
  • 3. More info... • The larger the affinity of an atom for an electron, the more negative the value • Electron affinity trends are related to the trends of ionization energy because both represent the energy involved in the gain or loss of an electron by an atom, respectively
  • 4. The trend down the column... Electron affinity decreases as it goes down a column
  • 5. This is because... • Electrons are added increasingly farther from the nucleus, so the attractive force between the nucleus and electrons decreases • The outer electrons experience less of a positive charge as you go up the periodic table (effective nuclear charge)
  • 6. The trend across a period... Electron affinity increases as it goes across a period
  • 7. This is because... • The octet rule states that atoms with close to full valence shells will tend to gain electrons. When they gain the electrons, they use energy, which allows the ion to become more stable • The outer electrons experience less of a positive charge as you go across a period (effective nuclear charge)
  • 8.
  • 9. Units of EA KJ/Mol ** electron affinity is negative
  • 10. Exceptions... • Nitrogen atoms have no affinity - in N- ions, electron-electron repulsion makes these ions unstable • Beryllium anion has no affinity - Be- is not stable, because the added electron is assigned to a higher energy subshell (2p) than the valence electrons (2s)
  • 11. More Exceptions... • Noble gases have no affinity - they have full valence shells and by adding or taking away electrons, they become unstable • Fluorine has a low affinity - because it has a small amount of shells and when you add another electron, electron-electron repulsion happens, creating an unstable ion